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Direct ink writing of polycaprolactone/polyethylene oxide based 3D constructs

Progress in Natural Science:Materials International 2021年第2期31卷 180-191页

作者： Bin Zhang se hun chung Susan Barker Duncan Craig Roger J.Narayan Jie Huang Department of Mechanical Engineering University College London Medway School of Pharmacy Universities of Greenwich and Kent School of Pharmacy University College London Joint Department of Biomedical Engineering University of North Carolina and North Carolina State University

There has been increasing interest over recent years in the application of three-dimensional(3 D) printing technologies in the biomedical field. One such method is Direct Ink Writing(DIW); this approach has the potential advantage of allowing room-temperature deposition of materials, presented as an ink, to build complex architectures. DIW offers the ability to process biomaterials containing temperature-sensitive components. Due to the fabrication principles of DIW, there are specific rheological requirements that the ink must exhibit for the 3 D construction. For this reason, hydrogel-based liquid feed stocks have been the focal point of ink development. As a consequence, studies based on inks comprising hydrophobic biomaterials, which are insoluble in water and hence unsuited to the hydrogel approach, have been *** this study, we investigate novel inks that utilize polycaprolactone(PCL), a hydrophobic polymer, as the primary constituent by dissolving the polymer in solvent systems based on dichloromethane(DCM) and acetone(ACE). Moreover, polyethylene oxide(PEO) was incorporated into the PCL systems in order to extend the range of hydrophilicity of the systems. The rheological properties of the inks were investigated as a function of polymer composition and solvent system. Woodpile constructs of PCL and PCL/PEO were fabricated using DIW method and were assessed by a series of material characterisation. The type of solvent system had a noticeable impact on the ink rheology, which ultimately affected the surface properties. The incorporation of PEO particularly enhanced the roughness and wettability of the constructs. Our results support the use of DIW as a new means to process hydrophobic polymers for biomedical applications.

关键词： Direct ink writing Polycaprolactone Polyethylene oxide Ink rheology Material characterisation 3D construct

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Combined Insights from Leachate Structure and Microstructure Characteristics for Eating Quality of Convenience Rice Processed by Super-Heated and Pressurized Steam Technologies

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Rice science 2024年第4期31卷 475-488,I0035,I0036页

作者： Mingyo HA Hyo-Young JEONG Ju hun LEE Hyun-Jung chung Division of Food and Nutrition Chonnam National UniversityGwangju 61186South Korea Department of Biotechnology College of Life Sciences and BiotechnologyKorea UniversitySeoul 02841South Korea Division of Food Science&Culinary Arts Shinhan UniversityGyeonggi 11644South Korea

Convenience rice has become widely popular due to its easy availability for cooking. This study investigated the starch structure and composition of leachate and the microstructure of reheated convenience rice using novel processing technologies: super-heated steaming(SHS), auto-electric cooking(AEC), and pressurized-steam cooking(PSC). Additionally, the effect of two different target water contents(58% and 63%) was also evaluated. The PSC_63% sample had the highest total solids and amylopectin amount in the leachate. The amylopectin amount in the leachate differed significantly based on the targeted water content. Morphological characterization revealed that the swelling of starch and the coated layer on the surface of rice grains were most pronounced in the PSC_63% sample due to the pressure processing. The textural hardness of the AEC_58% sample was much higher than that of the other samples. The PSC_63% sample had the highest textural adhesiveness value, which can be attributed to the highest amylopectin amount in the leachate. sensory characterization showed that the PSC_63% sample had the highest glossiness, whiteness, moistness, and overall acceptability. The principal component analysis score plots presented substantial differences in the leachate and textural and sensory characteristics of reheated convenience rice among the different processing technologies.

关键词： reheated convenience rice starch structure leachate multi-scale structure eating quality processing technology

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Two distinct subpopulations of marginal zone B cells exhibit differential antibody-producing capacities and radioresistance

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Cellular & Molecular Immunology 2024年第4期21卷 393-408页

作者： Sujin Lee Yeunjung Ko Hyun Woo Lee Won Joon Oh hun Gi Hong Dinuka Ariyaratne se Jin Im Tae Jin Kim Department of Immunology Graduate School of Basic Medical ScienceSungkyunkwan University School of MedicineSuwon16419Republic of Korea Department of Immunology and Molecular Medicine Faculty of Medical SciencesUniversity of Sri JayewardenepuraNugegodaSri Lanka Present address:Immunology and Microbiology Graduate Program Baylor College of MedicineHoustonTX77030USA

