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Chinese Journal of Chemical Engineering 2018年第11期26卷 2327-2336页

作者： Yue Wu Fan Wu Guoping Hu Nouman R.Mirza Geoffrey W.Stevens Kathryn A.Mumford Department of Chemical and Biomolecular Engineering The University of Melbourne peter cook centre for ccs research The University of Melbourne Particulate Fluids Processing centre (PFPC) The University of Melbourne

The process models for an equilibrium CO_2 absorber and a rate based CO_2 absorber using potassium carbonate(K2 CO3) solvents were developed in Aspen Custom Modeller(ACM) to remove CO_2 from a flue gas. The process model utilised the Electrolyte Non-Random Two Liquid(ENRTL) thermodynamic model and various packing correlations. The results from the ACM equilibrium model shows good agreement with an inbuilt Aspen Plus?model when using the same input conditions. By further introducing a Murphree efficiency which is related to mass transfer and packing hydraulics, the equilibrium model can validate the experimental results from a pilot plant within a deviation of 10%. A more rigorous rate based model included mass and energy flux across the interface and the enhancement effect resulting from chemical reactions. The rate based model was validated using experimental data from pilot plants and was shown to predict the results to within 10%. A parametric sensitivity analysis showed that inlet flue gas flowrate and K2 CO3 concentration in the lean solvent has significant impact on CO_2 recovery. Although both models can provide reasonable predictions based on pilot plant results, the rate based model is more advanced as it can explain mass and heat transfer, transport phenomena and chemical reactions occurring inside the absorber without introducing an empirical Murphree efficiency.

关键词： Equilibrium Rate based Modelling Absorber Potassium carbonate

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Critical review of strategies for CO_2 delivery to large-scale microalgae cultures

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Chinese Journal of Chemical Engineering 2018年第11期26卷 2219-2228页

作者： Qi Zheng Xiaoyin Xu Gregory J.O.Martin Sandra E.Kentish peter cook centre for ccs research Department of Chemical EngineeringThe University of Melbourne Algal Processing Group Department of Chemical EngineeringThe University of Melbourne

Microalgae have great, yet relatively untapped potential as a highly productive crop for the production of animal and aquaculture feed, biofuels, and nutraceutical products. Compared to conventional terrestrial crops they have a very fast growth rate and can be produced on non-arable land. During microalgae cultivation, carbon dioxide(CO_2) is supplied as the carbon source for photosynthesising microalgae. There are a number of potential CO_2 supplies including air, flue gas and purified CO_2. In addition, several strategies have been applied to the delivery of CO_2 to microalgae production systems, including directly bubbling CO_2-rich gas, microbubbles, porous membrane spargers and non-porous membrane contactors. This article provides a comparative analysis of the different CO_2 supply and delivery strategies and how they relate to each other.

关键词： Bubble Carbon dioxide Flue gas Bioreactors

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Review of solvent based carbon-dioxide capture technologies

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Frontiers of Chemical Science and Engineering 2015年第2期9卷 125-141页

作者： Kathryn A. MUMFORD Yue WU Kathryn H. SMITH Geoffrey W. STEVENS peter cook centre for ccs research Particulate Fluids Processing Centre Cooperative Centre for Greenhouse Gas Technologies Department of Chemical and Biomolecular Engineering The University of Melbourne Victoria Australia

Currently, a large proportion of global fossil fuel emissions originate from large point sources such as power generation or industrial processes. This trend is expected to continue until the year 2030 and beyond. Carbon capture and storage （ccs）, a straightforward and effective carbon reduction approach, will play a significant role in reducing emissions from these sources into the future if atmospheric carbon dioxide （CO2） emissions are to be stabilized and global warming limited below a threshold of 2 ℃. This review provides an update on the status of large scale integrated ccs technologies using solvent absorption for CO2 capture and provides an insight into the development of new solvents, including advanced amine solvents, amino acid salts, carbonate systems, aqueous ammonia, immiscible liquids and ionic liquids. These proposed new solvents aim to reduce the overall cost CO2 capture by improving the CO2 absorption rate, CO2 capture capacity, thereby reducing equipment size and decreasing the energy required for solvent regeneration.

