Cu(OAc)_(2)-Mediated Synthesis of Fullerodihydropyridine-3-ones via the Reaction of[60]Fullerene with β-Substituted Ethylamines in the Absence or Presence of Arylacetaldehydes
作者机构：State Key Laboratory of Biocatalysis and Enzyme EngineeringSchool of Life SciencesHubei UniversityWuhanHubei430062 China State Key Laboratory of Magnetic Resonance and Atomic and Molecular PhysicsWuhan Center for Magnetic ResonanceWuhan Institute of Physics and MathematicsInnovation Academy for Precision Measurement Science and TechnologyChinese Academy of SciencesWuhanHubei430071 China Collaborative Innovation Center for Advanced Organic Chemical Materials Co-constructed by the Province and MinistryMinistry of Education Key Laboratory for the Synthesis and Application of Organic Functional MoleculesCollege of Chemistry and Chemical EngineeringHubei UniversityWuhanHubei430062 China
出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)
年 卷 期：2023年第41卷第13期
页 面：1557-1565页
核心收录：
学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学]
基 金：grateful for the financial support from the National Natural Science Foundation of China(No.22271083) the Open Project Funding of the State Key Laboratory of Biocatalysis and Enzyme Engineering(No.SKLBEE2021026) the Innovation and Entrepreneurship Training Program for Undergraduates of Hubei University(No.X202210512001)
主 题：Fullerenes Copper β-Substituted ethylamines Arylacetaldehydes Fullerodihyd ropyridine-3-ones Radical reactions
摘 要：A series of unreported fullerodihydropyridine-3-ones were synthesized as a new family of fullerene derivatives in moderate to good yields by a simple one-step reaction of[60]fullerene with cheap and readily available β-substituted ethylamines in the absence or presence of arylacetaldehydes under the assistance of Cu(OAc)_(2).The in situ generation of arylacetaldehydes by the C—N bond cleavage of arylethylamines avoided their complex synthesis in advance and realized the preparation of fullerodihydropyridine-3-ones with structural and functional diversities,which may have promising applications in perovskite solar cells to improve the performance of photovoltaic devices due to the existence of a largeπ-conjugated system on the dihydropyridine-3-one ring.
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