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Wastewater treatment using Fe-doped perovskite manganites by photocatalytic degradation of methyl orange,crystal violet and indigo carmine dyes in tungsten bulb/sunlight

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稀土学报:英文版 2023年第9期41卷 1311-1322,I0002页

作者： Brajendra Singh Priyanka Singh Saiqua Siddiqui Divyanshu Singh Mukul Gupta Materials Chemistry Lab Centre of Material SciencesUniversity of AllahabadPrayagraj21002India ugc-dae consortium for scientific research University CampusKhandwa Road Indore452001India

We documented(ⅰ) the decolorization of wastewater in visible light,which contains methyl orange,crystal violet and indigo carmine dyes,using La_(0.7)Sr_(0.3)Mn_(1-x)Fe_(x)O_(3)(x=0.0,0.05,0.1 and 0.5) manganites and(ⅱ) efficient separation of photocatalysts from water using magnetic *** ceramic photocatalysts were sintered at 1050℃ for 12 *** were characterized by X-ray diffraction(XRD),soft X-ray absorption spectroscopy(SXAS),Fourier transform infrared spectroscopy(FTIR) and UV-visible diffuse reflectance spectroscopy(DRS).SXAS studies show the presence of Mn(Mn^(3+)/Mn^(4+)) and Fe(Fe^(3+)/Fe^(4+)) mixes valences in Fe-doped *** band gap is found in visible light range for La_(0.7)Sr_(0.3)Mn_(1-x)Fe_(x)O_(3)(x=0.0,0.05,0.1) ***_(0.7)Sr_(0.3)MnO_(3) degrades 94.6% methyl orange in7 min,81.9% crystal violet in 10 min and 99.1% indigo carmine in 5 ***_(0.7)Sr_(0.3)Mn_(0.9)Fe_(0.1)O_(3) degrades the 92.6% methyl orange dye solution in 9 min,94.8% crystal violet in 25 min and 97.1% indigo carmine in3 *** and Fe doped manganites can be separated in 60 s from wastewater.

关键词： Synchrotron X-ray absorption Dye degradation Magnetic separation Mixed valences Rare earths Wastewater treatment

A catalyst-free new polyol method synthesized hot-pressed Cu-doped Bi2S3 nanorods and their thermoelectric properties

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Nano research 2016年第11期9卷 3291-3304页

作者： Tarachand Vikash Sharma Ranu Bhatt Vedachalaiyer Ganesan Gunadhor Singh Okram ugc-dae consortium for scientific research Indore 452001 India Technical Physics Division Bhabha Atomic Research Centre Mumbai 400085 India

This is the first report on the thermoelectric properties of a catalyst-free polyol method used to prepare stoichiometric Bi2-xCuxS3 samples, x = 0.1, 0.2, 0.3, 0.4, via hot pressing. Various systematic approaches to arrive at in their stoichiometric compositions are explored precisely with introduction of excess precursor of S. X-ray diffraction data analysis using Rietveld refinement confirms a polyhedral orthorhombic crystal structure with a space group Pnma, in contrast to Pbnm reported earlier. Raman data further substantiates this. X-ray photoelectron spectroscopy confirms the valence states of the constituent elements （Bi^3＋, Cu^2＋, and S^2-） and energy dispersive X-ray analysis corroborates their compositions. The particle sizes of the pure Bi2S3 nanoparticles were 20, 35, and 82 nm as determined from the Scherrer formula, atomic force microscopy, and dynamic light scattering, respectively. Their transmission electron microscopy image shows rod-like nanostructures elongated in the 〈010〉 direction with an average diameter of 23 nm and a length of several hundreds of nanometers. A 34% improvement in the thermoelectric figure of merit is observed for Bi.6Cu0.4S3 as compared to pure Bi2S3 at 300 K.

