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Lowering Sodium-Storage Lattice Strains of Layered Oxide Cathodes by Pushing Charge Transfer on Anions

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Energy & Environmental materials 2024年第4期7卷 99-106页

作者： Na Li Wen Yin Baotian Wang Fangwei Wang Xiaoling Xiao Jinkui Zhao Enyue Zhao songshan lake materials laboratory Beijing National laboratory for Condensed Matter Physics Institute of Physics Chinese Academy of Sciences Spallation Neutron Source science Center Institute of High Energy Physics Chinese Academy of Sciences College of materials science and Opto-electronic Technology Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences

Due to a high energy density,layered transition-metal oxides have gained much attention as the promising sodium-ion batteries ***,they readily suffer from multiple phase transitions during the Na extraction process,re... 详细信息

关键词： anionic redox reaction lattice strains layered oxide cathodes phase transitions sodium-ion battery

High energy density in ultra-thick and flexible electrodes enabled by designed conductive agent/binder composite

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Journal of Energy Chemistry 2024年第3期90卷 133-143,I0005页

作者： Xiaoyu Shen Hailong Yu Liubin Ben Wenwu Zhao Qiyu Wang Guanjun Cen Ronghan Qiao Yida Wu Xuejie Huang Beijing National laboratory for Condensed Matter Physics Institute of PhysicsChinese Academy of SciencesBeijing 100190China Center of materials science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China songshan lake materials laboratory Dongguan 523808Guangdong China

Thick electrodes can increase incorporation of active electrode materials by diminishing the proportion of inactive constituents,improving the overall energy density of ***,thick electrodes fabricated using the conventional slurry casting approach frequently exhibit an exacerbated accumulation of carbon additives and binders on their surfaces,invariably leading to compromised electrochemical *** this study,we introduce a designed conductive agent/binder composite synthesized from carbon nanotube and *** agent/binder composite facilitates production of dry-process-prepared ultra-thick electrodes endowed with a three-dimensional and uniformly distributed percolative architecture,ensuring superior electronic conductivity and remarkable mechanical *** this approach,ultra-thick LiCoO_(2)(LCO) electrodes demonstrated superior cycling performance and rate capabilities,registering an impressive loading capacity of up to 101.4 mg/cm^(2),signifying a 242% increase in battery energy *** another analytical endeavor,time-of-flight secondary ion mass spectroscopy was used to clarify the distribution of cathode electrolyte interphase(CEI) in cycled LCO *** results provide unprecedented evidence explaining the intricate correlation between CEI generation and carbon distribution,highlighting the intrinsic advantages of the proposed dry-process approach in fine-tu ning the CEI,with excellent cycling performance in batteries equipped with ultra-thick electrodes.

关键词： Conductive agent/binder composite Dry process Ultra-thick electrodes High energy density CEI reconstruction ToF-SIMS

High-tenacity in-situ Ti/Zr-based bulk metallic glasses composites fabricated by industrial high-pressure die casting

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Journal of materials science & Technology 2024年第3期170卷 177-185页

作者： Yang Li Wenbo Luo Ying Jin Zhiyong Xue Guiqing Wang Yanan Ren Haoxin Li Haibo Ke Baoan Sun Weihua Wang Institute for Advanced materials North China Electric Power UniversityBeijing 102206China songshan lake materials laboratory Dongguan 523808China Institute of Physics Chinese Academy of SciencesBeijing 100190China

The glass-forming ability and mechanical properties of metallic glasses and their composites are well known to be sensitive to the preparation conditions and are highly deteriorated by industrial preparing conditions such as low-purity raw materials and low ***,we showed that a series of in-situ bulk metallic glass composites(BMGCs)which exhibit excellent ductility and segmental work hardening were successfully developed utilizing a high vacuum high-pressure die casting(HV-HPDC)technology along with industrial-grade raw *** tensile properties of these BMGCs are systematically investigated and correlated with the alloy *** compared with the copper mold suction casting method,the volume fraction difference of the dendrite phase for the BMGCs with the same composition is not significant when fabricated by the HV-HPDC,whereas the size of theβ-phase is generally *** BMGCs with the composition of Ti_(48)Zr_(20)(V_(12/17)Cu_(5/17))19 Be 13 obtained by the HV-HPDC process show ductility up to 11.3%under tension at room temperature and exhibit a certain amount of work *** conditions need to be met to enable the BMGCs,which are prepared by vacuum die-casting to retain favorable ductility:(1)The volume fraction ofβphase stays below 62%±2%;(2)The equiaxed crystals with a more uniform size in the range of 5-10μ***,the results of the present study provided guidance for developing BMGCs with good ductile properties under industrial conditions.

