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Geobacter sulfurreducens promoted the biosynthesis of Reduced graphene oxide and coupled it for nitrobenzene reduction

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Journal of Environmental Sciences 2024年第4期138卷 458-469页

作者： Shoujuan Zhang Qi Liu Linrui Zhong Jianhong Jiang Xiaozhe Luo Xingxin Hu Qian Liu Yue Lu College of Environmental Science and Engineering Hunan UniversityChangsha 410082China Shenzhen Research Institute Hunan UniversityShenzhen 510082China Key Laboratory of Environment Biology and Pollution Control Hunan UniversityMinistry of EducationChangsha 410082China China Machinery International Engineering Design&Research Institute Co. LtdChangsha 410007China Hunan Engineering Research Center for Water Treatment Process&Equipment Changsha 410007China

In order to explore an efficient and green method to deal with nitrobenzene(NB)pollutant,Reduced graphene oxide(r GO)as an electron shuttle was applied to enhance the extracellular electron transfer(EET)process of Geobacter sulfurreducens,which was a typical electrochemically active bacteria(EAB).In this study,r GO biosynthesis was achieved via the reduction of graphene oxide(GO)by G.sulfurreducens PCA within 3 days.Also,the r GOPCA combining system completely reduced 50-200μmol/L of NB to aniline as end product within one day.SEM characterization revealed that PCA cells were partly wrapped by rGO,and therefore the distance of electron transfer between strain PCA and r GO material was reduced.Beside,the ID/IGof GO,r GO,and r GO-PCA combining system were 0.990,1.293 and 1.31,respectively.Moreover,highest currents were observed in r GO-PCA-NB as 12.950μA/-12.560μA at -408 m V/156 m V,attributing to the faster electron transfer efficiency in EET process.Therefore,the NB reduction was mainly due to:(I)direct EET process from G.sulfurreducens PCA to NB;(II)r GO served as electron shuttle and accelerated electron transfer to NB,which was the main degradation pathway.Overall,the biosynthesis of r GO via GO reduction by Geobacter promoted the NB removal process,which provided a facile strategy to alleviate the problematic nitroaromatic pollution in the environment.

关键词： Reduced graphene oxide Geobacter Nitrobenzene Removal Extracellular electron transfer

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Reduced graphene oxide-embedded nerve conduits loaded with bone marrow mesenchymal stem cell-derived extracellular vesicles promote peripheral nerve regeneration

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Neural Regeneration Research 2023年第1期18卷 200-206页

作者： Wei Zhang Xing-Xing Fang Qi-Cheng Li Wei Pi Na Han Department of Orthopedics and Trauma Peking University People’s HospitalBeijingChina National Center for Trauma Medicine BeijingChina Central Laboratory Peking University People’s HospitalBeijingChina

We previously combined Reduced graphene oxide(rGO)with gelatin-methacryloyl(GelMA)and polycaprolactone(PCL)to create an rGO-GelMA-PCL nerve conduit and found that the conductivity and biocompatibility were improved.However,the rGO-GelMA-PCL nerve conduits differed greatly from autologous nerve transplants in their ability to promote the regeneration of injured peripheral nerves and axonal sprouting.Extracellular vesicles derived from bone marrow mesenchymal stem cells(BMSCs)can be loaded into rGO-GelMA-PCL nerve conduits for repair of rat sciatic nerve injury because they can promote angiogenesis at the injured site.In this study,12 weeks after surgery,sciatic nerve function was measured by electrophysiology and sciatic nerve function index,and myelin sheath and axon regeneration were observed by electron microscopy,immunohistochemistry,and immunofluorescence.The regeneration of microvessel was observed by immunofluorescence.Our results showed that rGO-GelMA-PCL nerve conduits loaded with BMSC-derived extracellular vesicles were superior to rGO-GelMA-PCL conduits alone in their ability to increase the number of newly formed vessels and axonal sprouts at the injury site as well as the recovery of neurological function.These findings indicate that rGO-GelMA-PCL nerve conduits loaded with BMSC-derived extracellular vesicles can promote peripheral nerve regeneration and neurological function recovery,and provide a new direction for the curation of peripheral nerve defect in the clinic.

