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Synthesis and characterization of rare earth metal doped tungsten trioxide photocatalyst for degradation of Rhodamine B dye

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稀土学报:英文版 2023年第9期41卷 1302-1310,I0002页

作者： Pooja Nehra Amita Khatri Anil kumar Satyendra Singh Pawan S.Rana Department of Physics Deenbandhu Chhotu Ram University of Science and TechnologyMurthal1339SonipatHaryanaIndia Special Centre for Nanoscience Jawaharlal Nehru University New Delhi10067India

Nowadays,it is concern for researchers that due to high recombination rate of photogenerated charge carriers in tungsten trioxide(WO_(3)) nanoparticles,the future applications are limited in the field of *** we attempt to synthesize tungsten trioxide nanoparticles with different doping concentrations of lanthanum i.e.2 wt%,4 wt%,6 wt% and 8 wt%.The synthesized samples were characterized by using various characterization techniques:X-ray diffraction(XRD),raman spectroscopy,Fourier transform infrared spectroscopy(FTIR),photoluminescence spectra(PL),transmission electron microscopy(TEM),energy dispersive X-ray(EDX) and UV-Vis ***_(3) retains its monoclinic structure even after doping which was confirmed by XRD *** helps to descry functional groups present in the *** size of nanoparticles was calculated by using *** confirms the absence of any impurity in the synthesized *** spectroscopy confirms the presence of a large number of imperfections induced in the lattice of WO_(3).The rate of recombination was analyzed by photoluminescence(PL) spectroscopy and is minimum in 4 wt% doping of *** optical bandgap was calculated using UV-Vis spectroscopy and becomes narrow along with the doping ***,it is found that doping of La in WO_(3) has considerably ameliorate the photocatalytic activity by reducing rate of recombination due to the trapping of electrons by defects introduced in the *** decolorization of Rhodamine B(RhB) dye was performed and the values of c/c_0 and rate constant(k) confirm that the 4 wt% doping shows maximum degradation *** kinetic study for photodegradation of Rhodamine B was done by using various kinetic models and results show that the reaction follows first order kinetics very ***,optimum doping of lanthanum increases the decolorization ability of WO_(3) towards RhB dye.

关键词： Photocatalytic activity WO_(3)nanoparticles Rhodamine B dye Rare earth doping Visible light

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Low temperature raman study of PrCoO_3 thin films on LaAlO_3(100) substrates grown by pulsed laser deposition

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Journal of Central South University 2010年第6期17卷 1144-1147页

作者： PRAKASH R kumar S LEE C G SONG JI Department of Mechanical Engineering Changwon National UniversityChangwon 641773Korea School of Nano and Advanced Materials Engineering Changwon National UniversityChangwon 641773Korea

Thin films of PrCoO3 were deposited on LaAlO3 substrates by pulsed laser deposition technique.X-ray diffraction result indicates that films are single phase and c-axis *** investigate the spin state transition,raman spectroscopy measurements were performed at different *** position of the raman modes is found to increase while full width at half maximum(FWHM) of these modes is found to decrease with the decrease of temperature across spin state transition temperature(220 K) of PrCoO3.

关键词： PrCoO3 thin films raman spectroscopy pulsed laser deposition

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Probing On-Surface Chemistry at the Nanoscale Using Tip-Enhanced raman Spectroscopy

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CCS Chemistry 2023年第1期5卷 55-71页

作者： Zhen-Feng Cai Naresh kumar Renato Zenobi Department of Chemistry and Applied Biosciences ETH ZurichZurich CH-8093

Chemistry on solid surfaces is central to many research areas of practical interest,such as synthesis,catalysis,electrochemistry,photochemistry,and materials science.A comprehensive understanding of the nanoscale on-surface chemistry involved in these areas is important for establishing composition-structure-performance *** the rapid development of tip-enhanced raman spectroscopy(TERS),it has become possible to investigate physical and chemical processes on suitable surfaces at the nanoscale level and in real *** this review,after a brief introduction of the background of onsurface chemistry and TERS,we systematically discuss the progress in the application of TERS in this *** focus is the applications of TERS to nanoscale coordination processes,decomposition reactions,polymerization processes,electrochemical reactions,catalytic chemistry,and functionalization chemistry on solid *** conclude by discussing the future challenges and development of TERS techniques and related applications in on-surface chemistry.

