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Optoelectronics Letters 2025年第3期21卷 160-166页

作者： ZHANG Run ZHONG Xingli LIN Zhongxi QIU Weibin su hui Key Laboratory of Optoelectronic Materials Chemistry and Physics Collaborative Innovation Center for Optoelectronic Semiconductors and Efficient Devices Fujian Institute of Research on the Structure of Matter Chinese Academy of Science University of Chinese Academy of Sciences Chinese Academy of Sciences College of Information Science and Engineering Huaqiao University Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China

Realizing the valley Hall effect by breaking the spatial inversion symmetry of photonic systems has become a cutting-edge field of micro-nano-optics, since the valley degree of freedom was introduced into photonic system. Various novel devices based on the domain walls of the valley photonic crystals have also been demonstrated. In this article,we investigate the variation of edge states by the modulation of refractive index within the domain walls, and the geometric difference between the dielectric columns of the sublattices. Straight photonic crystal waveguides with three types of domain walls (bearded, zigzag, armchair) are constructed. Simulation results show that the creation of a double-edge state in the band diagram results in two windows of stable transmission in tunable bands. Our findings might have significant implications in the field of novel optical devices.

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岩石蠕变模型的二次开发

价值工程 2025年第1期44卷 65-67页

作者：王宇茆苏徽三峡库区地质灾害教育部重点实验室宜昌443002 三峡大学土木与建筑学院宜昌443002 三峡大学防灾减灾湖北省重点实验室宜昌443002

岩石的非线性蠕变本构模型的二次开发是研究岩石非线性蠕变的重点。本文对前人建立的本构模型进行三维差分公式推导,将三维公式写入FLAC^(3D)软件,进行本构模型的二次开发;对比分析数值模拟和试验数据的拟合程度,验证模型的正确性。

关键词：岩石本构方程卸荷蠕变二次开发

PRECISE SYNTHESIS OF OLEFIN BLOCK COPOLYMERS USING A SYNDIOSPECIFIC LIVING POLYMERIZATION SYSTEM

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Chinese Journal of Polymer Science 2013年第4期31卷 541-549页

作者：蔡正国 Hai-hui su Takeshi Shiono State Key Lab for Modification of Chemical Fibers and Polymer Materials College of Material Science and EngineeringDonghua University Graduate School of Engineering Hiroshima University

This feature article summarizes the synthesis of novel olefin block copolymers using fast syndiospecific living homo- and copolymerization of propylene, higher 1-alkene, and norbornene with ansa-fluorenylamidodimethyltitanium- based catalyst according to the authors＇ recent results. The catalytic synthesis of monodisperse polyolefin and olefin block copolymer was also described using this living system.

关键词： Single-site catalyst Propylene Norbomene Living polymerization Block copolymer.

Analysis on hot deformation and following cooling technology of 25Cr2Ni4MoVA steel

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Journal of Iron and Steel Research International 2021年第10期28卷 1305-1314页

作者： Jie Yang Zong-hui su Feng-li sui School of Metallurgical Engineering Anhui University of TechnologyMa’anshan243032AnhuiChina

The true stress–true strain curves of 25Cr2Ni4MoVA steel were obtained by uniaxial compression experiments at 850–1200℃ in the strain rate range of 0.001–10.0 s^(−1).And the dynamic continuous cooling transformation curves were obtained at the cooling rate range of 0.5–15.0℃ s^(−1) from the austenitization temperature of 1000℃ to the room temperature by pre-strain of 0.2 as *** power dissipation map and the dynamic continuous cooling transformation diagram were constructed based on the data provided by these *** with the optical micrographs of the compressed samples,the full dynamic recrystallization region is located between 1000 and 1200℃ and at the strain rate range from 0.01 to 10.0 s^(−1) with the power dissipation efficiency not less than *** the full dynamic recrystallization region,the power dissipation efficiency increases and the dynamic recrystallization activation energy decreases with the temperature *** the strain rate decreasing,the power dissipation efficiency increases firstly and then starts to decrease as the strain rate is less than 0.1 s^(−1),and dynamic recrystallization activation energy changes on the *** to the dynamic continuous cooling transformation diagram,slow cooling is a better way for the hot-deformed piece with large size or complex shape to avoid cracking as the temperature of the piece is lower than 400℃,and different cooling ways can be used for the hot-deformed piece with small size and simple shapes to obtain certain microstructure and meet good compressive properties.

