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Self-healable gels in electrochemical energy storage devices

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Nano Research 2024年第4期17卷 3302-3323页

作者： Yang Li PeiPei Ding Yuzhe Gu Sheng Qian Yuncong Pang Lele Wang Jiayang Feng Baoguang Liu Qi Wan Ping Li Zhiwei Liu College of Electronic and Optical Engineering&College of Flexible Electronics(Future Technology) Nanjing University of Posts&Telecommunications(NJUPT)Nanjing 210023China State Key Laboratory of Organic Electronics and Information Displays&Jiangsu Key Laboratory for Biosensors Institute of Advanced Materials(IAM)Nanjing University of Posts and Telecommunications(NJUPT)Nanjing 210023China College of Materials Science&Engineering Beijing University of TechnologyBeijing 100124China Beijing Advanced Innovation Center for Materials Genome Engineering Institute for Advanced Materials and TechnologyUniversity of Science and Technology BeijingBeijing 100083China Pillar of Engineering Product Development Singapore University of Technology and DesignSingapore 487372Singapore School of Energy and Environmental Engineering University of Science and Technology BeijingBeijing 100083China

In the green energy and carbon-neutral technology,electrochemical energy storage devices have received continuously increasing attention recently.However,due to the unavoidable volume expansion/shrinkage of key materials or irreversible mechanical damages during application,the stability of energy storage and delivery as well as the lifetime of these devices are severely shortened,leading to serious performance degradation or even safety issues.Therefore,the utilization of self-healable gels into electrochemical energy storage devices,such as electrodes,binders,and electrolytes,is proven as an effective method to realize long-term stable operation of these devices via the self-repairing of mechanical and electrochemical characteristics.Herein,this review first summarizes the feature and fabrication of different gels,paying special attention to hydrogels,organohydrogels,and ionogels.Then,basic concepts and figure of merit of self-healable gels are analyzed with a detailed discussion at the healing mechanisms,from reversible dynamic bonds to physical molecular diffusion,and to external healing trigger.Then we introduce all the important parts of electrochemical energy storage devices,which could be replaced by healable gels to enhance the durability,including electrodes,binders,and electrolytes.Finally,the critical challenges and future perspectives regarding the future development of healable gels based high-performance electrochemical energy storage devices or electronics are provided.

关键词： self-healable gels healing mechanisms electrodes binders gel electrolytes

Metal-organic frameworks and their composites for advanced lithium-ion batteries:Synthesis,progress and prospects

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Journal of Energy Chemistry 2024年第2期89卷 449-470,I0011页

作者： Chengcai Liu Borong Wu Tao Liu Yuanxing Zhang Jingwen Cui Lingjun Huang Guoqiang Tan Ling Zhang Yuefeng Su Feng Wu School of Material Science and Engineering Beijing Institute of TechnologyBeijing 100081China Chonging Innovation Center Beijing Institute of TechnologyChongqing 401120China Collaborative Innovation Center of Electric Vehicles in Beijing Beijing 100081China

Metal-organic frameworks(MOFs)are among the most promising materials for lithium-ion batteries(LIBs)owing to their high surface area,periodic porosity,adjustable pore size,and controllable chemical composition.For instance,their unique porous structures promote electrolyte penetration,ions transport,and make them ideal for battery separators.Regulating the chemical composition of MOF can introduce more active sites for electrochemical reactions.Therefore,MOFs and their related composites have been extensively and thoroughly explored for LIBs.However,the reported reviews solely include the applications of MOFs in the electrode materials of LIBs and rarely involve other aspects.A systematic review of the application of MOFs in LIBs is essential for understanding the mechanism of MOFs and better designing related MOFs battery materials.This review systematically evaluates the latest developments in pristine MOFs and MOF composites for LIB applications,including MOFs as the main materials(anode,cathode,separators,and electrolytes)to auxiliary materials(coating layers and additives for electrodes).Furthermore,the synthesis,modification methods,challenges,and prospects for the application of MOFs in LIBs are discussed.

关键词： Metal-organic frameworks electrodes Electrolytes Separators Lithium-ion batteries

Magnetic resonance imaging techniques for lithium-ion batteries:Principles and applications

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Magnetic Resonance Letters 2024年第2期4卷 22-39页

作者： Hongxin Lin Yanting Jin Mingming Tao Yingao Zhou Peizhao Shan Danhui Zhao Yong Yang State Key Laboratory for Physical Chemistry of Solid Surfaces Collaborative Innovation Center of Chemistry for Energy Materials and Department of ChemistryCollege of Chemistry and Chemical EngineeringTan Kah Kee Innovation Laboratory(IKKEM)Xiamen UniversityXiamen361005China School of Energy Xiamen UniversityXiamen361005China

Operando monitoring of internal and local electrochemical processes within lithium-ion batteries(LIBs)is crucial,necessitating a range of non-invasive,real-time imaging characterization techniques including nuclear magnetic resonance(NMR)techniques.This review provides a comprehensive overview of the recent applications and advancements of non-invasive magnetic resonance imaging(MRI)techniques in LIBs.It initially introduces the principles and hardware of MRI,followed by a detailed summary and comparison of MRI techniques used for characterizing liquid/solid electrolytes,electrodes and commercial batteries.This encompasses the determination of electrolytes'transport properties,acquisition of ion distribution profile,and diagnosis of battery defects.By focusing on experimental parameters and optimization strategies,our goal is to explore MRI methods suitable to a variety of research subjects,aiming to enhance imaging quality across diverse scenarios and offer critical physical/chemical insights into the ongoing operation processes of LIBs.

