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Ru(Ⅱ)-Catalyzed Selective C-H Alkynylation of Isoquinolones,Quinazolones and Phthalazinones with Bromoalkynes

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Chinese Journal of Chemistry 2024年第15期42卷 1686-1690页

作者： Quan-Jian Luo Han-Chi Wang jing Zhang jin-Heng Li Bo sun State Key Laboratory Base of Eco-Chemical Engineering College of Chemical EngineeringQingdao University of Science and TechnologyQingdaoShandong 266042China State Key Laboratory of Applied Organic Chemistry Lanzhou UniversityLanzhouGansu 730000China School of Chemistry and Chemical Engineering Henan Normal UniversityXinxiangHenan 453007China

A new,selective Ru(Ⅱ)-catalyzed alkynylation reaction of isoquinolones,quinazolones and phthalazinones with readily available bromoalkynes has been *** reaction enables the selective construction of a new C(sp^(2))-C(sp)bond through C-H activation and C-Br functionalization,and offers an effective and selective route to synthesizing highly valuable alkynylated isoquinolone,quinazolone and phthalazinonederivatives with a wide substrate scope and highselectivity.

关键词： Ru(Ⅱ) Alkynylation Isoquinolones Bromoalkynes Heterocyclic compounds C-H activation C-C coupling Synthetic methods

Improving the Accuracy of Vegetation Index Retrieval for Biomass by Combining Ground-UAV Hyperspectral Data-A New Method for Inner Mongolia Typical Grasslands

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Phyton-International Journal of Experimental Botany 2024年第2期93卷 387-411页

作者： Ruochen Wang Jianjun Dong Lishan jin Yuyan sun Taogetao Baoyin Xiumei Wang The College of Resources and Environmental Engineering Inner Mongolia University of TechnologyHohhot010000China The College of Ecology and Environment Inner Mongolia UniversityHohhot010000China Key Laboratory of Environmental Pollution Control and Remediation at Universities of Inner Mongolia Autonomous Region Inner Mongolia University of TechnologyHohhot010000China

Grassland biomass is an important parameter of grassland *** complexity of the grassland canopy vegetation spectrum makes the long-term assessment of grassland growth a *** studies have explored the original spectral information of typical grasslands in Inner Mongolia and examined the influence of spectral information on aboveground biomass(AGB)*** order to improve the accuracy of vegetation index inversion of grassland AGB,this study combined ground and Unmanned Aerial Vehicle(UAV)remote sensing technology and screened sensitive bands through ground hyperspectral data transformation and correlation *** narrow band vegetation indices were calculated,and ground and airborne hyperspectral inversion models were ***,the accuracy of the model was *** results showed that:(1)The vegetation indices constructed based on the ASD FieldSpec 4 and the UAV were significantly correlated with the dry and fresh weight of AGB.(2)The comparison between measured R^(2) with the prediction R^(2) indicated that the accuracy of the model was the best when using the Soil-Adjusted Vegetation Index(SAVI)as the independent variable in the analysis of AGB(fresh weight/dry weight)and four narrow-band vegetation *** SAVI vegetation index showed better applicability for biomass monitoring in typical grassland areas of Inner Mongolia.(3)The obtained ground and airborne hyperspectral data with the optimal vegetation index suggested that the dry weight of AGB has the best fitting effect with airborne hyperspectral data,where y=17.962e^(4.672x),the fitting R^(2) was 0.542,the prediction R^(2)was 0.424,and RMSE and REE were 57.03 and 0.65,***,established vegetation indices by screening sensitive bands through hyperspectral feature analysis can significantly improve the inversion accuracy of typical grassland biomass in Inner *** with ground monitoring,airborne hyperspectral monitoring better reflec

关键词： Aboveground biomass inversion model vegetation index unmanned aerial vehicle typical grassland

Accurate prediction of myopic progression and high myopia by machine learning

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Precision Clinical Medicine 2024年第1期7卷 14-20页