关键词： 25Cr2Ni4MoVA steel Power dissipation map Dynamic continuous cooling transformation diagram Hot deformation Cooling rate

One-pot degradation of cellulose into carbon dots and organic acids in its homogeneous aqueous solution

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Green Energy & Environment 2019年第4期4卷 391-399页

作者： hui su Zhihao Bi Yong Ni Lifeng Yan CAS Key Laboratory of Soft Matter Chemistry Hefei National Laboratory for Physical Sciences at the Microscale Department of Chemical Physics i CHEMUniversity of Science and Technology of China

As the abundant biopolymer, cellulose can be used as a feedstock for chemicals and materials. Effective conversion of cellulose by simple processes is a key point. Degradation of cellulose in its homogeneous solution is attractive for the molecular chains are free and spread. Here,microcrystalline cellulose was first dissolved in aqueous solution of Na OH and urea, and then hydrothermal reaction was carried out at various temperature and time. Fluorescence carbon dots(CDs) were generated accompanied with six organic acids: oxalic acid, formic acid, malonic acid, lactic acid, acetic acid, and fumaric acid. The yields of all organic acids and CDs, and the fluorescence quantum yield(QY) of CDs were studied at different reaction conditions. It was found that the maximum yield of organic acids and CDs are 80.1% and 6.03%, respectively, and the highest QY of the CDs is 10.9%. Fluorescence studies reveal that the as-prepared CDs has efficient selectivity and sensitivity toward iron ions in acidic condition, indicating it is a potential fluorescent sensor to the detection of Fe3+. Importantly, it provides a panorama to summary the degradation routes of cellulose in its homogeneous aqueous solution with both organic molecules and CDs as products.

关键词： Cellulose Homogeneous aqueous solution Degradation Organic acids Carbon dots (CDs)

Interaction of Chelerythrine Choloride in Acid Buffer with Calf-thymus DNA

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Chinese Chemical Letters 2006年第5期17卷 691-694页

作者： Yah Jing su Xiong hui WEI Department of Applied Chemistry College of Chemistry and Molecular Engineering Peking University Beijing 100871

The binding of chelerythrine （CHE） iminium to calf-thymus （CT） DNA is characterized by hypochromism and bathochromism in the absorption band, enhancement of fluorescence intensity, increase in fluorescence polarization, and the perturbation of the CD spectra of DNA. These changes are characteristic of intercalation. Scatchard plots constructed from fluorescence titration data gave a binding constant of 5.77×10^5 and a binding site size of 3,4 base pairs at 25 ℃. The intercalative interaction is exothermic with a Van＇t Hoff enthalpy of -33.7 kJ/mol. In addition, △G =-32.9 kJ/mol, and △S =-2.9 J/mol/K. The intercalation of CHE into the DNA helix is enthalpy-driven.

关键词： Chelerythrine CT-DNA intercalation thermodynamic.

The Feasibility of Constraining Dark Energy Using LAMOST Redshift survey

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Chinese Journal of Astronomy and Astrophysics 2006年第2期6卷 155-164页

作者： Lei sun Meng su Zu-hui Fan Department of Astronomy Peking University Beijing 100871

We consider using future redshift surveys with the Large Sky Area Multi-Object Fiber Spectroscopic Telescope （LAMOST） to constrain the equation of state of dark energy w. We analyze the Alcock ＆ Paczynski （AP） effect imprinted on the two-point correlation function of galaxies in redshift space. The Fisher matrix analysis is applied to estimate the expected error bounds of w0 and wα from galaxy redshift surveys, w0 and wα being the two parameters in the equation of state parametrization w（z） = w0 ＋ wαz/（1 ＋ z）. Strong degeneracies between w0 and wα are found. The direction of the degeneracy in w0 - wα plane, however, rotates counter-clockwise as the redshift increases. LAMOST can potentially contribute in the redshift range up to 0.5. In combination with other high redshift surveys, such as the proposed Kilo-Aperture Optical Spectrograph project （KAOS）, the joint constraint derived from galaxy surveys at different redshift ranges is likely to efficiently break the degeneracy of w0 and wα. We do not anticipate that the nature of dark energy can be well constrained with LAMOST alone, but it may help to reduce the error bounds expected from other observations, such as the supernova/Acceleration Probe （SNAP）.

