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Extraction and recycling technologies of cobalt from primary and secondary resources:A comprehensive review

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International Journal of Minerals,Metallurgy and Materials 2024年第4期31卷 628-649页

作者： Yukun Huang pengxu Chen Xuanzhao Shu Biao Fu Weijun peng Jiang Liu Yijun Cao Xiaofeng zhu ZhongYuan Critical Metals Laboratory Zhengzhou UniversityZhengzhou 450001China State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals Lanzhou University of TechnologyLanzhou 730050China

Cobalt has excellent electrochemical,magnetic,and heat *** a strategic resource,it has been applied in many hightech ***,the recent rapid growth of the battery industry has substantially depleted cobalt resources,leading to a crisis of cobalt resource *** paper examines cobalt ore reserves and distribution,and the recent development and consumption of cobalt resources are summarized as *** addition,the principles,advantages and disadvantages,and research status of various methods are discussed *** can be concluded that the use of diverse sources(Cu-Co ores,Ni-Co ores,zinc plant residues,and waste cobalt products)for cobalt production should be enhanced to meet developmental ***,in recovery technology,the pyro-hydrometallurgical process employs pyrometallurgy as the pretreatment to modify the phase structure of cobalt minerals,enhancing its recovery in the hydrometallurgical stage and facilitating high-purity cobalt ***,it represents a promising technology for future cobalt ***,based on the above conclusions,the prospects for cobalt are assessed regarding cobalt ore processing and sustainable cobalt recycling,for which further study should be conducted.

关键词： cobalt recovery copper-cobalt ore nickel-cobalt ore zinc plant residue waste cobalt products

Application of dynamic programming algorithm in winter heating control of greenhouse

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International Journal of Agricultural and Biological Engineering 2024年第4期17卷 60-66页

作者： Fei Gao Hongbin Tu Delan zhu Mengyang Liu Changyang shi Rui Zhang Ruixin Wang zhu Li College of Water Resources and Architectural Engineering Northwest A&F UniversityYangling 712100ShaanxiChina Institute of Water-saving Agriculture in Arid Areas of China Northwest A&F UniversityYangling 712100ShaanxiChina College of Engineering Purdue UniversityIndiana 47906USA

In order to solve the immaturity of decision-making methods in the regulation of winter heating in greenhouses,this study proposed a solution to the problem of greenhouse winter heating regulation using a dynamic programming algorithm.A mathematical model that included indoor environmental state variables,optimization decision variables,and outdoor random variables was *** temperature is kept close to the expected value and the energy consumption is *** model predicts the control solution by considering the cost function within the next 10 *** two-stage planning method was used to optimize the state of each moment step by *** temperature control strategy model was obtained by training the relationship between indoor temperature,outdoor temperature,and heating time after optimization using a regression *** on a typical Internet of Things(IoT)structure,the greenhouse control system was designed to regulate the optimal control according to the feedback of the current *** testing and verification,the optimized control method could stabilize the temperature near the target *** to the threshold control(threshold interval of 2.0°C)under similar weather conditions,the optimized control method reduced the temperature fluctuation range by 0.9°C and saved 7.83 kW·h of electricity,which is about 14.56%of the total experimental electricity *** shows that the dynamic programming method is feasible for environmental regulation in actual greenhouse production,and further research can be expanded in terms of decision variables and policy models to achieve a more comprehensive,scientific,and precise regulation.

关键词： greenhouse dynamic programming heating control model predictive control Internet of Things

Chlorfenapyr poisoning:mechanisms,clinical presentations,and treatment strategies

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World Journal of Emergency Medicine 2024年第3期15卷 214-219页

作者： Ji Cheng Yulu Chen Weidong Wang Xueqi zhu Zhenluo Jiang peng Liu Liwen Du Emergency Department Ningbo No.2 HospitalNingbo 315010China