关键词： on-surface chemistry tip-enhanced raman spectroscopy scanning probe microscopy chemical imaging nanoscale chemical analysis spatial resolution

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Fabrication of cost-effective, highly reproducible large area arrays of nanotriangular pillars for surface enhanced raman scattering substrates

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Nano Research 2016年第10期9卷 3075-3083页

作者： Kudilatt Hasna Aldrin Antony Joaquim Puigdollers kumaran Rajeev kumar Madambi Kunjukuttan Jayaraj Nanophotonic & Optoelectronic Devices Laboratory Department of Physics Cochin University of Science & Technology Kochi 682 022 India Department of Instrumentation Cochin University of Science & Technology Kochi 682 022 India Department of Energy Science and Engineering Indian Institute of Technology Bombay Maharashtra 400 076 India Department of Enginyeria Electronica Universitat Politecnica Catalunya C/Jordi Girona 31 Modul C4 Barcelona 08034 Spain

Development of cost-effective, highly reproducible non-conventional fabrication techniques for anisotropic metal nanostructures is essential to realizing potential applications of plasmonic devices, photonic devices, and surface enhanced raman scattering （SERS） phenomenon based sensors. This report highlights the fabrication of nanotriangle arrays via nanoimprinting to overcome difficulties in creating large-area SERS active substrates with uniform, reproducible raman signals. Electron beam lithography of anisotropic nanostructures, formation of arrays of nanotriangles in silicon and the transfer of triangular shapes to polymethylmethacrylate （PMMA） sheets via nanoimprinting have not been reported elsewhere. The reuse of silicon masters offers potential for production of low cost SERS substrates. The SERS activity and reproducibility of nanotriangles are illustrated and a consistent average enhancement factor of up to -2.9 × 1011, which is the highest value reported for a patterned SERS substrate, is achieved.

关键词： metal nanostructures localized surface plasmon resonance (LSPR) surface enhanced ramanscattering (SERS) substrate enhancement factor

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Spectral narratives of microstructural restyling and their controls on hydrocarbon generation potential from coal

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International Journal of Coal Science & Technology 2023年第3期10卷 167-189页

作者： Tushar Adsul Santanu Ghosh Anwita Ojha Sudip Bhattacharyya Atul kumar Varma Coal Geology and Organic Petrology Laboratory Department of Applied GeologyIndian Institute of Technology(Indian School of Mines)DhanbadJharkhand 826004India Department of Geology Mizoram UniversityAizawlMizoram 796004India Specialized Coal Petrography Laboratory Natural Energy ResourcesMission II-BGeological Survey of IndiaDK-6Sector-IlSalt Lake CityKolkataWest Bengal 700091India

The low to medium-rank Tertiary coals from Meghalaya,India,are explored for the first time for their comprehensive micro-structural characterization using the FTIR and raman ***,results from these coals are compared with the Permian medium and high-rank coals to understand the microstructural restyling during coalification and its controls on hydrocarbon *** coal samples are grouped based on the mean random vitrinite reflectance values to record the transformations in spectral attributes with increasing coal *** aliphatic carbon and the apparent aromaticity respond sharply to the first coalification jump(R:0.50%)during low to medium-rank transition and anchizonal metamorphism of the high-rank ***,the raman band intensity ratio changes during the first coalification jump but remains invari-able in the medium-rank coals and turns subtle again during the onset of pregraphitization in high-rank coals,revealing a polynomial trend with the coal *** Rock-Eval hydrogen index and genetic potential also decline sharply at the first coalification ***,an attempt to comprehend the coal microstructural controls on the hydrocarbon poten-tial reveals that the Tertiary coals comprise highly reactive aliphatic functionalities in the type I-S kerogen,along with the low paleotemperature(74.59-112.28℃)may signify their potential to generate early-mature ***,the presence of type II-II admixed kerogen,a lesser abundance of reactive moieties,and overall moderate paleotemperature(91.93-142.52℃)of the Permian medium-rank coals may imply their mixed hydrocarbon ***,anchizonal metamorphism,polycondensed aromatic microstructure,and high values of paleotemperature(~334.25 to~366.79℃)of the high-rank coals indicate a negligible potential of producing any hydrocarbons.

