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CHEMICAL STRUCTURE DEPENDENCE OF THE INTERNAL ENERGY CONTRIBUTION IN RUBBER ELASTICITY

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chinese Journal of Polymer Science 2001年第5期19卷 447-449页

作者： Juan Sun Xiao-zhen Yang Polymer physics Laboratory Center for Molecular sciences, institute of Chemistry chinese academy of sciences beijing 100080 china 中科院化学所高分子物理及化学国家重点实验室北京

Conformational elasticity theory recently developed has been used to explore the internal energy contribution to the elastic force f(e)/f as a function of strain for poly(cis-1,4-isoprene) and poly(trans-1,4-isoprene). Calculated f(e)/f values are in good agreement with those obtained experimentally. Results show that behavior of f(e)/f is mainly contributed by chemical structure, or intramolecular interaction, supporting the experimental observations, and that the internal energy contribution is strain dependent.

关键词： conformational elasticity theory internal energy contribution poly(cis-1,4-isoprene) poly(trans-1,4-isoprene)

THERMALLY STIMULATED SHAPE MEMORY BEHAVIOR OF POLYMERS WITH PHYSICAL CROSSLINKS

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chinese Journal of Polymer Science 1999年第3期17卷 203-213页

作者： Mao Xu Feng-kui Li Polymer physics Laboratory, institute of Chemistry, chinese academy of sciences, beijing 100080, china 中科院化学所高分子物理及化学国家重点实验室北京 100080 中科院化学所高分子物理及化学国家重点实验室北京

The shape memory effect of polymers was investigated for the purpose of improving the processing conditions of their preparation and broadening the list of polymers for shape memory applications. Emphasis was put on the possibility of using polymers with physical crosslinks as shape memory materials and their structure-function relationships. Segmented block polyurethanes and polyethylene/nylon 6 graft copolymers were used as examples of polymers with physical crosslinks. It was found that these copolymers can really be used as thermally stimulated shape memory materials with large recoverable strain and high final recovery rate. The main advantage of using copolymers is their improved processing conditions as compared with polymers with chemical crosslinks. As only physical crosslinks are introduced, all conventional processing techniques for thermal plastics can be used, and the materials become easily reusable. The results indicate that the high crystallinity of these copolymers at room temperature and the formation of stable physical crosslinks are the two prerequisites for these polymers to exhibit shape memory effect. The successful use of block and graft copolymers imply the possibility of using polymers of various structure and properties as shape memory materials.

关键词： shape memory effect segmented polyurethanes polyethylene nylon graft copolymers

The influence of tropical Indian Ocean warming on the Southern Hemispheric stratospheric polar vortex

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Science china Earth sciences 2009年第3期52卷 323-332页

作者： LI ShuangLin Nansen-Zhu International Research Centre, institute of Atmospheric physics, chinese academy of sciences, beijing 100029, china Nansen-Zhu International Research Centre Institute of Atmospheric Physics Chinese Academy of Sciences Beijing China

During the past decades, concurrent with global warming, most of global oceans, particularly the tropical Indian Ocean, have become warmer. Meanwhile, the Southern Hemispheric stratospheric polar vortex (SPV) exhibits a deepening trend. Although previous modeling studies reveal that radiative cooling effect of ozone depletion plays a dominant role in causing the deepening of SPV, the simulated ozone-depletion-induced SPV deepening is stronger than the observed. This suggests that there must be other factors canceling a fraction of the influence of the ozone depletion. Whether the tropical Indian Ocean warming (IOW) is such a factor is unclear. This issue is addressed by conducting ensemble atmospheric general circulation model (AGCM) experiments. And one idealized IOW with the amplitude as the observed is prescribed to force four AGCMs. The results show that the IOW tends to warm the southern polar stratosphere, and thus weakens SPV in austral spring to summer. Hence, it offsets a fraction of the effect of the ozone depletion. This implies that global warming will favor ozone recovery, since a warmer southern polar stratosphere is un-beneficial for the formation of polar stratospheric clouds (PSCs), which is a key factor to ozone depletion chemical reactions.

