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Nano Research 2024年第8期17卷 7614-7620页

作者： Yue Qin Yawei Wang Xinxin Wang Yaqi Zhang Jiahao Xu Kanchi Dong Yuehua Chen Wenyong Lai Xinwen Zhang state key laboratory of organic electronics and information displays and Institute of Advanced Materials(IAM) Nanjing University of Posts and TelecommunicationsNanjing 210023China

The progress of stretchable organic light-emitting devices(OLEDs)has brought about new possibilities for highly functional wearable ***,the efficiency and durability of stretchable OLEDs have been limited by the performance of stretchable transparent ***,we proposed an interface engineering strategy that involves anchoring the growth of silver(Ag)atoms with amine-enriched biomaterials for high-quality stretchable transparent *** strong interactions between the Ag atom and the amine group enable the uniform Ag electrodes at an ultralow thickness of 7 nm,and provide remarkable mechanical flexibility and strain endurance to the Ag *** distinct effects of different amino acids were investigated,and a deep understanding of their unique contributions to the film formation process was *** resulting ultrathin Ag electrodes exhibit outstanding optoelectrical properties(transmittance of~98%and sheet resistance of~8.7Ω/sq)and excellent stretchability during 500 stretching cycles at 100%*** green phosphorescent OLEDs based on the Ag electrodes have been demonstrated with a current efficiency of up to~70.4 cd/***,the devices show excellent stretching stability,retaining~89%of the original luminance and~78%of the original current efficiency after 200 stretching cycles at 100%*** work opens up new possibilities for stretchable transparent electrodes,fostering advancements in wearable displays and other innovative flexible devices.

关键词： transparent flexible electrodes ultrathin metal film interface mechanical stability

Polyimide covalent organic frameworks as efficient solid-state Li^(+) electrolytes

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Science China Chemistry 2024年第5期67卷 1647-1652页

作者： Xu Liu Shi Wang Siqi Liu Chengfang Liu Xiangchun Li Jian Wu Dazhi Li Shihao Xu Chongyang Liu Wen-Yong Lai state key laboratory of organic electronics and information displays(SKLOEID) Institute of Advanced Materials(IAM)School of Chemistry and Life SciencesNanjing University of Posts&TelecommunicationsNanjing 210023China

Covalent organic frameworks(COFs) are attractive porous crystalline materials with extremely high stability, easy functionalization, and open channels, which are expected to be unique ion conductors/transporters in lithium ion batteries(LIBs). Despite recent advances, low ion conductivity and low transference number, resulting in low charging/discharging rate, low energy density, and short battery life, are the main issues that limit their direct application as solid electrolytes in LIBs. Here, we designed and synthesized a novel polyimide COF, namely, TAPA-PDI-COF, with abundant C=O groups, which has been successfully employed as high-performance solid electrolytes by doping TAPA-PDI-COF and succinonitrile(SN). Both the well-defined nanochannels of COFs and SN confined in the well-aligned channels restricted the free migration of anions, while C=O on COFs and CN groups of SN enhanced Li^(+) transport, thus achieving a high ion conductivity of 0.102 m S cm^(-1)at 80 °C and a high lithium-ion transference number of 0.855 at room temperature. According to density functional theory(DFT)calculations, Li-ion migration mainly adopted in-plane transport rather than the axial pathway, which may be due to the shorter hopping distances in the planar pathway. The results suggest an effective strategy for the design and development of all-solidstate ionic conductors for achieving high-performance LIBs.

关键词： lithium ion batteries(LIBs) covalent organic frameworks(COFs) solid-state ion conductors solid-state electrolytes ion conductivity

Rational design of biodegradable semiconducting polymer nanoparticles for NIR-II fluorescence imaging-guided photodynamic therapy

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Nano Research 2024年第6期17卷 5399-5408页

作者： Xuxuan Gu Jinlong Shen Zhiwei Xu Wenqi Wang Ying Wu Wen Zhou Chen Xie Quli Fan state key laboratory of organic electronics and information displays&Institute of Advanced Materials(IAM) Nanjing University of Posts&Telecommunications9 Wenyuan RoadNanjing 210023China

Semiconducting polymer nanoparticles(SPNs)have shown great promise in second near-infrared window(NIR-II)***,the issue of long metabolic time significantly restricts the clinical application of *** this study,we rationally designed a biodegradable SPN(BSPN50)for NIR-II fluorescence imaging-guided photodynamic therapy(PDT).BSPN50 is prepared by encapsulating a biodegradable SP(BSP50)with an amphiphilic copolymer ***50 is composed of NIR-II fluorescent diketopyrrolopyrrole(DPP)segment and degradable poly(phenylenevinylene)(PPV)segment with the ratio of 50/***50 has both satisfactory degradability under myeloperoxidase(MPO)/hydrogen peroxide(H_(2)O_(2))and NIR-II fluorescence emission upon 808 nm laser ***,BSPN50 shows good photodynamic efficacy under 808 nm laser ***50 shows a faster degradation rate than BSPN100 which has no PPV segment both in vitro and in *** addition,BSPN50 can effectively diagnose tumor via NIR-II fluorescence imaging and inhibit the tumor growth by ***,our study provides a rational approach to construct biodegradable nanoplatforms for efficient tumor NIR-II phototheranostics.