关键词： angiogenesis axon bone mesenchymal stem cell extracellular vesicles hybrid nanofibers myelin sheath nerve conduit neurological function peripheral nerve injury Reduced graphene oxide

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Mechanically flexible Reduced graphene oxide/carbon composite films for high-performance quasi-solid-state lithium-ion capacitors

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Journal of Energy Chemistry 2023年第5期80卷 68-76,I0003页

作者： Wenjie Liu Yabin An Lei Wang Tao Hu Chen Li Yanan Xu Kai Wang Xianzhong Sun Haitao Zhang Xiong Zhang Yanwei Ma Institute of Electrical Engineering Chinese Academy of SciencesBeijing 100190China University of Chinese Academy of Sciences Beijing 100049China Institute of Electrical Engineering and Advanced Electromagnetic Drive Technology Qilu ZhongkeJinan 250013ShandongChina Key Laboratory of Advanced Technologies of Materials Ministry of EducationSchool of Materials Science and EngineeringSouthwest Jiaotong UniversityChengdu 6003 SichuanChina School of Materials Science and Engineering Zhengzhou UniversityZhengzhou 450001HenanChina

Practical applications of diverse flexible wearable electronics require electrochemical energy storage(EES)devices with multiple configurations.Moreover,to fabricate flexible EES devices with high energy density and stability,organic integration from electrode design to device assembly is required.To address these challenges,a free-standing Reduced graphene oxide(rGO)/carbon film with a unique sandwich structure has been designed via the assistance of vacuum-assistant filtration for lithium-ion capacitors(LICs).The graphene acts as not only a binder to construct a three-dimensional conductive network but also an active material to provide additional capacitive lithium storage sites,thus enabling fast ion/electron transport and improving the capacity.The designed rGO/hard carbon(rGO/HC)and rGO/activated carbon(rGO/AC)free-standing films exhibit enhanced specific capacities(513.7 mA h g^(-1)for rGO/HC and 102.8 mA h g^(-1)for rGO/AC)and excellent stability.Moreover,the integrated flexible quasi-solid-state rGO/AC//rGO/HC LIC devices possess a maximum energy density of 138.3 Wh kg^(-1),a high power density of 11 kW kg^(-1),and improved cycling performance(84.4%capacitance maintained after 10,000 cycles),superior to the AC//HC LIC(43.5%retention).Such a strategy enlightens the development of portable flexible LICs.

关键词： Lithium-ion capacitors Free-standing films Reduced graphene oxide Carbon materials

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Multi-effect anthraquinone-based polyimide enclosed SnO_(2)/Reduced graphene oxide composite as high-performance anode for lithium-ion battery

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化学科学与工程前沿:英文版 2023年第9期17卷 1231-1243页

作者： Lin Wang Yinjie Kuang Qian Cui Junyu Shi Liubin Song Qionghua Li Tianjian Peng Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation School of Chemistry and Chemical EngineeringChangsha University of Science and TechnologyChangsha410114China Guizhou Dalong Huicheng New Material Co. Ltd.Tongren554000China

The cycling stability of SnO_(2)anode as lithium-ion battery is poor due to volume expansion.Polyimide coatings can effectively confine the expansion of SnO_(2).However,linear polyimides are easily dissolved in ester electrolytes and their carbonyls is not fully utilized during charging/discharging process.Herein,the SnO_(2)enclosed with anthraquinone-based polyimide/Reduced graphene oxide composite was prepared by self-assembly.Carbonyls from the anthraquinone unit provide fully available active sites to react with Li^(+),improving the utilization of carbonyl in the polyimide.More exposed carbonyl active sites promote the conversion of Sn to SnO_(2)with electrode gradual activation,leading to an increase in reversible capacity during the charge/discharge cycle.In addition,the introduction of Reduced graphene oxide cannot only improve the stability of polyimide in the electrolyte,but also build fast ion and electron transport channels for composite electrodes.Due to the multiple effects of anthraquinone-based polyimide and the synergistic effect of reducing graphene oxide,the composite anode exhibits a maximum reversible capacity of 1266 mAh·g^(−1) at 0.25 A·g^(−1),and maintains an excellent specific capacity of 983 mAh·g^(−1) after 200 cycles.This work provides a new strategy for the synergistic modification of SnO_(2).

