Excellent Electrochemical Performances of Intrinsic Polyaniline Nanofibers Fabricated by Electrochemical Deposition

作     者：CHEN Shaoyun HU Chenglong 陈韶云;LIU Ben;WANG Yuan;CHENG Huan;ZHANG Xingying;XU Shaoqin;LIU Hui;LIU Wenfeng;胡成龙

作者机构：Key Laboratory of Optoelectronic Chemical Materials and Devices Ministry of Education School of Chemical and Environmental Engineering Jianghan University 

出 版 物：《Journal of Wuhan University of Technology(Materials Science)》 (武汉理工大学学报（材料科学英文版）)

年 卷 期：2019年第34卷第1期

页      面：216-222页

核心收录：

学科分类：08[工学] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 

基　　金：Funded by the National Natural Science Foundation of China(No.21706092) the Hubei Province Natural Science Foundation of China(No.2018CFB520) 

主　　题：polyaniline nanofibers nanostructured electrodes electrochemical capacitors 

摘      要：A simple route to synthesize the polyaniline(PANI) nanofibers with diameter about 150 nm was reported. In this strategy, the PANI nanofibers were fabricated by electrochemical deposition by using two-electrode configuration in 0.01 M aniline and 0.01 M H_2SO_4 electrolytes. The as-prepared materials were characterized by scanning electron microscopy(SEM), infrared spectroscopy(FTIR), Raman spectroscopy and thermogravimetric analysis(TGA). The electrochemical properties of the PANI nanofibers electrode as supercapacitor materials were investigated. The PANI nanofibers electrode showed high capacitance of 485 F·g^(-1)at 0.1 A·g^(-1), and the decrease in the specific capacitance is about 3.5% in 1 000 cycles. The results indicate that the PANI nanofibers electrode shows high stability and retains its electrochemical capacitance property over 1 000 cycles, suggesting PANI nanofibers have promising applications in high-performance supercapacitors.