Marginal zone(MZ)B cells,which are splenic innate-like B cells that rapidly secrete antibodies(Abs)against blood-borne pathogens,are composed of heterogeneous ***,we showed that MZ B cells can be divided into two distinct subpopulations according to their CD80 expression ***80^(high)MZ B cells exhibited greater Ab-producing,proliferative,and IL-10-secreting capacities than did CD80^(low)MZ B ***,CD80^(high)MZ B cells survived 2-Gy whole-body irradiation,whereas CD80^(low)MZ B cells were depleted by irradiation and then repleted with one month after *** of CD80^(low)MZ B cells led to accelerated development of type II collagen(CII)-induced arthritis upon immunization with bovine ***80^(high)MZ B cells exhibited higher expression of genes involved in proliferation,plasma cell differentiation,and the antioxidant ***80^(high)MZ B cells expressed more autoreactive B cell receptors(BCRs)that recognized double-stranded DNA or CII,expressed more immunoglobulin heavy chain sequences with shorter complementarity-determining region 3 sequences,and included more clonotypes with no N-nucleotides or with B-1a BCR sequences than CD80^(low)MZ B *** transfer experiments showed that CD21^(+)CD23^(+)transitional 2 MZ precursors preferentially generated CD80^(low)MZ B cells and that a proportion of CD80^(low)MZ B cells were converted into CD80^(high)MZ B cells;in contrast,CD80^(high)MZ B cells stably remained CD80^(high)MZ B *** summary,MZ B cells can be divided into two subpopulations according to their CD80 expression levels,Ab-producing capacity,radioresistance,and autoreactivity,and these findings may suggest a hierarchical composition of MZ B cells with differential stability and BCR specificity.

关键词： Marginal Zone B Cell CD80 Autoreactivity Radioresistance

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RIP140, a Janus metabolic switch involved in defense functions

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Cellular & Molecular Immunology 2013年第1期10卷 7-9页

作者： hun Taeg chung School of Biological Sciences University of Ulsan Meta-Inflammation Basic Research Laboratory Ulsan KoreaCorrespondence: Dr HT Chung School of BiologicalSciences University of Ulsan Meta-lnflammation BasicResearch Laboratory Ulsan Korea.

Since its discovery almost 15 years ago, the receptor-interacting protein RIP140has been determined to be a corepressor of various transcription factors and nuclear receptors. Mice lacking the RIP140 gene are lean, exhibit resistance to high-fat diet- induced obesity and have increased glucose tolerance and insulin sensitivity. In 2008, RIP140 was determined to be a coactivator of nuclear factor-~cB, a master transcriptional regulator of inflammation in immune cells, including macrophages. This year, it was reported that RIP 140 degradation is involved in the resolution of inflammation and in endotoxin tolerance. The general picture that had emerged indicates that RIP140 is a ]anus metabolic switch that convergently regulates metabolic pathways involved in defense func- tions through its pleotropic interactions with transcription factors.

关键词： RIP140 Janus metabolic switch defense functions

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SHP gains citizenship of the AMPK kingdom

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Cellular & Molecular Immunology 2011年第6期8卷 450-452页

作者： hun-Taeg chung School of Biological Sciences University of UlsanMetaInflammation Basic Research LaboratoryUlsanKorea

Various cytokines and chemokines are produced as a result of signaling through innate immune *** signaling is initiated by host–pathogen interactions in which the host’s germline-encoded pattern recognition receptors,including Toll-like receptors(TLRs),recognize conserved microbial structures termed pathogen-associated molecular *** are broadly distributed in immune cells and are responsible for eliciting innate responses and enhancing adaptive immunity to *** 12 members of the TLR family in mammals are characterized by an extracelluar leucine-rich repeat domain and an intracellular Toll/IL-1 receptor domain.

关键词： immunity cytokines initiated

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Formation of nanocrystalline microstructure in arc ion plated CrN films

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Transactions of Nonferrous Metals Society of China 2011年第A1期21卷 73-77页

作者： Qi-min WANG se-hun KWON Kwang-Ho KIM National Core Research Center for Hybrid Materials Solution Pusan National University Busan 609-735 Korea School of Materials Science and Engineering Pusan National University Busan 609-735 Korea

Applying negative bias voltages caused significant microstructure changes in arc ion plated CrN films. Nanocrystalline microstructures were obtained by adjusting the negative bias voltage. Structural characterizations of the films were carried out using X-ray diffractometry (XRD) and high-resolution transmission electron microscopy (HR-TEM). The results indicated that increasing ion bombardment by applying negative bias voltages resulted in the formation of defects in the CrN films, inducing microstructure evolution from micro-columnar to nanocrystalline. The microhardness and residual stresses of the films were also affected. Based on the experimental results, the evolution mechanisms of the film microstructure and properties were discussed by considering ion bombardment effects.