BACKGROUND:Chlorfenapyr is used to kill insects that are resistant to organophosphorus *** poisoning has a high mortality rate and is difficult to *** article aims to review the mechanisms,clinical presentations,and treatment strategies for chlorfenapyr *** RESOURCES:We conducted a review of the literature using PubMed,Web of Science,and SpringerLink from their beginnings to the end of October *** inclusion criteria were systematic reviews,clinical guidelines,retrospective studies,and case reports on chlorfenapyr poisoning that focused on its mechanisms,clinical presentations,and treatment *** references in the included studies were also examined to identify additional ***:We included 57 studies in this *** can be degraded into tralopyril,which is more toxic and reduces energy production by inhibiting the conversion of adenosine diphosphate to adenosine *** fever and altered mental status are characteristic clinical presentations of chlorfenapyr *** it occurs,respiratory failure occurs immediately,ultimately leading to cardiac arrest and *** poisoning is diflcult to treat,and there is no specific ***:Chlorfenapyr is a new pyrrole *** it has been identified as a moderately toxic pesticide by the World Health Organization(WHO),the mortality rate of poisoned patients is extremely *** is no specific antidote for chlorfenapyr ***,based on the literature review,future efforts to explore rapid and effective detoxification methods,reconstitute intracellular oxidative phosphorylation couplings,identify early biomarkers of chlorfenapyr poisoning,and block the conversion of chlorfenapyr to tralopyril may be helpful for emergency physicians in the diagnosis and treatment of this disease.

关键词： Chlorfenapyr poisoning Mechanism Clinical presentation Treatment

Sustainable all-weather CO2 utilization by mimicking natural photosynthesis in a single material

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National Science Review 2024年第2期11卷 177-187页

作者： Xianjin shi Yu Huang Ran Long Zhenyu Wang Liqin Wang Junji Cao Gangqiang zhu Yujie Xiong State Key Laboratory of Loess and Quaternary Geology(SKLLQG) Key Laboratory of Aerosol Chemistry and Physics Institute of Earth EnvironmentChinese Academy of Sciences Center of Excellence in Quaternary Science and Global Change Chinese Academy of Sciences University of Chinese Academy of Sciences Hefei National Research Center for Physical Sciences at the Microscale School of Chemistry and Materials Science and National Synchrotron Radiation Laboratory University of Science and Technology of China Institute of Atmospheric Physics Chinese Academy of Sciences School of Physics and Information Technology Shaanxi Normal University

Solar-driven CO2conversion into hydrocarbon fuels is a sustainable approach to synchronously alleviating the energy crisis and achieving net ***,the dependence of the conversion process on solar illumination hinders its practical application due to the intermittent availability of sunlight at night and on cloudy or rainy ***,we report a model material of Pt-loaded hexagonal tungsten trioxide（Pt/h-WO3） for decoupling light and dark reaction processes,demonstrating the sustainable CO2conversion under dark conditions for the first *** such a material system,hydrogen atoms can be produced by photocatalytic water splitting under solar illumination,stored together with electrons in the h-WO3through the transition of W6+to W5+and spontaneously released to trigger catalytic CO2reduction under dark ***,we demonstrate using natural light that CH4production can persist at night and on rainy days,proving the accomplishment of all-weather CO2conversion via a sustainable way.

关键词： sustainable CO2 utilization artificial photosynthesis all-weather application charge storage

Mitochondrial dysfunction and quality control lie at the heart of subarachnoid hemorrhage

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Neural Regeneration Research 2024年第4期19卷 825-832页

作者： Jiatong Zhang Qi zhu Jie Wang Zheng peng Zong zhuang Chunhua Hang Wei Li Department of Neurosurgery Nanjing Drum Tower HospitalAffiliated Hospital of Medical SchoolNanjing University Department of Neurosurgery Nanjing Drum Tower HospitalClinical College of Nanjing Medical University

The dramatic increase in intracranial pressure after subarachnoid hemorrhage leads to a decrease in cerebral perfusion pressure and a reduction in cerebral blood *** are directly affected by direct factors such as ischemia,hypoxia,excitotoxicity,and toxicity of free hemoglobin and its degradation products,which trigger mitochondrial *** mitochondria release large amounts of reactive oxygen species,inflammatory mediators,and apoptotic proteins that activate apoptotic pathways,further damaging *** response to this array of damage,cells have adopted multiple mitochondrial quality control mechanisms through evolution,including mitochondrial protein quality control,mitochondrial dynamics,mitophagy,mitochondrial biogenesis,and intercellular mitochondrial transfer,to maintain mitochondrial homeostasis under pathological *** interventions targeting mitochondrial quality control mechanisms have emerged as promising therapeutic strategies for subarachnoid *** review provides an overview of recent research advances in mitochondrial pathophysiological processes after subarachnoid hemorrhage,particularly mitochondrial quality control *** also presents potential therapeutic strategies to target mitochondrial quality control in subarachnoid hemorrhage.

