Recent progresses of late-transition metal complexes with nonsymmetric diimine ligands in ethylene polymerization and oligomerization

作     者：Guoliang Mao Yue Jiang Ning Li Qin Wang Dejin Zheng Meijiao Li Yingnan Ning 

作者机构：Provincial Key Laboratory of Oil & Gas Chemical TechnologyCollege of Chemistry and Chemical EngineeringNortheast Petroleum University 

出 版 物：《Chinese Science Bulletin》 (科学通报(英文版))

年 卷 期：2014年第59卷第21期

页      面：2505-2512页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 0703[理学-化学] 

基　　金：supported by the National Natural Science Foundation of China (20972025,U1362110) the China National Petroleum Corporation (CNPC) Innovation Foundation (2013D-5006-0503) the Scientific Research Foundation for the Returned Overseas Chinese Scholars,Heilongjiang Province (41417837-8-08016) the Scientific Research Foundation for Overseas Chinese Scholars,Department of Education of Heilongjiang Province (1154H14) 

主　　题：过渡金属配合物 乙烯聚合 二亚胺 非对称 后期 齐聚 配体 聚合反应速率 

摘      要：Researches of late-transition metal complexes for ethylene polymerization and oligomerization have attracted a lot of attention in the last two decades.A large number of late-transition metal complexes with symmetric diimine ligands have been extensively *** the research of unsymmetric diimine late-transition metal complexes was still in the initial stage,some superior performances were observed in olefin *** developments in the research of ethylene polymerization and oligomerization catalyzed by late-transition metal complexes with unsymmetric diimine ligands were summarized in this review,with the influence of complex structure on the catalytic performance of the catalyst analyzed.