关键词： Early mature oil generation Meghalaya high-sulfur coal Type II-S kerogen Microstructural ordering Coalification jump Hydrocarbon generation potential

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Effect of rare earth(Nd^(3+))metal doping on structural,morphological,optical and magnetic traits of Zn-Mg nano-ferrites

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Journal of Rare Earths 2023年第11期41卷 1763-1770,I0004页

作者： Rohit Jasrotia Nisha kumari Ritesh Verma Suman Sachin kumar Godara Jahangeer Ahmed Saad M.Alshehri Bidhan Pandit Sanjay kumar Himanshi Shubham Sharma Kirti Pradip K.Maji School of Physics&Materials Science Shoolini University of Biotechnology and Management SciencesSolanHimachal Pradesh173229India Himalayan Centre of Excellence in Nanotechnology Shoolini UniversityBajholSolanH.P173229India Department of Physics Baddi University of Emerging Science and TechnologyMakhnumajraBaddiHimachal Pradesh173205India Department of Physics Amity University HaryanaGururgram122413India Department of Mathematics School of Basic and Applied SciencesMaharaja Agrasen UniversityBaddiH.P174103India Department of Apparel and Textile Technology Guru Nanak Dev UniversityAmritsar143005India Department of Chemistry College of ScienceKing Saud UniversityP.O.Box 2455Riyadh11451Saudi Arabia Department of Materials Science and Engineering and Chemical Engineering Universidad Carlos III de MadridAvenida de la Universidad 3028911LeganésMadridSpain School of Advanced Chemical Sciences Shoolini University of Biotechnology and Management SciencesSolanHimachal Pradesh173229India Dept.of Polymer&Process Engineering Indian Institute of Technology RoorkeeSaharanpurUttar Pradesh247001India

Herein,we report the synthesis of Zn_(0.7)Mg_(0.3)Nd_(x)Fe_(2-x)O_(4)(where,x=0,0,0,01,0,02)ferrite nanoparticles by employing the sol-gel auto-combustion *** X-ray diffraction(XRD)pattern suggests the formation of a pure cubic structure,without any impurity phase,with an Fd3m space group at room *** increasing doping amount,the crystallite size is reported as 35-41 nm,while the lattice parameters rise from 0.8381 to 0.8395 *** emission scanning electron microscopy(FESEM)images show the formation of spherical grains with agglomerated morphology in all the samples,with grain sizes ranging from 49 to 103 *** dispersive X-ray spectroscopy(EDX)and elemental mapping investigation confirm the chemical purity of all the *** transform infrared(FTIR)analysis shows the presence of two prominent peaks around 440 and 560 cm^(-1)that correspond to the octahedral and tetrahedral *** addition,the existence of five raman active vibratio nal modes in all produced specimens again confirms the structural purity of all the *** M-H curve shows that saturation magnetization(M_(s))first increases from 14.98 to 28.22 emu/g and then decreases to 18.98emu/g with increasing doping *** is due to the A-B type super-exchange interaction for the synthesized *** variation in coercivity(H_(c))and magnetic anisotropy(K_(1))suggest the thermal stability of all the samples and can be utilized in transformers and solenoids.

