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Peroxidase-like nanozyme based microenvironment-responsive injectable hydrogel for bacteria-infected wound healing

science China Technological sciences 2024年第10期67卷 3247-3260页

作者： ZHOU Wei LI XiaNan TANG MengCheng PAN LingFeng WANG BeiBei ZHANG Hao ZHANG Han WANG ShiBo KONG XiangDong Institute of Smart Biomaterial materials School of Materials Science and EngineeringZhejiang University of Science & Technology Zhejiang-Mauritius Joint Research Center for Biomaterials and Tissue engineering Zhejiang University of Science & Technology

Hydrogel stands out as one of the most attractive wound dressings due to its excellent moisturizing properties and capacity to absorb wound exudates. However, conventional hydrogel dressings often lack responsiveness to the microenvironment, merely acting as protective barriers for the wound. Consequently, they exhibit limited effectiveness in preventing infection and facilitating wound repair. To address these problems, we have developed a multifunctional injectable hydrogel, CF/MS@HG, based on peroxidase-like nanozymes, aiming at rapidly healing bacterial-infected wounds. The hydrogel is mainly composed of oxidized sodium alginate, aminated gelatin, and polylysine, encapsulating MIL-101(CuFe) NPs(CF) and manganese selenide nanoparticles(MnSe2NPs, or MS NPs). After injection, the complex rapidly gelatinizes at the infected wound site through a Schiff base reaction. In vitro experiments have demonstrated the hydrogel's strong adhesion and self-healing ***, CF exhibiting peroxidase(POD)-like activity, catalyzes in situ hydrogen peroxide(H2O2) to generate highly toxic hydroxyl radicals(·OH) within the wound microenvironment, inducing oxidative damage to bacteria. Meanwhile, MS decomposes into H2Se in the slightly acidic wound microenvironment, disrupting bacterial metabolism and inhibiting *** addition of polylysine further enhances the hydrogel's antibacterial properties. In vivo experiments have shown that the hydrogel exhibits excellent biological safety and significantly promotes wound healing. This multifunctional smart hydrogel holds great promise for the treatment of bacterial-infected wounds.

关键词： peroxidase-like nanozyme manganese selenide injectable hydrogel bacterial infection wound healing

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Metal±organic cage as fluorescent probe for LiPF6 in lithium batteries

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Green Energy & Environment 2024年第10期9卷 1592-1600页

作者： Xi Li Dehua Xu Aoxuan Wang Chengxin Peng Xingjiang Liu Jiayan Luo Key Laboratory for Green Chemical Technology of Ministry of Education School of Chemical Engineering and TechnologyTianjin University school of materials science and engineering University of Shanghai Science and Technology State Key Laboratory of Metal Matrix Composites School of Materials Science and EngineeringShanghai Jiao Tong University

Lithium hexafluorophosphate （LiPF6）,the most commonly used lithium battery electrolyte salt,is vulnerable to heat and *** and qualitative determination the variation of Li PF6have always relied on advanced ***,we develop a fast,convenient,high-selective fluorescence detection method based on metal±organic cages （MOC）,whose emission is enhanced by nearly 20 times in the presence of Li PF6with good stability and photobleaching *** fluorescent probe can also detect moisture in battery *** propose and verify that the luminescence enhancement is due to the presence of hydrogen bond-induced enhanced emission effect in *** excitation-emission matrix spectra and variable-temperature nuclear magnetic resonance spectroscopy are employed to clarify the role of hydrogen bonds in guest-loaded *** functional theory （DFT） calculation is applied to simulate the structure of host-guest complexes and estimate the adsorption energy involved in the *** precisely matched lock-and-key model paves a new way for designing and fabricating novel host structures,enabling specific recognition of other target compounds.

