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Highly Transparent Fire-resistant Coatings with Intumescent Three-source Integration

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Chinese Journal of Polymer Science 2024年第7期42卷 907-915,I0005页

作者： Xiao-Liang Zeng Xin-Sheng Lan Yan Wang Lin Zhang de-Ming guo Hai-Bo Zhao State Grid Sichuan Electric Power Research Institute Chengdu610041China The Collaborative Innovation Center for Eco-Friendly and Fire-Safety Polymeric Materials(Ministry of Education) National Engineering Laboratory of Eco-Friendly Polymeric Materials(Sichuan)State Key Laboratory of Polymer Materials EngineeringCollege of ChemistrySichuan UniversityChengdu610064China

Wood,a readily available and sustainable natural resource,has found widespread use in construction and ***,its inherent flammability poses a potential fire *** intumescent fire-retardant coatings effectively mitigate this risk,achieving high transparency in such coatings presents a significant *** our approach,we employed a cross-linked network of phytic acid anion and N-[3-(trimethoxysilyl)propyl]-N,N,N-trimethylammonium cation to create a transparent"three-in-one"intumescent *** collaborative P/N/Si flame-retardant effect markedly improved the intumescent char-forming capability,preventing the wood from rapid *** resulted in a substantial reduction in heat release(13.9%decrease in THR)and an increased limiting oxygen index(LOI)value of 35.5%.Crucially,the high transparency of the coating ensured minimal impact on the wood's appearance,allowing the natural wood grains to remain clearly *** innovative approach provides a straightforward method for developing transparent intumescent flame-retardant coatings suitable for wooden *** potential applications extend to preserving ancient buildings and heritage conservation efforts.

关键词： Fire-resistant coating Flame retardancy Wood Transparency

Functional characterization,structural basis,and protein engineering of a rare flavonoid 2′-O-glycosyltransferase from Scutellaria baicalensis

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Acta Pharmaceutica Sinica B 2024年第8期14卷 3746-3759页

作者： Zilong Wang Xueqing Du guo Ye Haotian Wang Yizhan Liu Chenrui Liu Fudong Li HansÅgren Yang Zhou Junhao Li Chao He de-an guo Min Ye State Key Laboratory of Natural and Biomimetic Drugs School of Pharmaceutical SciencesPeking UniversityBeijing 100191China Anhui Key Laboratory of Modern Biomanufacturing and School of Life Sciences Anhui UniversityHefei 230601China National Science Center for Physical Sciences at Microscale Division of Molecular&Cell Biophysics and School of Life Sciences University of Science and Technology of ChinaHefei 230026China department of Physics and Astronomy Uppsala UniversityUppsala SE-75120Sweden School of Pharmacy Jinan UniversityGuangzhou 510632China Shanghai Research Center for Modernization of Traditional Chinese Medicine Shanghai Institute of Materia MedicaChinese Academy of SciencesShanghai 201203China

Glycosylation is an important post-modification reaction in plant secondary metabolism,and contributes to structural diversity of bioactive natural *** plants,glycosylation is usually catalyzed by *** 2′-O-glycosides are rare ***,no UGTs have been reported,thus far,to specifically catalyze 2′-O-glycosylation of *** this work,UGT71AP2 was identified from the medicinal plant Scutellaria baicalensis as the first flavonoid 2′-*** could preferentially transfer a glycosyl moiety to 2′-hydroxy of at least nine flavonoids to yield six new *** of the 2′-O-glycosides showed noticeable inhibitory activities against cyclooxygenase *** crystal structure of UGT71AP2(2.15Å)was solved,and mechanisms of its regio-selectivity was interpreted by pKa calculations,molecular docking,MD simulation,MM/GBSA binding free energy,QM/MM,and hydrogen‒deuterium exchange mass spectrometry *** structure-guided rational design,we obtained the L138T/V179D/M180T mutant with remarkably enhanced regio-selectivity(the ratio of 7-O-glycosylation byproducts decreased from 48%to 4%)and catalytic efficiency of 2′-O-glycosylation(kcat/Km,0.23 L/(s·μmol),12-fold higher than the native).Moreover,UGT71AP2 also possesses moderate UDP-dependent de-glycosylation activity,and is a dual function *** work provides an efficient biocatalyst and sets a good example for protein engineering to optimize enzyme catalytic features through rational design.