关键词： Magnetic nanoparticles Saturation magnetization Sol-gel auto-combustion synthesis Super-exchange interaction Cubic crystal structure Rare earths

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快速热处理化学气相沉积法制备用于电子产品热管理的轻质柔性石墨烯

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新型炭材料（中英文） 2023年第3期38卷 534-542页

作者： Satendra kumar Manoj Goswami Netrapal Singh Uday Deshpande Surender kumar N.Sathish Academy of Scientific and Innovative Research(AcSIR) Ghaziabad 201002India CSIR-Advanced Materials and Processes Research Institute(AMPRI) Bhopal 462026India UGC-DAE Consortium for Scientific Research University CampusIndore 452001India

下一代电子产品的飞速发展对热管理提出了更高的要求。初始石墨烯的导热性是铜的13倍。本文通过快速热处理化学气相沉积(RTP-CVD)法制备了具有大sp^(2)结构域的单层、双层和多层石墨烯(SLG、BLG、FLG),进一步通过低浓度H_(2)还原制备了... 详细信息

下一代电子产品的飞速发展对热管理提出了更高的要求。初始石墨烯的导热性是铜的13倍。本文通过快速热处理化学气相沉积(RTP-CVD)法制备了具有大sp^(2)结构域的单层、双层和多层石墨烯(SLG、BLG、FLG),进一步通过低浓度H_(2)还原制备了高导热石墨烯。在1000℃下生长25 min制备出SLG,利用拉曼光谱和透射电子显微镜(TEM)研究了石墨烯的品质。为了验证RTP-CVD法生成的石墨烯的散热能力,将其作为2TB固态硬盘的散热器,通过红外热成像仪进行了研究。结果证明,RTP-CVD生长的石墨烯用于消费电子产品的热管理测试时性能表现优异。SLG显示温度(最高)比商用铜散热器低5℃,SLG的散热能力比商用铜散热器快200倍左右。综上,利用RTP-CVD法制备的轻质的柔性石墨烯可以成为下一代5G设备和消费电子产品热管理的更好选择。

关键词：石墨烯热管理消费类电子产品化学气相沉积

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Adoption and Impact of Modern Rice Varieties on Poverty in Eastern India

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Rice science 2020年第1期27卷 56-66页

作者： Richard Kwasi BANNOR Gupta Amarnath Krishna kumar Helena OPPONG-KYEREMEH Camillus Abawiera WONGNAA Department of Agricultural Economics Agribusiness and ExtensionUniversity of Energy and Natural ResourcesSunyaniGhana Indian Council of Agricultural Research-National Rice Research Institute Cuttack 753006OrissaIndia Department of Agricultural Economics Agribusiness and ExtensionKwame Nkrumah University of Science and TechnologyKumasiGhana

The factors affecting the adoption of modern varieties(MVs) of rice and impact on poverty in Odisha, India were discussed. A total of 363 households from Cuttack and Sambalpur districts of Odisha via multistage sampling technique participated in the survey. The Cragg's Double hurdle model was used to model the determinants of adoption and intensity of adoption of MVs of rice, and the propensity score matching was used to analyze the impact of adoption on poverty. The results showed that age, education, risk aversion, land size, yield, perception of MVs as high yielding, resistant to diseases and availability of MVs positively influenced the decision to adopt. However, variables such as household size, experience of a farmer, off-farm job participation, amount of credit received, cost of seeds, insecticides and fertilizers negatively influenced the adoption of MVs. Intensity of adoption of MVs was negatively influenced by experience of a farmer, cost of fertilizer and marketability of MVs, and positively affected by household size, risk aversion, land size, cost of insecticides, perception of MVs as high yielding and availability of MV seeds. Poverty incidence, gap and severity were high among non-adopters to adopters of MVs. After matching adopters and non-adopters of MV groups using four different algorithms of nearest neighbour matching, stratification matching, radius matching and kernel matching, the impact of MV adoption resulted in higher per capita monthly household expenditure by about US$ 52.82 to US$ 63.17.

关键词： rice adoption poverty Cragg's Double hurdle model modern variety

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Direct laser writing of volumetric gradient index lenses and waveguides

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Light(Science & Applications) 2020年第1期9卷 89-102页