关键词： carbon dioxide carbon capture solventabsorption large scale

Carbon dioxide capture by solvent absorption using amino acids: A review

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Chinese Journal of Chemical Engineering 2018年第11期26卷 2229-2237页

作者： Guoping Hu Kathryn H.Smith Yue Wu Kathryn A.Mumford Sandra E.Kentish Geoffrey W.Stevens peter cook centre for Carbon Capture and Storage research (PCC) Particulate Fluids Processing Centre (PFPC)Department of Chemical EngineeringThe University of Melbourne

The emission of large amounts of carbon dioxide is of major concern with regard to increasing the risk of climate change. Carbon capture, utilisation and storage (CCUS) has been proposed as an important pathway for slowing the rate of these emissions. Solvent absorption of CO_2 using amino acid solvents has drawn much attention over the last few years due to advantages including their ionic nature, low evaporation rate, low toxicity, high absorption rate and high biodegradation potential, compared to traditional amine solvents. In this review, recent progress on the absorption kinetics of amino acids is summarised, and the engineering potential of using amino acids as carbon capture solvents is discussed. The reaction orders between amino acids and carbon dioxide are typ- ically between 1 and 2. Glycine exhibits a reaction order of 1, whilst, by comparison, lysine, proline and sarcosine have the largest reaction constants with carbon dioxide which is much larger than that of the benchmark solvent monoethanolamine (MEA). Ionic strength, p H and cations such as sodium and potassium have been shown to be important factors influencing the reactivity of amino acids. Corrosivity and reactivity with impurities such as SOx and NOxare not considered to be significant problems for amino acids solvents. The precipitation of CO_2 loaded amino acid salts is thought to be a good pathway for increasing CO_2loading capacity and cutting desorption energy costs if well-controlled. It is recommended that more detailed research on amino acid degradation and overall process energy costs is conducted. Overall, amino acid solvents are recognised as promising potential solvents for car- bon dioxide capture.

关键词： Amino acids Carbon capture Absorption Solvents

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Pilot plants of membrane technology in industry:Challenges and key learnings

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Frontiers of Chemical Science and Engineering 2020年第3期14卷 305-316页

作者： Colin A.Scholes peter cook centre for Carbon Capture and Storage research Department of Chemical EngineeringThe University of MelbourneVIC3010Australia

Membrane technology holds great potential in gas separation applications,especially carbon dioxide capture from industrial *** achieve this potential,the outputs from global research endeavours into membrane technologies must be trialled in industrial processes,which requires membrane-based pilot *** pilot plants are critical to the commercialization of membrane technology,be it as gas separation membranes or membrane gas-solvent contactors,as failure at the pilot plant level may delay the development of the technology for ***,the author reports on his experience of operating membrane-based pilot plants for gas separation and contactor configurations as part of three industrial carbon capture initiatives:the Mulgrave project,H3 project and Vales Point ***,the challenges of developing and operating membrane pilot plants are presented,as well as the key learnings on how to successfully manage membrane pilot plants to achieve desired performance *** purpose is to assist membrane technologists in the carbon capture field to achieve successful outcomes for their technology innovations.

关键词： membrane gas separation membrane contactors carbon capture pilot plants key learnings

Perspective of mixed matrix membranes for carbon capture

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Frontiers of Chemical Science and Engineering 2020年第3期14卷 460-469页

作者： Shinji Kanehashi Colin AScholes Graduate School of Engineering Tokyo University of Agriculture and TechnologyTokyo184-8588Japan peter cook centre for Carbon Capture and Storage research Department of Chemical EngineeringThe University of MelbourneMelbourne 3010Australia

Polymeric membrane-based gas separation has found wide applications in industry,such as carbon capture,hydrogen recovery,natural gas sweetening,as well as oxygen *** gas separation membranes are required to have high gas permeability and selectivity,while being cost-effective to *** matrix membranes(MMMs)have a composite structure that consists of polymers and fillers,therefore featuring the advantages of both *** effort has been made to improve the gas separation performance of MMMs as well as general membrane properties,such as mechanical strength and thermal *** perspective describes potential use of MMMs for carbon capture applications,explores their limitations in fabrication and methods to overcome them,and addresses their performance under industry gas conditions.

关键词： membranes polymeric mixed matrix impurities

Precipitation study of CO2-loaded glycinate solution with the introduction of ethanol as an antisolvent

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Frontiers of Chemical Science and Engineering 2020年第3期14卷 415-424页

作者： Siming Chen Yue Wu Geoffrey WStevens Guoping Hu Wenshou Sun Kathryn AMumford College of Environmental Sciences and Engineering Qingdao UniversityQingdao 266071China peter cook centre for Carbon Capture and Storage research(PCC) Particulate Fluids Processing Centre(PFPC)Department of Chemical EngineeringUniversity of MelbourneParkvilleVictoria 3010Australia

