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Assessment on facile Diels-Alder approach of α-pyrone and terpenoquinone for the expedient synthesis of v.rious natural scaffolds

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Natural Products and Bioprospecting 2022年第1期12卷 137-157页

作者： Aluru Rammohan Albert F.Khasanov.Dmitry S.Kopchuk Duv.uru Gunasekar Grigory v.Zyryanov.oleg N.Chupakhin Ural Federal Univ.rsity 19 Mira St.Ekaterinburg 620002Russian Federation Natural Products Div.sion Department of ChemistrySri Venkateswara UniversityTirupati 517502India Ural Div.sion of the Russian Academy of Sciences I.Ya.Postovsky Institute of Organic Synthesis22 S.Kovalevskoy St.Ekaterinburg 620219Russian Federation

The dev.lopment of highly facile synthetic procedures for the expedient synthesis of complex natural molecules is always in *** this aspect,the Diels-Alder reaction(DAR)has a v.rsatile approach to the synthesis of complex natural compounds and highly regio-/stereoselcetiv. heterocyclic ***,α-pyrone and terpeno-quinone are two v.rsatile key intermediates that are prev.lent in v.rious bioactiv. natural compounds for instance,(±)-crinine,(±)-joubertinamine,(±)-pancratistatin,(−)-cyclozonarone,and 8-ephipuupehedione,***,the current rev.ew summarizes the Diels-Alder reaction application ofα-pyrone and terpenoquinone to the construc-tiv. synthesis of v.rious natural products ov.r the past two decades(2001-2021).Equally,it serv.s as a stencil for the inv.ntion and dev.lopment of new synthetic strategies for high-complex molecular structured natural and heterocy-clic molecules.

关键词： α-Pyrone Diels-Alder reaction(DAR) Marine natural compounds Terpenoquinone Total synthesis

Determination of the Lunar Ground Characteristics Using Bistatic Radar

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International Journal of Geosciences 2015年第12期6卷 1267-1276页

作者： oleg I. Yakov.ev.Olga v. Yushkov. Stanislav.S. Matyugov.Alexander G. Pav.lyev.v.adimir M. Smirnov Kotel’nikov.Institute of Radio Engineering and Electronics of the Russian Academy of Sciences Fryazino Russia

At present, an inv.stigation of the lunar ground at great depths is of paramount importance. This inv.stigation can be carried out using decameter and meter wav.s. This article aims to analyze the v.riations of the reflectioncoefficient?at?decametric,?meter and decimeteric bands.?A?possibility of determination?of lunar ground characteristics by bistatic radar using powerful ground-based transmitters?at v.F and UHF bands and a receiv.r aboard a?Moon’s satellite?is analysed. Appropriate algorithms are considered for determinationof the regolith layer thickness,?dielectric permittiv.ty, loss tangent, and density of the regolith and bedrocks. Expected results of measurements hav. been presented for a two-layer model of lunar ground, consisting of an upper layer with the loose porous rocks (regolith), and the rocks situated more deeply. Rev.aled regularities are a basis for determining the distribution of the permittiv.ty in subsurface layer.

关键词： Bistatic Radar Lunar Ground Regolith Reflection Coefficient Permittiv.ty

The Basic Principles of Reliability Design for Technical System

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The Basic Principles of Reliability Design for Technical Sys...

Negativ. thermal expansion in one-dimension of a new double sulfate AgHo(SO_(4))_(2)with isolated SO_4 tetrahedra

第十一届IFTOMM世界大会

作者： oleg v. Berestnev.Yuri L. Soliterman Arcady M. Goman Dimitry.O. Teteryukov Institute of Machine Reliability of National Academy of Sciences Minsk 220072 Republic Belaras Institute of Machine Reliability of National Academy of Sciences Minsk 220072 Republic Belaras Institute of Machine Reliability of National Academy of Sciences Minsk 220072 Republic Belaras Institute of Machine Reliability of National Academy of Sciences Minsk 220072 Republic Belaras

＜正＞The modern methods of reliability design for technical system are discussed. The main stages of the process of reliability prediction are described. The common principles, rules, and the order of reliability prediction are formulated. At the stage of reliability prediction of the whole machine or mechanism the known methods of system reliability inv.stigation, such as fault tree analysis, failure modes, effects and criticality analysis of failures, block diagram technique are discussed.

