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Science China Chemistry 2025年

作者： Wenwen Zhang Huixia Xuan Xiaofei Xu Jiaming Lou Qingbao Guan Zhengwei You state Key Laboratory for Modification of chemical fibers and polymer materials Institute of Functional Materials College of Materials Science and Engineering Shanghai Key Laboratory of Lightweight Composite Shanghai Engineering Research Center of Nano-Biomaterials and Regenerative Medicine Donghua University

For room temperature self-healing triboelectric nanogenerators（TENGs）, the inherent contradiction between mechanical strength and self-healing properties was an urgent problem to be solved. Based on the phenol-carbamate bond, this paper proposed a strategy to design a new molecular structure and coordinate the triple dynamic bonds, which provided a feasible strategy to solve this contradiction. With polytetramethylene ether glycol（M_n= 1,000） as the soft segment in the main chain of polyurethane（PU）, meanwhile methylene diphenyl diisocyanate and 4,4′-dihydroxybiphenyl（BP） as the hard segment and chain extension agent, respectively, the combination of tetrad benzene ring endowed the resultant 4BP-PU with π-π interaction. The effective reversible dissociation and association with hydrogen bond not only bestowed 4BP-PU with high mechanical strength（16.14 MPa）, but also promoted high self-healing efficiency（94.8%） at room temperature. 4BP-PU was selected as the elastic substrate between polydimethylsiloxane and copper sheet to prepare a self-healing TENG to collect energy from natural ***, the rational molecular structure design provided new ideas for developing self-healing materials and fabricating energy harvest electronics.

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Tailor-made high elasticity and low-hysteresis hydrogels based on asymmetric H-bonding crosslinking for wearable applications

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Science China Chemistry 2025年

作者： Xiaofang Shi Nan Shi Miaomiao Dang Chengyu Ji Yingjie Li Peiyi Wu Zhiguo Hu Collaborative Innovation Centre of Henan Province for Green Manufacturing of Fine chemicals Henan Engineering Laboratory of Chemical Pharmaceutical and Biomedical Materials School of Chemistry and Chemical Engineering Henan Normal University state Key Laboratory for Modification of chemical fibers and polymer materials College of Chemistry Chemical Engineering and Biotechnology & Center for Advanced Low-dimension Materials Donghua University

The conventional method of fabricating hydrogels constantly confronts the conflict between elasticity and toughness, limiting their repetitive application. Achieving the desired elasticity through a simple and low-cost approach is a significant challenge for hydrogels, particularly through rational molecular design. Here, low-hysteresis and high-toughness hydrogels are developed from the design of a new feature monomer, N-acryloylethylsemicarbazide (NACE). Based on a concept of “asymmetric Hbonding design”, the unique double and triple H-bonding of NACE can result in a novel asymmetric crosslinking polymer with alternating strong and weak H-bonding regions. The NACE is copolymerized with acrylamide (AM) to regulate the mechanical properties of hydrogel via H-bonding density. The P(NACE-AM) ionic hydrogels are obtained simply and rapidly via one-step photopolymerization without a chemical cross-linking agent. The P(NACE-AM) hydrogels combine superb mechanical elasticity and toughness, and excellent ionic conductivity, showing great potential as durable ionic conductive devices for wearable utilization.

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Multiple Tin Compounds Modified Carbon fibers to Construct Heterogeneous Interfaces for Corrosion Prevention and Electromagnetic Wave Absorption

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Nano-Micro Letters 2025年第1期17卷 507-527页

作者： Zhiqiang Guo Di Lan Zirui Jia Zhenguo Gao Xuetao Shi Mukun He Hua Guo Guanglei Wu Pengfei Yin College of Science Sichuan Agricultural UniversityYa’an 625014People’s Republic of China School of materials Science and Engineering Hubei University of Automotive TechnologyShiyan 442002People’s Republic of China Institute of materials for Energy and Environment State Key Laboratory of Bio‑Fibers and Eco‑TextilesCollege of Materials Science and EngineeringQingdao UniversityQingdao 266071People’s Republic of China Shaanxi Key Laboratory of Macromolecular Science and Technology School of Chemistry and Chemical EngineeringNorthwestern Polytechnical UniversityXi’anShaanxi 710072People’s Republic of China

