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Improved Multiple Feature-electrochemical Thermal Coupling Modeling of Lithium-ion Batteries at Low-temperature with Real-time Coefficient Correction

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Protection and Control of Modern Power Systems 2024年第3期9卷 157-173页

作者： Shunli Wang Haiying Gao Paul Takyi-Aninakwa Josep M.Guerrero Carlos Fernandez Qi Huang IET the School of Electric Power Inner Mongolia University of TechnologyInner Mongolia 010051China the School of Information Engineering Southwest University of Science and TechnologyMianyang 621010China southwest University of Science and Technology(SWUST) the Smart Energy Storage institute the Department of Energy Technology Aalborg UniversityDenmark Robert Gordon University IEEE southwest University of Science and Technology

Monitoring various internal parameters plays a core role in ensuring the safety of lithium-ion batteries in power supply *** also influences the sustainability effect and online state of charge *** improved multiple feature-electrochemical thermal coupling modeling method is proposed considering low-temperature performance degradation for the complete characteristic expression of multi-dimensional *** is to obtain the parameter influence mechanism with a multi-variable coupling *** optimized decoupled deviation strategy is constructed for accurate state of charge prediction with real-time correction of time-varying current and temperature *** innovative decoupling method is combined with the functional relationships of state of charge and open-circuit voltage to capture energy management ***,an adaptive equivalent-prediction model is constructed using the state-space equation and iterative feedback correction,making the proposed model adaptive to fractional *** maximum state of charge estimation errors of the proposed method are 4.57% and 0.223% under the Beijing bus dynamic stress test and dynamic stress test conditions,*** improved multiple feature-electrochemical thermal coupling modeling realizes the effective correction of the current and temperature variations with noise influencing coefficient,and provides an efficient state of charge prediction method adaptive to complex conditions.

关键词： Adaptive inner state characterization lithium-ion batteries low-temperature automatic-guided-vehicle multiple feature-electrochemical thermal coupling modeling real-time coefficient correction

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浮置板轨道周期结构弹性波传播特性及异常多普勒效应

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Journal of Central South University 2024年第5期31卷 1711-1722页

作者：张鑫浩赵才友惠庆敏耿明婧乐明静易强吕涛王平 School of Civil Engineering Southwest Jiaotong UniversityChengdu 610031China Key Laboratory of High-speed Railway Engineering Southwest Jiaotong UniversityChengdu 610031China Railway Engineering research institute China Academy of Railway Sciences Corporation LimitedBeijing 100081China SWJTU-Leeds Joint School Southwest Jiaotong UniversityChengdu 611756China

浮置板轨道因其良好的减振性能被广泛应用于城市轨道交通中。为研究浮置板结构的弹性波传播模式,本文基于广义平面波展开法,对其特征方程进行程序求解,得到了无限周期结构的复频散曲线。发现在0至300 Hz范围内存在八个带隙,并提出了相... 详细信息

浮置板轨道因其良好的减振性能被广泛应用于城市轨道交通中。为研究浮置板结构的弹性波传播模式,本文基于广义平面波展开法,对其特征方程进行程序求解,得到了无限周期结构的复频散曲线。发现在0至300 Hz范围内存在八个带隙,并提出了相应的理论分析。力锤激励试验也验证了带隙对弹性波的阻碍作用。根据波模式特性,发现双周期轨道结构的带隙形成机制与单周期轨道结构不同,即在双周期情况下,局部布拉格散射或局部共振无法阻止耦合弹性波的传播。频率-波数域的计算结果表明,异常多普勒效应发生在带隙范围,而常规多普勒效应发生在通带范围。

关键词：浮置板轨道带隙弹性波多普勒效应力锤激励试验

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Microfluidic preparation of surfactant-free ultrafine DAAF with tunable particle size for insensitive initiator explosives

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Defence Technology（防务技术） 2024年第9期39卷 42-52页

作者： Bo Yang Rui Li Wei Cao Si-min He Jincan Zhu Qi Wu Heng Ding Jin Chen Weimiao Wang Zhiqiang Qiao Xiaodong Li Guangcheng Yang institute of Chemical Materials China Academy of Engineering PhysicsMianyang 621900China southwest University of Science and Technology Mianyang 621010China School of Chemical Engineering Nanjing University of Science and TechnologyNanjing 210094China

