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Ligand-free monophasic CuPd alloys endow boosted reaction kinetics toward energy-efficient hydrogen fuel production paired with hydrazine oxidation

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Journal of Materials Science & Technology 2023年第12期143卷 20-29页

作者： Yujeong Jeong Shreyanka Shankar Naik Yiseul Yu Jayaraman Theerthagiri Seung Jun Lee Pau Loke Show hyun chul choi Myong Yong choi Department of Chemistry(BK21 FOUR) Research Institute of Natural SciencesGyeongsang National UniversityJinju 52828Republic of Korea Core-Facility Center for Photochemistry&Nanomaterials Gyeongsang National UniversityJinju 52828Republic of Korea Zhejiang Provincial Key Laboratory for Subtropical Water Environment and Marine Biological Resources Protection Wenzhou UniversityWenzhou 325035China Department of Chemical and Environmental Engineering Faculty of Science and EngineeringUniversity of Nottingham MalaysiaJalan Broga43500 SemenyihSelangor Darul EhsanMalaysia Department of Chemistry Chonnam National UniversityGwangju 61186Republic of Korea

Optimizing the structure and components is a prevalent strategy for increasing electrocatalytic energy-saving H 2 fuel *** of the sustainable and efficient techniques is electrocatalytic water split-ting for H 2 generation,but it is still restricted by the kinetically sluggish *** to the lower standard oxidation potential of−0.33 V,replacing the OER with anodic hydrazine oxidation reaction(HzOR)is an effective way to extensively reduce the use of electricity in water *** alloying,the semiconductor and adsorption characteristics of Cu,interlaced by Pd 2+solution on the Pd surface by pulsed laser ablation(PLA)in methanol,are selectively altered to maximize cathodic HER and anodic HzOR *** optimal Cu1Pd3/C ratio demonstrates outstanding HER performance with a low overpotential of 0.315 V at 10 mA cm^(−2),as well as an ultralow overpotential of 0.560 V for HzOR in 0.5 M N_(2) H_(4)/1.0 M ***,the constructed HzOR-assisted electrolyzer cell with Cu1Pd3/C||Cu1Pd3/C as anode and cathode exhibits a cell voltage of 0.505 V at 10 mA cm^(−2) with exceptional en-durance over 5 *** current study advances competent CuPd alloys as multifunctional electrocatalysts for H 2 fuel production using a HzOR-assisted energy-efficient electrolyzer.

关键词： PLA CuPd alloy Sonochemical process HzOR Hydrazine evolution reaction Hydrazine splitting Water splitting

Diagnosis of building energy consumption in the 2012 CBECS data using heterogeneous effect of energy variables:A recursive partitioning approach

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Building Simulation 2021年第6期14卷 1737-1755页

作者： Doowon choi chul Kim Department of Industrial and Systems Engineering College of EngineeringTexas A&M UniversityCollege StationTX 77843USA Indoor Air Quality Research Center Korea Institute of Civil Engineering and Building TechnologyGoyang-Si10223R.O.Korea

Numerous previous literature has attempted to apply machine learning techniques to analyze relationships between energy variables in energy ***,most machine learning methods are primarily used for prediction through complicated learning processes at the expense of *** methods have difficulties in evaluating the effect of energy variables on energy consumption and especially capturing their heterogeneous ***,to identify the energy consumption of the heterogeneous relationships in actual buildings,this study applies the MOdel-Based recursive partitioning(MOB)algorithm to the 2012 CBECS survey data,which would offer representative information about actual commercial building characteristics and energy *** resultant tree-structured subgroups,the MOB tree reveals the heterogeneous effect of energy variables and mutual influences on building energy *** results of this study would provide insights for architects and engineers to develop energy conservative design and retrofit in *** buildings.

关键词： CBECS,commercial building decision tree analysis MOdel-Based recursive partitioning(MOB)algorithm recursive partitioning subgroup identification

Deposition and Characterization of (Ba, Sr)RuO3 Oxide Electrode Using TMHD-Based Single Cocktail Source

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Journal of Rare Earths 2004年第Z2期22卷 8-12页

作者： hyun chul Kim Kyung Il Hong Young Bae Kim Duck Kyun choi Department of Ceramic Engineering Hanyang University17 Haengdang-dongSeongdong-kuSeoul 133-791Korea Department of Ceramic EngineeringHanyang University17 Haengdang-dongSeongdong-kuSeoul 133-791Korea Department of Ceramic EngineeringHanyang University17 Haengdang-dongSeongdong-kuSeoul 133-791Korea Department of Ceramic EngineeringHanyang University17 Haengdang-dongSeongdong-kuSeoul 133-791Korea