关键词： Metal-organic cage Selective fluorescence probe Moisture detection Hydrogen bond Host-guest complex

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Effect of temperature and time on the precipitation ofκ-carbides in Fe-28Mn-10Al-0.8C low-density steels:Aging mechanism and its impact on material properties

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International Journal of Minerals,Metallurgy and materials 2024年第10期31卷 2189-2198页

作者： Yulin Gao Min Zhang Rui Wang Xinxin Zhang Zhunli Tan Xiaoyu Chong school of Mechanical Electronic and Control EngineeringMaterials Science and Engineering Research CenterBeijing Jiaotong UniversityBeijing 100044China Faculty of materials science and engineering Kunming University of Science and TechnologyKunming 650093China

In low-density steel,κ-carbides primarily precipitate in the form of nanoscale particles within austenite ***,their precipitation within ferrite matrix grains has not been comprehensively explored,and the second-phase evolution mechanism during aging remains *** this study,the crystallographic characteristics and morphological evolution ofκ-carbides in Fe-28Mn-10Al-0.8C(wt%)low-density steel at different aging temperatures and times and the impacts of these changes on the steels’microhardness and properties were comprehensively *** different heat treatment conditions,intragranularκ-carbides exhibited various morpho-logical and crystallographic characteristics,such as acicular,spherical,and short rod-like *** the initial stage of aging,acicularκ-carbides primarily precipitated,accompanied by a few spherical carbides.κ-Carbides grew and coarsened with aging time,the spherical carbides were considerably reduced,and rod-like carbides *** hardness testing demonstrated that the material’s hardness was affected by the volume fraction,morphology,and size ofκ-*** aging at higher temperatures led to an increase in carbide size and volume fraction,resulting in a gradual rise in *** deformation,the primary mechanisms for strengthening were dislocation strengthening and second-phase *** on these findings,potential strategies for improving material strength are proposed.

关键词： low-density steel κ-carbide solution-aging treatment hardness

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Improved piezoelectric and luminescent properties in Sm-modified Bi_(0.5)Na_(0.5)TiO_(3)-BaTiO_(3) multifunctional ceramics

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Journal of Materiomics 2024年第4期10卷 803-810页

作者： Shuai Cheng Kehong Zhang Chongyang Li Boping Zhang Jianguo Chen Kang Sun Changrong zhou Jingtai Zhao Qisheng Lin Guanghui Rao Siqi Shi school of materials science and engineering Shanghai UniversityShanghai200444China Guangxi Key Laboratory of Information materials&school of materials science and engineering Guilin University of Electronic TechnologyGuilin541004GuangxiChina school of materials science and engineering University of Science and Technology BeijingBeijing100083China school of Information engineering Lanzhou University of Finance and EconomicsLanzhou730020China

The 0.93(Na_(0.5)Bi_(0.5))_(1–x)Sm_(x)TiO_(3)-0.07BaTiO_(3) multifunctional ceramics were prepared by solid-phase reaction *** phase structure,microstructure,electrical and photoluminescent properties were systematically *** increasing x,the ceramics undergoes the phase transition from rhombohedral to tetragonal with some rhombohedral distortion,along with a reduced grain size and increased relative *** the other hand,the Sm3+doping enhances the electric-field driven reversible phase transition and domain size,and reduces the domain walls,thereby contributing to improved piezoelectricity and decreased depolarization temperature(T_(d))from 91℃ to 40℃.Excellent piezoelectric properties of d_(33)=213 pC/N and kp=29.9% are achieved in the x=0.010 *** excitation(407 nm),the Sm^(3+)-doped ceramic exhibits bright reddish-orange fluorescence at 564,599,646 nm and 710 nm.A polarization-induced enhancement of photoluminescence is obtained in BNBT-_(x)Sm ceramics with an improved relative intensity of emission band at 646 *** results indicate that Sm^(3+)-doped BNBT ceramics show great potential in electro-optic integration and coupling device applications.

