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Journal of Modern Power Systems and Clean energy 2016年第4期4卷 593-603页

作者： Xiangjun LI Liangzhong YAO Dong HUI State Key Laboratory of Control and Operation of Renewable energy and storage Systems China Electric Power Research InstituteBeijing 100192China

Battery energy storage system(BESS)is one of the effective technologies to deal with power fluctuation and intermittence resulting from grid integration of large renewable *** this paper,the system configuration of a China’s national renewable generation demonstration project combining a large-scale BESS with wind farm and photovoltaic(PV)power station,all coupled to a power transmission system,is introduced,and the key technologies including optimal control and management as well as operational status of this BESS are ***,the technical benefits of such a large-scale BESS in dealing with power fluctuation and intermittence issues resulting from grid connection of large-scale renewable generation,and for improvement of operation characteristics of transmission grid,are discussed with relevant case studies.

关键词： Battery energy storage systems Renewable generations Power fluctuation Battery energy management system Power control

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枯竭油气藏地下储氢技术研究进展（英文）

Engineering 2024年第9期40卷 211-225页

作者： Lingping Zeng Regina Sander Yongqiang Chen Quan Xie CSIRO energy Hydrogen Industry Mission CSIRO Permanent Carbon Locking Future Science Platform CSIRO Energy WA School of Mines: Minerals Energy and Chemical Engineering Curtin University

Hydrogen has emerged as a promising alternative to meet the growing demand for sustainable and renewable energy sources. Underground hydrogen storage(UHS) in depleted gas reservoirs holds significant potential for large-scale energy storage and the seamless integration of intermittent renewable energy sources, due to its capacity to address challenges associated with the intermittent nature of renewable energy sources, ensuring a steady and reliable energy supply. Leveraging the existing infrastructure and well-characterized geological formations, depleted gas reservoirs offer an attractive option for large-scale hydrogen storage implementation. However, significant knowledge gaps regarding storage performance hinder the commercialization of UHS operation. Hydrogen deliverability, hydrogen trapping, and the equation of state are key areas with limited understanding. This literature review critically analyzes and synthesizes existing research on hydrogen storage performance during underground storage in depleted gas reservoirs; it then provides a high-level risk assessment and an overview of the techno-economics of UHS. The significance of this review lies in its consolidation of current knowledge,highlighting unresolved issues and proposing areas for future research. Addressing these gaps will advance hydrogen-based energy systems and support the transition to a sustainable energy *** efficient and safe deployment of UHS in depleted gas reservoirs will assist in unlocking hydrogen's full potential as a clean and renewable energy carrier. In addition, this review aids policymakers and the scientific community in making informed decisions regarding hydrogen storage technologies.

关键词： Underground hydrogen storage storage performance Hydrogen deliverability Hydrogen trapping Risk assessment Techno-economic analysis

Simulation of gas-solid flow characteristics of the circulating fluidized bed boiler under pure-oxygen combustion conditions

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Chinese Journal of Chemical Engineering 2024年第6期70卷 9-19页

作者： Kaixuan Gao Xiwei Ke Bingjun Du Zhenchuan Wang Yan Jin Zhong Huang Yanhong Li Xuemin Liu Key Laboratory of Special Equipment Safety and energy-Saving for State Market Regulation China Special Equipment Inspection&Research InstituteBeijing 100029China Department of energy and Power Engineering Tsinghua UniversityBeijing 100084China School of Electrical and Power Engineering Taiyuan University of TechnologyTaiyuan 030024China