关键词： anthraquinone-based polyimide multi-effect tin dioxide Reduced graphene oxide lithium-ion battery

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Enhanced photocatalytic performance of Bi_(2)O_(2)CO_(3)/Bi_(4)O_(5)Br_(2)/Reduced graphene oxide Z-schemehe terojunction via a one-pot room-temperature synthesis

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Journal of Environmental Sciences 2024年第4期138卷 418-427页

作者： Xiaoge Wu Lei Yan Rongrong Qin Qikai Zhang Wei Yang Xiaozhi Wang Yongcai Zhang Min Luo Jianhua Hou College of Environmental Science and Engineering Yangzhou UniversityYangzhouJiangsu 225009China Jiangsu Collaborative Innovation Center for Solid Organic Waste Resource Utilization Nanjing 210095China Beijing Xinfeng Aerospace Equipment Co. Ltd.Beijing 100854China Beijing System Design Institute of Electro-Mechanic Engineering Beijing 100005China College of Chemistry and Chemical Engineering Ningxia UniversityYinchuanNingxia 750021China

Bi_(2)O_(2)CO_(3)(BOC)/Bi_(4)O_5Br_(2)(BOB)/Reduced graphene oxide(rGO)Z-scheme heterojunction with promising photocatalytic properties was synthesized via a facile one-pot room-temperature method.Ultra-thin nanosheets of BOC and BOB were grown in situ on r GO.The formed 2D/2D direct Z-scheme heterojunction of BOC/BOB with oxygen vacancies(OVs)effectively leads to lower negative electron reduction potential of BOB as well as higher positive hole oxidation potential of BOC,showing improved reduction/oxidation ability.Particularly,rGO is an acceptor of the electrons from the conduction band of BOC.Its dual roles significantly improve the transfer performance of photo-induced charge carriers and accelerate their separation.With layered nanosheet structure,rich OVs,high specific surface area,and increased utilization efficiency of visible light,the multiple synergistic effects of BOC/BOB/rGO can achieve effective generation and separation of the electron-holes,thereby generating more·O_(2)^(-)and h^(+).The photocatalytic reduction efficiency of CO_(2)to CO(12.91μmol/(g·hr))is three times higher than that of BOC(4.18μmol/(g·hr)).Moreover,it also achieved almost 100%removal of Rhodamine B and cyanobacterial cells within 2 hours.

关键词： Bi_(2)O_(2)CO_(3) Bi_(4)O_(5)Br_(2) Reduced graphene oxide Z-scheme heterojunction Photocatalysis CO_(2)reduction

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Graphitic carbon nitride/ferroferric oxide/Reduced graphene oxide nanocomposite as highly active visible light photocatalyst

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Nano Research 2023年第1期16卷 371-376页

作者： Juhua Luo Ziyang Dai Mengna Feng Mingmin Gu Yu Xie School of Materials Science and Engineering Yancheng Institute of TechnologyYancheng 224051China School of Environmental and Chemical Engineering Nanchang Hangkong UniversityNanchang 330063China

High stability and efficient charge separation are two critical factors to construct high-performance photocatalysts.Here,an efficient strategy was provided to fabricate the nanocomposite of graphitic carbon nitride/ferroferric oxide/Reduced graphene oxide(g-C_(3)N_(4)/Fe_(3)O_(4)/RGO).The degradation of rhodamine B(RhB)by g-C_(3)N_(4)/Fe_(3)O_(4)/RGO nanocomposite followed the pseudofirst-order kinetics.The g-C_(3)N_(4)/Fe_(3)O_(4)/RGO nanocomposite exhibited excellent stability and magnetically separable performance.It was ascertained that the quantum efficiency and separation efficiency of photoexcited charge carriers of g-C_(3)N_(4)/Fe_(3)O_(4)/RGO nanocomposite were obviously improved.Particularly,the g-C_(3)N_(4)/Fe_(3)O_(4)/RGO nanocomposite with 3 wt.%RGO presented 100%degradation efficiency under visible light irradiation for 75 min.The remarkable photocatalytic degradation activity is attributed to the synergistic interactions among g-C_(3)N_(4),Fe_(3)O_(4),and RGO,along with the efficient interfacial charge separation.