关键词： Piezoelectricity Curie temperature Phase transitions Thermal stability Photoluminescence

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Bifunctional electrolyte addition for longer life and higher capacity of aqueous zinc-ion hybrid supercapacitors

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Rare Metals 2024年第10期43卷 5060-5069页

作者： Fan Zhang Si-Qi Li Li-Nan Xia Chao Yang Lei Li Kai-Ming Wang Chen-Liang Xu Yuan-Yuan Feng Bin Zhao Fei Shen Xiao-Gang Han Ling-Yun Zhu school of Electric Power Civil Engineering and ArchitectureShanxi University State Key Laboratory of Electrical Insulation and Power Equipment School of Electrical EngineeringXi’an Jiaotong University Department of science materials and engineering National University of Singapore school of materials science and engineering Anhui University

Owing to uncontrolled and uneven electrodeposition and side reactions,Zn metal anodes inevitably suffer from issues such as dendrite growth,hydrogen evolution reactions,and surface *** paper proposes an efficient strategy to address these critical issues for realizing long-life and high-capacity aqueous zinc-ion hybrid supercapacitors （ZHSCs） by incorporating low-concentration (0.05 mol·L-1) redox RbI electrolyte ***,rubidium cations have the ability to influence the negative Zn electrode surface via an electrostatic shielding mechanism,effectively protecting the electrode and minimizing undesired side *** an aqueous solution,iodide anions actively solvate Zn2+ions by stabilizing and modulating the solvation shell surrounding Zn2+.Moreover,the presence of iodide ions promotes the uniform deposition of Zn2+species by selective adsorption onto the electrode *** synergistic effect of the electrostatic shielding and halogen ions enables the realization of aqueous symmetric Zn||Zn cells with a substantial cycle life of more than 2000 h Additionally,when applied to commercial activated carbon（AC）,the proposed strategy facilitates the development of aqueous ZHSCs,exhibiting high specific capacitances(148.8 F·g-1at 4 A·g-1) and ultra-long cycling stability.

关键词： Aqueous zinc-ion hybrid supercapacitor Rubidium iodide Synergistic effects of anions and cations Zn dendrite Zn metal anode

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Oxidation behavior of FeV_(2)O_(4)and FeCr_(2)O_(4)particles in the air:Nonisothermal kinetic and reaction mechanism

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International Journal of Minerals,Metallurgy and materials 2024年第8期31卷 1839-1848页

作者： Junyi Xiang Xi Lu Luwei Bai Hongru Rao Sheng Liu Qingyun Huang Shengqin Zhang Guishang Pei Xuewei Lü school of Metallurgy and materials engineering Chongqing University of Science and TechnologyChongqing 401331China Department of materials science and engineering Seoul National UniversitySeoul 08826Rep.of Korea College of materials science and engineering Chongqing UniversityChongqing 400044China

High-temperature oxidation behavior of ferrovanadium(FeV_(2)O_(4))and ferrochrome(FeCr_(2)O_(4))spinels is crucial for the application of spinel as an energy material,as well as for the clean usage of high-chromium vanadium ***,the nonisothermal oxidation behavior of FeV_(2)O_(4)and FeCr_(2)O_(4)prepared by high-temperature solid-state reaction was examined by thermogravimetry and X-ray diffraction(XRD)at heating rates of 5,10,and 15 K/*** apparent activation energy was determined by the Kissinger-Akahira-Sunose(KAS)method,whereas the mechanism function was elucidated by the Malek ***,in-situ XRD was conducted to deduce the phase transformation of the oxidation mechanism for FeV_(2)O_(4)and FeCr_(2)O_(4).The results reveal a gradual increase in the overall apparent activation energies for FeV_(2)O_(4)and FeCr_(2)O_(4)during *** stages of the oxidation process are observed based on the oxidation conversion rate of each *** oxidation mechanisms of FeV_(2)O_(4)and FeCr_(2)O_(4)are complex and have distinct *** particular,the chemical reaction controls the entire oxidation process for FeV_(2)O_(4),whereas that for FeCr_(2)O_(4)transitions from a three-dimensional diffusion model to a chemical reaction *** to the in-situ XRD results,numerous intermediate products are observed during the oxidation process of both compounds,eventually resulting in the final products FeVO_(4)and V2O_(5)for FeV_(2)O_(4)and Fe_(2)O_(3)and Cr_(2)O_(3)for FeCr_(2)O_(4),respectively.