关键词： Cosmology: theory - galaxies: distances and redshifts - galaxy clustering - large-scale structure of Universe

Critical Role of Ethylene-Propylene Block Copolymer in Impact Polypropylene Copolymer

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Chinese Journal of Polymer Science 2024年第3期42卷 344-351,I0007页

作者： Yu-hui Tang Na Zhang Wei Bao Wei Jiang Yuan Lin Zhao-hui su State Key Laboratory of Polymer Physics and Chemistry Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchun 130022China School of Applied Chemistry and Engineering University of Science and Technology of ChinaHefei 230026China

Ethylene-propylene block copolymer(EbP) is a vital component in impact polypropylene copolymer(IPC), yet its distribution in the multiphase composite material and how it influences the phase structure and the mechanical properties are not well understood. In this work,four IPCs were investigated by atomic force microscopy-infrared(AFM-IR) to assess the phase compositions in situ, based on which in conjunction with the chain microstructure information obtained ex situ the distributions of the copolymer components were derived for each alloy. For the IPCs whose EbP comprises long P and long E segments, the EbP fraction was found to phase separate from the rubber and the PP matrix to form the cores of the disperse particles with the E-P segmented copolymer(EsP). In contrast, in the IPC with EbP composed of long P and short E segments, the EbP fraction formed an outer shell for the rubber particles with the cores comprising the EsP alone, and this IPC, containing a lower E comonomer content than its counterpart, exhibited both better impact resistance and higher flexural modulus. These results clarify how the chain structure of EbP governs the phase morphology in IPC, which in turn impacts the properties of the composite material.

关键词： Impact polypropylene copolymers AFM-IR Ethylene-propylene block copolymers Core-shell rubber particles

Using highly concentrated chloride solutions to leach valuable metals from cathode-active materials in spent lithium-ion batteries

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Rare Metals 2021年第7期40卷 1971-1978页

作者： Ai-Fei Yi Zhao-Wu Zhu Ya-hui Liu Jian Zhang hui su Tao Qi National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China Key Laboratory of Green Process and Engineering Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China School of Chemistry and Chemical Engineering University of Chinese Academy of SciencesBeijing 101407China

This study focused on the extraction of valuable metals from the cathode-active materials in spent lithiumion batteries using a high-concentration chloride *** effects of the concentrations of ammonium chloride(NH4 Cl),hydrochloric acid(HCl),and reductants such as hydrogen peroxide(H_(2)O_(2))and urea(CO(NH_(2))_(2))on metal extraction and chlorine production were studied *** leaching mechanism was analyzed,and a leaching model was *** was found that the addition of solid NH4 Cl to an HCl solution significantly improved the metal extraction capability of the latter and reduced the formation of chlorine gas by 96.0%compared to that only using *** activation energies for leaching Li,Ni,Co,and Mn were determined to be 30.4,38.5,30.6,and 38.2 kJ·mol^(-1),*** study demonstrates an environmentally friendly method for recycling metal resources from cathode-active materials and furthers understanding of how NH4 Cl inhibits chlorine production when leaching with mixed solutions of HCl and NH4 Cl.

关键词： Lithium-ion batteries Hydrochloric acid Ammonium chloride Chlorine gas

Genomic landscape of gastric cancer： molecular classification and potential targets

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Science China(Life Sciences) 2017年第2期60卷 126-137页

作者： Jiawei Guo Weiwei Yu hui su Xiufeng Pang Shanghai Key Laboratory of Regulatory Biology Institute of Biomedical Sciences and School of Life Sciences East China Normal University Shanghai 200241 China

Gastric cancer imposes a considerable health burden worldwide, and its mortality ranks as the second highest for all types of cancers. The limited knowledge of the molecular mechanisms underlying gastric cancer tumorigenesis hinders the development of therapeutic strategies. However, ongoing collaborative sequencing efforts facilitate molecular classification and unveil the genomic landscape of gastric cancer. Several new drivers and tumorigenic pathways in gastric cancer, including chromatin remodeling genes, Rho A-related pathways, TP53 dysregulation, activation of receptor tyrosine kinases, stem cell pathways and abnormal DNA methylation, have been revealed. These newly identified genomic alterations await translation into clinical diagnosis and targeted therapies. Considering that loss-of-function mutations are intractable, synthetic lethality could be employed when discussing feasible therapeutic strategies. Although many challenges remain to be tackled, we are optimistic regarding improvements in the prognosis and treatment of gastric cancer in the near future.

关键词： gastric cancer chromatin remodeling RhoA p53 receptor tyrosine kinase DNA methylation