关键词： graphitic carbon nitride ferroferric oxide Reduced graphene oxide visible light photocatalyst

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Constructing central hollow cylindrical Reduced graphene oxide foams with vertically and radially orientated porous channels for highly efficient solar-driven water evaporation and purification

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Nano Research 2023年第5期16卷 6343-6352页

作者： Changjun Li Wei Li Hao-Yu Zhao Xin-Yue Feng Xiaofeng Li Zhong-Zhen Yu State Key Laboratory of Organic-Inorganic Composites College of Materials Science and EngineeringBeijing University of Chemical TechnologyBeijing 100029China Beijing Key Laboratory of Advanced Functional Polymer Composites Beijing University of Chemical TechnologyBeijing 100029China College of Materials Science and Engineering Shandong University of Science and TechnologyQingdao 266590China

Although solar steam generation is an eco-friendly approach for desalinating seawater and purifying wastewater,there are still issues on how to improve the efficiency of solar energy utilization and accelerate the water and heat transport inside the solardriven water evaporators.Herein,we design a central hollow cylindrical Reduced graphene oxide(RGO)foam with vertically and radially orientated channels as a solar steam generation device for efficient water evaporation and purification.The vertically aligned porous channels accelerate upward transport of water to the top evaporation surface,while the radially aligned porous channels facilitate water transport and heat transfer along the radial directions for fully utilizing the heat accumulated inside the central cylindrical hole of the foam.The central hole of the foam plays a highly positive role in accumulating more heat for accelerating the water evaporation,the newly generated inner sidewall resulted from the central hole can gain extra thermal energy from surrounding environment in the same way as the outer sidewall of the foam due to the surface cooling effect of the water evaporation.As a result,the vertically and radially aligned RGO foam evaporator with central hollow cylinder achieves a high solar steam generation rate of 2.32 kg·m^(−2)·h^(−1)with an exceptional energy conversion efficiency of 120.9%under 1-sun irradiation,superior to the vertically aligned RGO foam without the central hole(1.83 kg·m^(−2)·h^(−1),96.9%)because of the enhanced water and heat transfer inside the porous channels,the efficient utilization of environmental energy.

关键词： hollow cylindrical foams Reduced graphene oxide solar steam generation water evaporation rate seawater desalination

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Synergistic Effects of Carbon Nanotube(CNT)and Reduced graphene oxide(RGO)on Mechanical and Thermal Properties of ZK61 Alloy

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Acta Metallurgica Sinica(English Letters) 2024年第3期37卷 577-585页

作者： Fanjing Meng Wenbo Du Ning Ding Jian Sun Xian Du Ke Liu Shubo Li College of Materials Science and Engineering Faculty of Materials and ManufacturingBeijing University of TechnologyBeijing 100124China

The hybrid of carbon nanotube(CNT)and Reduced graphene oxide(RGO)reinforced ZK61 composite was fabricated by a hot extrusion process.Compared with the raw ZK61 alloy and single-reinforced composites,the hybrid-reinforced by RGO+CNT complex exhibited significant enhancements both in mechanical and thermal performance.By adjusting the proportion of RGO and CNT in ZK61 alloy,the obtained optimum ZK61/(0.06 wt%RGO+0.54 wt%CNT)composite exhibited increase of 25.4%in yield strength,26.5%in ultimate tensile strength,104%in failure strain and 30.4%in thermal conductivity,respectively,in comparison with ZK61 alloy.The superior properties of the nano-hybrid composite are attributed to the synergetic effects of RGO and CNT,leading to a uniform dispersion and integrated structure as well as the enhanced interfacial bonding with matrix.The strengthening ability of RGO and CNT was calculated to quantify their individual contribution to the improvement in mechanical and thermal properties of the ZK61 matrix composite.The RGO+CNT hybrids provide a promising way to develop Mg matrix composites with impressive performances.