关键词： FeV_(2)O_(4) FeCr_(2)O_(4) oxidation nonisothermal kinetics mechanism

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Oxygen-assisted zinc recovery from electric arc furnace dust using magnesium chloride

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International Journal of Minerals,Metallurgy and materials 2024年第10期31卷 2300-2311页

作者： Jingdong Huang Xiao Yang school of materials science and engineering Zhejiang UniversityHangzhou 310027China school of engineering Westlake UniversityHangzhou 310030China

Electric arc furnace(EAF)dust is an important secondary resource containing metals,such as zinc(Zn)and iron(Fe).Recover-ing Zn from EAF dust can contribute to resource recycling and reduce environmental ***,the high chemical stability of ZnFe_(2)O_(4)in EAF dust poses challenges to Zn *** address this issue,a facile approach that involves oxygen-assisted chlorination using molten MgCl_(2)is *** work focused on elucidating the role of O2 in the reaction between ZnFe_(2)O_(4)and molten MgCl_(2).The results demonstrate that MgCl_(2)effectively broke down the ZnFe_(2)O_(4)structure,and the high O2 atmosphere considerably promoted the sep-aration of Zn from other components in the form of ZnCl_(2).The presence of O2 facilitated the formation of MgFe_(2)O_(4),which stabilized Fe and prevented its ***,the excessive use of MgCl_(2)resulted in increased evaporation loss,and high temperatures pro-moted the rapid separation of *** on these findings,we successfully extracted ZnCl_(2)-enriched volatiles from practical EAF dust through oxygen-assisted *** optimized conditions,this method achieved exceptional Zn chlorination percentage of over 97%within a short period,while Fe chlorination remained below 1%.The resulting volatiles contained 85wt%of ZnCl_(2),which can be further processed to produce metallic *** findings offer guidance for the selective recovery of valuable metals,particularly from solid wastes such as EAF dust.

关键词： electric arc furnace dust zinc oxygen magnesium chloride chlorination

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A universal and ultrafast method for fabricating a library of nanocellulose-supported metal nanoparticles

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Progress in Natural science:materials International 2024年第2期34卷 389-395页

作者： Ziyi Luo Xiaoyang Wang Baihua Cui Hao Luo Tao Zhang Jia Ding Yanan Chen Yida Deng Wenbin Hu school of materials science and engineering Tianjin University Department of Chemistry National University of Singapore State Key Laboratory of Marine Resource Utilization in South China Sea School of Materials Science and Engineering Hainan University

Using nanocatalysts to catalyze water electrolysis for hydrogen production is an ideal solution to address the energy *** most well-adopted fabrication methods for nanocatalysts are tube furnace annealing,Hydrothermal method,etc.,hardly satisfying the trade-off among coarsening,dispersity,and particle size due to mutual ***,a universal,ultrafast and facile cellulose nanometer whiskers-high temperature shock（CNWHTS） method was reported for fabricating a library of ultrafine metal nanoparticles with uniform dispersion and narrow size *** metal-anchor functional groups in CNW（i.e.,-OH and-COOH） and the characteristics of the HTS method for ultrafast heating and powerful quenching synergistically contribute to the successful synthesis of metal *** an initial demonstration,the as-prepared Pt nanocatalyst(η10 mA cm-2=51.8 mV) shows more excellent catalytic hydrogen evolution reaction（HER） performance than the Pt catalyst prepared in the tubular furnace(η10 mA cm-2=169.4 mV).This rapid and universal CNW-HTS method can pave the way for nanomanufacturing to produce high-quality metal nanoparticles,thereby expanding applications of energy conversion and electrocatalysis.