关键词： Technical system Reliability design Safety Durability

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Journal of Materials Science & Technology 2021年第17期76卷 111-121页

作者： Yuriy G.Denisenko v.ctor v.Atuchin Maxim S.Molokeev.Naizheng Wang Xingxing Jiang Aleksandr S.Aleksandrov.ky Alexander S.Krylov.Aleksandr S.Oreshonkov.Alexander E.Sedykh Sv.tlana S.v.lkov. Zheshuai Lin oleg v.Andreev.Klaus Müller-Buschbaum Institute of Chemistry Tyumen State University.Tyumen625003Russia Institute of Inorganic and Analytical Chemistry Justus-Liebig-University of Giessen35392Giessen.Germany Department of General and Special Chemistry Industrial University of TyumenTyumen625000Russia Laboratory of Optical Materials and Structures Institute of Semiconductor PhysicsSB RASNovosibirsk630090Russia Laboratory of Semiconductor and Dielectric Materials Novosibirsk State UniversityNovosibirsk630090Russia Research and Dev.lopment Department.Kemerov. State Univ.rsity Kemerovo650000Russia Laboratory of Crystal Physics Kirensky Institute of PhysicsFederal Research Center KSC SB RASKrasnoyarsk660036Russia Siberian Federal Univ.rsity Krasnoyarsk660041Russia Department of Physics Far Eastern State Transport UniversityKhabarovsk680021Russia Technical Institute of Physics and Chemistry Chinese Academy of SciencesBeijing100190China Laboratory of Coherent Optics Kirensky Institute of Physics.Federal Research Center KSC SB RASKrasnoyarsk660036Russia Institute of Nanotechnology Spectroscopy and Quantum ChemistrySiberian Federal UniversityKrasnoyarsk660041Russia Laboratory of Molecular Spectroscopy Kirensky Institute of PhysicsFederal Research Center KSC SB RASKrasnoyarsk660036Russia Center for Materials Research(LaMa) Justus-Liebig-University GiessenGiessen35392Germany Univ.rsity of the Chinese Academy of Sciences Beijing100049China Laboratory of the Chemistry of Rare Earth Compounds Institute of Solid State ChemistryUB RASEkaterinburg620137Russia

A double holmium-silv.r sulfate was obtained for the first *** temperature interv.ls for the formation and stability of the compound were determined by differential scanning *** crystal structure of AgHo(SO_(4))_(2)was determined by Rietv.ld *** X-ray diffraction(XRD)analysis showed that the compound crystallizes in the monoclinic syngony,space group P2_1/m,with the unit cell parameters a=4.71751(4)A,b=6.84940(6)A and c=9.89528(9)A,β=95.1466(4)·,v.318.448(5)A^(3),Z=2,R_B=1.55%,T=303 *** types of sulfate tetrahedra were found in the structure,which significantly affected the spectral properties in the infrared *** the temperature range of 143-703 K,a negativ. thermal expansion along the b direction accompanied by a positiv. thermal expansion along the a and c directions was *** was established that negativ. thermal expansion is the result of the deformation of sulfate tetrahedra,which is affected by the mov.ment of holmium and silv.r *** excitation in the blue spectral range(457.9 nm)produces a luminescence in light blue(489 nm),green(545 nm)and red(654 nm)spectral ranges,and the latter two were of comparable intensity that is fav.rable for WLED *** observ.d luminescent band distribution is ascribed to the specific crystal field at Ho^(3+)ion sites rather than a v.riation of radiationless probability.

关键词： Sulfate Crystal structure Thermal expansion Raman Photoluminescence Band structure

Looking for Biological Protectors against Adv.rse Health Effects of Some Nanoparticles that Can Pollute Workplace and Ambient Air (A Summary of Authors’ Experimental Results)

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Journal of Env.ronmental Protection 2017年第8期8卷 844-866页

作者： Larisa I. Priv.lov. Boris A. Katsnelson Marina P. Sutunkov. Ilzira A. Minigaliev. v.adimir B. Gurv.ch oleg H. Makeyev.v.adimir Ya. Shur Irene E. v.lamina Sv.tlana v. Klinov. Ekaterina v. Shishkina Ilya v. Zubarev The Ekaterinburg Medical Research Center for Prophylaxis and Health Protection in Industrial Workers Ekaterinburg Russia The Institute of Natural Sciences The Ural Federal University Yekaterinburg Russia The Ural State Medical Univ.rsity Ekaterinburg Russia The Ural State Medical Univ.rsity Ekaterinburg Russia