关键词： tropical Indian Ocean warming Southern Hemispheric stratospheric polar vortex atmospheric general circulation model ensemble experiments planetary wave

Prediction model for spring dust weather frequency in North china

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Science china Earth sciences 2008年第5期51卷 709-720页

作者： LANG XianMei Center for Disastrous Climate Research and Prediction, institute of Atmospheric physics, chinese academy of sciences, beijing 100029, china Center for Disastrous Climate Research and Prediction Institute of Atmospheric Physics Chinese Academy of Sciences Beijing China

It is of great social and scientific importance and also very difficult to make reliable prediction for dust weather frequency (DWF) in North china. In this paper, the correlation between spring DWF in beijing and Tianjin observation stations, taken as examples in North china, and seasonally averaged surface air temperature, precipitation, Arctic Oscillation, Antarctic Oscillation, South Oscillation, near surface meridional wind and Eurasian westerly index is respectively calculated so as to construct a prediction model for spring DWF in North china by using these climatic factors. Two prediction models, i.e. model-I and model-II, are then set up respectively based on observed climate data and the 32-year (1970 -2001) extra-seasonal hindcast experiment data as reproduced by the nine-level Atmospheric General Circulation Model developed at the institute of Atmospheric physics (IAP9L-AGCM). It is indicated that the correlation coefficient between the observed and predicted DWF reaches 0.933 in the model-I, suggesting a high prediction skill one season ahead. The corresponding value is high up to 0.948 for the subsequent model-II, which involves synchronous spring climate data reproduced by the IAP9L-AGCM relative to the model-I. The model-II can not only make more precise prediction but also can bring forward the lead time of real-time prediction from the model-I’s one season to half year. At last, the real-time predictability of the two models is evaluated. It follows that both the models display high prediction skill for both the interannual variation and linear trend of spring DWF in North china, and each is also featured by different advantages. As for the model-II, the prediction skill is much higher than that of original approach by use of the IAP9L-AGCM alone. Therefore, the prediction idea put forward here should be popularized in other regions in china where dust weather occurs frequently.

关键词： spring dust weather frequency prediction model iap9l-agcm hindcast experiment real-time prediction

A new approach of cascade utilization of the chemical energy of fuel

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Progress in Natural Science:Materials International 2006年第5期16卷 518-523页

作者： HAN Wei, JIN Hongguang and LIN Rumou ( institute of Engineering Thermophysics, chinese academy of sciences, beijing 100080, china Graduate School of the chinese academy of sciences, beijing 100080, china) institute of Engineering Thermophysics Chinese Academy of Sciences Beijing 100080 China Graduate School of the chinese academy of sciences Beijing 100080 China

The indirect release of chemical energy of fuel is investigated, and a new mechanism is proposed to identify the cascade utilization of chemical energy of fuel more clearly. Based on the concept of energy level, the internal phenomenon of the indirect chemical energy release is disclosed, and the equations of energy level describing the utilization of chemical energy and thermal energy during the indirect chemical energy release process are obtained. From theoretical analysis, we find that the superiority of the indirect chemical energy release of fuel comes from the cascade utilization of the fuel's chemical energy. Moreover, the cascade utilization of chemical energy is verified by the investigation of CRGT (chemically recuperated gas turbine). As a result, the thermal exergy obtained from the chemical energy release of fuel increases by 2 % -3 % . The results obtained here may help a deeper understanding of indirect chemical energy release of fuel and provide a theoretical basis for the synthesis of innovative energy systems.

关键词： chemically recuperated gas turbine methane/steam reforming chemical energy level cascade utilization.

An efficient chiral synthesis of (R)-N-[3-acetyl-4-(2-hydroxy-3-isopropylamino-propoxy)phenyl]-butanamide with high enantioselectivity

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Science china Chemistry 2009年第8期52卷 1216-1219页

作者： WANG NaiXing1,2 & TANG XinLiang1,3 1 Technical institute of physics and Chemistry,chinese academy of sciences,beijing 100080,china 2 College of Chemistry and Chemical Engineering,Graduate University of chinese academy of sciences,beijing 100049,china 3 School of Chemical Engineering and Environment,beijing institute of Technology,beijing 100081,china Technical institute of physics and Chemistry Chinese Academy of Sciences Beijing China College of Chemistry and Chemical Engineering Graduate University of Chinese Academy of Sciences Beijing China School of Chemical Engineering and Environment Beijing Institute of Technology Beijing China

R-Enantiomer of the β-receptor antagonist N-[3-acetyl-4-(2-hydroxy-3-isopropylamino-propoxy)phenyl] butanamide with high enantioselectivity was synthesized from cheap starting materials and enantiopure chiral reagent through an efficient,convenient and practical synthetic *** product was detected by 1H NMR,13C NMR,and MS,and the enatiomeric excess was determined by chiral HPLC analysis using a chiracel AD-H column.