关键词： Bi2S3 polyol nanorods thermoelectrics

Dielectric relaxation and conduction mechanism in Aurivillius ceramic Bi_(5)Ti_(3)FeO_(15)

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International Journal of Minerals,Metallurgy and Materials 2021年第6期28卷 1063-1071页

作者： Rasmita Jena K.Chandrakanta P.Pal Md.F.Abdullah S.D.Kaushik A.K.Singh Department of Physics and Astronomy National Institute of Technology RourkelaRourkela-769008OdishaIndia ugc-dae consortium for scientific research mumbai centre BARCMumbai-400085India

For this study,we synthesized Aurivillius Bi_(5)Ti_(3)FeO_(15) ceramic using the generic solid-state reaction route and then performed roomtemperature X-ray diffraction to confirm that the compound had a single phase with no *** surface morphology of the prepared sample was observed to contain microstructural grains approximately 0.2–2μm in *** dielectric properties of the sample were determined as a function of frequency in a range of approximately 100 Hz to 1 MHz at various temperatures(303 K≤T≤773 K).Nyquist plots of the impedance data were found to exhibit a semi-circular arc in the high-temperature region,which is explained by the equivalent electrical circuit(R_(1)C_(1))(R_(2)QC_(2)),where R_(1) and R_(2) represent the resistances associated with the grains and grain boundaries,respectively,C_(1) and C_(2) are the respective capacitances,and Q is the constant phase element(CPE),which accounts for non-Debye type of *** results indicate that both the resistance and capacitance of the grain boundaries are more prominent than those of the *** alternating current(ac)conductivity data were analyzed based on the Jonscher universal power law,which indicated that the conduction process is dominated by the hopping *** calculated activation energies of the relaxation and conduction processes were very similar(0.32 to 0.53 eV),from which we conclude that the same type of charge carriers are involved in both processes.

关键词： Nyquist plot impedance spectroscopy activation energy ac conductivity hopping

Optical characterization of nano-sized organic carbon particles emitted from a small gasoline engine

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Particuology 2013年第3期11卷 249-255页

作者： Bireswar Paul Amitava Datta Aparna Datta Abhijit Saha Department of Power Engineering Jadavpur University ugc-dae consortium for scientific research

The nano-sized organic carbon （NOC） particles emitted from a small gasoline engine were characterized using various ex situ optical techniques to assess their hazardous impact. The exhaust gas was sampled iso-kinetically by a quartz probe and passed through de-ionized water to gather the hydrophilic car- bonaceous particulates as hydrosol. The hydrodynamic diameter of the particles ranged between 1.7 and 3.6 nm at no load, with a mean diameter of 2.4 nm. The particle size in the engine exhaust was found to increase at higher loads, which is attributed to coagulation of the particles. The chemical structure of the particles was analyzed using UV-vis and infra-red spectroscopy. Both the band gap energy and oscillator strength data evaluated from the UV-vis absorbance showed that the NOC particles contained polyaromatic hydrocarbon structures with three to five aromatic rings. Infra-red spectroscopy analysis further confirmed the presence of aliphatic and carbonyl functionalities in the aromatic structures of the particles. The fine size of the particles, their high number concentration for the type of the engine under study and their structural features, make the particles extremely hazardous for environment and health.

关键词： Gasoline engine Combustion Emission Carbon nano-particle Characterization

Effect of Co substitution on the structural,dielectric and optical properties of KBiFe_(2)O_(5)

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International Journal of Minerals,Metallurgy and Materials 2021年第11期28卷 1861-1867页

作者： K.Chandrakanta R.Jena P.Pal Md.F.Abdullah S.D.Kaushik A.K.Singh Department of Physics and Astronomy National Institute of TechnologyRourkela-769008OdishaIndia ugc-dae consortium for scientific research mumbai centre R-5 ShedBARCMumbai-400085India

Cobalt(Co)-modified brownmillerite KBiFe_(2)O_(5)(KBFO;[KBiFe_(2(1−x))Co_(2x)O_(5)(x=0,0.05)])polycrystalline is synthesized following the solid-state reaction *** refinement of X-ray diffraction data confirmed the phase purity of KBFO and KBiFe_(1.9)Co_(0.1)O_(5)(KBFCO).The optical bandgap energy(Eg)of KBFO decreased from 1.59 to 1.51 eV because of Co *** decrease in bandgap can be attributed to the tilting of the Fe–O tetrahedral structure of *** observed room-temperature Raman peaks of KBFCO shifted by 3 cm^(−1) toward a lower wavenumber than that of *** shift in Raman active modes can be attributed to the change in the bond angles and bond lengths of the Fe–O tetrahedral structure and modification in response to oxygen deficiency in KBFO because of Co *** with that of KBFO,the frequency-dependent dielectric constant and dielectric loss of KBFCO decrease at room temperature,which is a consequence of the reduction in oxygen migration and modification in response to vibrational modes present in the sample.