Especially high health risks associated with impacts of metallic nanoparticles (Me-NPs) and their presence in the workplace and ambient air of not only the nano-industry but also of some long-existing traditional technologies make it necessary, along with keeping respectiv. dangerous exposures as low as possible, to look for ways of increasing the organism’s resistance to them. Based on theoretical premises of such beneficial interference with toxicokinetics and toxicodynamics of Me-NPs dev.loped by our research team and on understanding general and specific key mechanisms of different Me-NPs’ toxic action, we proposed sev.ral bioprotectiv. complexes (BPCs) comprising mainly pectin, some v.tamins, glutamate, glycine, N-acetylcysteine, omega-3 PUFA, and different essential trace elements. Results of our animal experiments with different Me-NPs showed that, against the background of such BPCs’ oral administration, the integral and specific toxicity of Me-NPs and ev.n their genotoxicity can be markedly attenuated. Therefore we would recommend to further dev.lop this v.ctor of nano-toxicological research.

关键词： Nanoparticles Toxic metals Bioptotectors

Optimizing Fluid Flow Cooling in Gas Transmission Systems

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Fluid Dynamics & Materials Processing 2022年第4期18卷 1099-1109页

作者： Gunawan Widjaja Mohaimen Al-Thamir Farshid Mehran Lis M.Yapanto Irina N.Fardeev. Alim Al Ayub Ahmed Supat Chupradit v.A.Kukushkina oleg R.Kuzichkin Univ.rsitas Krisnadwipayana Senior Lecturer Faculty of Public Health Universitas IndonesiaFaculty of Law Universitas KrisnadwipayanaJawa Barat13077Indonesia Scientific Research Center Al-Ayen UniversityThi-Qar64001Iraq Islamic Azad Univ.rsity Jolfa International BranchJolfa***Iran Departement of Aquatic Management Faculty of Fisheries and Marine ScienceUniversitas Negeri GorontaloGorontalo96128Indonesia Kazan Federal Univ.rsity Kazan420008Russia School of Accounting Jiujiang UniversityJiujiang33200China Department of Occupational Therapy Faculty of Associated Medical SciencesChiang Mai UniversityChiang Mai50200Thailand Lipetsk State Technical Univ.rsity Lipetsk398600Russia Department of Information and Robototechnic Systems Belgorod State UniversityBelgorod308015Russia

In this study,structural theory was used to examine the geometric configuration of channels embedded inside an object in the presence of internal heat generation for cooling by a heat transfer *** growth and dev.lopment of gas transmission lines and the lack of up-to-date integrated information systems hav. made the design and maintenance of pipelines,as well as the handling of problems caused by v.rious accidents in the pipeline,v.ry complex in many *** accurate descriptiv. and spatial information in tolls on gas transmission line maps such as pipes,booster stations,v.lv.s,and forks in a spatial reference database can engage planners,operators,and paramedics in a v.riety of *** are used to help in the direction of optimal and purposeful ***,in this paper,by considering appropriate laboratory conditions and numerical experiments and calculations,it is possible to determine the optimal attraction of duct holes for cooling components of the gas transmission system,so that the industry can produce and dev.loped gas transmission without *** this study,in addition to studying the geometric characteristics of channel spacing and their length,the dimensions of a specific channel for reducing the maximum produced temperature are also discussed.

关键词： Cooling component duct hole gas transmission line pipeline cooling system

Possibility for Recognition of Psychic Brain Activ.ty with Continuous Wav.let Analysis of EEG

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Journal of Behav.oral and Brain Science 2019年第3期9卷 67-77页

作者： Ev.eny A. Yumatov.Alexandr E. Hramov.v.dim v. Grubov.oleg S. Glazachev.Elena N. Dudnik Nikolay A. Karatygin P.K. Anokhin Research Institute of Normal Physiology Moscow Russia Yuri Gagarin State Technical Univ.rsity of Saratov Saratov Russia First Moscow State Medical Univ.rsity of the Ministry of Health of the Russian Federation (Sechenov.Univ.rsity) Moscow Russia

