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Precise separation and efficient recovery of Pd(Ⅱ) from high-level liquid waste by XAD-based adsorbents

Rare Metals 2024年第10期43卷 5372-5390页

作者： Hao-Ran Dong Shun-Yan Ning Zeng-Yuan Li Si-Zhi Xu Feng-Tao Hu Feng Gao You-Bin Wang Li-Feng Chen Xiang-Biao Yin Toyohisa Fujita Mohammed F.Hamza Yue-Zhou Wei school of Resources Environment and MaterialsGuangxi University school of Nuclear science and Technology University of South China

Efficient separation of palladium (Pd（II）) from high-level liquid waste （HLLW） not only helps the safe disposal of nuclear waste,but also is a vital importan supplement to Pd（II） ***,16 kinds of nove Amberlite XAD resins-based adsorbents were prepared by vacuum impregnation method for the separation of Pd（II）from simulated HLLW,and the MMBT/XAD7HP prepared using 4-methyl-2-mercaptobenzothiazole （MMBT） as ligand and Amberlite XAD7HP resin （XAD7HP） as the carrier was selected as the optimal research *** analysis experiments proved the successful preparation of MMBT/XAD7HP,which exhibited ultrahigh adsorption selectivity for Pd（II）(distribution coefficient （Kd）≥12584.5 ml·g-1,separation factor (SFPd/M)≥2818.4) and superior adsorption capacity(Q≥130.1 mg·g-1).The adsorption kinetics and adsorption isotherms for Pd（II） matched with pseudo-secondorder （PSO） kinetics model and Langmuir model,indicating that the adsorption mode for Pd（II） by MMBT/XAD7 HP was monolayer chemical *** dynamic column experiments showed that MMBT/XAD7 HP achieved efficiently separation of Pd（II） from simulated HLLW,and the recovery rate was nearly 100% The adsorption mechanism was analyzed by Fourier transform infrared spectroscopy （FTIR）,X-ray photoelectron spectroscopy （XPS） and density functional theory（DFT）,and the ultrahigh selectivity of MMBT/XAD7 HP is attributed to the preferred affinity of the soft-N,S donor atoms in MMBT for Pd（II）.MMBT has the shortest frontline molecular orbital energy band gap （HOMO–LUMO） among the four ligands,which makes it easier to become an electron donor to attract Pd2+to participate in ***3-participates in the adsorption to keep charge *** summary,MMBT/XAD7 HP has broad application prospects for the treatment of Pd（II） in HLLW

关键词： Adsorption Column experiments HLLW Palladium XAD

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Building a domain-specific compiler for emerging processors with a reusable approach

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science China(Information sciences) 2024年第1期67卷 20-38页

作者： Mingzhen LI Yi LIU Bangduo CHEN Hailong YANG Zhongzhi LUAN Depei QIAN State Key Laboratory of Software Development environment school of Computer science and Engineering Beihang University

High-performance computing and deep learning domains have been motivating the design of domain-specific *** these processors can provide promising computation capability,they are notorious for exotic programming *** improve programming productivity and fully exploit the performance potential of these processors,domain-specific compilers(DSCs) have been ***,building DSCs for emerging processors requires tremendous engineering efforts because the commonly used compilation stack is difficult to be *** to the advent of multilevel intermediate representation(MLIR),DSC developers can leverage reusable infrastructure to extend their customized functionalities without rebuilding the entire compilation *** this paper,we further demonstrate the effectiveness of MLIR by extending its reusable infrastructure to embrace a heterogeneous many-core processor(Sunway processor).In particular,we design a new Sunway dialect and corresponding backend for the Sunway processor,fully exploiting its architectural advantage and hiding its programming *** show the ease of building a DSC,we leverage the Sunway dialect and existing MLIR dialects to build a stencil compiler for the Sunway *** experimental results show that our stencil compiler,built with a reusable approach,can even perform better than state-of-the-art stencil compilers.

