Frequency and temperature dependent electrical characteristics of CaTiO_(3) nano-ceramic prepared by high-energy ball milling
作者机构:School of Electrical EngineeringKIIT UniversityBhubaneswar 751024India Center for NanotechnologyKIIT UniversityBhubaneswar 751024India School of Applied SciencesKIIT UniversityBhubaneswar 751024India
出 版 物:《Journal of Advanced Ceramics》 (先进陶瓷(英文))
年 卷 期:2013年第2卷第3期
页 面:291-300页
核心收录:
学科分类:0808[工学-电气工程] 0809[工学-电子科学与技术(可授工学、理学学位)] 0817[工学-化学工程与技术] 08[工学] 0805[工学-材料科学与工程(可授工学、理学学位)] 080502[工学-材料学] 0702[理学-物理学]
主 题:high-energy ball milling dielectric study impedance spectroscopy thermistor conductivity
摘 要:Nanocrystalline calcium titanate(CT)ceramic has been synthesized by a combination of solid-state reaction and high-energy ball *** nano-ceramic is characterized by X-ray diffraction(XRD),dielectric study and impedance *** XRD pattern shows single phase ceramic of orthorhombic *** frequency-dependent dielectric study shows that the dielectric constant is maximized at low frequencies and decreases with an increase in *** spectroscopy analyses reveal a non-Debye type relaxation phenomenon.A significant shift in impedance loss peaks toward the higher-frequency side indicates conduction in the material favoring the long-range motion of mobile charge *** grain conduction effect is observed from the complex impedance spectrum by the appearance of one semicircular arc in Nyquist *** is also observed that the resistance decreases with an increase in temperature showing a negative temperature coefficient of resistance(NTCR).Various thermistor parameters have been calculated by fitting with Steinhart-Hart *** modulus plots represent the presence of temperature-dependent electrical relaxation phenomenon with the *** frequency-dependent AC conductivity at different temperatures indicates that the conduction process is thermally *** activation energy has been calculated from an Arrhenius plot of DC conductivity and relaxation frequency.