关键词： Lithium-ion batteries Magnetic resonance imaging(MRI) Electrolytes electrodes Commercial batteries

Biomass-based materials for advanced supercapacitor:principles,progress,and perspectives

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Aggregate 2024年第1期5卷 95-114页

作者： Yaxuan Wang Ting Xu Kun Liu Meng Zhang Xu-Min Cai Chuanling Si State Key Laboratory of Biobased Fiber Manufacturing Technology Tianjin Key Laboratory of Pulp and PaperTianjin University of Science and TechnologyTianjinChina Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources College of Chemical EngineeringNanjing Forestry UniversityNanjingChina

Supercapacitors exhibit considerable potential as energy storage devices due to their high power density,fast charging and discharging abilities,long cycle life,and ecofriendliness.With the increasing environmental concerns associated with synthetic compounds,the use of environment friendly biopolymers to replace conventional petroleum-based materials has been widely studied.Biomass-based materials are biodegradable,renewable,environment friendly and non-toxic.The unique hierarchical nanostructure,excellent mechanical properties and hydrophilicity allow them to be used to create functional conductive materials with precisely controlled structures and different properties.In this review,the latest development of biomass-based supercapacitor materials is reviewed and discussed.This paper describes the physical and chemical properties of various biopolymers and their impact on supercapacitors,as well as the classification and basic principles of supercapacitors.Then,a comprehensive discussion is presented on the utilization of biomass-based materials in supercapacitors and their recent applications across a range of supercapacitor devices.Finally,an overview of the future prospects and challenges pertaining to the utilization of biomass-based materials in supercapacitors is provided.

关键词： biomass electrodes electrolyte energy storage supercapacitor

Self-assembled microtubular electrodes for on-chip low-voltage electrophoretic manipulation of charged particles and macromolecules

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Microsystems & Nanoengineering 2022年第1期8卷 341-352页

作者： Apratim Khandelwal Nagendra Athreya Michael Q.Tu Lukas L.Janavicius Zhendong Yang Olgica Milenkovic Jean-Pierre Leburton Charles M.Schroeder Xiuling Li Department of Electrical and Computer Engineering University of Illinois Urbana-ChampaignUrbanaIL 61801USA Nick Holonyak Micro and Nanotechnology Laboratory University of Illinois Urbana-ChampaignUrbanaIL 61801USA Department of Chemical Engineering University of Illinois Urbana-ChampaignUrbanaIL 61801USA Beckman Institute for Advanced Science and Technology University of Illinois Urbana-ChampaignUrbanaIL 61801USA Department of Electrical and Computer Engineering Microelectronics Research CenterUniversity of TexasAustinTX 78758USA Coordinated Science Laboratory University of Illinois Urbana-ChampaignUrbanaIL 61801USA

On-chip manipulation of charged particles using electrophoresis or electroosmosis is widely used for many applications,including optofluidic sensing,bioanalysis and macromolecular data storage.We hereby demonstrate a technique for the capture,localization,and release of charged particles and DNA molecules in an aqueous solution using tubular structures enabled by a strain-induced self-rolled-up nanomembrane(S-RuM)platform.Cuffed-in 3D electrodes that are embedded in cylindrical S-RuM structures and biased by a constant DC voltage are used to provide a uniform electrical field inside the microtubular devices.Efficient charged-particle manipulation is achieved at a bias voltage of<2-4 V,which is~3 orders of magnitude lower than the required potential in traditional DC electrophoretic devices.Furthermore,Poisson-Boltzmann multiphysics simulation validates the feasibility and advantage of our microtubular charge manipulation devices over planar and other 3D variations of microfluidic devices.This work lays the foundation for on-chip DNA manipulation for data storage applications.

关键词： electrodes cylindrical planar

Role of electrodes in study of hydrovoltaic effects

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Nano Research 2023年第8期16卷 11320-11325页

作者： Chunxiao Zheng Sunmiao Fang Weicun Chu Jin Tan Bingkun Tian Xiaofeng Jiang Wanlin Guo Key Laboratory for Intelligent Nano Materials and Devices of Ministry of Education State Key Laboratory of Mechanics and Control of Mechanical StructuresNanjing University of Aeronautics and AstronauticsNanjing 210016China Institute for Frontier Science of Nanjing University of Aeronautics and Astronautics Nanjing 210016China