关键词： chiral synthesis enantioselectivity enatiomeric excess chiral HPLC analysis

NONPARAMETRIC APPROACH TO IDENTIFYING NARX SYSTEMS

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Journal of Systems Science & Complexity 2010年第1期23卷 3-21页

作者： Qijiang SONG·Han-Pu CHEN Key Laboratory of Systems and Control,institute of Systems Science,academy of Mathematics and Systems Science,chinese academy of sciences,beijing 100190,china Key Laboratory of Systems and Control Institute of Systems Science Academy of Mathematics and Systems Science Chinese Academy of Sciences Beijing China

This paper considers identification of the nonlinear autoregression with exogenous inputs(NARX system).The growth rate of the nonlinear function is required be not faster than linear withslope less than *** value of f(·) at any fixed point is recursively estimated by the stochasticapproximation (SA) algorithm with the help of kernel *** consistency of the estimatesis established under reasonable conditions,which,in particular,imply stability of the *** simulation is consistent with the theoretical analysis.

关键词： α-mixing geometrically ergodic Markov chains NARX nonparametric recursive estimate stochastic approximation strongly consistent.

Model for Unidirectional Movement of Axonemal and Cytoplasmic Dynein Molecules

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Acta Biochimica et Biophysica Sinica 2006年第10期38卷 711-724页

作者： Ping XIE* Shuo-Xing DOU Peng-Ye WANG Laboratory of Soft Matter physics,beijing National Laboratory for Condensed Matter physics,institute of physics,chinese academy of sciences,beijing 100080,china Laboratory of Soft Matter physics Beijing National Laboratory for Condensed Matter Physics Institute of Physics Chinese Academy of SciencesBeijing 100080 China

A model for the unidirectional movement of dynein is presented based on the structuralobservations and biochemical experimental results *** this model,the binding affinity of dynein formicrotubule (MT) is independent of its nucleotide state and the change between strong and weak MT-bindingis determined naturally by the variation of relative orientation between the stalk and MT,as the stalk rotatesfollowing nucleotide-state *** the enigmatic communication from the adenosine triphosphate(ATP)-binding site in the globular domain to the far MT-binding site in the tip of the stalk,which is aprerequisite in conventional models,is not *** the present model,the previous experimentalresults such as the effect of ATP and adenosine diphosphate (ADP) bindings on dissociation of dynein fromMT,the movement of single-headed axonemal dyneins at saturating ATP concentration,the load dependenceof step-size for the movement of two-headed cytoplasmic dyneins and the dependence of stall force on ATPconcentration can be well explained.

关键词： dynein mechanism mechanochemistry molecular motor

North Pacific sea ice cover, a predictor for the Western North Pacific typhoon frequency?

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Science china Earth sciences 2007年第8期50卷 1251-1257页

作者： FAN Ke institute of Atmospheric physics, chinese academy of sciences, beijing 100029, china Department of Atmospheric Science, Yun-nan University, Kunming 650091, china institute of Atmospheric physics Chinese Academy of Sciences Beijing China Department of Atmospheric Science Yunnan University Kunming China

The relationship between the sea ice cover in the North Pacific and the typhoon frequency has been studied in this paper. It follows that the index for the sea ice cover in the North Pacific (ISA) both in December-January-February (DJF) and in March-April-May (MAM) is negatively correlated with annual typhoon number over the western North Pacific (TNWNP) during 1965―2004, with correlation coeffi-cients of -0.42 and -0.49 respectively (above 99% significant level). Large sea ice cover in the North Pacific tends to decrease TNWNP. Positive ISA (MAM) is associated with the tropical circulation and SST anomalies in the North Pacific, which may lead to unfavorable dynamic and thermal conditions for typhoon genesis over WNP from June to October (JJASO). The variability of the atmospheric circula-tion over the North Pacific, associated with the ISA anomaly in MAM is connected to the tropical at-mospheric circulation variability in MAM via the teleconnection wave train. Besides, as the tropical circulation has strong seasonal persistency from the MAM to JJASO, thus, the ISA in MAM-related variability of the tropical atmospheric circulation as well as the SST can affect the typhoon activity over the western North Pacific.

关键词： typhoon sea ice cover North Pacific teleconnection