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Hard carbon derived from rice husk as low cost negative electrodes in Na-ion batteries

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Journal of Energy Chemistry 2019年第2期28卷 17-22页

作者： maria K.Rybarczyk Yunming Li Mo Qiao Yong-Sheng Hu maria-magdalena Titirici Marek Lieder Gdansk University of Technology Chemical Faculty Key Laboratory for Renewable Energy Beijing Key Laboratory for New Energy Materials and DevicesNational Laboratory for Condensed Matter PhysicsInstitute of PhysicsChinese Academy of Sciences Queen Mary University London School of Materials Science & Engineering

Here,we report the synthesis of hard carbon materials(RH) made from natural rice husk through a single pyrolysis process and their application as an anode in sodium-ion *** studies show that the electrochemical properties of RHs are affected by the treatment temperatures,which determine the materials morphology,in particular,their degree of graphitization and extent of continuous channels(nanovoids).The latter are accessible to sodium ions and significantly contribute to charge storage capacity of the produced *** RHs obtained at 1600 °C deliver the highest reversible capacity of276 mAh g^(-1) mainly due to insertion of sodium ions into the *** work deepens the basic understanding of the influence of the carbonization temperature on the sodium storage mechanism.

关键词： Nanovoids in rice husk Sustainable energy storage Na-ion batteries

High concentration of antimitochondrial antibodies predicts progressive primary biliary cirrhosis

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World Journal of Gastroenterology 2005年第36期11卷 5706-5709页

作者： Robert Flisiak maria Pelszynska Danuta Prokopowicz magdalena Rogalska Urszula Grygoruk Department of Infectious Diseases Medical University of Bialystok Poland

AIM： To evaluate the serum concentration of antimitochondrial antibodies （AMAs） as a prognostic indicator of progressive primary biliary cirrhosis （pPBC）. METHODS： Serum concentrations of AMA subtypes （anti-M2, anti-M4, and anti-M9）, biochemical indices of liver function and Mayo risk factor （MRF） were determined in 30 women with diagnosed primary biliary cirrhosis （PBC） selected among 348 females with elevated alkaline phosphatase but without signs of hepatic decompensation. They were followed up for 5 years for possible development of hepatic decompensation. RESULTS： Anti-M2 concentration was significantly correlated with bilirubin and albumin levels as well as MRF, whereas anti-M4 was significantly correlated with albumin level, prothrombin time and MRF. During the 5-year follow-up, progressive PBC （pPBC） was diagnosed in 3 among 23 patients available for evaluation. These 3 patients were positive for both anti-M2 and anti-M4. Anti-M2 serum concentration exceeded 1 300 RU/mL in patients with pPBC and only in 1 among 20 non-progressive PBC persons （5%）. Anti-M4 serum concentration exceeded 400 RU/mL in 2 of the progressive patients and none in the non-progressive group. In contrast, anti-M9 serum concentration was below 100 RU/mL in all patients with pPBC, and higher than 100 RU/mL in 11 women （55%） among the non-progressive group. CONCLUSION： Females with elevated alkaline phosphatase and high anti-M2 and anti-M4 concentrations are at a high risk for developing pPBC. Quantitative AMA detection should be considered as a method for early diagnosis of pPBC. 2005 The WJG Press and Elsevier Inc. All rights reserved.

关键词： Primary biliary cirrhosis Autoantibodies Liver

Disordered carbon anodes for Na-ion batteries—quo vadis?

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Science China Chemistry 2021年第10期64卷 1679-1692页

作者： Fei Xie Zhen Xu Zhenyu Guo Yaxiang Lu Liquan Chen maria-magdalena Titirici Yong-Sheng Hu Key Laboratory for Renewable Energy Beijing Key Laboratory for New Energy Materials and DevicesBeijing National Laboratory for Condensed Matter PhysicsInstitute of PhysicsChinese Academy of SciencesBeijing 100190China Department of Chemical Engineering Imperial College LondonLondon SW72AZUK

Na-ion batteries(NIBs)are gradually attracting much attention as an alternative to lead-acid batteries and supplement to Li-ion batteries(LIBs)owing to the abundant Na resources and excellent *** the most commonly used graphite as an anode material in LIBs cannot be inherently used in NIBs,tremendous efforts have been made to advance the fundamental understanding and design of suitable anode materials for NIBs,including the improvement of Na storage capacity and the study on Na storage *** to all these studies,disordered carbons are now the most promising anode candidates for *** this review,we discuss the current challenges and remaining problems to be solved in the area of disordered carbon anode materials for NIBs and provide future insights and research directions.

