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Key role of electron accessibility at the noble metal-free catalytic interface in hydrogen evolution reaction

Nano Research 2024年第4期17卷 2538-2545页

作者： Dongchen Han Nanxing Gao Yuyi Chu Zhaoping Shi Ying Wang Junjie ge Meiling Xiao Changpeng Liu Wei Xing State Key Laboratory of Electroanalytical Chemistry Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchun 130022China School of Applied Chemistry and Engineering University of Science and Technology of ChinaHefei 230026China Laboratory of Advanced Power Sources Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchun 130022China Jilin Province Key Laboratory of Low Carbon Chemical Power Sources Changchun 130022China State Key Laboratory of Rare Earth Resource Utilization Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchun 130022China

The reactant concentration at the catalytic interface holds the key to the activity of electrocatalytic hydrogen evolution reaction(HER),mainly referring to the capacity of adsorbing hydrogen and electron *** hydrogen adsorption free energy(ΔGH)as a reactivity descriptor,the volcano curve based on Sabatier principle is established to evaluate the hydrogen evolution activity of ***,the role of electron as reactant received insufficient attention,especially for noble metal-free compound catalysts with poor conductivity,leading to cognitive gap between electronic conductivity and apparent catalytic *** we successfully construct a series of catalyst models with gradient conductivities by regulating molybdenum disulfide(MoS_(2))electronic bandgap via a simple solvothermal *** demonstrate that the conductivity of catalysts greatly affects the overall catalytic *** further elucidate the key role of intrinsic conductivity of catalyst towards water electrolysis,mainly concentrating on the electron transport from electrode to catalyst,the electron accumulation process at the catalyst layer,and the charge transfer progress from catalyst to *** and experimental evidence demonstrates that,with the enhancement in electron accessibility at the catalytic interface,the dominant parameter governing overall HER activity gradually converts from electron accessibility to combination of electron accessibility and hydrogen adsorbing *** results provide the insight from various perspective for developing noble metal-free catalysts in electrocatalysis beyond HER.

关键词： conductivity molybdenum disulfide catalytic interface electron accessibility hydrogen evolution charge transfer.

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RNA ac^(4)C modification in cancer biology:from regulatory mechanisms to clinical applications

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Science China(Life Sciences) 2024年第4期67卷 832-835页

作者： Lijun Tao Yunqing Lu Zhuojia Chen Lichen ge Junming He Jianxin Peng Hongsheng Wang School of Pharmaceutical Sciences Sun Yat-sen UniversityGuangzhou 510006China Sun Yat-sen University Cancer Center State Key Laboratory of Oncology in South ChinaCollaborative Innovation Center for Cancer MedicineGuangzhou 510060China Department of Hepatobiliary Surgery Guangdong Province Traditional Chinese Medical HospitalGuangzhou 510120China

RNA modifications are increasingly recognized for their significance in diverse physiological and pathological processes,with over 170 types of chemical modifications having been discovered since *** these modifications,N4-acetylcytidine(ac^(4)C)is the first acetylated modification identified on eukaryotic RNAs,previously reported in transfer RNA(t RNA)and ribosomal RNA(rRNA)。

关键词： clinical (4) modification

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Can near-to-mid Infrared Spectral Energy Distribution Quantitatively Trace Protoplanetary Disk Evolution?

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Research in Astronomy and Astrophysics 2024年第7期24卷 34-46页

作者： Mingchao Liu Jinhua He Zhen Guo Jixing ge Yuping Tang Yunnan Observatories Chinese Academy of SciencesKunming 650216China Chinese Academy of Sciences South America Center for Astronomy National Astronomical ObservatoriesChinese Academy of SciencesBeijing 100101China University of Chinese Academy of Sciences Beijing 100049China Departamento de Astronomía Universidad de ChileLas Condes7591245 SantiagoChile Instituto de Física y Astronomía Universidad de Valparaísoave.Gran Bretaña1111Casilla 5030ValparaísoChile Centre for Astrophysics Research University of HertfordshireHatfield AL109ABUK Millennium Institute of Astrophysics Nuncio Monseñor Sotero Sanz 100Of.104ProvidenciaSantiagoChile Xinjiang Astronomical Observatory Chinese Academy of SciencesUrumqi 830011China Xinjiang Key Laboratory of Radio Astrophysics Urumqi 830011China Shanghai Key Lab for Astrophysics Shanghai Normal UniversityShanghai 200234China

Infrared(IR)spectral energy distribution(SED)is the major tracer of protoplanetary *** was recently proposed to use the near-to-mid IR(or K-24)SED slopeαdefined between 2 and 24μm as a potential quantitative tracer of disk *** critically examine the viability of this idea and confront it with additional statistics of IR luminosities and SED *** point out that,because the statistical properties of most of the complicated physical factors involved in disk evolution are still poorly understood in a quantitative sense,the only viable way is to assume them to be random so that an idealized“average disk”can be defined,which allows theαhistogram to trace its *** confirm that the statistics of the zeroth order(luminosity),first order(slopeα),and second order characteristics(concavity)of the observed K-24 SEDs indeed carry useful information upon the evolutionary processes of the“average disk”.We also stress that intrinsic diversities in K-24 SED shapes and luminosities are always large at the level of individual stars so that the application of the evolutionary path of the“average disk”to individual stars must be done with *** data of most curves in plots are provided on GitHub(Disk-age package https://***/starage/disk-age/).

