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Nano Research 2025年第1期18卷 236-248页

作者： Yuchen Wang Kai Rong Shanlei Chang Youxing Fang Shaojun Dong State key laboratory of electroanalytical chemistry Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchun 130022China School of Applied chemistry and Engineering University of Science and Technology of ChinaHefei 230026China College of chemistry Jilin UniversityChangchun 130012China

The catalytic conversion of glucose to high valueadded platform chemical 5-hydroxymethylfurfural(HMF)is a promising biorefinery process,and alumina-boria catalysts are considered to be green and mild solid acid catalysts for this catalytic ***,compared to the common synthesis methods with complicated steps,we reported a simple and efficient strategy to prepare B_(2)O_(3)-Al_(2)O_(3)nanocomposites by calcining cost-effective glucose-urea deep eutectic solvent(DES)solution containing the *** prepared B_(2)O_(3)-Al_(2)O_(3)nanocomposites exhibited an open three-dimensional skeleton and two-dimensional porous lamellar substructure,endowing them with a high specific surface area(228.27 m2/g).The introduction of boron changed the ratios of different aluminum species(AlⅣ,AlⅤ,and AlⅥ)and borate species(BO3 and BO4),thus further affecting the acidity and the types of acid sites of the *** prepared B_(2)O_(3)-Al_(2)O_(3)bifunctional acid catalysts possessing abundant Lewis acid sites and adjustable Brønsted acid sites showed complete glucose conversion and 55.38%of HMF yield under the optimum *** study proposed a concise method to synthesize alumina-boria solid acid catalysts assisted by glucose-urea *** hope to extend the application and prospect of this efficient and simple synthesis strategy.

关键词： 5-hydroxymethylfurfural(HMF) deep eutectic solvent glucose alumina-boria acid catalyst

Amplified DNA Detection Sensitivity Using Streptavidin-Biotinylated Protein Complex: Characterization by Electrochemical Impedance Spectroscopy

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Chinese Journal of chemistry 2003年第10期21卷 1344-1348页

作者：程志亮杨帆黄海珍杨秀荣 State key laboratory of electroanalytical chemistry

Thiol terminated oligonucleotide was immobilized to gold surface by self assembly method. A novel amplification strategy was introduced for improving the sensitivity of DNA hybridization using biotin labeled protein streptavidin network complex. This complex can be formed in a cross linking network of molecules so that the amplification of the response signal will be realized due to the big molecular size of the complex. It could be proved from the impedance technique that this amplification strategy caused dramatic improvement of the detection sensitivity. These results give significant advances in the generality and sensitivity as it is applied to biosensing.

关键词： DNA hybridization amplification biotin streptavidin electrochemical impedance spectroscopy

3-Mercaptopropionic Acid Capped Gold Nanoclusters: Quantized Capacitance in Aqueous Media

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Chinese Journal of chemistry 2003年第4期21卷 392-395页

作者：李迪李景虹 State key laboratory of electroanalytical chemistry Changchun Institute of Applied Chemistry State key laboratory of electroanalytical chemistry Changchun Institute of Applied Chemistry

Mercaptopropionic acid monolayer protected gold nanoclusters (MPA MPCs) were synthesized and characterized by transmission electron microscopy, UV Vis spectroscopy, X ray photoelectron spectroscopy and Fourier transform infrared spectroscopy. The exact value of quantized double layer capacitance of MPCs in aqueous media was obtained by differential pulse voltammograms.

关键词： gold nanoparticle quantized double layer capacitance aqueous media

Toxicity detection of sodium nitrite,borax and aluminum potassium sulfate using electrochemical method

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Journal of Environmental Sciences 2013年第4期25卷 785-790页

作者： Dengbin Yu Daming Yong Shaojun Dong State key laboratory of electroanalytical chemistry Changchun Institute of Applied ChemistryChinese Academy of Sciences