(Ba, Sr)RuO3 has been paid an attention as a promising electrode for (Ba, Sr)TiO3 dielectric material due to its similarity in structure and chemical composition with BST. In this study, (Ba, Sr)RuO3 conductive oxide film was deposited on a 4 inch p-type Si wafer by metal organic chemical vapor deposition (MOCVD) using single cocktail source for the practical device application. Ba(TMHD)2, Sr(TMHD)2, Ru(TMHD)3 precursors and solvent [1-EtylePiPerdine (C7H15 N) ] as starting materials were mixed together for single cocktail source. A liquid delivery system (LDS) and a vaporization cell were utilized for the delivery and vaporization of single cocktail source, respectively. The source feeding rate was controlled by a liquid mass flow controller (LMFC). Deposition parameters, such as the oxygen flow and the source flow rate,were sensitive to phase formation, resistivity and the composition ratio of (Ba, Sr)RuO3 films. Highly (110)-textured (Ba,Sr)RuO3 film was obtained vhen the Ar/O2 ratio was 200/140 sccm at a source flow rate of 0.05 sccm. The process window of stoichiometric composition of BSR film was observed with varying the source flow rate from 0.05 sccm to 0.1 sccm.

关键词： (Ba, Sr)RuO3 (Ba, Sr)TiO3 MOCVD liquid delivery system(LDS) nozzle type injector

AC Conductance Through a Vibrating Molecular Dot in Kondo Regime

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Communications in Theoretical Physics 2007年第12期48卷 1107-1114页

作者： hyun-chul Yong School of Physics Peking UniversityBeijing 100871China

In the present paper,by applying the Lang-Firsov canonical transformation and the so-called non-crossingapproximation technique,we investigate the joint effects of the electron-phonon interaction and an external alternatinggate voltage on the transport of a quantum dot system in the Kondo *** find that,while the satellite Kondoresonant peaks appear in both the averaged local density of states and the differential conductance,the main Kondopeak at the Fermi energy is greatly *** results confirm the previous ones derived by other methods,suchas the equation of motion ***,based on the picture of virtual transition between quasi-eigenstates inthe system,we also give a slightly different explanation on these phenomena.

关键词： quantum dot Kondo effect electron-phonon interaction AC conductance

Unlocking power of neighboring vacancies in boosting hydrogen evolution reactions on two-dimensional NiPS3 monolayer

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eScience 2024年第3期4卷 104-115页

作者： hyun Gu Han Jae Won choi Minsu Son Ki chul Kim Computational Materials Design Laboratory Department of Chemical EngineeringKonkuk UniversitySeoul 05029The Republic of Korea Division of Chemical Engineering Konkuk UniversitySeoul 05029The Republic of Korea

This study investigates the effect of defect engineering on the catalytic activity of a NiPS3 monolayer catalyst for the hydrogen evolution reaction(HER).Three different types of vacancies on the basal plane of the monolayer are explored through a multi-step mechanism involving the dissociative adsorption of a water molecule and subsequent electrochemical adsorption of the dissociated ***-formation of vacancies in both Ni and S sites is found to be the most effective in enhancing the catalytic performance of the monolayer.A key resource for the reaction thermodynamics is the S-substitution-like physisorption of a water molecule on a vacant S site,followed by the dissociative occupation of OH and H into vacant sites of S and Ni elements,boosted by the NiS di-vacancy configuration with low activation energy *** reveals the highest contribution of bonding orbitals to the monolayer-H bond makes it the most desirable defect engineering approach for transition metal phosphorus chalcogenides with high HER ***,this study highlights the significance of controlled defect engineering in augmenting the catalytic performance of NiPS3 monolayer catalysts for HER.

关键词： Hydrogen evolution reaction Defect engineering Transition metal phosphorus trichalcogenide Density functional theory Reaction thermodynamics

Effects of design parameters and tension on behavior of a coil using finite element analysis

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Journal of Iron and Steel Research International 2018年第9期25卷 883-891页

作者： Kyu-tae ParkI hyun-chul Park Department of Mechanical Engineering Pohang Universityof Science and Technology Pohang Gyeongbuk 790-784Korea

During the thin strip coiling process, it is necessary to use a sleeve with a mandrel to prevent excessive deformation of the strip. Stress distribution in the sleeve and in the strip is an important factor that determines the quality of the coil. However, owing to the accumulation of high pressure, it is difficult to determine the stress distribution through experimentation. Thus, stress analysis of the strip coiling process was conducted. Finite element analysis was used to investigate the effects of the weight of the strip and the mandrel on the stress distribution and stress concentration near the starting point of the coil. The radial stress was predicted for a coil with a stacked thickness of 384 mm, which corresponds to a strip length of 1486 m, using the stress analysis model developed in a preceding research. A method was presented to reduce the weight and radial stress of a strip coil. It was found that the deformation of the sleeve can be reduced by decreasing the gap between the mandrel segments. The thickness of the sleeve can be reduced from 120 to 106 mm using the stress analysis results. Furthermore, coiling tension can be reduced by 44% compared to the existing value considering the interlayer slip of the strip coil.

