Synthesis of poly[methyl(3,3,3-trifluoropropyl)siloxane]-b-poly(ethylene oxide) block copolymers

作     者：Xiao-li ZHAN Bi CHEN Qing-hua ZHANG Ling-min YI Bo JIANG Feng-qiu CHEN 

作者机构：College of Materials Sclence and Chemical Engmeering Zhejiang University Hangzhou 310027 China MOE Key Laboratory of Advanced Textile Materials and Manufacturing Technology Zhejiang Sci-Tech University 

出 版 物：《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 (浙江大学学报（英文版）A辑（应用物理与工程）)

年 卷 期：2008年第9卷第9期

页      面：1304-1308页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 0703[理学-化学] 

基　　金：the National Natural Science Foundation of China (No. 20606029) the Postdoctoral Science Foundation of China (No. 20070420230) 

主　　题：Block copolymers Polysiloxanes Fluoropolymers Synthesis Polyethyleneoxide 

摘      要：A series of new amphiphilic poly[methyl（3,3,3-trifluoropropyl）siloxane]-b-poly（ethylene oxide） （PMTFPS-b-PEO） diblock copolymers with different ratios of hydrophobic segment to hydrophilic segment were prepared by coupling reactions of end-functlonal PMTFPS and PEO homopolymers. Copolymers were shown to be well defined and narrow molecular weight distribution （MWD） （1.07-1.3） by characterizations such as gel permeation chromatography （GPC） and ^1H-nudear magnetic resonance （^1H-NMR）.