关键词： Vacuum die casting Bulk metallic glass composites Mechanical properties β-phase

C-Type Antiferromagnetic Structure of Topological Semimetal CaMnSb2

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Chinese Physics Letters 2024年第03期41卷 119-125页

作者：李博曾旭涛徐千惠杨帆项俊森钟恒扬邓司浩何伦华徐菊萍殷雯鲁兴业刘慧颖胜献雷金文涛 School of Physics Beihang University Beijing National laboratory for Condensed Matter Physics and Institute of PhysicsChinese Academy of Sciences Center for Advanced Quantum Studies and Department of Physics Beijing Normal University Spallation Neutron Source science Center songshan lake materials laboratory

Determination of the magnetic structure and confirmation of the presence or absence of inversion （P） and time reversal （Τ） symmetry is imperative for correctly understanding the topological magnetic materials. He... 详细信息

关键词： Density functional theory

Wide temperature range,air stable,transparent,and self-powered photodetectors enabled by a hybrid film of graphene and singlewalled carbon nanotubes

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Nano Research 2024年第7期17卷 6582-6593页

作者： Ying Yue Di Zhang Pengyu Wang Xin Wu Yuejuan Zhang Yanchun Wang Xiao Zhang Xiaojun Wei Huaping Liu Weiya Zhou Beijing National laboratory for Condensed Matter Physics and Institute of PhysicsChinese Academy of SciencesBeijing 100190China School of Physical sciences and College of materials science and Optoelectronic Technology University of Chinese Academy of SciencesBeijing 100049China songshan lake materials laboratory Dongguan 523808China Beijing Key laboratory for Advanced Functional materials and Structure Research Beijing 100190China

Transparent photovoltaic devices(TPVDs)have attracted increasing attention in emerging electronic *** the application scenarios extend,there raise higher requirements regarding the stability and operating temperature range of *** this work,a unique preparation strategy is proposed for air stable TPVD with a wide operating temperature range,i.e.,a nanoscale architecture termed as H-TPVD is constructed that integrates a free-standing and highly transparent conductive hybrid film of graphene and single-walled carbon nanotubes(G-SWNT TCF for short)with a metal oxide NiO/TiO_(2)*** preparation approach is suitable for scaling *** to the excellent transparent conductivity of the freestanding G-SWNT hybrid film and the ultrathin NiO/TiO_(2)heterojunction(100 nm),H-TPVD selectively absorbs the ultraviolet(UV)band of sunlight and has a transparency of up to 71%in the visible *** integrated nanoscale architecture manifests the significant holecollecting capability of the G-SWNT hybrid film and the efficient carrier generation and separation within the ultrathin NiO/TiO_(2)heterojunction,resulting in excellent performance of the H-TPVD with a specific detectivity of 2.7×10^(10) ***,the freestanding G-SWNT TCF is a super stable and non-porous two-dimensional film that can insulate gas molecules,thereby protecting the surface properties of NiO/TiO_(2)heterojunctions and enhancing the stability of *** subjected to 20,000 cycles and storage in air for three months,the performance parameters such as photo-response signal,output power,and specific detectivity show no noticeable *** particular,the as-fabricated self-powered H-TPVD can operate over a wide temperature range from −180 to 300℃,and can carry out solar-blind UV optical communication in this *** addition,the 4×4 array H-TPVD demonstrates clear optical *** results make it possible for H-TPVD to expand its potential application scenarios.

关键词： transparent photovoltaic devices hybrid films of graphene and single-walled carbon nanotubes metal oxides stability wide temperature range

Experimental determination of the Young’s modulus of individual single-walled carbon nanotubes with single chirality

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Nano Research 2024年第8期17卷 7522-7532页

作者： Jianlin Sun Xiao Zhang Yanchun Wang Mingming Li Xiaojun Wei Huaping Liu Weiya Zhou Beijing National laboratory for Condensed Matter Physics and Institute of PhysicsChinese Academy of SciencesBeijing 100190China School of Physical sciences and College of materials science and Optoelectronic Technology University of Chinese Academy of SciencesBeijing 100049China songshan lake materials laboratory Dongguan 523808China Beijing Key laboratory for Advanced Functional materials and Structure Research Beijing 100190China

One-dimensional carbon nanotube(CNT)exhibits excellent mechanical properties and is considered to be an ideal candidate material for the space ***,subtle changes in its chirality strongly affect its physical and chemical properties,including mechanical properties(such as Young's modulus,YM).Theoretical studies reveal that the YMs of perfect single-walled carbon nanotubes(SWCNTs)are in the order of TPa and related to their ***,due to the lack of SWCNTs samples with well-defined structures and the difficulties in mechanical tests on individual SWCNTs,the theoretical correlations between YM and structure of SWCNTs have not been verified and are still in debate,which directly influences the practical utilization of the excellent mechanical properties of *** this work,we have developed an experimental method to measure the YM of an individual micrometer-scale suspended CNT by atomic force microscopy.A distinct regularity is found between the YM and chirality(i.e.,chiral angle and diameter)of SWCNT in the experiment for the first *** comparing the YMs of SWCNTs with similar diameters and different chiral angles,it manifests that the SWCNT with a near zigzag configuration has a larger *** finding suggests that the effect of SWCNT’s structures on the YMs cannot be *** developed method of measuring YMs of SWCNTs will be valuable for further experimental research on the inherent physical and chemical properties of SWCNTs.