作者： Christian R.Ocier Corey A.Richards Daniel A.Bacon-Brown Qing Ding raman kumar Tanner J.Garcia Jorik van de Groep Jung-Hwan Song Austin J.Cyphersmith Andrew Rhode Andrea N.Perry Alexander J.Littlefield Jinlong Zhu Dajie Xie Haibo Gao Jonah F.Messinger Mark L.Brongersma Kimani C.Toussaint Jr Lynford L.Goddard Paul V.Braun Department of Materials Science and Engineering University of Illinois at Urbana-ChampaignUrbanaILUSA Materials Research Laboratory University of Illinois at Urbana-ChampaignUrbanaILUSA Beckman Institute for Advanced Science and Technology University of Illinois at Urbana-ChampaignUrbanaILUSA Department of Electrical and Computer Engineering University of Illinois at Urbana-ChampaignUrbanaILUSA Department of Materials Science and Engineering Stanford UniversityStanfordCAUSA Carl R.Woese Institute for Genomic Biology University of Illinois at Urbana-ChampaignUrbanaILUSA Department of Mechanical Science and Engineering University of Illinois at Urbana-ChampaignUrbanaILUSA

Direct laser writing(DLW)has been shown to render 3D polymeric optical components,including lenses,beam expanders,and mirrors,with submicrometer ***,these printed structures are limited to the refractive index and dispersive properties of the ***,we present the subsurface controllable refractive index via beam exposure(SCRIBE)method,a lithographic approach that enables the tuning of the refractive index over a range of greater than 0.3 by performing DLW inside photoresist-filled nanoporous silicon and silica *** the laser exposure during printing enables 3D submicron control of the polymer infilling and thus the refractive index and chromatic *** SCRIBE’s unprecedented index range and 3D writing accuracy has realized the world’s smallest(15μm diameter)spherical Luneburg lens operating at visible ***’s ability to tune the chromatic dispersion alongside the refractive index was leveraged to render achromatic doublets in a single printing step,eliminating the need for multiple photoresins and writing *** also has the potential to form multicomponent optics by cascading optical elements within a *** a demonstration,stacked focusing structures that generate photonic nanojets were fabricated inside porous ***,an all-pass ring resonator was coupled to a subsurface 3D *** measured quality factor of 4600 at 1550 nm suggests the possibility of compact photonic systems with optical interconnects that traverse multiple *** is uniquely suited for constructing such photonic integrated circuits due to its ability to integrate multiple optical components,including lenses and waveguides,without additional printed supports.

关键词： index refractive render

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Analysis of TiO2 for microelectronic applications:effect of deposition methods on their electrical properties

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Frontiers of Optoelectronics 2011年第4期4卷 349-358页

作者： Davinder RATHEE Sandeep K ARYA Mukesh kumar Department of Electronics and Communication Engineering Guru Jambheshwar University of Science & Technology Department of Electronics Science Kurukshetra University

Metal oxide semiconductor（MOS） device down-scaling is a powerful driving force for the evolution of microelectronics. The downsizing rate of metal oxide semiconductor field effect transistors（MOSFETs） is really marvelous. Silicon dioxide（SiO2） has served as a perfect gate dielectric for the last four decades. Due to physical limitations, leakage current, high interface trap charge it now needs to be replaced with higher permittivity dielectric material. Keeping the motivation for the search of high-k materials, extensive studies have been carried out on several metal oxides, such as ZrO2, Ta2O5, TiO2, Al2O3and HfO2for the replacement of SiO2. The high dielectric constant（k） of titanium dioxide（TiO2） will open multifaceted prospects for the use of this material in microelectronic devices. In this paper, a comparative study of various deposition methods for fabrication of thin TiO2films has been presented. This work uses a combination of simulation results, experimental data and critical analysis of published data. Further, an experiment using sol-gel method has been carried out to deposit thin films of TiO2. It has been characterized and compared with the earlier reported fabrication methods. The X-ray diffraction analyses and raman spectra indicate the presence of anatase TiO2phase in the film. The dielectric constant as calculated using capacitance-voltage（C-V） analysis was found to be 23. The refractive index of the film was *** TiO2films studied for microelectronic applications and present acceptable properties such as low leakage current density of 1.0×10–5A/cm at 1 V and band gap of 3.6 eV. The leakage current has been found to be dominant by the Schottky emission at lower electric field, while Flower-Nordheim（F-N） tunneling occurs at higher biasing voltages.

关键词： titanium dioxide (TiO 2 ) high- k material sol-gel thin films atomic force microscopy (AFM) capacitance-voltage ( C-V ) analysis

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