关键词： domain-specific compiler emerging processor reusable dialect performance optimization MLIR

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Novel Cs-Mg-Al mixed oxide with improved mobility of oxygen species for passive NOx adsorption

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Green Energy & environment 2024年第10期9卷 1581-1591页

作者： Yimeng Yin Chizhong Wang Lei Qiu Xing Li Feilin Zhao Jie Yu Jinchi Han Huazhen Chang school of environment and Natural Resources Renmin University of China Department of Earth System science Tsinghua University

The development of passive NOxadsorbers with cost-benefit and high NOxstorage capacity remains an on-going challenge to after-treatment technologies at lower temperatures associated with cold-start ***,Cs1Mg3Al catalyst prepared by sol±gel method was cyclic tested in NOxstorage under 5 vol%*** 100°C,the NOxstorage capacity (1219μmol g-1) was much higher than that of Pt/Ba O/Al2O3(610μmol g-1).This provided new insights for non-noble metal catalysts in low-temperature passive *** addition of Cs improved the mobility of oxygen species and thus improved the NOxstorage *** XRD,XPS,IR spectra and in situ DRIFTs with NH3probe showed an interaction between CsOxand AlOxsites via oxygen species formed on Cs1Mg3Al *** improved mobility of oxygen species inferred from O2-TPD was consistent with high NOxstorage capacity related to enhanced formation of nitrate and additional nitrite species by ***,the addition of Mg might improve the stability of Cs1Mg3Al by stabilizing surface active oxygen species in cyclic experiments.

关键词： Passive NO x adsorber Low-temperature NO x storage Cesium Oxygen mobility

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Fast flow simulation study of pulsating ventilation performance on air contaminant removal

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Building Simulation 2024年第8期17卷 1309-1322页

作者： Pengzhi Zhou Haidong Wang Yuwei Dai Chen Huang school of environment and Architecture University of Shanghai for Science and Technology516 Jungong RoadShanghai200093China

Fast flow simulation is imperative in the design of pulsating ventilation,which is potentially efficient in indoor air contaminant *** execution of the conventional CFD method requires considerable amount of computational *** this study,five different numerical schemes were proposed based on fast fluid dynamics(FFD)and fractional step(FS)methods,and were evaluated to achieve quick simulation of airflow/contaminant *** of these numerical schemes was identified with the best overall computing efficiency for investigating the performance of pulsating *** this numerical scheme at hand,the air contaminant removal effectiveness of different ventilation types was *** kinds of pulsating ventilation and one kind of steady ventilation were tested upon a benchmark isothermal mixing *** effect of adjusting supply velocity parameters on the ventilation performance was also ***_(2)concentration,airflow pattern,and vortex structure of different ventilation types were illustrated and *** results reveal that the FS method is more suitable for transient simulation of wall-bounded indoor airflow than the FFD method,and 34%–51%of computing time could be saved compared to the conventional CFD *** the choice of ventilation type,steady ventilation might result in short-circuit airflow and stagnant zones;alternatively,pulsating ventilation has greater potential in air contaminant removal due to its ever-changing vortex structure.

关键词： pulsating ventilation fast fluid dynamics fractional step method contaminant removal efficiency time-periodic supply vortex structure

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Protein crystallization with DNA templates

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Particuology 2024年第3期86卷 262-268页

作者： Bo Zhang Jia Yu Zhe Pu Wenhui Guo Ruoqi Yang Yu Wen Zhijiang Rong Hui Wang Xiaoli Wu Bo Wang Hongyan Sun school of environment and Resources Taiyuan University of Science and TechnologyTaiyuan030024China school of Chemical Engineering and Technology Taiyuan University of Science and TechnologyTaiyuan030024China

Protein crystallization plays a significant role in three-dimensional structural analysis and protein *** is important to increase the crystallization efficiency,which is possible by adding hetero-geneous templates in crystallization *** is biologically compatible and artificially designable polymer,which is easy to *** this study,single-and double-stranded DNA of precise sequences were designed and used as templates to promote protein crystallization of lysozyme and ***-fluence of DNA,single-stranded DNA with 10,20,40 bases and double-stranded DNA with 10,20,40 base pairs,were *** success rate of obtaining crystals of lysozyme and catalase in equal period was significantly improved with the addition of DNA comparing without templates ***-stranded DNA led to higher nucleation rate than that with single-stranded *** promotion of nucleation was more obvious at low concentration of protein solution and with longer chain DNA *** number and crystallization rate was enhanced with addition of long double-stranded DNA *** the results confirm that DNA is an effective polymer additive to enhance protein crystallization,especially for the application of the scarce protein crystallization.