关键词： stars:formation stars:pre-main sequence stars:protostars infrared:stars protoplanetary disks

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Variation of microbiological and small molecule metabolite profiles of Nuodeng ham during ripening by high-throughput sequencing and GC-TOF-MS

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Food Science and Human Wellness 2024年第4期13卷 2187-2196页

作者： Cong Li Yingling Zou Guozhou Liao Zijiang Yang Dahai Gu Yuehong Pu Changrong ge Guiying Wang Livestock Product Processing and Engineering Technology Research Center of Yunnan Province Yunnan Agricultural UniversityKunming 650201China College of Food Science and Technology Yunnan Agricultural UniversityKunming 650201China

The internal microbial diversity and small molecular metabolites of Nuodeng ham in different processing years(the first,second and third year sample)were analyzed by high-throughput sequencing technology and gas chromatography-time of flight mass spectrography(GC-TOF-MS)to study the effects of microorganisms and small molecular metabolites on the quality of ham in different processing *** results showed that the dominant bacteria phyla of Nuodeng ham in different processing years were Proteobacteria and Firmicutes,the dominant fungi phyla were Ascomycota and Basidiomycota,while Staphylococcus and Aspergillus were the dominant bacteria and fungi of Nuodeng ham,***,252 kinds of small molecular metabolites were identified from Nuodeng ham in different processing years,and 12 different metabolites were screened through multivariate statistical *** metabolic pathway analysis showed that 23 metabolic pathways were related to ham fermentation,of which 8 metabolic pathways had significant effects on ham fermentation(Impact>0.01,P<0.05).The content of L-proline,phenyllactic acid,L-lysine,carnosine,taurine,D-proline,betaine and creatine were significantly positively correlated with the relative abundance of Staphylococcus and Serratia,but negatively correlated with the relative abundance of Halomonas,Aspergillus and Yamadazyma.

关键词： Nuodeng ham Microbial diversity Small molecule metabolites High-throughput sequencing Gas chromatography-time of flight mass spectrography

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A ratiometric optical thermometer with dual-color emission based on Eu^(2+)-doped CsCu_(2)I_(3) microcrystals

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Journal of Rare Earths 2024年第8期42卷 1429-1436,I0001页

作者： Xiaorong Li ge Gao Kaiyu Wang Zhaoqiong Chen Zejiang Gao Qingyong Qin Li Chen Bingsuo Zou State Key Laboratory of Featured Metal Materials and Life-cycle Safety for Composite Structures School of Physical Science and TechnologyGuangxi UniversityNanning530004China School of Resources Environments and MaterialsGuangxi UniversityNanning530004China

With the increasing demand for non-co ntact fluorescence intensity ratio-based optical thermometry,novel phosphor materials with high-efficiency,dual-emitting centers,and differentiable temperature sensitivity are highly desired,In this wo rk,rare earth Eu^(2+) ions were incorporated Wnto CsCu_(2)I_(3) microcrystals by solidstate reaction,Under a single UV excitation,the as-synthesized samples exhibit two emissions:452 nm blue emission from the 5d→4f transition of Eu^(2+)and 582 nm yellow emission from self-trapped exciton e mission of CsCu_(2)I_(3).The photoluminescence quantum yield reaches to 50%,The dual-band emission of Eu^(2+)-doped CsCu_(2)I_(3) shows different temperature responses in the range of 260-360 *** on fluorescence intensity ratio technology,the maximum absolute sensitivity and re Iative sensitivity are 0.091 K^(-1)(at 360 K) and 2.60%/K(at 260 K),*** results suggest that Eu^(2+)-doped GsCu_(2)I_(3) could be a good candidate for highly sensitive optical thermometer.