The last decade has witnessed the emergence of hydrovoltaic technology,which can harvest electricity from different forms of water movement,such as raindrops,waves,flows,moisture,and natural evaporation.In particular,the evaporation-induced hydrovoltaic effect received great attention since its discovery in 2017 due to its negative heat emission property.Nevertheless,the influence of electrode reactions in evaporation-induced power generation is not negligible due to the chemical reaction between active metal electrodes and water,which leads to“exceptional”power generation.Herein,we designed a series of experiments based on air-laid paper devices with electrodes of different activities as the top and bottom electrodes.To verify the contribution of electrodes,we compared the output performance of different electrode combinations when the device was partially-wetted and fully-wetted.The device hydrophilicity,salt concentration,and acidity or basicity of solutions were also comprehensively investigated.It is demonstrated that the chemical reaction of active metals(Zn,Cu,Ag,etc.)with different aqueous solutions can generate considerable electrical energy and significantly distort the device performance,especially for Zn electrodes with an output voltage from~1.26 to~1.52 V and current from~1.24 to~75.69μA.To promote the long-term development of hydrovoltaic technology,we recommend use of inert electrodes in hydrovoltaic studies,such as Au and Pt,especially in water and moisture environment.

关键词： hydrovoltaic effects electrodes water electrochemical reaction

Experimental investigation on the effect of surface characterization of electrodes on the gas bubble dynamics in electrolyte flow and performance of FLA batteries by using PIV

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Chinese Journal of Chemical Engineering 2021年第5期34卷 30-39页

作者： Saeed Nahidi Iraj Jafari Gavzan Seyfolah Saedodin Mahmoud Salari Department of Mechanical Engineering Semnan UniversitySemnanIran Department of Mechanical Engineering Imam Hossein UniversityTehranIran

In the flooded lead_acid batteries(FLAB),gas bubbles are initially formed on the surface of the electrodes,which are produced by electrochemical reactions,and then released into the electrolyte.In the present investigation,the effect of surface characterization of electrodes of FLAB on the gas bubble dynamic parameters in the electrolyte flow at different charging/discharging rates(C-rates)are studied utilizing particle image velocimetry(PIV)method.The results show that the capacity of FLAB have a linear behavior due to changes in each of the two parameters of the surface characterization of electrodes and the Crate.At all State of charges(SOCs)of FLAB cells in different tests,increasing average roughness(Ra)and average wavelength of the roughness(λa)in the electrode surfaces,results in an increase in average bubble diameter and bubble rising velocity.Nevertheless,a sharp decrease in the void fraction of bubbles within the electrolyte was observed due to the increment inλa and Ra.Also,the effect of the rising movement of gas bubbles within the electrolyte on the average electrolyte velocity pattern in the gap between the electrodes by changing the surface characterization of electrodes are investigated in detail.

关键词： Particle image velocimetry (PIV) Flooded lead_acid batteries (FLAB) Insoluble gas bubble Electrochemical reactions Surface characterization of electrodes

Generation of sodium hypochlorite (NaOCl) from sodium chloride solution using C/PbO_2 and Pb/PbO_2 electrodes

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International Journal of Minerals,Metallurgy and Materials 2012年第6期19卷 561-566页

作者： Nasser Abu Ghalwa Hassan Tamos Mohamed ElAskalni Abed Rhman El Agha Chemistry Department Al-Azhar University of GazaP.O.Box 1277Palestine

Two modified electrodes （Pb/PbO2 and C/PbO2） were prepared by electrodepositing a lead oxide layer on lead and carbon sub- strates. These modified electrodes were used as anodes for the generation of sodium hypochlorite （NaOC1） from sodium chloride solution. Different operating conditions and factors affecting the treatment process of NaOC1 generation, including current density, pH values, con- ductive electrolytes, and electrolysis time, were studied and optimized. By comparison the C/PbO2 electrode shows a higher efficiency than the Pb/PbO2 electrode for the generation of NaOC1.

关键词： sodium hypochlorite sodium chloride lead oxide electrodeposition electrodes

Investigation of the self-induced magnetic field characteristics in a pulsed plasma thruster with flared electrodes

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Plasma Science and Technology 2020年第3期22卷 46-53页

作者：刘祺杨磊黄玉平赵絮郑再平 Beijing Research Institute of Precise Mechatronics and Controls Beijing 100076People’s Republic of China

The self-induced magnetic field in a pulsed plasma thruster(PPT)with flared electrodes is investigated for a better understanding of the working process and the structural design of the thruster.A two-dimensional model of the magnetic field is built and is validated by comparing the simulated results with the experimental results in literature.The magnetic flux density in the discharge channel during the working process is presented and analyzed regarding the electrode structures.The calculated magnetic field flux density decreases from 0.8 T at the upstream to 0.1 T and below at the downstream in the discharge channel(68 J).The peak of the magnetic flux density over time lags behind the current peak,which provides evidence for the existence of a moving plasma sheet in the discharge process.The magnetic field induced by the current in the extra bending part of the anode enhances the Lorentz force,which acts on the charged particles near the propellant.Finally,the geometric study indicates that the electromagnetic impulse bit does not monotonically increase with the flared angle of the electrodes.Instead,it reaches a maximum at a certain flared angle,which could provide significant suggestions for structural optimization.

关键词： pulsed plasma thruster numerical investigation magnetic flux density flared electrodes