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Polythiophene-block-poly(phenyl isocyanide) Copolymers: One-pot Synthesis, Properties and Applications

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Chinese Journal of Polymer Science 2017年第12期35卷 1447-1447,1448-1456页

作者： Li Zhou zhi-qiang jiang Lei Xu 刘娜吴宗铨 Department of Polymer Science and Engineering School of Chemistry and Chemical Engineering and Anhui Key Laboratory of Advanced Catalytic Materials and Reaction EngineeringHefei University of Technology

Conjugated block copolymers have gained increasing interests in recent years. Development of a novel method for facile synthesis of conjugated block copolymers with desired structures and functions is greatly desired. In this mini review, we summarized the recent advances in one-pot synthesis of conjugated block copolymers containing π-conjugated polythiophene and helical polyisocyanide segments by using a nickel（Ⅱ） complex as single catalyst. The sequential living polymerization of the two monomers proceeded in a controlled manner, affording expected block copolymers in high yields with controlled molecular weights（Mns） and narrow molecular weight distributions（Mw/Mns）. By using this method, a family of block copolymers with expected structure and tunable compositions can be facilely prepared. Introducing functional groups onto the pendant, these block copolymers can exhibit interesting self-assembly property, tunable light emission and multi-responsiveness.

关键词： Conjugated polymer Helical polymer Polyisocyanide Block copolymer Living polymerization

Gradient nanostructured tungsten and the thermal shock response

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Tungsten 2023年第4期5卷 548-557页

作者： Yan jiang Ping Huang zhi-qiang jiang Jing Hou Zhong Xu En-Hui Wu Jun Li Vanadium and Titanium Resource Comprehensive Utilization Key Laboratory of Sichuan Province Panzhihua UniversityPanzhihua617000China

In fusion reactor or spallation neutron source environment,damage of tungsten components begins at the *** enhance the surface toughness,strength,and hardness of tungsten,a nano-to-micro sc ale lamellar gradient surface layer(thickness up to~50μm)was produced on as-rolled pure tungsten using a dry-sliding surface *** dry-sliding temperature and time were established by observing the grain-size evolution from room temperature to 750℃and the coefficient of friction on the surface layer after sliding from 10 to 50 *** grains changed into a slender fibrous structure at 250℃,which is higher than the ductile-brittle transition temperature but lower than the dynamic recrystallization temperature(750℃).The coefficient of friction of the surface layer decreased with sliding time and stabilized at approximately 50 min,indicating near-s aturation of the surface *** repetitive thermal loads of 10,20,and 30 MW·m^(-2)on the gradient modified layer,it exhibited mainly recrystallization and grain *** proportion of low-angle grain boundaries(<10°)reached50.6,42.2,and 17.3%,respectively,and the hardness decreased to 602,582,and 488HV.A heat load of 30 MW·m^(-2)was the threshold for the fast grain *** with unmodified tungsten,the recrystallization and grain growth are relatively ***,the gradient layer could suppress the formation of pits and protrusions in the as-rolled tungsten sample.

关键词： Gradient layer Tungsten Dry sliding Coefficient of friction

Thermal effect of holmium laser lithotripsy under ureteroscopy

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Chinese Medical Journal 2019年第16期132卷 2004-2007页

作者： Xin-Kun Wang zhi-qiang jiang Jing Tan Guang-Ming Yin Kai Huang Department of Urology Third Xiangya HospitalCentral South UniversityChangshaHunan 410013China

To the Editor: Ureteral calculus is a common urological disease. In recent years, one of the main treatment methods is ureteroscopy with holmium laser lithotripsy. However, with the extensive application of holmium laser lithotripsy, the increasing incidence of postoperative ureteral stricture or even occlusion has attracted the attention of clinicians to its etiology. The issue of the intraoperative holmium laser thermal effect has also gradually gained attention. The holmium laser is a long-wavelength pulsed laser, which crushes calculi by an optomechanical/photoacoustic mechanism as well as a photothermal mechanism, and it is mainly based on the photothermal mechanism.[1] Currently, multiple in vitro studies worldwide have confirmed that the holmium laser did increase the water temperature in the working area. However, these studies only simulated the lithotripsy process of the holmium laser in vitro, which did not completely reflect the thermal effect of the holmium laser during an actual operation. Accordingly, this study monitored the temperature changes of the lavage fluid in the operative field during the actual holmium laser lithotripsy process under an ureteroscope, with the aim of providing more information for the etiology study of ureteral stricture after ureteroscopy with holmium laser lithotripsy.