Under the pressure of carbon neutrality,many carbon capture,utilization and storage technologies have witnessed rapid development in the recent years,including oxy-fuel combustion(OFC)***,the conventional OFC technology usually depends on the flue gas recirculation system,which faces significant investment,high energy consumption,and potential low-temperature corrosion *** these deficiencies,the direct utilization of pure oxygen to achieve particle fluidization and fuel combustion may reduce the overall energy consumption and CO_(2)-capture *** this paper,the fundamental structure of a self-designed 130 t·h^(-1) pure-oxygen combustion circulating fluidized bed(CFB)boiler was provided,and the computational particle fluid dynamics method was used to analyze the gas-solid flow characteristics of this new-concept boiler under different working *** results indicate that through the careful selection of design or operational parameters,such as average bed-material size and fluidization velocity,the pure-oxygen combustion CFB system can maintain the ideal fluidization state,namely significant internal and external particle ***,the contraction section of the boiler leads to the particle backflow in the lower furnace,resulting in the particle suspension concentration near the wall region being higher than that in the center ***,the upper furnace still retains the classic core-annulus flow *** addition to increasing solid circulation rate by reducing the average bed-material size,altering primary gas ratio and bed inventory can also exert varying degrees of influence on the gas-solid flow characteristics of the pure-oxygen combustion CFB boiler.

关键词： Circulating fluidized bed Pure-oxygen combustion Gas-solid flow characteristics Simulation CO_(2)capture

High-stability temperature control and frequency-domain analysis of sandwich-like insulation design based on phase change materials for satellite thermal management

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Science China(Technological Sciences) 2024年第8期67卷 2387-2404页

作者： WANG ZiHan HE ChenBo HU Yang TANG GuiHua Key Laboratory of Thermo-Fluid Science and Engineering Ministry of EducationSchool of Energy and Power EngineeringXi’an Jiaotong UniversityXi’an 710049China

High-stability thermal management is critical for the measurements of high sensitivity for temperature, but also challenging because any small thermal disturbances could lead to unacceptable temperature fluctuations. The present work delivers a design for passive temperature control, customized for a component in the satellites for gravitational wave detection. A novel sandwichlike structure is proposed with the configurations of proper materials, consisting of a layer of insulation material and two layers of nanocomposite phase change materials, bringing an integration of heat insulation and absorption/storage. Its performance is examined using an improved thermal network model and the revised transfer function method(TFM). The basic results of the two methods are validated by present COMSOL simulations and available numerical and experimental data in the literature. An effective reduction of temperature fluctuation is achieved to the scale of 0.1 K, even under two thermal disturbances from different directions: a radiative heat flux of 20 W m~(-2)(inside) and a temperature fluctuation of about 20 K(outside). Moreover,the TFM is employed to analyze the effects of the frequency of thermal disturbance: excellent damping performance is obtained for over 3.2 mHz and the underlying mechanism is discussed. Overall, the present design is expected to be combined with active temperature control to explore more possible ways for temperature control with higher stability.

关键词： temperature control sandwich insulation structure phase change material thermal network model transfer function method

Robust Cross-Linked Na_(3)V_(2)(PO_(4))_(2)F_(3) Full Sodium-Ion Batteries

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energy & Environmental Materials 2024年第1期7卷 9-20页

作者： Jinqiang Gao Ye Tian Lianshan Ni Baowei Wang Kangyu Zou Yingchang Yang Ying Wang Craig E.Banks Dou Zhang Kechao Zhou Huan Liu Wentao Deng Guoqiang Zou Hongshuai Hou Xiaobo Ji College of Chemistry and Chemical Engineering Central South UniversityChangsha 410083China College of Material and Chemical Engineering Tongren UniversityTongren 554300China Department of Chemistry The Chinese University of Hong KongShatinN.T.Hong Kong S.A.R.China Faculty of Science and Engineering Manchester Metropolitan UniversityManchester UK State Key Laboratory of Powder Metallurgy Central South UniversityChangsha 410083China School of Materials Science and Engineering Hunan Provincial Key Lab of Advanced Materials for New Energy Storage and ConversionHunan University of Science and TechnologyXiangtan 411201China School of Materials and Engineering Zhengzhou UniversityZhengzhou 450001China

