Occurrence of Different Forms and Implications of Compound Specific Sterols in Continental Sediments of the Northeast South China Sea

作     者：QIU Hong ZOU Li ZHANG Minsheng ZHU Chaoqi JIA Yonggang 

作者机构：College of Environmental Science and Engineering Ocean University of China Education Key Laboratory fo r Marine Environment and Ecology Ocean University of China The Shandong Provincial Key Laboratory of Marine Environment and Geological Engineering Ocean University of China 

出 版 物：《Acta Geologica Sinica(English Edition)》 (地质学报（英文版）)

年 卷 期：2019年第93卷第2期

页      面：420-429页

核心收录：

学科分类：070704[理学-海洋地质] 0709[理学-地质学] 0819[工学-矿业工程] 07[理学] 0707[理学-海洋科学] 0818[工学-地质资源与地质工程] 0708[理学-地球物理学] 0816[工学-测绘科学与技术] 

基　　金：supported by National Key R&D Program of China (No. 2018YFC0309200) National Natural Science Foundation of China (No. 41176064 and No. 41427803) 

主　　题：sterols sediments occurrence forms transformation northeast South China Sea 

摘      要：The South China Sea(SCS) is one of the most productive and accumulative marginal shelves of organic carbon in the world. To expound the transformation and preservation of organic carbon in the Northeast SCS, where abundant oil and gas resources have been reported, compound specific sterols in free(FR), base hydrolytic(BH), and acid hydrolytic(AH) forms were analyzed in surface and columnar sediments in May, 2016. The results showed that the total contents of sterols detected ranged from 0.15 to 3.74 ppm dry weight in the surface sediments, and gradually decreased from 3.41 to0.17 ppm dry weight from surface to deep sediments, in which cholesterol(27^(△5)) was the most abundant component. Sterols mainly existed in the BH form(54.51%-74.20%), followed by the FR form(25.50%-45.49%) and then the AH form(0-3.77%) in turn, in the surface sediments. BH and FR sterols accounted for 0-49.08% and 50.92%-100% in the columnar sediments, while AH sterols were undetectable. The contents of specific sterols indicated that, the primary source of marine organic carbon was about 5 times as much as that from terrestrial input. More and more FR sterols transformed into BH sterols with increasing sedimentary depth, and BH sterols absolutely dominated in sediment depths under 25 cm. The forms of Sterols C27 were maintained at a relative consistence state, but Sterols C28 to C30 degraded gradually during the sedimentation process. It was suggested that the stability of sterols, based on the chemical structures, might be the primary factor controlling their degradation and preservation in deeper sediments. These results would help to understand the organic carbon(OC) transformation in a hydrate formation area in a marginal sea.