Based on the inhibition effect on the respiratory chain activity of microorganisms by toxicants, an electrochemical method has been developed to measure the current variation of a mediator in the presence of microorganisms contacted with a toxicant. Microelectrode arrays were adopted in this study, which can accelerate the mass transfer rate of an anaiyte to the electrode and also increase the total current signal, resulting in an improvement in detection sensitivity. We selected Escherichia coli as the testee and the standard glucose- glutamic acid as an exogenous material. Under oxygen restriction, the experiments in the presence of toxicant were performed at optimum conditions （solution pH 7.0, 37℃ and reaction for 3 hr）. The resulting solution was then separated from the suspended microorganisms and was measured by an electrochemical method, using ferricyanide as a mediator. The current signal obtained represents the reoxidation of ferrocyanide, which was transformed to inhibiting efficiency, IC50, as a quantitative measure of toxicity. The IC50 values measured were 410, 570 and 830 mg/L for sodium nitrite, borax and aluminum potassium sulfate, respectively. The results show that the toxicity sequence for these three food additives is consistent with the value reported by other methods. Furthermore, the order of damage degree to the microorganism was also observed to be： sodium nitrite 〉 borax 〉 aluminum potassium sulfate 〉 blank, according to the atomic force microscopy images of E. coli after being incubated for 3 hr with the toxic compound in buffer solutions. The electrochemical method is expected to be a sensitive and simple alternative to toxicity screening for chemical food additives.

关键词： food additives sodium nitrite borax aluminum potassium sulfate microelectrode arrays

Low-temperature synthesis of nitrogen doped carbon nanotubes as promising catalyst support for methanol oxidation

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Journal of Energy chemistry 2019年第1期28卷 118-122页

作者： Liang Liang Meiling Xiao Jianbing Zhu Junjie Ge Changpeng Liu Wei Xing laboratory of Advanced Power Sources Changchun Institute of Applied Chemistry Chinese Academy of Sciences University of Chinese Academy of Sciences Jilin Province key laboratory of Low Carbon Chemical Power Sources statestate key laboratory of electroanalytical chemistry Changchun Institute of Applied Chemistry Chinese Academy of Sciences

The electrochemical methanol oxidation reaction(MOR) is of paramount importance for direct methanol fuel cell(DMFC) application, where efficient catalysts are required to facilitate the complicated multiple charge transfer process. The catalyst support not only determines the dispersion status of the catalysts particles, but also exerts great influence on the electronic structure of the catalysts, thereby altering its intrinsic activity. Herein, we demonstrated that nitrogen atoms, assisted by the pre-treatment of carbon matrix with oxidants, can be easily doped into carbon nanotubes at low temperature. The obtained nitrogen-doped carbon nanotubes can effectively improve the dispersion of the supported platinum nanoparticles and facilitate the MOR by modifying the electronic structure of platinum atoms,through catalyst-support interaction.

关键词： Methanol oxidation Carbon nanotubes Hydrothermal method Nitrogen doping

Label-free surface-enhanced infrared spectro-electro-chemical analysis of the Redox potential shift of cytochrome c complexed with a cardiolipin-containing lipid membrane of varied composition

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Chinese Physics B 2015年第12期24卷 91-97页

作者：刘丽武烈曾丽姜秀娥 State key laboratory of electroanalytical chemistry Changchun Institute of Applied ChemistryChinese Academy of Sciences

In this study, a lipid membrane was fabricated by fusing cardiolipin-phosphatidylcholine（CL_PC, 1：4） vesicles onto a hydrophobic surface of 1-dodecanethiol（DT） preadsorbed on a nanostructured gold film. By changing the concentration of the DT adsorption solution, we constructed a series of CL PC-DT bilayers with different hydrophobicity to study the effects of lipid membrane characteristics on the adsorption conformation of cytochrome c（Cyt c）. Electrochemical analysis showed that the formal potential is 0.24 V for Cyt c-CL_PC-DT（10）, 0.2 V for Cyt c-CL_PC-DT（20）, and 0.16 V for Cyt c-CL_PC-DT（40） — a gradual positive shift with the decreasing DT concentration — relative to the potential of native cyt c（0.02 V）. Potential-induced surface-enhanced infrared adsorption difference spectroscopy revealed that the gradual positive shift of the formal potential of CL-bound cyt c is determined by the environment with the gradually lowered dielectric constant for the heme cofactor in CL-bound cyt c（Fe^3＋）.