关键词： near-infrared(NIR)-II fluorescence imaging semiconducting polymer nanoparticles photodynamic therapy tumor imaging

Nitrogen and fluorine co-doped graphene for ultra-stable lithium metal anodes

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Nano Research 2024年第8期17卷 7212-7220页

作者： Pan Li Yifan Liu Xujian Bao Jinghao Xie Zhao Li Hongcheng Li Qiang Ren Xiaomiao Feng Yue Hu Yanwen Ma state key laboratory for organic electronics and information displays(KLOEID)and Jiangsu key laboratory for Biosensors Institute of Advanced Materials(IAM)Nanjing University of Posts and TelecommunicationsNanjing 210023China key laboratory of Carbon Materials of Zhejiang Province College of Chemistry and Materials EngineeringWenzhou UniversityWenzhou 325000China

The heteroatom doping strategies have been utilized to effectively improve the performance of the carbon-based hosts,such as graphene,for lithium(Li)metal in high energy density lithium metal ***,solely doped graphene hosts often need the assistance of other materials with either better lithiophilicity or electronic conductance to achieve smooth and efficient deposition of Li,which adds extra weight or ***,graphene co-doped by nitrogen and fluorine(NFG)is employed as a stable host for Li,where the N-doping provides lithiophilicity and electronic conductivity lacked by F-doping and the F-doping facilitates fast formation of solid electrolyte interphase(SEI)retarded by *** well regulation of Li plating/stripping and SEI formation is verified by quickly stabilized and small-magnitude voltage hysteresis,which stands out in Li hosts based on doped graphene and leads to excellent long-term cycling performance of NFG based electrodes.A voltage hysteresis of 20 mV is observed for more than 850 h in the symmetrical *** remarkable efficiency of lithium usage is confirmed by the highcapacity retention of a full cell paired with LiFePO_(4)(LFP),which exceeds 70%after 500 *** work presents an innovative perspective on the control of Li plating/stripping by simultaneously introducing two kinds of dopants into graphene and paving the way for exploring practical Li metal batteries.

关键词： Co-doped graphene lithium metal anode dendrite suppression lithiophilic skeleton solid electrolyte interphase(SEI)formation

Cross-Modal Graph Semantic Communication Assisted by Generative AI in the Metaverse for 6G

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Research 2024年第2期7卷 19-27页

作者： Mingkai Chen Minghao Liu Congyan Wang Xingnuo Song Zhe Zhang Yannan Xie Lei Wang key laboratory of Broadband Wireless Communication and Sensor Network Technology Nanjing University of Posts and TelecommunicationsNanjng 210003China state key laboratory of organic electronics and information displays&Institute of Advanced Materials(IAM) Nanjing University of Posts and TelecommunicationsNanjing 210023China

Recently, the development of the Metaverse has become a frontier spotlight, which is an important demonstration of the integration innovation of advanced technologies in the Internet. Moreover, artificial intelligence (AI) and 6G communications will be widely used in our daily lives. However, the effective interactions with the representations of multimodal data among users via 6G communications is the main challenge in the Metaverse. In this work, we introduce an intelligent cross-modal graph semantic communication approach based on generative AI and 3-dimensional (3D) point clouds to improve the diversity of multimodal representations in the Metaverse. Using a graph neural network, multimodal data can be recorded by key semantic features related to the real scenarios. Then, we compress the semantic features using a graph transformer encoder at the transmitter, which can extract the semantic representations through the cross-modal attention mechanisms. Next, we leverage a graph semantic validation mechanism to guarantee the exactness of the overall data at the receiver. Furthermore, we adopt generative AI to regenerate multimodal data in virtual scenarios. Simultaneously, a novel 3D generative reconstruction network is constructed from the 3D point clouds, which can transfer the data from images to 3D models, and we infer the multimodal data into the 3D models to increase realism in virtual scenarios. Finally, the experiment results demonstrate that cross-modal graph semantic communication, assisted by generative AI, has substantial potential for enhancing user interactions in the 6G communications and Metaverse.