关键词： disordered carbon anode Na-ion batteries

The impact of having an oxygen-rich microporous surface in carbon electrodes for high-power aqueous supercapacitors

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Journal of Energy Chemistry 2021年第2期30卷 36-48,I0002页

作者： Servann Herou maria Crespo Ribadeneyr Philipp Schlee Hui Luo Liviu Cristian Tanase Christine Roβberg magdalena Titirici Chemical Engineering Department Imperial College LondonImperial College RdKensingtonLondon SW72AZUK National Institute of Materials Physics Atomiştilor 405A077125 Măgurele–IlfovRomania Fraunhofer-Zentrum für Chemisch-Biotechnologische Prozesse CBP Am Haupttor06237 LeunaGermany

The growth of electrical transportation is crucially important to mitigate rising climate change concerns regarding materials *** are high-power devices,particularly suitable for public transportation since they can easily store breaking energy due to their high-rate charging ***,they can function with two carbon electrodes,which is an advantage due to the abundance of carbon in biomass and other waste materials(i.e.,plastic waste).Newly developed supercapacitive nanocarbons display extremely narrow micropores(100 kW kg^(-1)),using fourty times less activating agent than traditionnal chemically activated *** also demonstrate that the affinity between the carbon and the electrolyte is of paramount importance to maintain rapid ionic diffusion in narrow ***,this facile synthesis method shows that low-cost and bio-based free-standing electrode materials with reliable supercapacitive performances can be used in electrochemistry.

关键词： Porous carbon materials Lignin Supercapacitors Oxygen groups

Achieving highly selective electrochemical CO_(2) reduction to C_(2)H_(4) on Cu nanosheets

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Journal of Energy Chemistry 2023年第4期79卷 312-320页

作者： Huan Xie Ruikuan Xie Zhiyuan Zhang Yongyu Pang Yuting Luo Jiong Li Bilu Liu maria-magdalena Titirici Guoliang Chai State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002FujianChina Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources International Innovation Center for Forest Chemicals and MaterialsCollege of Materials Science and EngineeringNanjing Forestry UniversityNanjing 210037JiangsuChina Shenzhen Geim Graphene Center(SGC) Tsinghua-Berkeley Shenzhen Institute(TBSI)and Tsinghua Shenzhen International Graduate School(TSIGS)Tsinghua UniversityShenzhen 518055GuangdongChina School of Chemical Science University of Chinese Academy of SciencesBeijing 100049China Shanghai Synchrotron Radiation Facility Shanghai Advanced Research Institute Chinese Academy of SciencesShanghai 201210China Department of Chemical Engineering Imperial College LondonSW72AZUK

The conversion of CO_(2)into value-added chemicals coupled with the storage of intermittent renewable electricity is *** nanosheets with an average size and thickness of~30 and~20 nm have been developed,which are in situ reduced into Cu nanosheets during electrochemical CO_(2)reduction reaction(ECO_(2)RR).The derived Cu nanosheets demonstrate much higher selectivity for C2H4production than commercial CuO derived Cu powder,with an optimum Faradaic efficiency of 56.2%and a partial current density of C_(2)H_(4)as large as 171.0 mA cm^(-2)in a gas diffusion flow *** operando attenuated total reflectance-Fourier transform infrared spectra measurements and density functional theory simulations illustrate that the high activity and selectivity of Cu nanosheets originate from the edge sites on Cu nanosheets with a coordinate number around 5(4–6),which facilitates the formation of^(*)CHO rather than^(*)COH intermediate,meanwhile boosting the C-C coupling reaction of^(*)CO and^(*)CHO intermediates,which are the critical steps for C_(2)H_(4)formation.

关键词： Electrochemical CO_(2)reduction Cu nanosheets C_(2)H_(4) High selectivity Coordination number

A Review of Advanced Energy Materials for Magnesium–Sulfur Batteries

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Energy & Environmental Materials 2018年第3期1卷 100-112页

作者： Long Kong Chong Yan Jia-Qi Huang Meng-Qiang Zhao maria-magdalena Titirici Rong Xiang Qiang Zhang Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology Department of Chemical EngineeringTsinghua UniversityBeijing 100084China Advanced Research Institute of Multidisciplinary Science Beijing Institute of TechnologyBeijing 100081China Department of Physics and Astronomy University of Pennsylvania209 South33rd StreetPhiladelphia PA 19104USA School of Engineering and Materials Science Queen Mary University of LondonMile End RoadE14NSLondon UK Department of Mechanical Engineering The University of TokyoTokyo 113-8656Japan

Magnesium–sulfur batteries promise high volumetric energy density,enhanced safety,and low cost for electrochemical energy *** current obstacles to practical applications of reliable magnesium–sulfur batteries are finding electrolytes that can meet a multitude of rigorous requirements along with efficient sulfur cathodes and magnesium *** review highlights recent advances in designing better electrolytes,cathodes,and anodes.A suitable electrolyte for magnesium-sulfur batteries should allow to reversibly electroplate/strip divalent magnesium ions and should be compatible with the sulfur cathode and the other cell’s components.

