Temperature dependent conductivity of Bi_4Ti_3O_(12) ceramics induced by Sr dopants
Temperature dependent conductivity of Bi_4Ti_3O_(12) ceramics induced by Sr dopants作者机构:Beijing Key Laboratory of Construction Tailorable Advanced Functional Materials and Green ApplicationsSchool of Materials Science and EngineeringBeijing Institute of Technology
出 版 物:《Journal of Advanced Ceramics》 (先进陶瓷(英文))
年 卷 期:2018年第7卷第3期
页 面:256-265页
核心收录:
学科分类:08[工学] 0805[工学-材料科学与工程(可授工学、理学学位)] 080502[工学-材料学]
基 金:supported by National Basic Research Program of China (No. 2016YFB0700502) National Natural Science Foundation of China (No. 51372024)
主 题:dielectric impedance analysis electrical properties defects Aurivillius compound
摘 要:Bi_4Ti_3O_(12) is an important lead-free ferroelectric *** modification of Bi_4Ti_3O_(12)has attracted great attention to improving its *** this work,the effect of Sr dopants on the microstructure,dielectric,and conductivity of Bi_4Ti_3O_(12) ceramic was investigated by XRD,SEM,and AC impedance *** of 1 at%Sr for Bi decreased the grain size,suppressed the dielectric dispersion of Bi_4Ti_3O_(12) ceramic at room temperature,and resulted in different effects on the conductivity of grains and grain *** conductivity of grains in Bi_4Ti_3O_(12) ceramic was increased by the small amount of Sr dopants in the whole experimental temperature *** the grain boundaries of 1 at%Sr-doped Bi_4Ti_3O_(12) exhibited lower conductivity than pure Bi_4Ti_3O_(12) below~380℃and higher conductivity above~380℃.The experimental phenomena were interpreted in term of compensating defects for Sr dopants.