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Synergistic Effect of Fullerene-Capped Gold Nanoparticles on Graphene Electrochemical Supercapacitors

Synergistic Effect of Fullerene-Capped Gold Nanoparticles on Graphene Electrochemical Supercapacitors

作     者:Virginia Yong H. Thomas Hahn 

作者机构:Department of Materials Science and Engineering University of California Los Angeles USA 

出 版 物:《Advances in Nanoparticles》 (纳米粒子(英文))

年 卷 期:2013年第2卷第1期

页      面:1-5页

学科分类:07[理学] 0703[理学-化学] 

主  题:Fullerenes Gold Nanoparticles Graphene Supercapacitors Energy Storage Electrochemistry Self-Assembly Nanocomposites 

摘      要:We report the synthesis of graphene/fullerene-capped gold nanoparticle nanocomposite film which was used to construct supercapacitor electrodes. The fullerene-based self-assembled monolayers on gold nanoparticles (AuNPs) were attained via the fullerene(C60)-gold interaction. The fullerene-capped AuNPs effectively separated the graphene sheets preventing aggregation. A synergistic effect was observed—the specific capacitance of graphene/fullerene-capped AuNP electrode is197 F/g, which is higher than that of graphene electrode (31 F/g), graphene/AuNP electrode (126 F/g), and graphene/fullerene electrode (118 F/g). The results render a novel route of synthesis and modification of graphene-based materials for the construction of electrochemical energy storage devices.

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