Currently,the demand for electromagnetic wave(EMW)absorbing materials with specific functions and capable of withstanding harsh environments is becoming increasingly ***-component interface engineering is considered an effective means to achieve high-efficiency EMW ***,interface modulation engineering has not been fully discussed and has great potential in the field of EMW *** this study,multi-component tin compound fiber composites based on carbon fiber(CF)substrate were prepared by electrospinning,hydrothermal synthesis,and high-temperature thermal *** utilizing the different properties of different substances,rich heterogeneous interfaces are *** effectively promotes charge transfer and enhances interfacial polarization and conduction *** prepared SnS/SnS_(2)/SnO_(2)/CF composites with abundant heterogeneous interfaces have and exhibit excellent EMW absorption properties at a loading of 50 wt%in epoxy *** minimum reflection loss(RL)is−46.74 dB and the maximum effective absorption bandwidth is 5.28 ***,SnS/SnS_(2)/SnO_(2)/CF epoxy composite coatings exhibited long-term corrosion resistance on Q235 steel ***,this study provides an effective strategy for the design of high-efficiency EMW absorbing materials in complex and harsh environments.

关键词： Electrostatic spinning Component regulation Heterogeneous interfaces Electromagnetic wave absorption Corrosion protection

Synergistic Effect of Atmospheric Pressure Plasma Pre-Treatment on Alkaline Etching of Polyethylene Terephthalate Fabrics and Films

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Plasma Science and Technology 2016年第4期18卷 346-352页

作者： Amel E.A.ELABID 郭颖石建军丁可张菁 state Key Laboratory for Modification of chemical fibers and polymer materials College of Material Science and EngineeringDonghua University state Key Laboratory for Modification of chemical fibers and polymer materials College of ScienceDonghua University

Dyeing of PET materials by traditional methods presents several *** technology has received enormous attention as a solution for the environmental problems related with textile surface modifications,and there has been a rapid development and commercialization of plasma technology over the past *** this work,the synergistic effect of atmospheric pressure plasma on alkaline etching and deep coloring of dyeing properties on polyethylene terephthalate（PET）fabrics and films was *** topographical changes of the PET surface were investigated by atomic force microscopy（AFM）images,which revealed a smooth surface morphology of the untreated sample whereas a high surface roughness for the plasma and/or alkaline treated *** effects of atmospheric pressure plasma on alkaline etching of the structure and properties of PET were investigated by means of differential scanning calorimetry（DSC）,the main objective of performing DSC was to investigate the effect of the plasma pre-treatment on the T_g and T_*** a tensile strength tester YG065 H and following a standard procedure the maximum force and elongation at maximum force of PET materials was *** and argon plasma pre-treatment was found to increase the PET fabric weight loss *** color strength of PET fabrics was increased by various plasma pre-treatment *** penetration of plasma and alkaline reactive species deep into the PET structure results in better dyeability and leaves a significant effect on the K/S values of the plasma pre-treated *** indicated that plasma pre-treatment has a great synergistic effect with the alkaline treatment of PET.

关键词： atmospheric pressure plasma synergistic effect alkaline treatment polyethylene terephthalate materials K/S value surface roughness

Wet spinning of PVA composite fibers with a large fraction of multi-walled carbon nanotubes

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Progress in Natural Science:materials International 2015年第5期25卷 445-452页

作者： Dengpan Lai Yizhe Wei Liming Zou Yongjing Xu Hongwei Lu state Key Laboratory for Modification of chemical fibers and polymer materials College of Materials Science and Engineering Donghua University

PVA composites fibers with a large fraction of multi-walled carbon nanotubes modified by both covalent and non-covalent functionalization were produced by a wet-spinning *** XQ-1 tensile tester,thermogravimetric analysis,scanning electron microscopy,differential scanning calorimetry,and wide-angle X-ray diffraction were used to characterize the properties of PVA/MWNT composite *** TGA results suggested that MWNTs content in composite fibers were ranged from 5.3 wt%to 27.6 wt%.The mechanical properties of PVA/MWNT composite fibers were obviously superior to pure PVA *** Young's modulus of composite fibers enhanced with increasing the content of MWNTs,and it rised gradually from 6.7 GPa for the pure PVA fiber to 12.8 GPa for the composite fibers with 27.6 wt%***,the tensile strength increased gradually from 0.39 GPa for the pure PVA fiber to 0.74 GPa for the composite fibers with 14.4 wt%***,the tensile strength of the composite fibers decreased as the MWNTs content up to 27.6 wt%.SEM results indicated that the MWNTs homogeneously dispersed in the composite fibers,however some agglomerates also existed when the content of MWNTs reached27.6 wt%.DSC results proved strong interfacial interaction between MWNTs and PVA chain,which benefited composite fibers in the efficient *** characterization showed that the orientation of PVA molecules declined from 94.1%to 90.9%with the increasing of MWNTs *** good dispersibility of MWNTs throughout PVA matrix and efficient stress-transfer between MWNTs and PVA matrix may contributed to significant enhancement in the mechanical properties.