关键词： Thermal effect holmium laser lithotripsy ureteroscopy

Engineering Fronts in 2018

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Engineering 2018年第6期4卷 748-753页

作者： Fang Cai Jiu-Ming Ji zhi-qiang jiang zhi-Rui Mu Xiang Wu Wen-jiang Zheng Wei-Xing Zhou Shan-Tung Tu Xuhong Qian College of Distance Education East China University of Science and TechnologyShanghai 200237China Institute of Science and Technology Information East China University of Science and TechnologyShanghai 200237China Research Center for Econophysics&School of Business East China University of Science and TechnologyShanghai 200237China Centre for Strategic Studies Chinese Academy of EngineeringBeijing 100088China Key Laboratory of Pressurized System and Safety Ministry of Education&School of Mechanical and Power EngineeringEast China University of Science and TechnologyShanghai 200237China East China Normal University Shanghai 200062China Shanghai Key Laboratory of Chemical Biology East China University of Science and TechnologyShanghai 200237China

*** Engineering science and technology is an important driving force in changing the world,and engineering frontiers(here referred to as“engineering fronts”)are important guidelines for future directions in the development of engineering science and *** trends in global engineering science and technology and quickly adapting to new directions in the current scientific and technological revolution have become strategic choices for countries all over the *** 2017,the Chinese Academy of Engineering has organized the Engineering Fronts research project,together with Clarivate Analytics and Higher Education Press,with the hope of bringing together the expert knowledge of global engineering and technology talents,assessing global frontiers in engineering research and development,and developing strategic opportunities to provide a reference for active responses to global challenges and sustainable development.

关键词： Engineering Fronts 2018

Synthesis and properties of poly(3-hydroxybutyrate-co-3-hydroxyvalerate)/chitin nanocrystals composite scaffolds for tissue engineering

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Chinese Chemical Letters 2014年第12期25卷 1635-1638页

作者： Hu-Yan Li He Li Bing-jie Wang Qun Gu zhi-qiang jiang Xue-Dong Wu College of Material Science and Chemical Engineering.Ningbo University Key Laboratory of Marine New Materials and Related Technology Zhejiang Key Laboratory of Marine Materials and Protection TechnologyNingbo Institute of Material Technology  EngineeringChinese Academy of Sciences Ningbo University of Technology

Poly（3-hydroxybutyrate-co-3-hydroxyvalerate）（PHBV）/chitin nanocrystals（CNC） composite scaffolds were synthesized by the salt leaching and thermally induced phase separation（TIPS） *** scaffolds have porous structures with macro-pores（100-300 μm in diameters） and micro-pores（10μm）.The surface characteristics of the scaffolds were characterized by X-ray photoelectron spectroscopy（XPS） and static water contact angle measurement,and the mechanical properties were investigated by a compression *** adipose-derived stem cells（hADSCs） were seeded onto the PHBV/CNC scaffolds and in vitro cell culture results showed that the composite scaffolds enhanced the hADSCs adhesion,which implies that the material may have potential application in tissue engineering.

关键词： PHBV Chitin nanocrystals Composite scaffolds hADSCs

Self-assembly Induced by Complexation of Diblock Copolyelectrolytes and Oppositely Charged Homopolymers

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Chinese Journal of Polymer Science 2024年第9期42卷 1321-1332,I0006页

作者： Ling Zhao zhi-Yuan Yin Jia-Di jiang Er-qiang Chen Shuang Yang Beijing National Laboratory for Molecular Sciences Key Laboratory of Polymer Chemistry and Physics of Ministry of EducationCenter for Soft Mater Science and EngineeringCollege of Chemistry and Molecular EngineeringPeking UniversityBeijing100871China Beijing National Laboratory for Molecular Sciences College of Chemistry and Molecular EngineeringPeking UniversityBeijing100871China