关键词： brownmillerite rietveld refinement Raman spectroscopy bandgap

Tissue-specific trace elements concentration and human health risk assessment in three marine fish species from Visakhapatnam to Kakinada coasts

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Radiation Detection Technology and Methods 2023年第4期7卷 611-626页

作者： A.Jaya Sree A.Srinivasulu Tanushree Panigrahi B.Aruna Jaganmoy Biswas A.D.P.Rao Department of Nuclear Physics Andhra UniversityVisakhapatnamAndhra PradeshIndia Department of Chemistry Gitam UniversityVisakhapatnamAndhra PradeshIndia ugc-dae consortium for scientific research KolkataIndia

Purpose The current study was aimed to evaluate the bioaccumulation of elements(As,Cd,Cu,Fe,Mn,Se and Zn)in the gills,liver and muscle of three distinct marine fish species,namely Nemipterus japonicas,Upeneus vittatus and Pampus argenteus species were collected from Visakhapatnam to Kakinada coastal *** The fish tissues were analyzed for trace metals using energy-dispersive X-ray fluorescence(EDXRF).To ensure the quality control,reliability of the experimental validation,two certified reference materials(CRMs)procured from National Institute of Standards and Testing(NIST SRM 1577c-Bovine Liver)and European Commission-Joint research centre,Institute for Reference Materials and Measurements(ERMBB422-Fish muscle)were analyzed using *** The evaluated estimated daily intake(EDI)values for each metal are below the reference dose levels established by World Health Organisation(WHO).The target hazard quotient(THQ)values of both the locations of the present study are lower than one(1)showing the presence of health *** cancer risk(CR)factor value for arsenic was below the acceptable lifetime carcinogenic risk(10^(–5)).The levels of heavy metals varied significantly among three fish species and *** mean concentrations of As,Cd,Cu,Fe,Mn,Se and Zn were slightly higher than the Ministry of Agriculture,Fisheries and Food(MAFF),Food and Agriculture Organization(FAO),Turkish food codex and Brazilian Legislation standard *** findings of this study revealed that muscles possessed the lowest concentrations mostly of all the metals when compared with liver and *** The study concluded that consumption of the muscle tissue may not pose severe health risk to human health but should be consumed moderately to prevent bioaccumulation of the metals especially As.

关键词： Health risk assessment Marine fish species-Trace elements Tissue specific

快速热处理化学气相沉积法制备用于电子产品热管理的轻质柔性石墨烯

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新型炭材料（中英文） 2023年第3期38卷 534-542页

作者： Satendra Kumar Manoj Goswami Netrapal Singh Uday Deshpande Surender Kumar N.Sathish Academy of scientific and Innovative research(AcSIR) Ghaziabad 201002India CSIR-Advanced Materials and Processes research Institute(AMPRI) Bhopal 462026India ugc-dae consortium for scientific research University CampusIndore 452001India

下一代电子产品的飞速发展对热管理提出了更高的要求。初始石墨烯的导热性是铜的13倍。本文通过快速热处理化学气相沉积(RTP-CVD)法制备了具有大sp^(2)结构域的单层、双层和多层石墨烯(SLG、BLG、FLG),进一步通过低浓度H_(2)还原制备了... 详细信息

下一代电子产品的飞速发展对热管理提出了更高的要求。初始石墨烯的导热性是铜的13倍。本文通过快速热处理化学气相沉积(RTP-CVD)法制备了具有大sp^(2)结构域的单层、双层和多层石墨烯(SLG、BLG、FLG),进一步通过低浓度H_(2)还原制备了高导热石墨烯。在1000℃下生长25 min制备出SLG,利用拉曼光谱和透射电子显微镜(TEM)研究了石墨烯的品质。为了验证RTP-CVD法生成的石墨烯的散热能力,将其作为2TB固态硬盘的散热器,通过红外热成像仪进行了研究。结果证明,RTP-CVD生长的石墨烯用于消费电子产品的热管理测试时性能表现优异。SLG显示温度(最高)比商用铜散热器低5℃,SLG的散热能力比商用铜散热器快200倍左右。综上,利用RTP-CVD法制备的轻质的柔性石墨烯可以成为下一代5G设备和消费电子产品热管理的更好选择。