关键词： DNA Polymer Additive Protein Crystallization

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Straw addition increases enzyme activities and microbial carbon metabolism activities in bauxite residue

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Journal of environmental sciences 2024年第1期135卷 332-344页

作者： Hao Wu Wei Sun Feng Zhu Yifan Jiang Shiwei Huang Johnvie Goloran Shengguo Xue school of Minerals Processing and Bioengineering Central South UniversityChangsha 410083China school of Metallurgy and environment Central South UniversityChangsha 410083China school of environment and science Griffith UniversityBrisbaneQLD 4072Australia

Recovery of microbial functions is one of the critical processes in the nutrient cycling of bauxite residue for improving *** is considered to be effective to increase microbial diversity and drive the development of the microbial community,but its effect on microbial carbon metabolism has not been *** present study evaluated the effects of phosphogypsum(PG),straw(SF)and phosphogypsum plus straw(PGSF)on physicochemical properties,enzyme activities,and microbial carbon metabolism activities in bauxite *** 180 days incubation,PG,SF and PGSF treatment significantly reduced the residue pH from 10.85 to 8.64,9.39 and 8.06,*** to CK treatment,SF treatment significantly increased the content of total organic carbon(TOC)and organic carbon fractions(DOC,MBC,EOC,and POC).In addition,straw addition significantly increased glucosidase,cellulose,urease,and alkaline phosphatase by 7.2-9.1 times,5.8-7.1 times,11.1-12.5 times,and 1.1-2.2 times,*** Biolog results showed that straw addition significantly increased microbial metabolic activity(AWCD)and diversity in bauxite *** analysis indicated total nitrogen(TN)and carbon fractions(POC,MBC and DOC)were the most important environmental factors affecting microbial metabolic activity and diversity in bauxite *** findings provided us with a biogeochemical perspective to reveal soil formation in bauxite residue and suggested that nutrient supplement and regulation of salinity-alkalinity benefit the establishment of microbial communities and functions in bauxite residue.

关键词： Bauxite residue Labile organic carbon fractions Enzyme activities Community-level physiological profiles Soil formation in bauxite residue

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An approach to estimate tree height using PolInSAR data constructed by the Sentinel-1 dual-pol SAR data and RVoG model

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Journal of Electronic science and Technology 2024年第3期22卷 69-79页

作者： Yin Zhang Ding-Feng Duan school of Resources and environment University of Electronic Science and Technology of ChinaChengdu611731China

We estimate tree heights using polarimetric interferometric synthetic aperture radar(PolInSAR)data constructed by the dual-polarization(dual-pol)SAR data and random volume over the ground(RVoG)*** the Sentinel-1 SAR dual-pol(SVV,vertically transmitted and vertically received and SVH,vertically transmitted and horizontally received)configuration,one notes that S_(HH),the horizontally transmitted and horizontally received scattering element,is *** S_(HH)data were constructed using the SVH data,and polarimetric SAR(PolSAR)data were *** proposed approach was first verified in simulation with satisfactory *** was next applied to construct PolInSAR data by a pair of dual-pol Sentinel-1A data at Duke Forest,North Carolina,*** to local observations and forest descriptions,the range of estimated tree heights was overall *** the heights with the ICESat-2 tree heights at 23 sampling locations,relative errors of 5 points were within±30%.Errors of 8 points ranged from 30%to 40%,but errors of the remaining 10 points were>40%.The results should be encouraged as error reduction is *** instance,the construction of PolSAR data should not be limited to using SVH,and a combination of SVH and SVV should be ***,an ensemble of tree heights derived from multiple PolInSAR data can be considered since tree heights do not vary much with time frame in months or one season.

