Self-assembly of 3p-Block Metal-based Metal-Organic Frameworks from Structural Perspective

作     者：QIAO Junyi LIU Xinyao ZHANG Lirong LIU Yunling QIAO Junyi;LIU Xinyao;ZHANG Lirong;LIU Yunling

作者机构：State Key Laboratory of Inorganic Synthesis and Preparative ChemistryCollege of ChemistryJilin UniversityChangchun 130012P.R.China Sinochem Holdings Corporation Ltd.Beijing 100031P.R.China 

出 版 物：《Chemical Research in Chinese Universities》 (高等学校化学研究（英文版）)

年 卷 期：2022年第38卷第1期

页      面：31-44页

核心收录：

学科分类：08[工学] 080502[工学-材料学] 0805[工学-材料科学与工程（可授工学、理学学位）] 

基　　金：This work was supported by the National Natural Science Foundation of China(No. 21771078) 

主　　题：Metal-organic framework 3p-Block metal Secondary building unit Structure Self-assembly 

摘      要：Metal-organic frameworks(MOFs) are a class of porous inorganic-organic hybrid materials, which are constructed from diverse inorganic building units and multi-functional organic ligands. Highly ordered pore structures and tailored functionalization have made MOF materials potential for applications in many fields. Among various MOF materials, 3p-block metal(Al, Ga, and In)-based MOFs exhibit higher chemical stability than divalent transition metal-based MOFs due to their higher valence. In this review, Al-MOFs and In-MOFs were mainly discussed from the perspective of categories of inorganic building blocks, coordination types, and numbers of organic ligands. This review will give intuitive guidance to the design and synthesis of novel 3p-block metal-based MOFs with potential applications.