关键词： electrolyte energymaterials magnesiumanode magnesium-sulfur batteries sulfur cathode

A review of nanocarbons in energy electrocatalysis: Multifunctional substrates and highly active sites

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Journal of Energy Chemistry 2017年第6期26卷 1077-1093页

作者： Cheng Tang maria-magdalena Titirici Qiang Zhang Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology Department of Chemical Engineering Tsinghua University Queen Mary University of London School of Engineering and Materials Science

Nanocarbons are of progressively increasing importance in energy electrocatalysis, including oxygen reduction, oxygen evolution, hydrogen evolution, COreduction, etc. Precious-metal-free or metal-free nanocarbon-based electrocatalysts have been revealed to potentially have effective activity and remarkable durability, which is promising to replace precious metals in some important energy technologies,such as fuel cells, metal–air batteries, and water splitting. In this review, rather than overviewing recent progress completely, we aim to give an in-depth digestion of present achievements, focusing on the different roles of nanocarbons and material design principles. The multifunctionalities of nanocarbon substrates(accelerating the electron and mass transport, regulating the incorporation of active components,manipulating electron structures, generating confinement effects, assembly into 3 D free-standing electrodes) and the intrinsic activity of nanocarbon catalysts(multi-heteroatom doping, hierarchical structure,topological defects) are discussed systematically, with perspectives on the further research in this rising research field. This review is inspiring for more insights and methodical research in mechanism understanding, material design, and device optimization, leading to a targeted and high-efficiency development of energy electrocatalysis.

关键词： Nanocarbon Energy electrocatalysis Oxygen reduction Oxygen evolution Hydrogen evolution CO_2 reduction Electron structure Strong coupling effect Hierarchical structure Doping Defect Metal–air battery Fuel cell Water splitting

The Calcineurin B-Like Calcium Sensors CBL1 and CBL9 Together with Their Interacting Protein Kinase ClPK26 Regulate the Arabidopsis NADPH Oxidase RBOHF

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Molecular Plant 2013年第2期6卷 559-569页

作者： maria magdalena Drerup Kathrin Schlückinga Kenji Hashimoto Prabha Manishankar Leonie Steinhorst Kazuyuki Kuchitsu Jōrg Kudl Institut for Biologie und Biotechnologie der Pflanzen Universitāt Münster Schlossplatz 4 48149 MOnster Germany Department of Applied Biological Science Tokyo University of Science Noda Chiba 278-8510 Japan

Stimulus-specific accumulation of second messengers like reactive oxygen species （ROS） and Ca^＋ are central to many signaling and regulation processes in plants. However, mechanisms that govern the reciprocal interrelation of Ca^＋ and ROS signaling are only beginning to emerge. NADPH oxidases of the respiratory burst oxidase homolog （RBOH） family are critical components contributing to the generation of ROS while Calcineurin B-like （CBL） Ca^＋ sensor proteins together with their interacting kinases （CIPKs） have been shown to function in many Ca^＋- signaling processes. In this study, we identify direct functional interactions between both signaling systems. We report that the CBL-interacting pro- tein kinase ClPK26 specifically interacts with the N-terminal domain of RBOHF in yeast two-hybrid analyses and with the full-length RBOHF protein in plant cells. In addition, CIPK26 phosphorylates RBOHF in vitro and co-expression of either CBL1 or CBL9 with CIPK26 strongly enhances ROS production by RBOHF in HEK293T cells. Together, these findings identify a direct interconnection between CBL-ClPK-mediated Ca^＋ signaling and ROS signaling in plants and provide evidence for a synergistic activation of the NADPH oxidase RBOHF by direct Ca^＋-binding to its EF-hands and Ca2＋-induced phospho-rylation by CBL1/9-ClPK26 complexes.

关键词： Calcium ROS CBL CIPK NADPH oxidase RBOH signal transduction.

磺化水热碳催化乙酰丙酸酯化生成戊酮酸乙酯(英文)

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催化学报 2014年第6期35卷 929-936页

作者： Filoklis D.Pileidis Maham Tabassum Sam Coutts maria-magdalena Ttitirici Queen Mary University of London School of Engineering and Materials Science Mile End Road E1 4NS London United Kingdom Queen Mary University of London School of Engineering and Materials ScienceMile End Road E1 4NS London United Kingdom

The synthesis of carbon-based, heterogeneous sulphonic catalysts for the production of levulinate esters. Hydrothermal treatment at moderated temperatures was employed to generate highly functional carbonaceous materials, referred to as hydrothermal carbons (HTCs), from both glucose, cellulose and rye straw. The products were sulfonated to generate solid acid-catalysts. Characterisation of the as-synthesised materials as well as catalyst activity tests were performed. SEM images indicate the micrometre-sized particles present in both HTCs were largely unaffected by sulfonation, although cellulose-derived HTC displayed signs of inadequate hydrolysis. FT-IR spectroscopy and elemental analysis confirmed successful incorporation of sulphonic groups. 13C solid state NMR, in addition to TGA, elucidated the carbons’ structural composition and supported the common-ly-proposed hydrothermal carbonisation mechanism. Finally, the catalysts were tested via levulinic acid-ethanol esterification and gave high conversion and ester-selectivities (> 90%).

关键词：固体酸催化剂乙酰丙酸碳材料酯化甲酸乙酯 FT-IR光谱酸水水热处理