关键词： Glycosyltransferase Regio-selectivity Crystal structure de-glycosylation Catalytic mechanisms

Hydrogen production from hydrolysis of NaBH_(4) solution over Co-Fe-B@g-C_(3)N_(4)/NF thin film catalyst

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Rare Metals 2024年第6期43卷 2648-2659页

作者： Yan Wang Jia-Xin Ma Jian Ren Di Zhang Feng-Yan Xu Ke Zhang Zhong-Qiu Cao Qiu-Ju Sun guo-de Li Shi-Wei Wu Hong-Hui Chen College of Chemistry and Chemical Engineering Shenyang Normal UniversityShenyang 110034China Experimental Center Shenyang Normal UniversityShenyang 110034China Hunan Shande Energy Storage New Materials Research Institute Limited Company Changde 415000China

In this study,the double loaded Co-Fe-B@g-C_(3)N_(4)/NF(NF:Ni foam)thin film catalysts were prepared for the first time via chemical deposition method at room *** optimizing the reducing agent concentration to 0.9 mol·L^(-1),the as-obtained Co-Fe-B@g-C_(3)N_(4)/NF exhibited the twisted ribbon structure with more distinct three-dimensional hierarchy and the smaller particle size,showing the good catalytic property for the hydrolysis of NaBH_(4)*** H_(2)generation rate of Co-Fe-B@g-C_(3)N_(4)/NF and binary Co-B@g-C_(3)N_(4)/NF under visible light irradiation surpassed the value under natural *** apparent activation energy of Co-Fe-B@g-C_(3)N_(4)/NF(45.0 kJ·mol^(-1))under visible light irradiation was obviously reduced when compared with the natural condition(48.4 kJ·mol^(-1))and binary Co-B@g-C_(3)N_(4)/NF(60.6 kJ·mol^(-1))under visible light ***,the catalytic performance of the optimized Co-Fe-B@g-C_(3)N_(4)/NF thin film catalyst was superior to most of the reported non-noble metal and even noble metal ***,it illustrated that the catalytic H_(2)production performance of Co-Fe-B@g-C_(3)N_(4)/NF thin film was distinctly improved after the introduction of light and multicomponent recombination.

关键词： Sodium borohydride Co-Fe-B@g-C_(3)N_(4)/NF catalyst Chemical deposition Hydrogen production

Medcheck:A novel software for automated de-formulation of traditional Chinese medicine(TCM)prescriptions by liquid chromatography-mass spectrometry

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Journal of Pharmaceutical Analysis 2024年第6期14卷 930-932页

作者： Xiao-lan Li Jian-qing Zhang Yun Li Xuan-jing Shen Huan-ya Yang Lin Yang Meng Xu Qi-rui Bi Chang-liang Yao de-an guo Shanghai Research Center for Modernization of Traditional Chinese Medicine National Engineering Research Center of TCM Standardization TechnologyShanghai Institute of Materia MedicaChinese Academy of SciencesShanghai201203China b University of Chinese Academy of Sciences Beijing100049China

Prescriptions are the main clinical application of traditional Chinese medicines(TCMs).Common forms include Chinese patent medicines,Kampo formulas,and hospital decoctions.A new pre-scription called“famous classical formulas”is recently developed and expected to boom in the *** constituent me-dicinal plants in prescriptions is critical for new drug development and quality control[1],which could avoid safety issues from adulteration or substandard ingredients,as seen in the notorious Longdan Xiegan Pill event.