关键词： mitochondrial biogenesis mitochondrial dynamics mitochondrial dysfunction mitochondrial fission and fusion mitochondrial quality control mitophagy subarachnoid hemorrhage

Designing metal sulfide-based cathodes and separators for suppressing polysulfide shuttling in lithium-sulfur batteries

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Nano Research 2024年第4期17卷 2574-2591页

作者： Guoyin zhu Qingzhu Wu Xianghua Zhang Yuwen Bao Xuan Zhang zhuoyao shi Yizhou Zhang Lianbo Ma Institute of Advanced Materials and Flexible Electronics(IAMFE) School of Chemistry and Materials ScienceNanjing University of Information Science&TechnologyNanjing 210044China School of Materials Science and Engineering Anhui University of TechnologyMaanshan 243002China School of Mechanical Engineering Jiangsu University of TechnologyChangzhou 213001China

Lithium-sulfur(Li-S)batteries,known for their high energy density,are attracting extensive research interest as a promising next-generation energy storage ***,their widespread use has been hampered by certain issues,including the dissolution and migration of polysulfides,along with sluggish redox *** sulfides present a promising solution to these obstacles regarding their high electrical conductivity,strong chemical adsorption with polysulfides,and remarkable electrocatalytic capabilities for polysulfide *** this review,the recent progress on the utilization of metal sulfide for suppressing polysulfide shuttling in Li-S batteries is systematically summarized,with a special focus on sulfur hosts and functional *** critical roles of metal sulfides in realizing high-performing Li-S batteries have been comprehensively discussed by correlating the materials’structure and electrochemical ***,the remaining issues/challenges and future perspectives are *** offering a detailed understanding of the crucial roles of metal sulfides,this review dedicates to contributing valuable knowledge for the pursuit of high-efficiency Li-S batteries based on metal sulfides.

关键词： lithium-sulfur batteries metal sulfides polysulfide shuttling sulfur hosts separator coating layers

Elemene Antitumor Drugs Development Based on "Molecular Compatibility Theory" and Clinical Application: A Retrospective and Prospective Outlook

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Chinese Journal of Integrative Medicine 2024年第1期30卷 62-74页

作者： JIANG Xiao-ying shi Li-ping zhu Jun-long BAI Ren-ren XIE Tian School of Pharmacy Hangzhou Normal UniversityHangzhou(311121)China Key Laboratory of Elemene Class Anti-cancer Chinese Medicines Engineering Laboratory of Development and Application of Traditional Chinese MedicinesCollaborative Innovation Center of Traditional Chinese Medicines of Zhejiang ProvinceHangzhou Normal UniversityHangzhou(311121)China Good Clinical Practice Center Affliliated Hospital of Nanjing University of Chinese MedicineNanjing(210000)China

Elemene, derived from Curcuma wenyujin, one of the "8 famous genuine medicinal materials of Zhejiang province," exhibits remarkable antitumor activity. It has gained wide recognition in clinical practice for effectiveness on tumors. Dr. XIE Tian introduced the innovative concept of "molecular compatibility theory" by combining Chinese medicine principles, specifically the "monarch, minister, assistant, and envoy" theory, with modern biomedical technology. This groundbreaking approach, along with a systematic analysis of Chinese medicine and modern biomedical knowledge, led to the development of elemene nanoliposome formulations. These novel formulations offer numerous advantages, including low toxicity, well-defined composition, synergistic effects on multiple targets, and excellent biocompatibility. Following the principles of the "molecular compatibility theory", further exploration of cancer treatment strategies and methods based on elemene was undertaken. This comprehensive review consolidates the current understanding of elemene's potential antitumor mechanisms, recent clinical investigations, advancements in drug delivery systems, and structural modifications. The ultimate goal of this review is to establish a solid theoretical foundation for researchers, empowering them to develop more effective antitumor drugs based on the principles of "molecular compatibility theory".