Sodium-ion batteries(SIBs)have rapidly risen to the forefront of energy storage systems as a promising supplementary for Lithium-ion batteries(LIBs).Na_(3)V_(2)(PO_(4))_(2)F_(3)(NVPF)as a common cathode of SIBs,features the merits of high operating voltage,small volume change and favorable specific energy ***,it suffers from poor cycling stability and rate performance induced by its low intrinsic ***,we propose an ingenious strategy targeting superior SIBs through cross-linked NVPF with multi-dimensional nanocarbon frameworks composed of amorphous carbon and carbon nanotubes(NVPF@C@CNTs).This rational design ensures favorable particle size for shortened sodium ion transmission pathway as well as improved electronic transfer network,thus leading to enhanced charge transfer kinetics and superior cycling *** from this unique structure,significantly improved electrochemical properties are obtained,including high specific capacity(126.9 mAh g^(-1)at 1 C,1 C=128 mA g^(-1))and remarkably improved long-term cycling stability with 93.9%capacity retention after 1000 cycles at 20 *** energy density of 286.8 Wh kg^(-1)can be reached for full cells with hard carbon as anode(NVPF@C@CNTs//HC).Additionally,the electrochemical performance of the full cell at high temperature is also investigated(95.3 mAh g^(-1)after 100 cycles at 1 C at 50℃).Such nanoscale dual-carbon networks engineering and thorough discussion of ion diffusion kinetics might make contributions to accelerating the process of phosphate cathodes in SIBs for large-scale energy storages.

关键词： dual-nanocarbon networks full sodium-ion battery ion transfer kinetics Na_(3)V_(2)(PO_(4))_(2)F_(3) NASICON structure

Research progresses on cathode materials of aqueous zinc-ion batteries

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Journal of energy Chemistry 2024年第10期97卷 237-264,I0005页

作者： Zengyuan Fan Jiawei Wang Yunpeng Wu Xuedong Yan Dongmei Dai Xing-Long Wu Jilin Provincial Science and Technology Innovation Centre of Optical Materials and Chemistry Jilin Provincial International Joint Research Center of Photo-functional Materials and ChemistrySchool of Chemistry and Environmental EngineeringChangchun University of Science and TechnologyChangchun 130022JilinChina PMOE Key Laboratory for UV LightEmitting Materials and Technology School of PhysicsNortheast Normal UniversityChangchun 130024JilinChina Chongqing Research Institute Changchun University of Science and TechnologyChongqing 401135China Institute of energy storage and Conversion Technology College of Chemical EngineeringNingbo PolytechnicNingbo 315800ZhejiangChina School of Chemistry and Chemical Engineering Henan Normal UniversityXinxiang 453007HenanChina

Electrochemical energy storage and conversion techniques that exhibit the merits such as high energy density,rapid response kinetics,economical maintenance requirements and expedient installation procedures will hold a pivotal role in the forthcoming energy storage technologies *** recent years,aqueous zinc-ion batteries(AZIBs)have garnered substantial attention as a compelling candidate for large-scale energy storage systems,primarily attributable to their advantageous featu res encompassing cost-effectiveness,environmental sustainability,and robust safety ***,one of the primary factors hindering the further development of AZIBs originates from the challenge of cathode ***,the three mainstream types of mainstream cathode materials,in terms of manganese-based compounds,vanadium-based compounds and Prussian blue analogues,surfer from the dissolution of Mn~(2+),in the low discharge voltage,and the low specific capacity,*** strategies have been developed to compensation the above intrinsic defects for these cathode materials,including the ionic doping,defect engineering,and materials ***,this review first provides a systematic summarization of the zinc storage mechanism in AZIBs,following by the inherent merit and demerit of three kind of cathode materials during zinc storage analyzed from their structure characteristic,and then the recent development of critical strategies towards the intrinsic insufficiency of these cathode *** this review,the methodologies aimed at enhancing the efficacy of manganese-based and vanadium-based compounds are emphasis ***,the article outlines the future prospective directions as well as strategic proposal for cathode materials in AZIBs.

