CONTINUOUS THERMODYNAMICS FOR POLYMER SOLUTIONS ***-PACKED LATTICE MODEL

作     者：胡英 英徐根 D.T.Wu J.M.Prausnitz 

作者机构：Marshall LaboratoryE.I.Du Pont de Nemours & Company PhiladelphiaPA 19146USA Department of Chemical EngineeringUniversity of CaliforniaBerkeley BerkeleyCA 94720USA 

出 版 物：《Chinese Journal of Chemical Engineering》 (中国化学工程学报（英文版）)

年 卷 期：1994年第2卷第3期

页      面：4-18页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

主　　题：continuous thermodynamics polymer solution polydispersity lattice model cloud-point curve shadow curve spinodal critical point 

摘      要：using close-packed lattice models,a continuous thermodynamic framework is presented forphase-equilibrium calculations for binary solutions with a polydisperse polymer *** expressionfor the Helmholtz function of mixing is based on the revised Freed model developed *** parameter c_r and an energy parameter ε are used;the former can be temperature dependent,while the latter can depend on both temperature and chain-length of the *** discretemulticomponent approach is adopted to derive expressions for chemical potentials,spinodals and criti-cal *** continuous distribution function is then used in calculations of moments occurring inthose *** programs are established for cloud-point-curve,shadow-curve,spinodal and critical-point calculations for polymer solutions with standard distribution or arbitrarydistribution of *** the latter case,the derivative method developed previously is *** for phase-equilibrium calculations are