关键词： Young's modulus single-walled carbon nanotubes single chirality atomic force microscopy

Strain-enhanced polarization sensitivity inβ-Ga_(2)O_(3)photodetector

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science China(Physics,Mechanics & Astronomy) 2024年第4期67卷 126-137页

作者： Yonghui Zhang Huili Liang Fei Xing Qiqian Gao Yu Feng Yuping Sun Zengxia Mei School of Physics and Optoelectronic Engineering Shandong University of TechnologyZibo 255000China songshan lake materials laboratory Dongguan 523808China Institute of Physics Chinese Academy of SciencesBeijing 100190China

Polarization-sensitive photodetection and imaging have great application value in fields such as polarization division multiplexing optical communication,remote sensing,near-field imaging and military *** a high polarization ratio has always been the research hotspot in polarization-sensitive *** this paper,we report a compression strain enhanced polarization ratio inβ-gallium oxide(β-Ga_(2)O_(3))single crystal flake.A rigorous crystallographic analysis confirmed its high crystalline quality and ***-resolved polarization Raman spectroscopy(ARPRS)was adopted to study the anisotropy of its optical *** ARPRS measurements and theoretical calculation consistently demonstrate the strong optical anisotropy in the high-qualityβ-Ga_(2)O_(3)flake.A polarization ratio of 0.96 was obtained in the flatβ-Ga_(2)O_(3)***,mechanical strain of±0.7%was introduced intoβ-Ga_(2)O_(3).An increased polarization ratio of 0.98 was achieved in the case of 0.7%compression strain,which is,to the best of our knowledge,the highest value for UVC polarization-sensitive *** corresponds to an improved polarization rejection ratio of *** work proposed a new path towards improving polarization sensitivity by applying strain engineering in the active material.

关键词： gallium oxide polarization photodetector anisotropy strain

Cryo-EM combined with image deconvolution to determine ZIF-8 crystal structure

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Chinese Physics B 2024年第7期33卷 44-49页

作者：吴抗杨柏松薛文华孙大鹏葛炳辉王玉梅 Information materials and Intelligent Sensing laboratory of Anhui Province Leibniz International Joint Research Center of Materials Sciences of Anhui ProvinceInstitutes of Physical Science and Information TechnologyAnhui UniversityHefei 230601China Beijing National laboratory for Condensed Matter Physics Institute of PhysicsChinese Academy of SciencesBeijing 100190China Beijing Branch of songshan lake materials laboratory Dongguan 523808China

Metal–organic frameworks(MOFs) are crystalline porous materials with tunable properties, exhibiting great potential in gas adsorption, separation and catalysis.[1,2]It is challenging to visualize MOFs with transmission electron microscopy(TEM) due to their inherent instability under electron beam irradiation. Here, we employ cryo-electron microscopy(cryoEM) to capture images of MOF ZIF-8, revealing inverted-space structural information at a resolution of up to about 1.7A and enhancing its critical electron dose to around 20 e^(-)/A^(2). In addition, it is confirmed by electron-beam irradiation experiments that the high voltage could effectively mitigate the radiolysis, and the structure of ZIF-8 is more stable along the [100] direction under electron beam irradiation. Meanwhile, since the high-resolution electron microscope images are modulated by contrast transfer function(CTF) and it is difficult to determine the positions corresponding to the atomic columns directly from the images. We employ image deconvolution to eliminate the impact of CTF and obtain the structural images of ZIF-8. As a result, the heavy atom Zn and the organic imidazole ring within the organic framework can be distinguished from structural images.

关键词： cryo-electron microscopy(cryo-EM) ZIF-8 image deconvolution crystal structure determination

Effect of overheating-induced minor addition on Zr-based metallic glasses

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Chinese Physics B 2024年第3期33卷 118-125页

作者：杨福薄振兴黄瑶王雨田孙博阳鲁振孙保安柳延辉汪卫华潘明祥 Institute of Physics Chinese Academy of SciencesBeijing 100190China Center of materials science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China School of Physical sciences University of Chinese Academy of SciencesBeijing 100049China songshan lake materials laboratory Dongguan 523808China

Melt treatment is well known to have an important influence on the properties of metallic glasses(MGs).However,for the MGs quenched from different melt temperatures with a quartz tube,the underlying physical origin responsible for the variation of properties remains poorly *** the present work,we systematically studied the influence of melt treatment on the thermal properties of a Zr50Cu36Al14 glass-forming alloy and unveiled the microscopic ***,we quenched the melt at different temperatures ranging from 1.1Tl to 1.5Tl(Tl is the liquidus temperature)to obtain melt-spun MG ribbons and investigated the variation of thermal properties of the MGs upon *** found that glass transition temperature,Tg,increases by as much as 36 K,and the supercooled liquid region disappears in the curve of differential scanning calorimetry when the melt is quenched at a high temperature up to *** careful chemical analyses indicate that the change in glass transition behavior originates from the incorporation of oxygen and silicon in the molten *** incorporated oxygen and silicon can both enhance the interactions between atoms,which renders the cooperative rearrangements of atoms difficult,and thus enhances the kinetic stability of the MGs.

关键词： metallic glass thermal properties melt treatment overheating oxygen content