We investigate the solution self-assembly of a mixture of positively charged homopolymers and AB diblock copolymers,in which the A blocks are negatively charged,and the B blocks are *** electrostatic complexation between oppositely charged polymers drives the formation of many ordered *** microstructures and phase diagrams are calculated using self-consistent field theory(SCFT)based on an ion-pair model with an equilibrium constant K to characterize the strength of binding between positively and negatively charged *** effects of the charge ratio,representing the ratio of charges from the homopolymer over all charges from polymers in the system,on the ordered structure are systematically studied,both for hydrophobic and hydrophilic A *** charge ratio plays an important role in determining the phase boundaries in the phase diagram of salt concentration versus polymer *** also provide information about the varying tendency of the domain spacing and core size of the spherical phase when the charge ratio is changed,and the results are in good agreement with *** studies provide a deep understanding of the self-assembled microstructures of oppositely charged diblock copolymer-homopolymer systems.

关键词： Self-assembly Polyelectrolyte complexation Self-consistent field theory Ion-pair

Gelfand-Kirillov Dimension and Reducibility of Scalar Generalized Verma Modules for Classical Lie Algebras

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Acta Mathematica Sinica,English Series 2024年第3期40卷 658-706页

作者： Zhan qiang BAI Jing jiang School of Mathematical Sciences Soochow UniversitySuzhou 215006P.R.China E-mail:zqbai@*** jjsd6514@***

Let g be a classical complex simple Lie algebra and q be a parabolic *** M be a generalized Verma module induced from a one dimensional representation of *** M is called a scalar generalized Verma *** this paper,we will determine the reducibility of scalar generalized Verma modules associated to maximal parabolic subalgebras by computing explicitly the Gelfand-Kirillov dimension of the corresponding highest weight modules.

关键词： Generalized Verma module Gelfand-Kirillov dimension Young tableau

A comprehensive review on microchannel heat sinks for electronics cooling

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International Journal of Extreme Manufacturing 2024年第2期6卷 133-162页

作者： zhi-qiang Yu Mo-Tong Li Bing-Yang Cao Key Laboratory for Thermal Science and Power Engineering of Ministry of Education Department of Engineering MechanicsTsinghua UniversityBeijing 100084People’s Republic of China

The heat generation of electronic devices is increasing dramatically,which causes a serious bottleneck in the thermal management of electronics,and overheating will result in performance deterioration and even device *** the development of micro-machining technologies,the microchannel heat sink(MCHS)has become one of the best ways to remove the considerable amount of heat generated by high-power *** has the advantages of large specific surface area,small size,coolant saving and high heat transfer *** paper comprehensively takes an overview of the research progress in MCHSs and generalizes the hotspots and bottlenecks of this *** heat transfer mechanisms and performances of different channel structures,coolants,channel materials and some other influencing factors are ***,this paper classifies the heat transfer enhancement technology and reviews the related studies on both the single-phase and phase-change flow and heat *** comprehensive review is expected to provide a theoretical reference and technical guidance for further research and application of MCHSs in the future.

关键词： microchannel heat sink thermal management of electronics microscale heat transfer heat transfer enhancement

Precise Asymptotics in Limit Theorems for a Supercritical Branching Process with Immigration in a Random Environment

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Acta Mathematica Sinica,English Series 2024年第8期40卷 1850-1874页

作者： Chun Mao HUANG Rui ZHANG zhi qiang GAO Department of Mathematics Harbin Institute of Technology(Weihai)Weihai 264209P.R.China School of Mathematical Sciences Beijing Normal UniversityBeijing 100875P.R.China

Let(Zn)be a supercritical branching process with immigration in an independent and identically distributed random *** necessary moment conditions,we show the exact convergence rate in the central limit theorem on log Zn and establish the corresponding local limit theorem by using the moments of the natural submartingale and the convergence rates of its *** similar approach and with the help of a change of measure,we also present the so-called integrolocal theorem and integral large deviation theorem to characterize the precise asymptotics of the upper large deviations.

关键词： Branching process with immigration random environment central limit theorem large deviation