Organic additives in all-inorganic perovskite solar cells and modules:from moisture endurance to enhanced efficiency and operational stability

作     者：Yameen Ahmed Bilawal Khan MBilal Faheem Keqing Huang Yuanji Gao Junliang Yang Yameen Ahmed;Bilawal Khan;M.Bilal Faheem;Keqing Huang;Yuanji Gao;Junliang Yang

作者机构：State Key Laboratory of Powder MetallurgySchool of Physics and ElectronicsCentral South UniversityChangsha 410083HunanChina Department of Materials Science and EngineeringCity University of HongkongHongkong SAR 999077China Institute of Fundamental and Frontier SciencesUniversity of Electronic Science and Technology of ChinaChengdu 610054SichuanChina 

出 版 物：《Journal of Energy Chemistry》 (能源化学（英文版）)

年 卷 期：2022年第31卷第4期

页      面：361-390页

核心收录：

学科分类：08[工学] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 080502[工学-材料学] 0813[工学-建筑学] 0703[理学-化学] 

基　　金：supported by the National Key Research and Development Program of China(2017YFA0206600) the National Natural Science Foundation of China(52173192) the Science and Technology Innovation Program of Hunan Province(2020RC4004) the Special Funding for the Construction of Innovative Provinces in Hunan Province(2020GK2024) 

主　　题：Perovskite solar cells Organic additives Chemical instability Phase segregation Modules 

摘      要：Power conversion efficiency(PCE) of perovskite solar cells(PSC) has been skyrocketed to certified 25.5% owing to their improved and tunable optoelectronic properties. Although, various strategies have been adopted to date regarding PCE and stability enhancement within PSC technology, certain instability factors(moisture, heat, light) are hindering their commercial placement. Recently, all-inorganic PSCs got hype in the photovoltaic research community after they attained PCE 20% and due to their significant endurance against heat and light mishmashes, but there only left moisture sensitivity as the only roadblock for their industrial integration. Here, we review the recent progress of additive inclusion into allinorganic(CsPbX_(3)) PSCs to stabilize their intrinsic structure and to withstand the performance limiting factors. We start with the detailed description of chemical instability of different perovskite compositions, phase segregation, and how organic molecules and dyes help to repair the structural defects to improve the overall PCE and stability of PSCs. Moisture endurance as a result of chemical passivation through organic additives, low-dimensional inorganic PSCs to enhance device stability and scalable fabrication of CsPbX_(3) PSCs are also reviewed. The challenges of module degradation and design implications with proposed strategies and outlook are interpreted in the ending phrases of this review.