关键词： Aqueous zinc-ion batteries Cathode materials Optimization strategies

Experimental investigation on the distribution uniformity and pressure drop of perforated plate distributors for the innovative spray-type packed bed thermal storage

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Particuology 2022年第2期20卷 60-73页

作者： Lin Lin Liang Wang Xipeng Lin Ningning Xie Haisheng Chen Institute of Engineering Thermophysics Chinese Academy of SciencesBeijing 100190China University of Chinese Academy of Sciences Beijing 100049China Dalian National Laboratory for Clean energy Chinese Academy of SciencesDalian 116023China National energy large scale Physical energy storage Technologies R&D Center of Bijie High-tech Industrial Development Zone Guizhou 551712China Institute of Science and Technology China Three Gorges CorporationBeijing 100038China

As an innovative thermal energy technology,the spray-type packed bed has advantages of high efficiency and low cost.A liquid distributor is the key component for the spray-type packed bed for scattering heat-transfer liquid drops *** this study,the distribution performance and pressure drop of the perforated plate distributors of different orifice diameters were studied *** experimental results indicate that orifice diameter has a greater effect on the distribution performance compared to flow *** an increase in flow rate,the flow pattern through the distributor changes from the uncovered drop to the covered drop and then to the jet *** covered drop pattern shows the best performance with a good distribution and a small pressure drop simultaneously,which is the design and optimization principle of the distributor for a spray-type packed bed.

关键词： Spray-type packed bed Perforated plate distributor Distribution Pressure drop Thermal energy storage

Seasonal thermal energy storage using natural structures:GIS-based potential assessment for northern China

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Building Simulation 2024年第4期17卷 561-574页

作者： Yichi Zhang Jianjun Xia Midea HVAC Heating&Ventilation Equipment Co. LtdFoshan528311China Building energy Research Center Tsinghua UniversityBeijing100084China

Seasonal thermal energy storage(STES)allows storing heat for long-term and thus promotes the shifting of waste heat resources from summer to winter to decarbonize the district heating(DH)*** being a promising solution for sustainable energy system,large-scale STES for urban regions is lacking due to the relatively high initial investment and extensive land *** close the gap,this study assesses the potentials of using two naturally available structures for STES,namely valley and ground pit *** on geographical information system(GIS)methods,the available locations are searched from digital elevation model and selected considering several criteria from land uses and construction *** costs of dams to impound the reservoir and the yielded storage capacities are then quantified to guide the choice of suitable *** assessment is conducted for the northern China where DH systems and significant seasonal differences of energy demand *** total,2,273 valley sites and 75 ground pit sites are finally identified with the energy storage capacity of 15.2 billion GJ,which is much larger than the existing DH demand in northern *** results also prove that 682 valley sites can be achieved with a dam cost lower than 20 CNY/m^(3).By conducting sensitivity analysis on the design dam wall height and elevations,the choices of available natural structures are expanded but practical issues about water pressures and constructions are also ***,the identified sites are geographically mapped with nearest urban regions to reveal their roles in the DH *** general,560 urban regions are found with potential STES units and most of them have STES storage capacities larger than their own DH *** novel planning methodology of this study and publicly available datasets create possibilities for the implementations of large-scale STES in urban DH systems.

关键词： seasonal thermal energy storage geographical information system district heating water reservoir

Temperature inversion enables superior stability for low-temperature Zn-ion batteries

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Journal of energy Chemistry 2024年第4期91卷 245-253页

作者： Fu-Da Yu Zhe-Jian Yi Rui-Yang Li Wei-Hao Lin Jie Chen Xiao-Yue Chen Yi-Ming Xie Ji-Huai Wu Zhang Lan Lan-Fang Que Bao-Sheng Liu Hao Luo Zhen-Bo Wang Engineering Research Center of Environment-Friendly Functional Materials Ministry of EducationInstitute of Materials Physical ChemistryHuaqiao UniversityXiamen 361021FujianChina b2 School of Electronic Engineering Guangxi University of Science and TechnologyLiuzhou 545006GuangxiChina School of Materials Science and Engineering Xiamen University of TechnologyXiamen 361024FujianChina School of Materials Science and Engineering Zhengzhou UniversityZhengzhou 450001HenanChina MIIT Key Laboratory of Critical Materials Technology for New energy Conversion and storage State Key Laboratory of Space Power-SourcesSchool of Chemistry and Chemical EngineeringHarbin Institute of TechnologyHarbin 150001HeilongjiangChina College of Materials Science and Engineering Shenzhen UniversityShenzhen 518071GuangdongChina

