Polythiophene-block-poly(phenyl isocyanide) Copolymers: One-pot Synthesis, Properties and Applications

作     者：Li Zhou Zhi-qiang Jiang Lei Xu 刘娜 吴宗铨 

作者机构：Department of Polymer Science and Engineering School of Chemistry and Chemical Engineering and Anhui Key Laboratory of Advanced Catalytic Materials and Reaction EngineeringHefei University of Technology 

出 版 物：《Chinese Journal of Polymer Science》 (高分子科学（英文版）)

年 卷 期：2017年第35卷第12期

页      面：1447-1447,1448-1456页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

基　　金：financially supported by the National Natural Science Foundation of China(Nos.21622402,51673057 and 21574036) 1000 plan Program for Young Talents of China 

主　　题：Conjugated polymer Helical polymer Polyisocyanide Block copolymer Living polymerization 

摘      要：Conjugated block copolymers have gained increasing interests in recent years. Development of a novel method for facile synthesis of conjugated block copolymers with desired structures and functions is greatly desired. In this mini review, we summarized the recent advances in one-pot synthesis of conjugated block copolymers containing π-conjugated polythiophene and helical polyisocyanide segments by using a nickel（Ⅱ） complex as single catalyst. The sequential living polymerization of the two monomers proceeded in a controlled manner, affording expected block copolymers in high yields with controlled molecular weights（Mns） and narrow molecular weight distributions（Mw/Mns）. By using this method, a family of block copolymers with expected structure and tunable compositions can be facilely prepared. Introducing functional groups onto the pendant, these block copolymers can exhibit interesting self-assembly property, tunable light emission and multi-responsiveness.