High purity and ultrafine DAAF(u-DAAF)is an emerging insensitive charge in *** there are many ways to obtain u-DAAF,developing a preparation method with stable operation,accurate control,good quality consistency,equipment miniaturization,and minimum manpower is an inevitable requirement to adapt to the current social technology development *** reported is the microfluidic preparation of u-DAAF with tunable particle size by a passive swirling *** the guidance of recrystallization growth kinetics and mixing behavior of fluids in the swirling microreactor,the key parameters(liquid flow rate,explosive concentration and crystallization temperature)were screened and optimized through screening *** the condition that no surfactant is added and only experimental parameters are controlled,the particle size of recrystallized DAAF can be adjusted from 98 nm to 785 nm,and the corresponding specific surface area is 8.45 m^(2)·g^(-1)to 1.33 m^(2)·g^(-1).In addition,the preparation method has good batch stability,high yield(90.8%-92.6%)and high purity(99.0%-99.4%),indicating a high practical application *** explosion derived flyer initiation tests demonstrate that the u-DAAF shows an initiation sensitivity much lower than that of the raw DAAF,and comparable to that of the refined DAAF by conventional spraying crystallization *** study provides an efficient method to fabricate u-DAAF with narrow particle size distribution and high reproducibility as well as a theoretical reference for fabrication of other ultrafine explosives.

关键词： Microfluidic preparation Screening crystallization conditions Narrow particle size distribution Low initiation sensitivity Ultrafine DAAF

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Spin gap in quasi-one-dimensional S=3/2 antiferromagnet CoTi2O5

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Chinese Physics B 2024年第3期33卷 609-617页

作者：徐浩航刘庆元辛潮申沁鑫罗军周睿程金光刘健陶玲玲刘志国霍明学王先杰隋郁 School of Physics Harbin Institute of TechnologyHarbin 150001China School of Science Changchun University of Science and TechnologyChangchun 130022China Beijing National Laboratory for Condensed Matter Physics and Institute of PhysicsChinese Academy of SciencesBeijing 100190China Laboratory for Space Environment and Physical Sciences Harbin Institute of TechnologyHarbin 150001China southwest institute of Applied Magnetics Mianyang 621000China

Quasi-one-dimensional(1D)antiferromagnets are known to display intriguing phenomena especially when there is a spin gap in their spin-excitation *** we demonstrate that a spin gap exists in the quasi-1D Heisenberg antiferromagnet CoTi2O5 with highly ordered Co2+/Ti4+occupation,in which the Co2+ions with S=3/2 form a 1D spin chain along the ***2O5 undergoes an antiferromagnetic transition at TN~24 K and exhibits obvious anisotropic magnetic susceptibility even in the paramagnetic *** a gapless magnetic ground state is usually expected in a quasi-1D Heisenberg antiferromagnet with half-integer spins,by analyzing the specific heat,the thermal conductivity,and the spin-lattice relaxation rate(1/T1)as a function of temperature,we found that a spin gap is opened in the spin-excitation spectrum of CoTi2O5 around TN,manifested by the rapid decrease of magnetic specific heat to zero,the double-peak characteristic in thermal conductivity,and the exponential decay of 1/T1 below *** the magnetic measurements and the first-principles calculations results indicate that there is spin-orbit coupling in CoTi2O5,which induces the magnetic anisotropy in CoTi2O5,and then opens the spin gap at low temperature.

关键词： quasi-one-dimensional antiferromagnet magnetic anisotropy spin gap

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Hyperbranched polyamidoamine protective layer with phosphate and carboxyl groups for dendrite-free Zn metal anodes

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Chinese Chemical Letters 2024年第10期35卷 495-499页

作者： Xinxiu Yan Xizhe Huang Yangyang Liu Weishang Jia Hualin Chen Qi Yao Tao Chen Key Laboratory of General Chemistry of the National Ethnic Afairs Commission School of Chemistry and EnvironmentSouthwest Minzu UniversityChengdu 610041China institute of smart city and inteligent transportation Southwest Jiaotong UniversityChengdu 611756China School of Materials Science and Engineering Guangdong University of Petrochemical TechnologyMaoming 525000China

Zinc metal is regarded as one of the most promising anodes for Zn-based batteries in next-generation energy storage ***,the dendrite growth and interfacial corrosion lead to poor reversibility and cycle life of Zn ***,we synthesize a 2-phosphate-1,2,4-butane tricarboxylic acid modified hyperbranched polyamidoamine containing rich terminal groups of phosphate and carboxyl(HPC)as modified layer for the Zn ***,the in situ acid-etching promotes the exposure of(002)Zn plane and the generated salt-polymer complexes could be adhered to the Zn anodes *** greatly favors the uniform deposition of Zn and inhibits interfacial ***,stable HPC@Zn anode plating/stripping for over 1200 h at a high areal capacity of 4 mAh/cm^(2)and a current density of 4 m A/cm^(2)is *** study provides a new avenue of hyperbranched polymer in interfacial design for highly reversible and stable Zn metal anodes.