关键词： Electrocatalysis High-temperature shock Hydrogen evolution reaction (HER) Nanocellulose Nanomanufacturing Nanoparticles

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Contrasting strategies of optimizing carrier concentration in bulk InSe for enhanced thermoelectric performance

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Rare Metals 2024年第9期43卷 4425-4432页

作者： Hao-Nan Shi Shu-Lin Bai Yu-Ping Wang Li-Zhong Su Qian Cao Cheng Chang Li-Dong Zhao school of materials science and engineering Beihang UniversityBeijing 100191China school of materials science and engineering Taiyuan University of Science and TechnologyTaiyuan 030024China Huabei Cooling Device Co.Ltd. Hebei 065400China

Indium selenide(InSe),as a wide-bandgap semiconductor,has received extensive attention in the flexible electronics field in recent years due to its exceptional plasticity and promising thermoelectric ***,the low carrier concentration severely limits its thermoelectric performance *** this work,we conducted contrasting strategies that can be employed to increase the carrier concentration of InSe,including bandgap narrowing and heterovalent ***,the carrier concentration initially increases as a result of the reduced bandgap upon Te alloying and then slightly decreases due to the weak electronegativity of *** Br doping realizes high carrier concentration by pushing the Fermi level into the conduction bands and activating the multiple *** the other hand,both Te and Br obviously suppress the thermal conductivity due to the point defect *** contrast,Br doping realizes a higher thermoelectric performance with a maximum ZT of~0.13 at 773 K benefiting from the better optimization of carrier *** work elucidates the strategies for enhancing carrier concentration at anion sites and demonstrates the high efficiency of halogen doping in ***,the carrier concentration of InSe is promising to be further optimized,and future work should focus on employing approaches such as cation doping or secondphase compositing.

关键词： Thermoelectric InSe Carrier concentration Bandgap Heterovalent doping

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Simple preparation of C(CS)/g-C_(3)N_(4)/Co carbon aerogel and its catalytic performance for ammonium perchlorate

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Defence Technology（防务技术） 2024年第3期33卷 186-196页

作者： Yujie Yan Bo Jin Rufang Peng State Key Laboratory of Environment-friendly Energy materials School of Materials Science and EngineeringSouthwest University of Science and TechnologyMianyang621010China

Biomass chitosan(CS)was used as a template,graphitic phase carbon nitride(g-C_(3)N_(4))with high nitrogen content and certain catalytic activity was used as a dopant,and nano-transition metal cobalt(Co)was used as a catalytic center *** carbon aerogel(C(CS)/g-C_(3)N_(4)/Co)with a three-dimensional network-like structure was prepared by assembling the three materials through experimental operations such as freeze-drying and high-temperature *** was demonstrated by scanning and transmission characterization that the CS in the carbon aerogel could provide more active sites for the cobalt nanoparticles,and the doping of graphite-phase carbon nitride as a template dispersed the cobalt nanoparticles and changed the conductivity of the *** investigate the catalytic effect of carbon aerogel on ammonium perchlorate(AP),it was investigated by differential thermal analyzer and TG thermal *** carbon aerogel was very effective in catalyzing AP,and the 10 wt% content of the catalyst reduced the AP pyrolysis peak from 703.9 to 595.5 *** to further investigate the synergistic effect of the three materials,further carbon aerogels such as C(CS)/Co,g-C_(3)N_(4)/Co were prepared and applied to catalyze AP,and the same ratio reduced the AP pyrolysis peak by 98.1℃ and 97.7℃.This result indicates a synergistic effect of the assembly of the three materials.

关键词： g-C_(3)N_(4) Chitosan Co Ammonium perchlorate Pyrolysis kinetics

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