Nitric oxide(NO) decomposition on catalysts, containing oxides of lanthanum and cerium, supported on γ-alumina

作     者：D.Stoyanova P.Georgieva I.Avramova K.Aleksieva D.Marinova D.Mehandjiev 

作者机构：Institute of General and Inorganic Chemistry-BAS Institute of Catalysis-BAS 

出 版 物：《Journal of Rare Earths》 (稀土学报（英文版）)

年 卷 期：2019年第37卷第2期

页      面：151-159页

核心收录：

学科分类：083002[工学-环境工程] 0830[工学-环境科学与工程（可授工学、理学、农学学位）] 0709[理学-地质学] 0819[工学-矿业工程] 081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 0708[理学-地球物理学] 0703[理学-化学] 

基　　金：Bulgarian Academy of Sciences  BAS 

主　　题：Rare earths Catalysts Catalytic activity Decomposition of nitric oxide 

摘      要：The present work was devoted to study the catalytic activity of lanthanum and cerium oxides separately,deposited on g-alumina in the reaction of decomposition of nitric oxide. The catalyst samples were prepared by the method of impregnation of g-Al_2 O_3 using solutions, containing nitrates of lanthanum and cerium. The prepared samples were calcined for 4 h at temperature 650℃ in an oven in air atmosphere. The catalysts were characterized by: chemical analysis by inductively coupled plasma atomic emission spectrometry(ICP-AES), X-ray diffraction(XRD), X-ray photoelectron spectroscopy(XPS),scanning electron microscopy(SEM) combined with energy-dispersive X-ray spectroscopy(EDS), electron paramagnetic resonance(EPR) and infrared(IR) spectroscopy, as well as measurement of the specific surface area. The results show that the catalysts based on lanthanum oxide and cerium oxide deposited on alumina display high catalytic activity over 60% conversion degree with respect to decomposition of nitric oxide in the absence of reducing agent. In the presence of reducer the activity reaches 90% conversion degree.