关键词： molecular compatibility theory Chinese integrative medicine elemene antitumor activity drug delivery structural modification

Wetting sub-nanochannels via ionic hydration effect for improving charging dynamics

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Green Energy & Environment 2024年第3期9卷 473-480页

作者： Yayun shi Xiaoli Zhao Qihang Liu Zhenghui Pan Congcong Liu Shanyi zhu Zhijun Zuo Xiaowei Yang State Key Laboratory of Clean and Efficient Coal Utilization Taiyuan University of TechnologyTaiyuan030024China School of Materials Science and Engineering Tongji UniversityShanghai201804China School of Chemistry and Chemical Engineering Shanghai Jiao Tong UniversityShanghai200240China

The ionic transport in sub-nanochannels plays a key role in energy storage,yet suffers from a high energy *** sub-nanochannels is crucial to accelerate ionic transport,but the introduction of water is challenging because of the hydrophobic extreme *** propose wetting the channels by the exothermic hydration process of pre-intercalated ions,the effect of which varies distinctly with different ionic hydration structures and *** to the failed pre-intercalation of SO_(4)^(2-),HSO_(4)^(-) with weak hydration energy results in a marginal effect on the HOMO(Highest Occupied Molecular Orbital)level of water to avoid water splitting during the electrochemical ***,the ability of water introduction is reserved by the initial incomplete dissociation state of HSO_(4)^(-),so the consequent exothermic reionization and hydration processes of the intercalated HSO_(4)^(-) promote the water introduction into sub-nanochannels,finally forming the stable confined water through hydrogen bonding with functional *** wetted channels exhibit a significantly enhanced ionic diffusion coef-ficient by~9.4 times.

关键词： Sub-nanochannels Ionic hydration Ionic transport Supercapacitors Confined water

Mapping upland crop–rice cropping systems for targeted sustainable intensification in South China

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The Crop Journal 2024年第2期12卷 614-629页

作者： Bingwen Qiu Linhai Yu peng Yang Wenbin Wu Jianfeng Chen Xiaolin zhu Mingjie Duan Key Laboratory of Spatial Data Mining&Information Sharing of Ministry of Education Academy of Digital China(Fujian)Fuzhou UniversityFuzhou 350116FujianChina Key Laboratory of Agricultural Remote Sensing Ministry of Agriculture and Rural AffairsBeijing 100081China Department of Land Surveying and Geo-Informatics The Hong Kong Polytechnic UniversityKowloon 999077Hong KongChina

Upland crop-rice cropping systems(UCR)facilitate sustainable agricultural *** UCR cultivation mapping is needed to ensure food security,sustainable water management,and rural ***,datasets describing cropping systems are limited in spatial coverage and crop *** UCR is more challenging than crop identification and most existing approaches rely heavily on accurate phenology calendars and representative training samples,which limits its applications over large *** describe a novel algorithm(RRSS)for automatic mapping of upland crop-rice cropping systems using Sentinel-1 Synthetic Aperture Radar(SAR)and Sentinel-2 Multispectral Instrument(MSI)*** indicator,the VV backscatter range,was proposed to discriminate UCR and another two indicators were designed by coupling greenness and pigment indices to further discriminate tobacco or oilseed *** RRSS algorithm was applied to South China characterized by complex smallholder rice cropping systems and diverse topographic *** study developed 10-m UCR maps of a major rice bowl in South China,the Xiang-Gan-Min(XGM)*** performance of the RRSS algorithm was validated based on 5197 ground-truth reference sites,with an overall accuracy of 91.92%.There were7348 km^(2) areas of UCR,roughly one-half of them located in *** UCR was represented mainly by oilseed-UCR and tobacco-UCR,which contributed respectively 69%and 15%of UCR *** patterns accounted for only one-tenth of rice production,which can be tripled by intensification from single rice *** to complex and fragmented subtropical regions suggested the spatiotemporal robustness of the RRSS algorithm,which could be further applied to generate 10-m UCR datasets for application at national or global scales.

关键词： Cropping-pattern mapping Paddy rice Sentinel-1/2 China Sustainable intensification