One-dimensional (1D) europium coordination polymer wires:Synthesis,characterization and photoluminescence properties
One-dimensional (1D) europium coordination polymer wires:Synthesis,characterization and photoluminescence properties作者机构:College of Chemistry and Chemical EngineeringJiangxi Normal University Division of Nanomaterials and ChemistryHefei National Laboratory for Physical Sciences at MicroscaleUniversity of Science and Technology of China
出 版 物:《Journal of Rare Earths》 (稀土学报(英文版))
年 卷 期:2010年第28卷第S1期
页 面:106-110页
核心收录:
学科分类:08[工学] 080502[工学-材料学] 0805[工学-材料科学与工程(可授工学、理学学位)]
基 金:Project supported by the China Postdoctoral Science Foundation (20100470841) the Natural Science Foundation of Jiangxi Province (2009GQH0057)
主 题:one dimensional solvothermal synthesis europium coordination polymer rare earths
摘 要:1D europium coordination polymer wires were successfully prepared by reacting europium chloride with tributyl phosphate(TBP) at 160 oC for 12 h. The products were characterized by XRD,IR,TG,DTA,SEM,and EDS. SEM results showed that the wires were with diameters ranging from several hundreds of nanometers to ~5 μm and lengths going up to several hundreds of micrometers. Influencing factors such as the dosage of reactants and reaction time on the preparation were systematically investigated. Strong emission centering at 590 nm was realized in the coordination polymer wires on excitation at 395 nm.