作者： Jiahui Li Simiao zeng Zhihuan Li Jie Xu Zhuo sun jing Zhao Meiyan Li Zixing Zou Taihua Guan jin zeng Zhuang Liu Wenchao Xiao Ran Wei Hanpei Miao Ian Ziyar Junxiong Huang Yuanxu Gao Yangfa zeng Xing-Tao Zhou Kang Zhang Guangzhou Women and Children's Medical Center Guangzhou Medical UniversityGuangzhou 510120China Guangzhou National Laboratory Guangzhou 510o0oChina Zhuhai International Eye Center of the First Affiliated Hospital of Faculty of Medicine Macao University of Science and TechnologyZhuhai 519000China Beijing Institute of Ophthalmology Beijing Tongren Eye CenterBeijing Tongren HospitalCapital Medical UniversityBeijing 100069China Key Laboratory of Myopia Ministry of HealthShanghai Key Laboratory of Visual Impairment and RestorationDepartment of OphthalmologyEye InstituteEye and EarNoseand Throat HospitalFudan UniversityShanghai 200031China DongguanPeople's Hospital The First School of Clinical MedicinelSouthern Medical UniversityDongguan 523059China State Key Laboratory of Ophthalmology Zhongshan Ophthalmic CenterSun Yat-sen UniversityGuangzhou 510060China Wenzhou Eye Hospital and Institute for Advanced Study on Eye Health and Diseases Wenzhou Medical UniversityWenzhou 32500oChina

Background Myopia is a leading cause of visual impairment in Asia and ***,accurately predicting the progression of myopia and the high risk of myopia remains a *** study aims to develop a predictive model for the development of *** We first retrospectively gathered 612530 medical records from five independent cohorts,encompassing 227543 patients ranging from infants to young ***,we developed a multivariate linear regression algorithm model to predict the progression of myopia and the risk of high *** The model to predict the progression of myopia achieved an R^(2) value of 0.964 vs a mean absolute error(MAE)of 0.119D[95%confidence interval(CI):0.119,1.146]in the internal validation *** demonstrated strong generalizability,maintaining consistent performance across external validation sets:R^(2)=0.950 vs MAE=0.119D(95%CI:0.119,1.136)in validation study 1,R^(2)=0.950 vs MAE=0.121D(95%CI:0.121,1.144)in validation study 2,and R^(2)=0.806 vs MAE=−0.066D(95%CI:−0.066,0.569)in the Shanghai Children Myopia *** the Beijing Children Eye Study,the model achieved an R^(2) of 0.749 vs a MAE of 0.178D(95%CI:0.178,1.557).The model to predict the risk of high myopia achieved an area under the curve(AUC)of 0.99 in the internal validation set and consistently high area under the curve values of 0.99,0.99,0.96 and 0.99 in the respective external validation *** Our study demonstrates accurate prediction of myopia progression and risk of high myopia providing valuable insights for tailoring strategies to personalize and optimize the clinical management of myopia in children.

关键词： myopia progression machine learning prevention precision medicine

放电电流对热阴极等离子体化学气相沉积金刚石膜影响

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大连理工大学学报 2007年第3期47卷 313-316页

作者：白亦真金曾孙吕宪义韩雪梅大连理工大学三束材料改性国家重点实验室吉林大学超硬材料国家重点实验室吉林长春130023

建立了快速沉积高品质金刚石膜的热阴极辉光放电等离子体化学气相沉积新方法．相对于常规冷阴极辉光放电而言，热阴极辉光放电是一种新型放电形式，具有许多新的特性，其中重要一点是具有较高的放电电流（6．0～10．0A）．较高的放电电... 详细信息

建立了快速沉积高品质金刚石膜的热阴极辉光放电等离子体化学气相沉积新方法．相对于常规冷阴极辉光放电而言，热阴极辉光放电是一种新型放电形式，具有许多新的特性，其中重要一点是具有较高的放电电流（6．0～10．0A）．较高的放电电流既是热阴极辉光放电本身的突出特点，同时对于化学气相沉积金刚石膜工艺也产生重要影响．实验研究了放电电流于金刚石膜沉积速率、表面形貌和热导率的影响，发现由于放电电流影响辉光放电的等离子体区和阳极区，进而对金刚石膜的沉积速率和品质有很大影响．特别是通过放电电流的提高，可以有效地提高金刚石膜的品质，这对于制备优质金刚石膜产品有重大意义．