关键词： CrN thin films deposition microstructure arc ion plating ion bombardment

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Effect of carbon on microstructure of CrAlC_xN_(1-x) coatings by hybrid coating system

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Transactions of Nonferrous Metals Society of China 2011年第A1期21卷 78-82页

作者： Sung-Kyu AHN se-hun KWON Kwang-Ho KIM National Core Research Center for Hybrid Materials Solution Pusan National University School of Materials Science and Engineering Pusan National University

A systematic investigation of the microstructure of CrA1CxN1-x coatings as a function of carbon contents was conducted. Quaternary CrA1CxN1-x coatings were deposited on Si wafers by a hybrid coating system combining an arc-ion plating technique and a DC reactive magnetron sputtering technique using Cr and AI targets in the Ar/N2/CH4 gaseous mixture. The effect of carbon content on microstructure of CrA1C^N~ x coatings was investigated with instrumental analyses of X-ray diffraction, X-ray photoelectron, and high-resolution transmission electron microscopy. The results show that the carbon content of CrA1CxN1-x coatings linearly increases with increasing CH4/（CH4/N2） gas flow rate ratio. The surface roughness of the CrA1CxN1-x coating layer decreases with the increase of carbon content.

关键词： CrA1C,N1-x, coating nanocomposite microstructure hybrid coating system

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Cryptanalysis of the obfuscated round boundary technique for whitebox cryptography

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Science China(Information Sciences) 2020年第3期63卷 257-265页

作者： Yongjin YEOM Dong-Chan KIM chung hun BAEK Junbum SHIN Department of Information security Cryptology and Mathematics Kookmin University Samsung Research Samsung Electronics

Dear editor,The security of cryptographic techniques heavily relies on the confidentiality of the key, and everything except keys can be made open to public without affecting security. When working with cryptographic services, we must protect the keys from a variety of attackers, including eavesdroppers and malware. A whitebox adversary is an attacker

关键词： II Cryptanalysis of the obfuscated round boundary technique for whitebox cryptography

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Electrical and Corrosion Properties of Titanium Aluminum Nitride Thin Films Prepared by Plasma-Enhanced Atomic Layer Deposition

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Journal of Materials Science & Technology 2017年第3期33卷 295-299页

作者： Eun-Young Yun Woo-Jae Lee Qi Min Wang se-hun Kwon School of Materials Science and Engineering Pusan National University School of Electromechanical Engineering Guangdong University of Technology

Titanium-aluminum-nitride（TiAlN） films were grown by plasma-enhanced atomic layer deposition（PEALD）on 316 L stainless steel at a deposition temperature of 200 °C. A supercycle, consisting of one AlN and ten TiN subcycles, was used to prepare TiAlN films with a chemical composition of Ti（0.25）Al（0.25）N（0.50）. The addition of AlN to TiN resulted in an increased electrical resistivity of TiAlN films of 2800 μΩ cm, compared with 475 μΩ cm of TiN films, mainly due to the high electrical resistivity of AlN and the amorphous structure of TiAlN. However, potentiostatic polarization measurements showed that amorphous TiAlN films exhibited excellent corrosion resistance with a corrosion current density of 0.12 μA/cm^2, about three times higher than that of TiN films, and about 12.5 times higher than that of 316 L stainless steel.

关键词： Titanium-aluminum nitride Plasma-enhanced atomic layer deposition Corrosion protection Ternary transition metal nitrides

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Interface properties and phase formation between surface coated SKD61 and aluminum alloys

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中国有色金属学会会刊：英文版 2009年第4期19卷 875-878页

作者： se-Weon CHOI Young-Chan KIM se-hun CHANG Ik-Hyun OH Joon-Sik PARK Chang-seog KANG Automotive Components Center Korea Institute of Industrial Technology Division of Advanced Materials Engineering Hanbat National University

The intermediate phase formation and surface protection effects between SKD61 die mold alloys and aluminum alloys were investigated during a simulated die-casting *** surface coatings of SKD61 alloy were carried out via Si pack cementation coatings at 900 ℃ for 10 h and the ε-FeSi phase *** the coated SKD61 alloy was dipped in the liquid aluminum alloy(ALDC12),the surface coated SKD61 alloys showed better surface properties compared with uncoated SKD61 alloys,i.e.,the intermediate phases(FeSiAl compound) were not produced for the coated SKD61 *** coating layer of ε-FeSi served as a diffusion barrier for the formation of FeSiAl compounds.

关键词：表面涂层铝合金接口特性表面合金涂层表面保护合金生产化合物中间相

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