关键词： medicines formulation prescription

Invitation Letter for Contributions

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World Journal of Traditional Chinese Medicine 2024年第2期10卷 F0002-F0002页

作者： de-an guo Jing-Yan Han WJTCM

World Journal of Traditional Chinese Medicine(WJTCM),a peer reviewed and open access journal,is sponsored by WFCMS,and it is the official journal of Good Practice in Traditional Chinese Medicine Research Association(GP-TCM RA).WJTCM(ISSN 2311-8571,quarterly)aims to report the research progress in clinical efficacy and action mechanism of TCM.

关键词： journal TCM official

Shenqi Fuzheng injection alleviates chemotherapy-induced cachexia by restoring glucocorticoid signaling in hypothalamus

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Journal of Pharmaceutical Analysis 2024年第3期14卷 431-434页

作者： Entezar Berik Zijia Zhang Wei Li Yawen Liu Sihan Chen Wenyong Wu Zhaojun Wang Xinqin Kong Wenqiang Pei Huiqing Dong Huali Long Min Lei Jennifer Yiyang Wang Liangfeng Liu Jinjun Hou Jing Feng Zhaoxia Li Wanying Wu de-an guo Beijing Key Lab of TCM Collateral Disease Theory Research School of Traditional Chinese MedicineCapital Medical UniversityBeijing100069China National Engineering Research Center of TCM Standardization Technology Shanghai Institute of Materia MedicaChinese Academy of SciencesShanghai201203China University of Chinese Academy of Sciences Beijing100049China School of Chinese Materia Medica Nanjing University of Chinese MedicineNanjing210029China Limin Pharmaceutical Factory Livzon Group LimitedShaoguanGuangdong512028China Guangdong Corporate Key Laboratory of High-End Liquid Medicine R&D IndustrilizationShaoguanGuangdong512028China Center for Neurological and Psychiatric Research and Drug Discovery Shanghai Institute of Materia MedicaChinese Academy of ScienceShanghai201203China

Chemotherapy-induced cachexia(CIC)is a debilitating condition characterized by weight loss,muscle atrophy,and anorexia[1].While peripheral mechanisms of cachexia have been extensively studied,the involvement of the central nervous system(CNS)in CIC is often *** drugs cause stress responses and inflammation,which may impact the hypothalamus and disrupt systemic energy and neuroendocrine *** hypothalamic roles in regulating these processes can provide insights into CIC's mechanisms and aid in developing novel therapies.

关键词： injection drugs glucocorticoid chemotherapy

TC21合金在不同温度下进行连续多步置氢处理时的显微组织及室温力学性能

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Transactions of Nonferrous Metals Society of China 2024年第5期34卷 1520-1532页

作者：袁宝国钱德国张小雪陈强汤爱闯合肥工业大学材料科学与工程学院合肥230009 安徽三联学院机械工程学院合肥230601 西南技术工程研究所重庆400039

利用OM、XRD、TEM以及压缩试验等方法研究TC21钛合金经不同温度连续多步置氢处理后的显微组织及室温力学性能。结果表明:当氢处理温度超过1073 K时,α相的尺寸明显降低,β相成为主要相。随着氢处理温度的升高,δ氢化物的含量呈先增加后... 详细信息

利用OM、XRD、TEM以及压缩试验等方法研究TC21钛合金经不同温度连续多步置氢处理后的显微组织及室温力学性能。结果表明:当氢处理温度超过1073 K时,α相的尺寸明显降低,β相成为主要相。随着氢处理温度的升高,δ氢化物的含量呈先增加后逐渐降低的趋势。当氢处理温度超过1073 K时,TC21钛合金在室温压缩变形过程中出现应变软化现象,且该现象随氢处理温度的升高而越来越显著。随着氢处理温度的升高,TC21钛合金的极限变形率呈先降低后增加的趋势。当氢处理温度为1123 K时,TC21钛合金的极限变形率比原始合金增加67.51%。