关键词： Zn anode Znmetal batteries Surface chemistry Functional groups Hyperbranched polyamidoamine

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Metal-Organic Framework Enabling Poly(Vinylidene Fluoride)-Based Polymer Electrolyte for Dendrite-Free and Long-Lifespan Sodium Metal Batteries

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Energy & Environmental Materials 2024年第1期7卷 68-76页

作者： Yusi Lei Liang Yue Yuruo Qi Yubin Niu Shujuan Bao Jie Song Maowen Xu Faculty of Materials and Energy Institute for Clean Energy&Advanced MaterialsSouthwest UniversityChongqing 400715China Shandong Zero-One-Four Advanced Materials Co. Ltd.Feicheng 271099China

Sodium dentrite formed by uneven plating/stripping can reduce the utilization of active sodium with poor cyclic stability and,more importantly,cause internal short circuit and lead to thermal runaway and ***,sodium dendrites and their related problems seriously hinder the practical application of sodium metal batteries(SMBs).Herein,a design concept for the incorporation of metal-organic framework(MOF)in polymer matrix(polyvinylidene fluoride-hexafluoropropylene)is practiced to prepare a novel gel polymer electrolyte(PH@MOF polymer-based electrolyte[GPE])and thus to achieve high-performance *** addition of the MOF particles can not only reduce the movement hindrance of polymer chains to promote the transfer of Na^(+)but also anchor anions by virtue of their negative charge to reduce polarization during electrochemical reaction.A stable cycling performance with tiny overpotential for over 800 h at a current density of 5 mA cm^(-2)with areal capacity of 5 mA h cm^(-2)is achieved by symmetric cells based on the resulted GPE while the Na_(3)V_(2)O_(2)(PO_(4))_(2)F@rGO(NVOPF)|PH@MOF|Nacell also displays impressive specific cycling capacity(113.3 mA h g^(-1)at 1 C)and rate capability with considerable capacity retention.

关键词： dendrite-free gel polymer electrolyte metal organic framework sodium batteries

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Construction of core@double-shell structured energetic composites with simultaneously enhanced thermal stability and safety performance

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Defence Technology（防务技术） 2024年第4期34卷 134-142页

作者： Peng Wang Wen Qian Ruolei Zhong Fangfang He Xin Li Jie Chen Li Meng Yinshuang Sun Guansong He institute of Chemical Materials China Academy of Engineering PhysicsMianyang 621900China State Key Laboratory of Environment-friendly Energy Materials School of Materials and ChemistrySouthwest University of Science and TechnologyMianyang 621010China

The poor thermal stability and high sensitivity severely hinder the practical application of hexanitrohexaazaisowurtzitane(CL-20).Herein,a kind of novel core@double-shell CL-20 based energetic composites were fabricated to address the above *** coordination complexes which consist of natural polyphenol tannic acid(TA) and Fe~Ⅲ were chosen to construct the inner shell,while the graphene sheets were used to build the outer *** resulting CL-20/TA-Fe~Ⅲ/graphene composites exhibited simultaneously improved thermal stability and safety performance with only 1 wt% double-shell content,which should be ascribed to the intense physical encapsulation effect from inner shell combined with the desensitization effect of carbon nano-materials from outer *** phase transition(ε to γ) temperature increased from 173.70 ℃ of pure CL-20 to 191.87℃ of CL-20/TA-Fe~Ⅲ/graphene ***,the characteristic drop height(H_(50)) dramatically increased from 14.7 cm of pure CL-20 to112.8 cm of CL-20/TA-Fe~Ⅲ/graphene composites,indicating much superior safety performance after the construction of the double-shell *** general,this work has provided an effective and versatile strategy to conquer the thermal stability and safety issues of CL-20 and contributes to the future application of high energy density energetic materials.

关键词： CL-20 Double-shell structure Thermal stability Safety performance Tannic acid Graphene sheets

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In-situ building of multiscale porous NiFeZn/NiZn-Ni heterojunction for superior overall water splitting

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Transactions of Nonferrous Metals Society of China 2024年第9期34卷 2972-2986页

作者： Ya-xin LI Hong-xiao YANG Qiu-ping ZHANG Tian-zhen JIAN Wen-qing MA Cai-xia XU Qiu-xia ZHOU institute for Advanced Interdisciplinary research(iAIR) University of JinanJinan 250022China School of Medical Information and Engineering Southwest Medical UniversityLuzhou 646000China