It is challenging for aqueous Zn-ion batteries(ZIBs)to achieve comparable low-temperature(low-T)performance due to the easy-frozen electrolyte and severe Zn ***,an aqueous electrolyte with a low freezing point and high ionic conductivity is *** with molecular dynamics simulation and multi-scale interface analysis(time of flight secondary ion mass spectrometry threedimensional mapping and in-situ electrochemical impedance spectroscopy method),the temperature independence of the V_(2)O_(5)cathode and Zn anode is observed to be ***,dominated by the solvent structure of the designed electrolyte at low temperatures,vanadium dissolution/shuttle is significantly inhibited,and the zinc dendrites caused by this electrochemical crosstalk are greatly relieved,thus showing an abnormal temperature inversion *** the disclosure and improvement of the above phenomena,the designed Zn||V_(2)O_(5)full cell delivers superior low-T performance,maintaining almost 99%capacity retention after 9500 cycles(working more than 2500 h)at-20°*** work proposes a kind of electrolyte suitable for low-T ZIBs and reveals the inverse temperature dependence of the Zn anode,which might offer a novel perspective for the investigation of low-T aqueous battery systems.

关键词： Aqueous Zn-ion batteries Low-temperature performance Opposite temperature dependence Zndendrite growth Vanadium dissolution

Facilitating prelithiation of silicon carbon anode by localized high-concentration electrolyte for high-rate and long-cycle lithium storage

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Carbon energy 2024年第6期6卷 216-233页

作者： Yuanxing Zhang Borong Wu Jiaying Bi Xinyu Zhang Daobin Mu Xin-Yu Zhang Ling Zhang Yao Xiao Feng Wu School of Materials Science and Engineering Beijing Institute of TechnologyBeijingChina Chongqing Innovation Center Beijing Institute of TechnologyChongqingChina College of New energy Xi′an Shiyou UniversityXi′anChina Institute for Carbon Neutralization College of Chemistry and Materials EngineeringWenzhou UniversityWenzhouChina Key Laboratory of Advanced energy Materials Chemistry(Ministry of Education) Nankai UniversityTianjinChina

The commercialization of silicon-based anodes is affected by their low initial Coulombic efficiency(ICE)and capacity decay,which are attributed to the formation of an unstable solid electrolyte interface(SEI)***,a feasible and cost-effective prelithiation method under a localized highconcentration electrolyte system(LHCE)for the silicon-silica/graphite(Si-SiO_(2)/C@G)anode is designed for stabilizing the SEI layer and enhancing the *** thin SiO_(2)/C layers with-NH_(2) groups covered on nano-Si surfaces are demonstrated to be beneficial to the prelithiation process by density functional theory calculations and electrochemical *** SEI formed under LHCE is proven to be rich in ionic conductivity,inorganic substances,and flexible organic ***,faster Li+transportation across the SEI further enhances the prelithiation effect and the rate performance of Si-SiO_(2)/C@G *** also leads to uniform decomposition and high stability of the SEI with abundant organic *** a result,the prepared anode shows a high reversible specific capacity of 937.5 mAh g^(-1)after 400 cycles at a current density of 1 *** 811‖Li-SSGLHCE full cell achieves a high-capacity retention of 126.15 mAh g^(-1)at 1 C over 750 cycles with 84.82%ICE,indicating the great value of this strategy for Si-based anodes in large-scale applications.

关键词： localized high-concentration electrolytes prelithiation SEI layer silicon anode