关键词： cytochrome c cardiolipin surface-enhanced infrared adsorption spectroscopy protein-solvent interaction

Nanoparticulate X-ray CT contrast agents

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Science China chemistry 2015年第5期58卷 753-760页

作者： Wenya He Kelong Ai Lehui Lu State key laboratory of electroanalytical chemistry Changchun Institute of Applied chemistry Chinese Academy of Sciences

X-ray computed tomography(CT) has been widely used as a powerful diagnostic tool in clinics because it can provide high-resolution 3D tomography of the anatomic structure based on the distinctive X-ray absorptions between different tissues. Currently, CT contrast agents are mainly small iodinated molecules, which suffer from drawbacks such as short blood- retention time, nonspecific in vivo biodistribution, and renal toxicity. Utilization of nanoparticles as potential CT contrast agents to overcome the aforementioned issues has advanced rapidly. In this mini review, we introduce current research efforts in the development of nanoparticulate CT contrast agents and discuss the challenges for additional breakthroughs in this field.

关键词： X-ray computed tomography (CT) contrast agents nanoparticles iodine

Luminescent nanoscale metal–organic frameworks for chemical sensing

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Chinese Chemical Letters 2015年第12期26卷 1439-1445页

作者： Xiao-Yan Ren Le-Hui Lu State key laboratory of electroanalytical chemistry Changchun Institute of Applied Chemistry Chinese Academy of Sciences

Metal–organic frameworks（MOFs） are a fascinating class of crystalline materials constructed from selfassembly of metal cations/clusters and organic ligands. Both metal and organic components can be used to generate luminescence, and can further interact via antenna effect to increase the quantum yield,providing a versatile platform for chemical sensing based on luminescence emission. Moreover, MOFs can be miniaturized to nanometer scale to form nano-MOF（NMOF） materials, which exhibit many advantages over conventional bulk MOFs in terms of the facile tailorability of compositions, sizes and morphologies, the high dispersity in a wide variety of medium, and the intrinsic biocompatibility. This review will detail the development of NMOF materials as chemical sensors, including the synthetic methodologies for designing NMOF sensory materials, their luminescent properties and potential sensing applications.

关键词： luminescent nanometer luminescence crystalline facile sizes fascinating microemulsion nucleation encapsulation

Study of the Ion Channel Behavior of Didodecyldimethylammonium Bromide Formed Bilayer Lipid Membrane Stimulated by PF_6^-

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Chinese Journal of chemistry 2003年第1期21卷 62-65页

作者：佟月红韩晓军汪尔康 State key laboratory of electroanalytical chemistry Changchun Institute of Applied Chemistry Chinese Academy of Sciences

Bilayer lipid membranes (BLM) formed from didodecyldimethylammonium bromide were made on the freshly exposed surface of a glassy carbon (GC) and were demonstrated by the ac impedance spectroscopy. The ion channels of membrane properties induced by PF -_6 were studied by the cyclic voltammetric methods. Experimental results indicated that the ion channel of BLM was open in the presence of the PF -_6 due to the interaction of PF -_6 with the BLM, while it was switched off in the absence of PF -_6. Because the ion channel behavior was affected by the concentration of PF -_6, a sensor for PF -_6 can be developed.

关键词： ion channel bilayer lipid membrane hexafluorophos-phate anions (PF -_6) tris(2,2′-bipyridine)ruthenium(II) chloride

Phenylboronic acid and dopamine as probe set for electrochemical detection of saccharides

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Chinese Chemical Letters 2013年第4期24卷 291-294页

作者： Jian Li Ya-Qin Sun Yin-Mao Wei Jian-Bin Zheng Institute of Analytical Science/Shaanxi key laboratory of electroanalytical chemistry Northwest University

A novel electrochemical approach for detection of saccharides via indicator displacement assay was presented. In this system, 2-fluorophenylboronic acid and dopamine （DA） were performed as probe set. The electrochemical properties of DA and the binding to 2-fluorophenylboronic acid in phosphate buffer at different pH values were investigated by cyclic voltammetry. After addition of fructose to the solution, a competition for the binding 2-fluorophenylboronic acid occurred that led to the release of the DA. The regenerate oxidation current of DA increased with increasing fructose concentration. Under optimized experimental conditions, the peak current was linearly related to fructose concentration in the range of 0.3-5.0 mmol[L with a detection limit of 0.1 mmolJL In addition, the interaction between 2- fluorophenylboronic acid and other cis-diol compounds such as glucose, galactose and mannose was investigated.

关键词： ElectrochemistrySaccharidesDopaminePhenylboronic acidIndicator displacement assay