关键词： Multi-walled carbon nanotubes(MWNTs) Poly(vinyl alcohol)(PVA) Wet-spinning Composite fibers

Role of humidity on the structures and properties of regenerated silk fibers

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Progress in Natural Science:materials International 2015年第5期25卷 430-436页

作者： Qingfa Peng Huili Shao Xuechao Hu Yaopeng Zhang state Key Laboratory for Modification of chemical fibers and polymer materials College of Materials Science and Engineering Donghua University

Silk fiber was processed from highly concentrated spinning dope to solid fibers along with water removal. To understand the mechanism of water removal during silk fiber spinning process, a microfluidic chip was designed and applied to investigate the structures and mechanical properties of two kinds of regenerated silk fibroin fibers dry-spun at different relative humidity. The experimental results showed that the diameters of the fibers spun at 40% RH are always larger than the fibers spun at 50% RH due to different removal rates of water. The fibers spun at low humidity contain more β-sheet structure and lower degree of chain orientation and crystalline orientation. These results indicate that the fast phase transition of silk fibroin from sol–gel to silk fiber undergoes with rapid water removal and higher fiber orientation relates to more residue water and drawing force.

关键词： Dry spinning Relative humidity Biomimetic Regenerated silk fibroin Wide angle X-ray diffraction

Synthesis and Characterization of Easily Colored Meta-aramid Copolymer Containing Ether Bonds

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Chinese Journal of polymer Science 2019年第3期37卷 227-234页

作者： Na Li Xing-Ke Zhang Jun-Rong Yu Yan Wang Jing Zhu Zu-Ming Hu state Key Laboratory for Modification of chemical fibers and polymer materials College of Materials Science and Engineering Donghua University

This work described the preparation of easily colored meta-aramid(PMIA) copolymers from m-phenylenediamine(MPD),isophthaloyl dichloride(IPC), and 3,4′-oxydianiline(3,4′-ODA) via solution polycondensation in N,N-dimethylacetamide(DMAc). The novel co-PMIAs were obtained in relatively high inherent viscosities ranging from 1.32 dL/g to 2.53 dL/g, which could be easily cast into flexible films with high transparence or spun into fibers. All the newly synthesized copolymers possessed excellent thermal stabilities even better than that of commercial PMIA, with 5% weight loss temperatures higher than 430 °C in nitrogen measured by TGA and glass transition temperature of 267–277 °C measured by DSC. The cast films exhibited good mechanical properties with a tensile strength up to107 MPa and a tensile modulus up to 2.2 GPa. The resultant PMIAs also showed good solubility and better dye ability for cationic dyes.

关键词： Copolymerized meta-aramid Solution polycondensation Dyeability

Fabrication of 6FDA-HFBAPP Polyimide Asymmetric Hollow Fiber Membranes and Their CO2/CH4 Separation Properties

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Chinese Journal of polymer Science 2019年第8期37卷 815-826页

作者： Cong-Jun Gan Xiao-Chen Xu Xue-Wei Jiang Feng Gan Jie Dong Xin Zhao Qing-Hua Zhang state Key Laboratory for Modification of chemical fibers and polymer materials College of Materials Science and Engineering Donghua University

In this work, poly(amide acid) solution, the precursor of polyimide, was synthesized by the reaction of 4,4′-(hexafluoroisopropylidene)diphthalicanhydride and 2,2-bis[4-(4-aminophenoxy)phenyl]-hexafluoropropanane in the solvent of N-methyl-2-pyrrolidone(NMP) and tetrahydrofuran(THF). Then, hollow fiber membranes for high flux gas separation were prepared by dry-jet wet spinning using the precursor solution of poly(amide acid) as the spinning dope and a subsequent imidization process. Silicone rubber was further coated outside the obtained hollow fiber membranes to repair the defects on the denser layer. The effects of internal, external coagulation bath ratios with air gap, and coating solution concentrations on the morphologies, structures, and separation performance of the membranes were studied. Results showed that the sponge-like support layer was formed when the content of NMP was increased from 50% to 90% in the internal coagulation bath. The outer surface of the membrane became denser when the water content in the external coagulation bath increased from 40% to 100%, and the separation coefficient of CO2/CH4 increased by 2 times. This value could reach up to 1.4 when the air gap was 6 cm. With tuning the mass fraction of silicone rubber as 5%, hollow fiber composite membranes with uniform coating layer and an improved separation coefficient of 5.4 could be obtained.