关键词： Mg matrix composite Carbon nanotube Reduced graphene oxide Mechanical performance Thermal conductivity

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A tightly bonded Reduced graphene oxide coating on magnesium alloy with photothermal effect for tumor therapy

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Journal of Magnesium and Alloys 2022年第11期10卷 3031-3040页

作者： Lidan Liu Feng Peng Dongdong Zhang Mei Li Jian Huang Xuanyong Liu State Key Laboratory of High Performance Ceramics and Superfine Microstructure Shanghai Institute of CeramicsChinese Academy of SciencesShanghai 200050China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China Department of Orthopedics Guangdong Provincial People's HospitalGuangdong Academy of Medical SciencesGuangzhou 510080China School of Chemistry and Materials Science Hangzhou Institute for Advanced StudyUniversity of Chinese Academy of Sciences1 Sub-lane XiangshanHangzhou 310024China

Photothermal therapy becomes a hotspot in the treatment of bone tumors. Magnesium and its alloys are regarded as potential bone implants for their favorable mechanical property and biodegradable in vivo. However, there is few research devoted to fabricating a photothermal coating on Mg alloy. In the present study, Reduced graphene oxide coating with a strong photothermal effect was prepared on the surface of AZ31via two steps. Firstly, graphene oxide coating was deposited on the surface via electrophoresis deposited(GO#), followed by a reduction process of the graphene oxide coating in ultrapure water(rGO#). GO# and rGO# coatings were characterized by SEM, Raman, XRD, FTIR,and XPS. The results revealed that, compared with GO# coating, the content of oxygen-containing(C-O/C-O-C, C=O, O-C=O) groups on rGO# coating was significantly decreased. rGO# coating was found tightly adhered to AZ31 substrate. According to the first-principles calculations, the well-bonded heterostructure between MgO and rGO is the main reason for the strong bonding force. Moreover, the prepared rGO# coating showed a superior photothermal effect, which brings a new strategy to the treatment of bone tumors with Mg-based implants.

关键词： Magnesium alloy Reduced graphene oxide Photothermal effect

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The confined growth of few-layered and ultrashort-slab Ni-promoted MoS_(2)on Reduced graphene oxide for deep-degree hydrodesulfurization

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Nano Research 2022年第8期15卷 7052-7062页

作者： Dongxu Wang Lei Wang Yanqing Jiao Aiping Wu Haijing Yan Xin Kang Chungui Tian Jiancong Liu Honggang Fu Key Laboratory of Functional Inorganic Material Chemistry Ministry of Education of the People’s Republic of ChinaHeilongjiang UniversityHarbin 150080China

Hydrodesulfurization(HDS)is an essential process in clean fuel oil production,however,the huge challenge is the synthesis of the catalyst with plentiful active sites.Here,we have shown the design of few-layered,ultrashort Ni-Mo-S slabs dispersed on Reduced graphene oxide(Ni-Mo-S/rGO-A)based on anchoring[PMo_(12)O_(40)]3−clusters and Ni^(2+)on polyethyleneimine(PEI)-modified graphite oxide.Structural characterizations(transmission electron microscopy(TEM),X-ray absorption fine structure(XAFS),etc.)show that Ni-Mo-S slabs with predominant monolayer and partial substitution of edge Mo atoms by isolated Ni atoms have rich accessible edge Ni-Mo-S sites and high sulfurization degree.All virtues endow it with plentiful edge-active sites,and consequently,the enhanced performance for hydrodesulfurization of dibenzothiophene(DBT).The hydrodesulfurization proceeds via a more-favorable direct desulfurization(DDS)route with a reaction rate constant(kHDS)of 48.6×10^(−7)mol·g^(−1)·s^(−1)over Ni-Mo-S/rGO-A catalyst,which is 4.3 times greater than that over traditional Ni-Mo-S/Al_(2)O_(3)catalyst and at the forefront of reported catalysts.

关键词： few-layered Ni-promoted MoS_(2) confined growth Reduced graphene oxide high sulfurization degree hydrodesulfurization

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