关键词： modal frontier guarantee

Multicolor emission from lanthanide ions doped lead-free Cs_(3)Sb_(2)Cl_(9) perovskite nanocrystals

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Journal of Rare Earths 2024年第5期42卷 940-946,I0005页

作者： He Shao Lifang Li Xiufeng Wu Lin Xu Biao Dong Donglei Zhou Xue Bai Hongwei Song state key laboratory of organic electronics and information displays&Institute of Advanced Materials College of Materials Science and EngineeringNanjing University of Posts&TelecommunicationsNanjing210023China state key laboratory of Integrated Optoelectronics College of Electronic Science and Engineering Jilin UniversityChangchun130012China

The toxicity of lead ions has become the severe challenge for the all-inorganic lead halide p erovskite materials,although some works have rep orted the lead-free perovskite nanocrystals(NCs),the photoluminescence quantum yield(PLQY)of these materials is still ***,because the halogen ions can be easily exchanged,the controllable multicolor emission in perovskite NCs is difficult to realize in current *** this work,we introduced lanthanide ions into lead-free Cs_(3)Sb_(2)Cl_(9) perovskite *** from the energy transfer between Cs_(3)Sb_(2)Cl_(9) perovskite NC host and lanthanide ions,the multicolor emission was *** on controlling the doping concentration of Tb^(3+)and Eu^(3+)ions,the white light emission under UV excitation would be turned easily in the Tb^(3+)/Eu^(3+)codoped *** addition,efficient energy transfer from perovskite NCs to Tb^(3+)or Eu^(3+)ions is beneficial to improving the optical properties of lead-free perovskite NCs,resulting in maximum PLQYs of red,green and white light emission of 22.6%,19.7%and 28.5%,***,a white light emitting device(WLED)was fabricated with a power efficiency of 18.5 lm/W,which presents the Commission Internationale de l'Eclairage(CIE)of(0.33,0.35).

关键词： Perovskite nanocrystals Lead free Lanthanide ions Energy transfer White light emitting device Rare earths

Single-Component Color-Tunable Smart organic Emitters with Simultaneous Multistage Stimuli-Responsiveness and Multimode Emissions

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Research 2024年第2期2023卷 719-728页

作者： Yu Yan Chengfang Liu Jianzhong Fan Yusheng Li Huanling Liu Qian Wang Xiangchun Lil Junfeng Li Wen-Yong Lai state key laboratory of organic electronics and information displays(SKLOEID) Institute of Advanced Materials(IAM)School of Chemistry and Life SciencesNanjing University of Posts&Telecommunications9 Wenyuan RoadNanjng 210023China Shandong Province key laboratory of Medical Physics and Image Processing Technology School of Physics and ElectronicsShandong Normal UniversityJinan 250358China

Achieving color-tunable emission in single-component organic emitters with multistage stimuli-responsiveness is of vital significance for intelligent optoelectronic applications,but remains enormously ***,we present an unprecedented example of a color-tunable single-component smart organic emitter(DDOP)that simultaneously exhibits multistage stimuli-responsiveness and multimode *** based on a highly twisted amide-bridged donor-tcceptor-donor structure has been found to facilitate intersystem crossing,form multimode emissions,and generate multiple emissive species with multistage *** pristine crystalline powders exhibit abnormal excitation-dependent emissions from a monomer-dominated blue emission centered at 470 nm to a dimer-dominated yellow emission centered at 550 nm through decreasing the ultraviolet(UV)excitation wavelengths,whereas DDOP single crystals show a wide emission band with a main emission peak at 585 nm when excited at different *** emission behaviors of pristine crystalline powders and single crystals are different,demonstrating emission features that are closely related to the aggregation *** work has developed color-tunable single-component organic emitters with simultaneous multistage stimuli-responsiveness and multimode emissions,which is vital for expanding intelligent optoelectronic applications,including multilevel information encryption,multicolor emissive patterns,and visual monitoring of UV wavelengths.

关键词： donor excitation Smart

An injectable,self-healable,and reusable PEDOT:PSS/PVA hydrogel patch electrode for epidermal electronics

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Nano Research 2024年第6期17卷 5479-5490页

作者： Yang Li Yuzhe Gu Sheng Qian Shuwen Zheng Yuncong Pang Lele Wang Baoguang Liu Shujuan Liu Qiang Zhao College of Electronic and Optical Engineering and College of Flexible electronics(Future Technology) Nanjing University of Posts and Telecommunications(NJUPT)Nanjing 210023China state key laboratory of organic electronics and information displays and Jiangsu key laboratory for Biosensors Institute of Advanced Materials(IAM)Nanjing University of Posts and Telecommunications(NJUPT)Nanjing 210023China