The development of efficient nonprecious bifunctional electrocatalysts for water electrolysis is crucial to enhance the sluggish kinetics of the oxygen evolution reaction(OER)and hydrogen evolution reaction(HER).A self-supporting,multiscale porous NiFeZn/NiZn-Ni catalyst with a triple interface heterojunction on nickel foam(NF)(NiFeZn/NiZn-Ni/NF)was in-situ fabricated using an electroplating-annealing-etching *** unique multiinterface engineering and three-dimensional porous scaffold significantly modify the mass transport and electron interaction,resulting in superior bifunctional electrocatalytic performance for water *** NiFeZn/NiZn-Ni/NF catalyst demonstrates low overpotentials of 187 m V for HER and 320 mV for OER at a current density of 600 mA/cm~2,along with high durability over 150 h in alkaline ***,an electrolytic cell assembled with NiFeZn/NiZn-Ni/NF as both the cathode and anode achieves the current densities of 600 and 1000 m A/cm2 at cell voltages of 1.796 and 1.901 V,respectively,maintaining the high stability at 50 mA/cm2 for over 100 *** findings highlight the potential of NiFeZn/NiZn-Ni/NF as a cost-effective and highly efficient bifunctional electrocatalyst for overall water splitting.

关键词： NiFeZn alloy multiple interface porous structure dealloying overall water splitting

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Impacts of interactions with low-mineralized water on permeability and pore behavior of carbonate reservoirs

Energy Geoscience

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Energy Geoscience 2024年第4期5卷 278-290页

作者： Dmitriy A.Martyushev Inna N.Ponomareva Vasiliy I.Chernykh Shadfar Davoodi Yousef Kazemzadeh Tianshou Ma Department of Oil and Gas Technologies Perm National Research Polytechnic UniversityPermRussia School of Earth Sciences&Engineering Tomsk Polytechnic UniversityLenin AvenueTomskRussia Enhanced Oil Recovery(EOR)research Center IOR/EOR Research InstituteShiraz UniversityShirazIran State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation Southwest Petroleum UniversityChengduSichuanPR China

Laboratory filtration experiments are employed to investigate effective well killing while minimizing its impacts on surrounding *** novelty of this experimental study lies in the prolonged exposure of rock samples to the killing fluid for seven days,corresponding to the average duration of well workovers in the oilfields in Perm Krai,*** findings indicate that critical factors influencing the interactions between rocks and the killing fluid include the chemical composition of the killing fluid,the mineralogical composition of the carbonate rocks,reservoir pressure and temperature,and the contact *** analyses using multi-scale X-ray computed tomography,field emission scanning electron microscopy,and X-ray diffraction were conducted on samples both before and after the well killing *** experiments were performed using real samples of cores,crude oil,and the killing *** results from this study indicate that low-mineralized water(practically fresh water)is a carbonate rock *** water causes the dissolution of rock components,the formation of new calcite crystals and amoeba-like secretions,and the migration of small particles(clay,quartz,and carbonates).The formation of deep channels was also *** assessment reveals that the change in the pH of the killing fluid indicates that the observed mineral reactions were caused by carbonate *** combined phenomena led to a decrease in the total number of voids in the core samples,which was 25%on average,predominantly among voids measuring between 45 and 70μm in *** change in the pore distribution in the bulk of the samples resulted in decreases in porosity of 1.8%and permeability of 67.0%in the studied core *** results from this study indicate the unsuitability of low-mineralized water as a well killing fluid in carbonate *** composition of the killing fluid should be optimized,for example,in terms of the ionic composition of water,

关键词： Fine particle Clay mineral Low-mineralized water Geochemical dissolution Carbonate reservoir

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Data Driven Vibration Control:A Review

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IEEE/CAA Journal of Automatica Sinica 2024年第9期11卷 1898-1917页

作者： Weiyi Yang Shuai Li Xin Luo Chongqing institute of Green and Intelligent Technology Chinese Academy of SciencesChongqing 400714 Chongqing School University of Chinese Academy of SciencesChongqing 400714China Faculty of Information Technology and Electrical Engineering University of OuluOulu 90570 VTT-Technology research Center of Finland Oulu 90570Finlan College of Computer and Information Science Southwest UniversityChongqing 400715China

With the ongoing advancements in sensor networks and data acquisition technologies across various systems like manufacturing,aviation,and healthcare,the data driven vibration control(DDVC)has attracted broad interests from both the industrial and academic *** shaping(IS),as a simple and effective feedforward method,is greatly demanded in DDVC *** convolves the desired input command with impulse sequence without requiring parametric dynamics and the closed-loop system structure,thereby suppressing the residual vibration *** on a thorough investigation into the state-of-the-art DDVC methods,this survey has made the following efforts:1)Introducing the IS theory and typical input shapers;2)Categorizing recent progress of DDVC methods;3)Summarizing commonly adopted metrics for DDVC;and 4)Discussing the engineering applications and future trends of *** doing so,this study provides a systematic and comprehensive overview of existing DDVC methods from designing to optimizing perspectives,aiming at promoting future research regarding this emerging and vital issue.

关键词： Data driven vibration control(DDVC) data science designing method feedforward control industrial robot input shaping optimizing method residual vibration

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