关键词：石墨烯热管理消费类电子产品化学气相沉积

Competition between axial anomaly and ferromagnetic ordering in Bi_(2-x)Fe_(x)Se_(3-x)S_(x) topological insulator:A study of magnetic and magnetotransport properties

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Journal of Materiomics 2022年第3期8卷 669-677页

作者： Rahul Singh Shiv Kumar A.Jain Mahima Singh Labanya Ghosh A.Singh Soma Banik A.Lakhani S.Patil E.F.Schwier K.Shimada S.M.Yusuf Sandip Chatterjee Solid State Physics Division Bhabha Atomic Research CenterTrombayMumbai400085India Hiroshima Synchrotron Radiation Center HiroshimaJapan Homi Bhabha National Institute AnushaktinagarMumbai400094India Department of Physics Indian Institute of Technology(BHU)Varanasi221005India Synchrotrons Utilization Section Raja Ramanna Centre for Advanced TechnologyIndore452013India ugc-dae consortium for scientific research IndoreMadhya Pradesh452017India Department of CMP&MS Tata Institute of Fundamental ResearchMumbai400005India

The topological insulators Bi_(2-x)Fe_(x)Se_(3-x)S_(x) have been investigated by the dc-magnetization,magnetotransport and angle resolved photoemission spectroscopy(ARPES)*** doping of Fe and S,a negative giant magneto-resistance(MR)is observed for parallel electric and magnetic fields(H||E).The MR behavior at lower magnetic field can be explained with the semi-classical theory whereas the MR behavior at higher field has been attributed to the axial ***,the system reached to the quantum limit at low magnetic field(~4.5T).The magnetic ordering can be explained with the presence of both the RKKY(surface)and van-Vleck(bulk)*** ARPES study reveals that a surface gap is suppressed when the magnetic ordering changes from ferromagnetic to anti-ferromagnetic *** ARPES study and the appearance of quantum oscillations(SdH)in the resistivity pattern reveal that the topological surface property is preserved with the co-doping of Fe and S.

关键词： Spintronics Magnetoresistance Magnetism Topological insulators RKKY interaction ARPES study

Maximizing the mechanical performance of Ti_(3)AlC_(2)-based MAX phases with aid of machine learning

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Journal of Advanced Ceramics 2022年第8期11卷 1307-1318页

作者： Xingjun DUAN Zhi FANG Tao YANG Chunyu GUO Zhongkang HAN Debalaya SARKER Xinmei HOU Enhui WANG Beijing Advanced Innovation Center for Materials Genome Engineering Collaborative Innovation Center of Steel TechnologyUniversity of Science and Technology BeijingBeijing 100083China Fritz-Haber-Institut der Max-Planck-Gesellschaft Faradayweg 4-6Berlin 14195Germany ugc-dae consortium for scientific research University CampusKhandwa RoadIndore 452001India

Mechanical properties consisting of the bulk modulus,shear modulus,Young’s modulus,Poisson’s ratio,etc.,are key factors in determining the practical applications of MAX *** mechanical properties are mainly dependent on the strength of M–X and M–A *** this study,a novel strategy based on the crystal graph convolution neural network(CGCNN)model has been successfully employed to tune these mechanical properties of Ti_(3)AlC_(2)-based MAX phases via the A-site substitution(Ti_(3)(Al1-xAx)C_(2)).The structure–property correlation between the A-site substitution and mechanical properties of Ti_(3)(Al1-xAx)C_(2)is *** results show that the thermodynamic stability of Ti_(3)(Al1-xAx)C_(2)is enhanced with substitutions A=Ga,Si,Sn,Ge,Te,As,or *** stiffness of Ti_(3)AlC_(2)increases with the substitution concentration of Si or As increasing,and the higher thermal shock resistance is closely associated with the substitution of Sn or *** addition,the plasticity of Ti_(3)AlC_(2)can be greatly improved when As,Sn,or Ge is used as a *** findings and understandings demonstrated herein can provide universal guidance for the individual synthesis of high-performance MAX phases for various applications.

关键词： Ti_(3)(Al1−xAx)C_(2) crystal graph convolution neural network(CGCNN)model stability mechanical properties