Asymmetric Catalytic Polymerization: Advances and Challenges

作     者：Xiao-Bing Lu Xiao-Bing Lu

作者机构：State Key Laboratory of Fine ChemicalsFrontiers Science Center for Smart MaterialsDalian University of Technology 

出 版 物：《高分子科学：英文版》 (Chinese Journal of Polymer Science)

年 卷 期：2023年第41卷第1期

页      面：1-2页

核心收录：

学科分类：08[工学] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 0703[理学-化学] 

主　　题：precise Catalytic bones 

摘      要：Most naturally occurring biomacromolecules are optically active owing to their unique chiral structural units and/or helical conformations.Some of them show specific functionalities,such as supersensitive responses to external stimuli,highly selective recognition abilities,superior mechanical properties,and excellent catalytic activity under extremely mild conditions.These functionalities result from the unique chiral structural units and orderly arrangement of building blocks in the main-chain backbones of these biological macromolecules,such as enzymes,genes,and proteins.Indeed,the sequence and stereochemistry of the repeating units in a polymeric chain also have significant influence on their material performance.Therefore,construction of functional polymers with precise control of chirality and sequence,similar to those in living systems,is of great significance.