关键词： Strip coiling process Structural analysis Finite element method Mandrel Coiling tension

Knot impingement after arthroscopic rotator cuff repair mimicking infection:A case report

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World Journal of Clinical Cases 2022年第15期10卷 5097-5102页

作者： Du-Han Kim Jong-Hyuk Jeon Byung-Chan choi chul-hyun Cho Department of Orthopedic Surgery Keimyung University Dongsan HospitalKeimyung University School of MedicineDaegu 42601South Korea

BACKGROUND Knot impingement as a complication after arthroscopic rotator cuff repair(ARCR)has been suggested as a cause of persistent pain with limited *** report on a case involving a patient who developed knot impingement after ARCR who complained of acute onset of pain with limited motion,which was confused with *** SUMMARY A 55-year-old female who complained of severe pain with limited motion of the right shoulder visited our emergency *** range of motion could not be evaluated due to the patient’s severe *** patient had undergone ARCR using a suture-bridge technique at a local clinic four months ago for treatment of a small supraspinatus tear of the right *** erosive change of the undersurface of the acromion was observed on plain radiographs of the right shoulder,and a moderate amount of bursal fluid and synovial thickening with enhancement was observed by magnetic resonance *** of an analysis of the aspirated fluid showed that the WBC count was 3960 with 90% *** arthroscopic view showed healing of the repaired supraspinatus tendon and loose suture threads and knots with severe subacromial bursitis were *** of inflammatory tissues of the glenohumeral joint and subacromial space was performed for the removal of all suture *** patient’s symptoms subsided immediately after the surgical *** Although the incidence of knot impingement is rare,the possibility of knot impingement after ARCR should be a consideration.

关键词： Rotator cuff Knot impingement Shoulder Infection Arthroscopy Case report

Cardiac metastasis from colorectal cancer:A case report

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World Journal of Gastroenterology 2009年第21期15卷 2675-2678页

作者： Pyong Wha choi chul Nam Kim Sun Hee Chang Woo Ik Chang Chang Young Kim hyun Min choi Department of Surgery Ilsan Paik HospitalInje University College of Medicine Department of Diagnostic Pathology Ilsan Paik HospitalInje University College of Medicine Department of Chest Surgery Ilsan Paik HospitalInje University College of Medicine Department of Internal Medicine Ilsan Paik HospitalInje University College of Medicine

The heart is an unusual site of metastasis from any malignancy. We report a case of cardiac metastasis from colorectal cancer. A 70-year-old woman was referred with a presumptive diagnosis of sigmoid colon cancer with cardiac myxoma. Two-dimensional echocardiography showed a 4 cm x 4.5 cm mobile mass on the lateral right atrial wall, and computed tomography revealed a low attenuated Iobulating mass in the right atrium. The patient underwent anterior resection for sigmoid colon cancer （T4N2）. Thereafter, she experienced progressive shortness of breath. Therefore, a cardiac operation was performed 2 wk after the colorectal operation. Histological examination revealed adenocarcinoma, which was identical to the primary lesion. Although two- dimensional echocardiography has become the diagnostic test of choice for detecting cardiac tumors, in patients with colorectal cancer showing a cardiac mass, further diagnostic evaluation such as a magnetic resonance imaging might be necessary.

关键词： Heart Cardiac metastasis Colorectalcancer Atrial myxoma Magnetic resonance imaging

Honokiol attenuates oxidative stress-induced cytotoxicity in human keratinocytes via activating AMPK signaling

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Asian Pacific Journal of Tropical Biomedicine 2021年第5期11卷 222-230页

作者： Yung hyun choi Anti-Aging Research Center Dong-eui UniversityBusan 47340Republic of Korea Department of Biochemistry College of Korean MedicineDong-eui UniversityBusan 47227Republic of Korea

Objective:To investigate the effect of honokiol on oxidative damage in HaCaT human ***:HaCaT cells were exposed to hydrogen peroxide(H_(2)O_(2)),following pretreatment with various concentrations of *** alleviating effects of honokiol on HaCaT cell viability and cell death,reactive oxygen species(ROS)production,DNA damage,mitochondrial dynamics,and inhibition of adenosine triphoaphate production against H_(2)O_(2)were *** blotting analysis was used to analyze the expression levels of specific ***:Honokiol suppressed H_(2)O_(2)-induced cytotoxicity and DNA damage by blocking abnormal ROS *** also prevented apoptosis by inhibiting loss of mitochondrial membrane potential and release of cytochrome c from the mitochondria into the cytosol,decreasing the Bax/Bcl-2 ratio,and reducing the activity of caspase-3 in H_(2)O_(2)-stimulated HaCaT *** addition,honokiol attenuated H_(2)O_(2)-induced reduction of adenosine triphosphate content,and activation of AMP-activated protein kinase(AMPK)was markedly promoted by honokiol in H_(2)O_(2)-stimulated ***,the anti-apoptosis and anti-proliferative activity of honokiol against H_(2)O_(2)was further enhanced by adding an activator of AMPK,indicating that honokiol activated AMPK in HaCaT keratinocytes to protect against oxidative ***:The present results indicate that honokiol may be useful as a potential therapeutic agent against various oxidative stress-related skin diseases.

关键词： Honokiol ROS DNA damage Apoptosis AMPK