关键词： TC21合金连续多步置氢处理室温力学性能压力-组成等温线

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生成式人工智能训练数据侵权风险与法律应对

湘潭大学学报（哲学社会科学版） 2024年第5期48卷 78-86页

作者：郭德忠张云蔚北京理工大学法学院北京102401

生成式人工智能模型训练数据的来源、使用和输出均有一定的不可控性,故其在训练中的各个环节和不同阶段均存在侵权风险。传统法律制度中的法定许可、强制许可无法适用于大规模训练数据获取和使用情形,合理使用条款虽涉及特定情形下的责... 详细信息

生成式人工智能模型训练数据的来源、使用和输出均有一定的不可控性,故其在训练中的各个环节和不同阶段均存在侵权风险。传统法律制度中的法定许可、强制许可无法适用于大规模训练数据获取和使用情形,合理使用条款虽涉及特定情形下的责任豁免例外,但并未对训练数据行为本身进行有效规制。“三步检验法”需要在司法实践中进一步探索各要素的具体认定标准和裁量规则。域外“转化性使用”标准虽可资借鉴,但其标准的具体考量因素亟待甄别。有必要完善相关领域的法律体系及其配套措施,促进人工智能技术发展,保障版权人的合法权利,进而协调好二者之间的利益关系。

关键词：生成式人工智能训练数据合理使用转化性使用利益平衡

基于多光谱图像角度融合测定库尔勒香梨理化指标

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光谱学与光谱分析 2024年第3期44卷 649-655页

作者：刘鸿阳孔德国罗华平高峰王聪颖塔里木大学机械电气化工程学院新疆阿拉尔843300 自治区教育厅普通高等学校现代农业工程重点实验室新疆阿拉尔843300

基于多光谱图像角度融合,提出了一种库尔勒香梨快速无损检测的方法。以库尔勒香梨为研究对象,应用多光谱成像采集系统,以10°为间隔,获取了相对方位角为10°~90°内的多光谱图像。使用ENVI5.1软件进行多光谱图像角度融合并提取感兴趣区... 详细信息

基于多光谱图像角度融合,提出了一种库尔勒香梨快速无损检测的方法。以库尔勒香梨为研究对象,应用多光谱成像采集系统,以10°为间隔,获取了相对方位角为10°~90°内的多光谱图像。使用ENVI5.1软件进行多光谱图像角度融合并提取感兴趣区域(ROI),获得多光谱数据。对光谱反射率、波段和相对方位角进行了皮尔逊相关性分析,发现波段和相对方位角都对光谱反射率呈极显著相关性,且相对方位角相关系数为0.1大于波段相关系数0.053,有必要在建模过程中加入相对方位角因素。采用标准正态变量变换(SNV)、均值中心化变换(MC)、卷积平滑处理(S_G)和归一化处理(Nor)等预处理方法,选用偏最小二乘回归(PLSR)建立全波段检测模型,通过校正集相关系数(R_(c))、预测集相关系数(R_(p))、校正集均方根误差(RMSEC)和预测集均方根误差(RMSEP)对模型的效果进行评价,对比探究特征角度下和角度融合下库尔勒香梨关键指标的模型检测效果。结果表明:采用角度融合处理后,所建立的PLSR和SVM模型预测效果都有显著提升。预测库尔勒香梨含水率最优模型为采用角度融合的偏最小二乘回归模型(AF-PLSR),其R_(c)为0.936, RMSEC为0.298,R_(p)为0.901, RMSEP为0.285;预测库尔勒香梨硬度和糖度的最优模型为以角度融合的支持向量机模型(AF-SVM),R_(c)分别为0.894、 0.905, RMSEC为0.527、 0.376;R_(p)为0.830、 0.901, RMSEP为0.532、 0.379。角度融合将不同角度下的光谱数据结合在一起,获得了比单一角度更加丰富的信息,得到了更加完善的光谱。所建立的检测模型精度更高。结果证明:基于多光谱图像角度融合技术预测库尔勒香梨的含水率、硬度和糖度是可行的。为提高多光谱无损检测精度和高光谱无损检测精度提供了一种新的思路。

关键词：多光谱成像融合光谱库尔勒香梨偏最小二乘回归