关键词： Polyimide Gas separation Preparation conditions Membrane structure Permeability

Loading and releasing behavior of carboxymethyl cellulose and chitosan complex beads

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Progress in Natural Science:materials International 2022年第6期32卷 715-723页

作者： Ali A.Altam Liping Zhu Dafaalla Babiker Hajo Yagoub Shuguang Yang state Key Laboratory for Modification of chemical fibers and polymer materials Center for Advanced Low-dimension Materials Donghua University

The complex beads of carboxymethyl cellulose（CMC） and chitosan（CHI） that are fabricated by interfacial complexation have a core-shell structure composed of a thin skin layer and a 3D entangled internal structure,which endows the beads with adsorption possibilities toward anionic and cationic molecules via electrostatic ***,the loading and releasing behavior of such a system is essential and fundamental for their application yet has not been studied *** this work,the influences of beads physical state,adsorbent dosage,agitation speed,solution pH and temperature on the loading behavior were *** CMC@CHI beads demonstrated different loading efficiency to three typical dyes of methylene blue（MB）,acid blue-113（AB）,and methyl orange（MO） with different charge *** adsorption rate followed an order of MB>AB>MO,giving 97.4%,73.3% and 20.2%,*** releasing of three dyes from CMC@CHI beads also exhibited different rates,and MB release was found to be prolonged compared to AB and *** loading mechanism of dyes was further investigated via X-ray photoelectron *** CMC@CHI beads may have possible applications in mixed dye removal as well as encapsulating systems of drugs or sensitive chemicals with different charges.

关键词： Polysaccharide Encapsulation Loading mechanism Dye removal Interfacial complexation

π-conjugated chromophore functionalized high-nuclearity titanium-oxo clusters containing structural unit of anatase for photocatalytic selective oxidation of sulfides

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Rare Metals 2024年第4期43卷 1736-1746页

作者： Ling-Rong Liao Dong-Chun Zheng Pin-Xi Ou Qi-Xin Zhao Wei-Min Xuan Qi Zheng state Key Laboratory for Modification of chemical fibers and polymer materials&College of materials Science and Engineering Donghua UniversityShanghai201620China state Key Laboratory for Modification of chemical fibers and polymer materials and College of Chemistry and chemical Engineering Donghua UniversityShanghai 201620China

N-doping has significant influence in manipulating the properties of TiO_(2),and this has stimulated the development of N-donor-functionalized titanium-oxo clusters(TOCs)as molecular models to study the structure-property ***,the structural type and photoresponsive application are still limited for such TOCs,especially regarding the high-nuclearity TOCs that contain structure unit of TiO_(2)for ***,we showed the synthesis of a series of high-nuclearity TOCs 1-3 compounds usingπ-conjugated 1,10-phenanthroline(phen)as chromophore and N-donor functional *** 1 features cocrystal structure composed of one[Ti_(26)]~(2+)and half[Ti_(22)]~(2+),which renders it as the first cocrystallized TOC containing two positively charged species and phen-functionalized TOC showing the highest nuclearity up to 37 Ti *** adjusting the synthetic conditions,the individual{Ti_(22)}and{Ti_(26)}clusters can also be isolated as Compounds 2 and 3,*** core structure of{Ti_(22)}is mainly constructed from four lacunary{Ti_(4)}derived from pentagonal{Ti(Ti)_5}unit,while{Ti_(26)}is built from four complete{Ti(Ti)_5}***,a{Ti_8O_(14)}structure unit of anatase TiO_(2)can be identified in{Ti_(26)}.Based on the unique structural features and proper photophysical and photochemical properties of Compounds 1-3,they are applied for photocatalytic *** to the presence of anatase structure unit in{Ti_(26)}and the synergistic effect from{Ti_(22)}and{Ti_(26)},the catalytic performance presents in the order of Compound 1>Compound 3>Compound *** work provides excellent models to understand the structureproperty relationship from the perspective of cocrystallization and Ti-O binding model and will further promote the application of TOCs as functional catalysts for organic transformation.

关键词： Titanium-oxo cluster Molecular model of anatase TiO_(2) High nuclearity π-conjugated chromophore Photocatalytic sulfoxidation