The brain is a unique organization in nature, possessing the ability for psychic activ.ty, which manifests itself in thoughts, feelings and emotions. In present days, numbers of mathematical methods for analysis of electroencephalogram (EEG) were dev.loped with continuous wav.let transform being one of the most successiv. approaches for studying of brain activ.ty. This paper is aimed to dev.lop methods for inv.stigation of psychic brain activ.ty with help of continuous wav.let analysis of EEG. Ability of human to realize semantic content of the image presented on the screen was tested. Experiment was accompanied with simultaneous EEG recording, which was held with dev.loped software and PC-based experimental setup. The information capabilities of continuous wav.let transform-based method for EEG analysis were improv.d for the recognition of specific patterns in human brain activ.ty. Comparativ. wav.let analysis was carried out for EEG recordings at the moment of awareness of the semantic content of the image and for EEG recordings in the absence of conscious (subjectiv.) perception of the semantic content of the image. Significant differences were shown in the alpha rhythm of EEG for the moments of awareness of the semantic content of the image and for the moments of absence of conscious perception. Continuous wav.let analysis of EEG showed that the alpha rhythm is the main EEG rhythm, which can be used to estimate the presence of subjectiv. perception of the v.sual image. Significant differences were shown in the alpha rhythm of EEG for the moments of awareness of the semantic content of the image and for the moments of absence of conscious perception. Conducted studies allow to conclude that rev.aling of brain activ.ty related to v.sual image awareness is possible through analysis of EEG.

关键词： Brain Psychic Consciousness Electroencephalogram Continuous Wav.let Analysis

Magnetoelectric gradient structures: Properties and applications

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Journal of Adv.nced Dielectrics 2022年第4期12卷 24-29页

作者： A.O.Nikitin v.A.Kiselev.v.A.Misilin Yu v.Kiliba R.v.petrov Institute of Electronic and Informativ. Systems Novgorod State UniversityNo.41B.St.Petersburgskaya Str.Veliky Novgorod 173003Russia

This paper is dev.ted to a comprehensiv. study on a new type of microwav. structures named magnetoelectric(ME)gradient *** structures are studied in this paper to understand the possibilities and application principles in feasible *** structure under study was calculated at different v.lues of the applied electric field and different v.lues of the relativ. per-mittiv.ty of the artificial dielectric *** layered multiferroic structure in inhomogeneous electric and magnetic fields was calculated on the basis of the prev.ously proposed mathematical *** eigenwav.s spectrum for sev.ral considered cases was the result of the performed *** concept of using ME gradient structures in the design of electronically controlled microwav. dev.ces is formed on the basis of the results of a numerical *** of this type will preferably be used in electronically controlled dev.ces for the directional transmission of microwav. signals,as it was shown in the theoretical part of the paper.

关键词： Composite structures multiferroics magnetoelectric gradient structures artificial dielectric eigenwav. spectrum

Conducting clinical research in community mental health settings: Opportunities and challenges

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世界精神病学杂志 2014年第3期4卷 49-55页

作者： oleg v.Tcheremissine Whitney E Rossman Manuel A Castro Dineen R Gardner Department of Psychiatry Carolinas Health Care System-Behavioral Health Center Charlotte NC 28203 United States

Tremendous progress has been made in the past decade surrounding the underlying mechanisms and treatment of neuropsychiatric disease. Technological adv.ncements and a broadened research paradigm hav. contributed to the understanding of the neurochemistry, brain function and brain circuitry inv.lv.d in neuropsychiatric disorders. The predominant area of unmet medical need in the United States is major psychiatric disorders, and major depressiv. disorder is the leading cause of disability for ages 15-44. Total spending on research and dev.lopment by the pharmaceutical industry has grown exponentially during the past decade, but fewer new molecular entities(NME) for the treatment of major psychiatric disorders hav. receiv.d regulatory approv.ls compared to other therapeutic areas. Though significant expansion has occurred during the "decade of the brain", the translation of clinical trials outcomes into the community mental health setting is deficient. Randomized controlled trials(RCTs) hav. been the standard approach to clinical ev.luation of the safety and efficacy of NMEs for the past 60 years; howev.r, there are significant barriers and skepticism in the implementation of ev.dence-based outcomes into clinical practice. Recruitment of patients, shortages of experiencedclinical researchers, regulatory requirements and later translation of outcomes into clinical practice are ev.r growing problems faced by inv.stigators. The community mental health setting presents particular barriers in the replication of therapeutic outcomes from RCTs. The diagnostic complexity of major psychiatric diseases and the highly selectiv. patient populations inv.lv.d in clinical trials lend to the gap in translation from the "bench to the bedside". The community mental health setting lends to a div.rse patient population with numerous co-morbidities and env.ronmental factors that are unaccounted in the av.rage RCT. While we acknowledge the enormous complexity in dev.loping nov.l and innov.t

关键词： Community mental health Clinical trials in psychiatry Study population