关键词： CsCu_(2)I_(3) Eu^(2+)-doping Fluorescence intensity ratio Optical thermometer Rare earths

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Improving actionable warning identification via the refined warning-inducing context representation

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Science China(Information Sciences) 2024年第5期67卷 321-322页

作者： Xiuting ge Chunrong FANG Xuanye LI Quanjun ZHANG Jia LIU Zhihong ZHAO Zhenyu CHEN State Key Laboratory for Novel Software Technology Nanjing University

Static analysis tools(SATs) have shown potential ability in software quality assurance [1]. However, SATs report an overwhelming number of warnings, where most warnings are unactionable ones(i.e., warnings that are not acted on or fixed by developers). It is not a trivial task for developers to find actionable warnings(i.e., warnings that are acted on and fixed by developers) in all reported warnings. Hence,the excessive unactionable warnings seriously impede the usability of SATs [2].

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Förster resonance energy transfer reveals phillygenin and swertiamarin concurrently target AKT on different binding domains to increase the anti-inflammatory effect

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Chinese Chemical Letters 2024年第5期35卷 207-212页

作者： Xiaoyao Ma Jinling Zhang ge Fang He Gao Jie Gao Li Fu Yuanyuan Hou Gang Bai State Key Laboratory of Medicinal Chemical Biology College of Pharmacy and Tianjin Key Laboratory of Molecular Drug ResearchNankai UniversityTianjin 300000China College of Life Health Dalian UniversityDalian 116622China Dalian Fusheng Pharmaceutical Co. Ltd.Dalian 116000China

The clinical benefit of combination therapy is significant,but it is not easy to define the mechanism of complexity and *** studies illustrate that phillygenin(Phi)binds in the allosteric inhibit pocket of protein kinase B(AKT),and swertiamarin(Swe)acts on the pleckstrin homology(PH)domain of ***,the combined synergistic effect of relieving the inflammatory response has yet to be *** on high sensitivity,specificity and fast-responsibility fluorescent sensors,the Förster resonance energy transfer(FRET)technique offers a route to provide clear insights into physiological and pathological *** the study,molecular docking,the fluorescent probes of Phi and Swe for FRET were designed and *** analysis shown that Swe and Phi concurrently acted on the PH domain and allosterically inhibited pocket of AKT,*** combination of Swe and Phi significantly increased the heat stability of AKT and decreased protease-induced *** lipopolysaccharides(LPS)-induced mice and cells,the combination arrested AKT activation,nuclear factor kappa-B(NF-κB)phosphorylation,and the expression of tumor necrosis factor-α(TNF-α),interleukin(IL)-6 and *** conclusion,FRET revealed Phi and Swe concurrently targeted AKT on different domains and the combination of Phi and Swe enhanced the anti-inflammatory effect.

关键词： FRET Swertiamarin Phillygenin AKT Anti-inflammation Combinatorial drug

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Microstructure Evolution and Mechanical Properties of Friction Stir Welded Al-Cu-Li Alloy

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Acta Metallurgica Sinica(English Letters) 2024年第5期37卷 855-871页

作者： Peng Chen Wenhao Chen Jiaxin Chen Zhiyu Chen Yang Tang ge Liu Bensheng Huang Zhiqing Zhang School of New Energy and Materials Southwest Petroleum UniversityChengdu 610500China Sichuan Provincial Engineering Research Center of Advanced Materials Manufacturing Technology for Shale Gas High-Efficient Exploitation Southwest Petroleum UniversityChengdu 610500China College of Materials Science and Engineering Chongqing UniversityChongqing 400045China School of Mechatronic Engineering Southwest Petroleum UniversityChengdu 610500China School of Robot Engineering Yangtze Normal UniversityChongqing 408100China

The investigation concentrates on friction stir welded(FSW)Al-Cu-Li alloy concerning its local microstructural evolution and mechanical *** grain features were characterized by electron back scattered diffraction(EBSD)technology,while precipitate characterization was conducted by using transmission electron microscopy(TEM)aligned along[011]Al and[001]Al zone *** mechanical properties are evaluated through micro-hardness and tensile *** can be found that nugget zones exhibit finely equiaxed grains evolved through complete dynamic recrystallization(DRX),primarily occurring in continuous dynamic recrystallization(CDRX)and discontinuous dynamic recrystallization(DDRX).In the thermal-mechanically affected zone(TMAZ),numerous sub-structured grains,exhibiting an elongated morphology,were created due to partial DRX,signifying the dominance of CDRX,DDRX,and geometric dynamic recrystallization(GDRX)in this region.T_(1)completely dissolves in the nugget zone(NZ)leading to the formation of Guinier-Preston zones and increase ofδ′,β′and S′.Conversely,T_(1)partially solubilizes in TMAZ,the lowest hardness zone(LHZ)and heat affected zone(HAZ),and the residual T_(1)undergoes marked coarsening,revealing various T_(1)*** solubilization and coarsening of T_(1)are primary contributors to the degradation of hardness and strength.θ′primarily dissolves and coarsens in NZ and TMAZ,whilst this precipitate largely coarsens in HAZ and LHZ.σ,TB,grain boundary phases(GBPs)and precipitate-free zone(PFZ)are newly generated during FSW.σexists in the TMAZ,LHZ and HAZ,whereas TB nucleates in *** and PFZ mostly develop in LHZ and HAZ,which can cause strain localization during tensile deformation,potentially leading to LHZ joint fracture.