关键词：放电电流热阴极等离子体化学气相沉积金刚石膜

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钽阴极在热阴极辉光放电中行为与防护

大连理工大学学报 2006年第2期46卷 157-159页

作者：白亦真吕宪义金曾孙姜志刚大连理工大学三束材料改性国家重点实验室吉林大学超硬材料国家重点实验室吉林长春130023

为快速沉积高品质金刚石膜，建立了热阴极等离子体化学气相沉积方法．相对于常规冷阴极辉光放电而言，热阴极辉光放电是一种新型放电形式，具有许多新的特性，其中重要一方面是阴极工作在较高的温度（700～1200℃）．研究了钽阴极在此... 详细信息

为快速沉积高品质金刚石膜，建立了热阴极等离子体化学气相沉积方法．相对于常规冷阴极辉光放电而言，热阴极辉光放电是一种新型放电形式，具有许多新的特性，其中重要一方面是阴极工作在较高的温度（700～1200℃）．研究了钽阴极在此温度条件下，在PCVD气氛中的反应情况．结果表明，钽与气氛中的碳反应形成了有益于放电和阴极防护的碳化钽表面，而气氛中氧的存在会影响阴极的正常工作，甚至造成阴极损坏．为有效保护阴极，需严格控制真空系统的本底真空度和漏气率．

关键词：钽热阴极辉光放电

3D interlocked all-textile structured triboelectric pressure sensor for accurately measuring epidermal pulse waves in amphibious environments

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Nano Research 2024年第3期17卷 1923-1932页

作者： Shaobo Si Chenchen sun Yufen Wu jingjing Li Han Wang Yinggang Lin jin Yang Zhong Lin Wang Department of Optoelectronic Engineering Key Laboratory of Optoelectronic Technology and Systems Ministry of EducationChongqing UniversityChongqing 400044China College of Physics and Electronic Engineering Chongqing Normal UniversityChongqing 401331China Beijing Institute of Nanoenergy and Nanosystems Chinese Academy of SciencesBeijing 100083China School of Materials Science and Engineering Georgia Institute of TechnologyAtlantaGA 30332USA

The performance degradation and even damage of the e-textiles caused by sweat,water,or submersion during all-weather health monitoring are the main reasons that e-textiles have not been commercialized and routinized so ***,we developed an amphibious,high-performance,air-permeable,and comfortable all-textile triboelectric sensor for continuous and precise measurement of epidermal pulse waves during full-day *** on the principle of preparing gas by acid-base neutralization reaction,a one-piece preparation process of amphibious conductive yarn(ACY)with densely porous structures is *** innovative three-dimensional(3D)interlocking fabric knitted from ACYs(0.6 mm in diameter)and polytetrafluoroethylene yarns exhibit high sensitivity(0.433 V·kPa^(-1)),wide bandwidth(up to 10 Hz),and stability(>30,000 cycles).With these benefits,98.8%agreement was achieved between wrist pulse waves acquired by the sensor and a high-precision laser ***,the polytetrafluoroethylene yarn with good compression resilience provides sufficient mechanical support for the contact separation of the ***,the unique skeletonized design of the 3D interlocking structure can effectively relieve the water pressure on the sensor surface to obtain stable and accurate pulse waves(underwater depth of 5 cm).This achievement represents an important step in improving the practicality of e-textiles and early diagnosis of cardiovascular diseases.

关键词： triboelectric pressure sensor amphibious fabric interlocking fabric pulse wave measurement one-piece preparation method

Electrochemically Deposited CZTSSe Thin Films for Monolithic Perovskite Tandem Solar Cells with Efficiencies Over 17%

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Energy & Environmental Materials 2024年第1期7卷 151-156页

作者： sun Kyung Hwang Ik Jae Park Se Won Seo Jae Hyun Park So Jeong Park jin Young Kim Department of Materials Science and Engineering Seoul National University Department of Applied Physics Sookmyung Women’s University Research Institute of Advanced Materials and Systems Sookmyung Women’s University Research Institute of Advanced Materials (RIAM) Seoul National University

In spite of the high potential economic feasibility of the tandem solar cells consisting of the halide perovskite and the kesterite Cu2ZnSn（S,Se）4（CZTSSe）,they have rarely been demonstrated due to the difficulty i... 详细信息