关键词： Constructed polarimetric SAR data Dual polarization Sentinel-1 SAR data Polarimetric interferometric SAR Random volume over the ground model Tree height estimation

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Inherent thermal-responsive strategies for safe lithium batteries

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Journal of Energy Chemistry 2024年第2期89卷 519-534,I0012页

作者： Jia-Xin Guo Chang Gao He Liu Feng Jiang Zaichun Liu Tao Wang Yuan Ma Yiren Zhong Jiarui He Zhi Zhu Yuping Wu Xin-Bing Cheng school of Energy and environment Southeast UniversityNanjing 211189JiangsuChina school of Chemistry and Materials science Nanjing University of Information Science and TechnologyNanjing 210044JiangsuChina

Safe batteries are the basis for next-generation application scenarios such as portable energy storage devices and electric vehicles,which are crucial to achieving carbon ***,separators,and electrodes as main components of lithium batteries strongly affect the occurrence of safety *** materials,which can respond to external stimuli or environmental change,have triggered extensive attentions recently,holding great promise in facilitating safe and smart *** review thoroughly discusses recent advances regarding the construction of high-safety lithium batteries based on internal thermal-responsive strategies,together with the corresponding changes in electrochemical performance under external ***,the existing challenges and outlook for the design of safe batteries are presented,creating valuable insights and proposing directions for the practical implementation of safe lithium batteries.

关键词： Lithium battery Thermal safety Thermal runaway Thermal-responsive

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Theoretical insights of the pharmaceutical compound fluoxetine in water:Role in direct photolysis and indirect photolysis by free radicals

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Journal of environmental sciences 2024年第8期142卷 269-278页

作者： Ying Lu Se Wang Yifan Shen school of environmental science and Engineering Collaborative Innovation Center of Atmospheric Environment and Equipment TechnologyJiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution ControlNanjing University of Information Science and TechnologyNanjing 210044China

The frequent detection of pharmaceutical compounds in the environment has led to a growing awareness,which may pose a major threat to the aquatic *** this study,photodegradation(direct and indirect photolysis)of two different dissociation states of fluoxetine(FLU)was investigated in water,mainly including the determination of photolytic transition states and products,and the mechanisms of indirect photodegradation with·OH,CO_(3)^(*-)and NO_(3)^(*).The main direct photolysis pathways are defluorination and C–C bond *** addition,the indirect photodegradation of FLU in water is mainly through the reactions with·OH and NO_(3)^(*),and the photodegradation reaction with CO_(3)^(*-)is relatively difficult to occur in the water *** results provide a theoretical basis for understanding the phototransformation process of FLU in the water environment and assessing its potential risk.

关键词： Fluoxetine Photochemical mechanism Direct photolysis Free radical reaction DFT

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Simple preparation of C(CS)/g-C_(3)N_(4)/Co carbon aerogel and its catalytic performance for ammonium perchlorate

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Defence Technology（防务技术） 2024年第3期33卷 186-196页

作者： Yujie Yan Bo Jin Rufang Peng State Key Laboratory of environment-friendly Energy Materials School of Materials Science and EngineeringSouthwest University of Science and TechnologyMianyang621010China

Biomass chitosan(CS)was used as a template,graphitic phase carbon nitride(g-C_(3)N_(4))with high nitrogen content and certain catalytic activity was used as a dopant,and nano-transition metal cobalt(Co)was used as a catalytic center *** carbon aerogel(C(CS)/g-C_(3)N_(4)/Co)with a three-dimensional network-like structure was prepared by assembling the three materials through experimental operations such as freeze-drying and high-temperature *** was demonstrated by scanning and transmission characterization that the CS in the carbon aerogel could provide more active sites for the cobalt nanoparticles,and the doping of graphite-phase carbon nitride as a template dispersed the cobalt nanoparticles and changed the conductivity of the *** investigate the catalytic effect of carbon aerogel on ammonium perchlorate(AP),it was investigated by differential thermal analyzer and TG thermal *** carbon aerogel was very effective in catalyzing AP,and the 10 wt% content of the catalyst reduced the AP pyrolysis peak from 703.9 to 595.5 *** to further investigate the synergistic effect of the three materials,further carbon aerogels such as C(CS)/Co,g-C_(3)N_(4)/Co were prepared and applied to catalyze AP,and the same ratio reduced the AP pyrolysis peak by 98.1℃ and 97.7℃.This result indicates a synergistic effect of the assembly of the three materials.

关键词： g-C_(3)N_(4) Chitosan Co Ammonium perchlorate Pyrolysis kinetics

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