Syntheses and Structures of Rare Earth Nitrate Complexes with 2.6-Diacetylpyridinebis(Semicarbazone)

作     者：Pan Xiangyang, Yan Shiping, Wang Genglin (Department of Chemistry, Nankai University, Tianjin) Wang Honggen, Wang Ruji and Yao Xinkan (Test center, Nankai University, Tianjin) Pan Xiangyang, Yan Shiping, Wang Genglin (Department of Chemistry, Nankai University, Tianjin) Wang Honggen, Wang Ruji and Yao Xinkan (Test center, Nankai University, Tianjin)

出 版 物：《高等学校化学学报(英文版)》 (Chemical Journal of Chinese Universities)

年 卷 期：1988年第2期

页      面：45-53页

学科分类：07[理学] 0703[理学-化学] 

主　　题：nitrate constants monoclinic conductance crystallized complexes Semicarbazone neutral EtOH titration 

摘      要： Six rare earth nitrate complexes of 2, 6-diacetylpyridinebis (semicarbazone) (DAPSC) were synthesized and characterized by elemental analysis, IR spectra and electrical conductance. Molecular and crystal structures of complex [Sm(DAPSC)(NO3)2(EtOH)]NO3 were determined by X-ray diffraction method. C13H21N10O12 Sm crystallized in the monoclinic apace group C2/c with the following unit-cell constants, a=16.674(2)A, b = 10. 715(2)A, c = 25.242(4)A . β = 100.077(11)°; z=8, the final R factor is 0.025. The coordination number of Sm3+ is ten.