关键词： Al-Cu-Li alloy Friction stir welding Microstructure evolution Mechanical properties

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Alloy as advanced catalysts for electrocatalysis:From materials design to applications

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Chinese Chemical Letters 2024年第6期35卷 104-122页

作者： Pingfan Zhang Shihuan Hong Ning Song Zhonghui Han Fei ge Gang Dai Hongjun Dong Chunmei Li Advanced Chemical Engineering Laboratory of Green Materials and Energy of Jiangsu Province Institute of Green Chemistry and Chemical TechnologySchool of Chemistry and Chemical EngineeringJiangsu UniversityZhenjiang 212013China Daqo Group Co.Ltd. Zhenjiang 212221China Key Laboratory of Groundwater Resources and Environment Ministry of EducationJilin Provincial Key Laboratory of Water Resource and EnvironmentCollege of New Energy and EnvironmentJilin UniversityChangchun 130021China

With the deep integration of electrochemical research with energy,environment,catalysis,and other fields,more and more new electrochemical catalytic reactions have entered our research *** catalysts have recently emerged as a new type of nanomaterial due to the rapid development of kinetic controlled synthesis *** materials offer several advantages over monometallic catalysts,including larger element combinations,complex geometries,bifunctional sites,and reduced use of precious *** paper provides a review of alloy electrocatalysts that are designed and prepared specifically for electrocatalytic *** use of alloy materials in electrocatalyst design is also discussed,highlighting their widespread application in this ***,various synthesis methods and synthesis mechanisms are systematically *** that,by correlating the properties of materials with the structure,relevant strategies toward advanced alloy electrocatalysts including composition regulation,size,morphology,surface engineering,defect engineering,interface engineering and strain engineering are *** addition,the important electrocatalytic applications and mechanisms of alloy electrocatalysts are described and ***,the current challenges and prospects regarding the development of alloy nanomaterials are *** review serves as a springboard from a fundamental understanding of alloy structural dynamics to design and various applications of electrocatalysts,particularly in energy and environmental sustainability.

关键词： Alloy Nanomaterial Electrocatalyst Materials design Electrocatalysis

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Efficacy of electroacupuncture on myocardial protection and postoperative rehabilitation in patients undergoing cardiac surgery with cardiopulmonary bypass:a systematic review and Meta-analysis

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Journal of Traditional Chinese Medicine 2024年第1期44卷 1-15页

作者： QIN Xiaoyu WANG Chunai XUE Jianjun ZHANG Jie LU Xiaoting DING Shengshuang ge Long WANG Minzhen the First Clinical Medical College Gansu University of Chinese MedicineLanzhou 730030China Department of Anesthesiology Gansu Provincial Hospital of Traditional Chinese MedicineLanzhou 730050China Evidence-based Medicine Center Lanzhou UniversityLanzhou 730030China Institute of Epidemiology and Statistics School of Public HealthLanzhou UniversityLanzhou 730030China

OBJECTIVE:To evaluate the efficacy of electroacupuncture(EA)intervention on myocardial protection and postoperative rehabilitation in patients undergoing cardiac surgery with cardiopulmonary bypass(CPB).METHODS:Eight databases,including Pub Med,Embase,the Cochrane Library,Web of Science,Chinese Bio Medical Literature Database,China National Knowledge Infrastructure Database,Wanfang Data,China Science and Technology Journal Database,and two clinical trial registries,were *** randomized controlled trials(RCTs)related to EA intervention in cardiac surgery with CPB were *** on the inclusion and exclusion criteria,two researchers independently screened articles and extracted *** the quality evaluation,RevMan 5.3 software was used for ***:Fourteen RCTs involving 836 patients were *** with the control treatment,EA significantly increased the incidence of cardiac automatic rebeat after aortic unclamping[relative risk(RR)=1.15,95%confidence interval(CI)(1.01,1.31),Pgesic[SMD=-0.96,95%CI(-1.53,-0.38),P<0.05;low]medication was significantly lower in the EA group than in the control ***,the postoperative tracheal intubation time[SMD=-0.92,95%CI(-1.40,-0.45),P<0.05;low]and intensive care unit stay[SMD=-1.

关键词： electroacupuncture cardiopulmonary bypass thoracic surgery myocardial ischaemia-reperfusion injury myocardial protection postoperative rehabilitation Meta-analysis randomized controlled trial

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