Injectability empowers conductive hydrogels to transcend traditional limitations,unlocking a realm of possibilities for innovative medical,wearable,and therapeutic applications that can significantly enhance patient care and quality of ***,we report an injectable,self-healable,and reusable hydrogel obtained by mixing the concentrated poly(3,4-ethylenedioxythiophene)doped with polystyrene sulfonate(PEDOT:PSS)suspension(~2 wt.%solid content),polyvinyl alcohol(PVA),and *** the presence of reversible borax/hydroxyl bonds and multiple hydrogen bonds,this PEDOT:PSS/PVA hydrogel exhibits notable shear-thinning behavior and self-healing capabilities,enabling it to be injected as a gel fiber from a ***-prepared injectable hydrogel also demonstrates an ultra-low modulus(~2.5 MPa),reduced on-skin impedance(~45%of commercial electrodes),and high signal-to-noise ratio(SNR)(~15-22 dB)in recording of electrocardiography(ECG),electromyography(EMG),and electroencephalogram(EEG)***,the injectable hydrogels can be remolded and reinjected as the reusable electrodes,maintaining nearly identical electrophysiological recording capabilities and brain-computer interface(BCI)performance compared to commercial wet *** their straightforward fabrication,excellent material properties and electronic performance,ease of cleaning,and remarkable reusability,our injectable PEDOT:PSS/PVA hydrogels hold promise for advancements in BCI based electronics and wearable bioelectronics.

关键词： epidermal hydrogel electrodes reusability injectability self-healing electrophysiological recording brain-computer interface

Advances of Electrochemical and Electrochemiluminescent Sensors Based on Covalent organic Frameworks

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Nano-Micro Letters 2024年第2期16卷 395-422页

作者： Yue Cao Ru Wu Yan‑Yan Gao Yang Zhou Jun‑Jie Zhu key laboratory for organic electronics and information displays(KLOEID)and Institute of Advanced Materials(IAM) Nanjing University of Posts and Telecommunications(NJUPT)Nanjing 210023People’s Republic of China state key laboratory of Analytical Chemistry for Life Science School of Chemistry and Chemical EngineeringNanjing UniversityNanjing 210023People’s Republic of China

Covalent organic frameworks(COFs),a rapidly developing category of crystalline conjugated organic polymers,possess highly ordered structures,large specific surface areas,stable chemical properties,and tunable pore *** the first report of boroxine/boronate ester-linked COFs in 2005,COFs have rapidly gained popularity,showing important application prospects in various fields,such as sensing,catalysis,separation,and energy *** them,COFs-based electrochemical(EC)sensors with upgraded analytical performance are arousing extensive *** this review,therefore,we summarize the basic properties and the general synthesis methods of COFs used in the field of electroanalytical chemistry,with special emphasis on their usages in the fabrication of chemical sensors,ions sensors,immunosensors,and ***,the emerged COFs in the electrochemiluminescence(ECL)realm are thoroughly covered along with their preliminary ***,final conclusions on state-of-the-art COFs are provided in terms of EC and ECL sensors,as well as challenges and prospects for extending and improving the research and applications of COFs in electroanalytical chemistry.

关键词： Covalent organic frameworks Electrochemistry Electrochemiluminescence Sensors

Flat Zn deposition at battery anode via an ultrathin robust interlayer

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Nano Research 2024年第9期17卷 8104-8111页

作者： Yizhou Wang Jianyu Chen Zibo Chen Qian He Zhengnan Tian Jin Zhao Yanwen Ma Husam N.Alshareef Materials Science and Engineering King Abdullah University of Science and Technology(KAUST)Thuwal 23955-6900Saudi Arabia state key laboratory of organic electronics and information displays(KLOEID)and Jiangsu key laboratory for Biosensors Institute of Advanced Materials(IAM)Nanjing University of Posts and TelecommunicationsNanjing 210023China Suzhou Vocational Institute of Industrial Technology Suzhou 215104China

Rechargeable aqueous zinc(Zn)ion batteries(AZIBs)using low-cost and safe Zn metal anodes are considered promising candidates for future grid-scale energy storage systems,but the Zn dendrite problem severely hinders the further prospects of *** Zn depositing behaviors toward horizontal alignment is highly effective and thus has received huge ***,such a strategy is usually based on previous substrate engineering,which requires complex preparation or expensive ***,it is essential to develop a novel solution that can realize horizontally aligned Zn flake deposition via easy operation and low ***,we report an ultrathin and robust Kevlar membrane as the interlayer to mechanically suppress Zn dendrite *** to the randomly distributed flaky dendrites in the control group,the deposited Zn sheets would grow into parallel alignment with the existence of such *** the dendrites are effectively suppressed,Zn||Cu asymmetric,Zn||Zn symmetric,and Zn||MnO_(2)full batteries using Kevlar interlayer deliver significantly improved cycling ***,the Zn||MnO_(2)pouch cell using a Kevlar interlayer delivers stable cycling performance and shows stable operation during multi-angle *** believe this work provides a new possibility for regulating Zn deposition from a crystallographic perspective.

关键词： Zn metal anodes Zn dendrites aqueous Zn ion batteries dendrite suppression (002)crystal plane