关键词： CZTSSe monolithic tandem solar cells perovskite solution process surface roughness control

A review of understanding electrocatalytic reactions in energy conversion and energy storage systems via scanning electrochemical microscopy

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Journal of Energy Chemistry 2024年第4期91卷 155-177页

作者： Jihye Park Jong Hwan Lim jin-Hyuk Kang Jiheon Lim Ho Won Jang Hosun Shin sun Hwa Park Interdisciplinary Materials Measurement Institute Korea Research Institute of Standards and ScienceDaejeon 34113Republic of Korea Department of Material Science and Engineering Seoul National UniversitySeoul 08826Republic of Korea Department of Applied Measurement Science University of Science and TechnologyDaejeon 34113Republic of Korea

To address climate change and promote environmental sustainability,electrochemical energy conversion and storage systems emerge as promising alternative to fossil fuels,catering to the escalating demand for *** optimal energy efficiency and cost competitiveness in these systems requires the strategic design of electrocatalysts,coupled with a thorough comprehension of the underlying mechanisms and degradation behavior occurring during the electrocatalysis *** electrochemical microscopy(SECM),an analytical technique for studying surface electrochemically,stands out as a powerful tool offering electrochemical *** possesses remarkable spatiotemporal resolution,enabling the visualization of the localized electrochemical activity and surface *** review compiles crucial research findings and recent breakthroughs in electrocatalytic processes utilizing the SECM methodology,specifically focusing on applications in electrolysis,fuel cells,and metal–oxygen batteries within the realm of energy conversion and storage *** with an overview of each energy system,the review introduces the fundamental principles of SECM,and aiming to provide new perspectives and broadening the scope of applied research by describing the major research categories within SECM.

关键词： Scanning electrochemical microscopy Electrocatalyst Electrocatalysis Water splitting Fuel cell Metal-oxygen battery

Implications for fault reactivation and seismicity induced by hydraulic fracturing

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Petroleum Science 2024年第2期21卷 1081-1098页

作者： Zi-Han sun Ming-Guang Che Li-Hong Zhu Shu-Juan Zhang Ji-Yuan Lu Chang-Yu jin Key Laboratory of Ministry of Education on Safe Mining of Deep Metal Mines School of Resources and Civil Engineering and Key Laboratory of Liaoning Province on Deep Engineering and Intelligent TechnologyNortheastern UniversityShenyang110819LiaoningChina Research Institute of Petroleum Exploration&Development PetroChina Company LimitedBeijing100084China The Exploration and Development Research Institute of Daqing Oilfield Limited Company Daqing163458HeilongjiangChina

Evaluating the physical mechanisms that link hydraulic fracturing(HF) operations to induced earthquakes and the anticipated form of the resulting events is significant in informing subsurface fluid injection operations. Current understanding supports the overriding role of the effective stress magnitude in triggering earthquakes, while the impact of change rate of effective stress has not been systematically addressed. In this work, a modified critical stiffness was brought up to investigate the likelihood, impact,and mitigation of induced seismicity during and after hydraulic fracturing by developing a poroelastic model based on rate-and-state fraction law and linear stability analysis. In the new criterion, the change rate of effective stress was considered a key variable to explore the evolution of this criterion and hence the likelihood of instability slip of fault. A coupled fluid flow-deformation model was used to represent the entire hydraulic fracturing process in COMSOL Multiphysics. The possibility of triggering an earthquake throughout the entire hydraulic fracturing process, from fracturing to cessation, was investigated considering different fault locations, orientations, and positions along the fault. The competition between the effects of the magnitude and change rate of effective stress was notable at each fracturing stage. The effective stress magnitude is a significant controlling factor during fracturing events, with the change rate dominating when fracturing is suddenly started or stopped. Instability dominates when the magnitude of the effective stress increases(constant injection at each fracturing stage) and the change rate of effective stress decreases(the injection process is suddenly stopped). Fracturing with a high injection rate, a fault adjacent to the hydraulic fracturing location and the position of the junction between the reservoir and fault are important to reduce the Coulomb failure stress(CFS) and enhance the critical stiffness as

关键词： Hydraulic fracturing Coulomb failure stress Rate-and-state fraction model Linear stability analysis Critical stiffness Seismically induced fault