Focused beam reflectance measurement(FBRM)and 13C nuclear magnetic resonance(13C NMR)analysis were used to study the precipitation process of CO2-loaded potassium glycinate(KGLY)solutions at different CO2 loadings,during the addition of ethanol as an antisolvent at a rate of 10 mL·min−*** volume ratio of ethanol added to the KGLY solution(3.0 mol·L−1,340 mL)ranged from 0 to *** solid-liquid-liquid phases were formed during the precipitation *** FBRM results showed that the number of particles formed increased with CO2 loading and ethanol addition for CO2-unsaturated KGLY solutions,whilst for CO2-saturated KGLY solution it first increased then decreased to a stable value with ethanol addition.13C NMR spectroscopic analysis showed that the crystals precipitated from the CO2-unsaturated KGLY solutions consisted of glycine only,and the quantity crystallised increased with CO2 loading and ethanol ***,a complex mixture containing glycine,carbamate and potassium bicarbonate was precipitated from CO2-saturated KGLY solution with the maximum precipitation percentages of 94.3%,31.4%and 89.6%,respectively,at the ethanol volume fractions of 1.6,2.5 and 2.3.

关键词： crystallization precipitation glycinate FBRM 13C NMR

Variability of the useful life of reservoirs in tropical locations:A case study from the Burdekin Falls Dam, Australia

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International Journal of Sediment research 2018年第2期33卷 93-106页

作者： Michelle Cooper Stephen E.Lewis Thomas C.Stieglitz Scott G.Smithers College of Scilence and Engineering James Cook University centre for Tropical Water ε Aquatic Ecosystem research TropWATER James Cook University

Large dam construction for irrigation, hydropower, water supply, and flood control in tropical to subtropical areas increased markedly after 1950. Many of the dams built during this period have filled with sediment and no longer perform to their original design specifications; in many cases, forecast dam life was greatly overestimated. This study investigates the useful life of Burdekin Falls Dam(BFD), northeastern Australia and compares the findings with other tropical reservoirs. Using two independent methods it is estimated that between 61 and 65 million m3 of sediment has been deposited in the reservoir over the 24 years of operation through 2011. This sediment volume equates to an average of0.15% of capacity lost per year since construction was completed. If current sediment loads/climate regimes persist, reservoir capacity will be reduced by 50% after 345 years. However, the useful life of the BFD reduces to just 276 years when drawdown data are considered; these data show reservoir use would be affected once 40% of storage was filled with sediment, with a 60% drawdown return period of 1 in 15 years. When compared to similar large tropical to sub-tropical reservoirs, the BFD has a slightly longer reservoir useful life than dams in India and a much longer half-life than for both similar-sized and larger dams in China, Brazil, and Iran. Properties of the BFD that promote a longer useful life include a lower trap efficiency, relatively low annual sediment load delivered to the reservoir, limited sediment deposition behind the dam wall(and uniform distribution of deposited sediment), and the export of highly turbid annual floodwaters before settling and deposition of any remaining sediment within the reservoir.

关键词： Reservoir half-life Lake Dalrymple Sediment trapping Trap efficiency Tropical reservoir Useful life

Assessing the potential for satellite image monitoring of seagrass thermal dynamics:for inter-and shallow sub-tidal seagrasses in the inshore Great Barrier Reef World Heritage Area,Australia

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International Journal of Digital Earth 2018年第8期11卷 803-824页

作者： S.R.Phinn E.M.Kovacs C.M.Roelfsema R.F.Canto C.J.Collier L.J.McKenzie Remote Sensing research centre School of Earth and Environmental SciencesUniversity of QueenslandSt LuciaAustralia centre for Tropical Water and TERRAtic Ecosystem research(TropWATER) James Cook UniversityCairnsAustralia

Seagrass meadows are at increasing risk of thermal stress and recent work has shown that water temperature around seagrass meadows could be used as an indicator for seagrass *** thermal data have not been linked to the thermal properties of seagrass *** work assessed the covariation between 20 in situ average daily temperature logger measurement sites in tropical seagrass meadows and satellite derived daytime SST(sea surface temperature)from the daytime MODIS and Landsat sensors along the Great Barrier Reef coast in *** significant(R2=0.787–0.939)positive covariations were found between in situ seagrass logger temperatures and MODIS SST temperature and Landsat sensor temperatures at all sites along the *** MODIS SST were consistently higher than in situ temperature at the majority of the sites,possibly due to the sensor’s larger pixel size and location offset from field *** thermal data were lower than field-measured SST,due to differences in measurement scales and *** refined significantly and tested over larger areas,this approach could be used to monitor seagrass health over large(106 km2)areas in a similar manner to using satellite SST for predicting thermal stress for corals.

关键词： Seagrass temperature thermal tolerance satellite sea surface temperature Landsat MODIS Great Barrier Reef

Combining in-situ water quality and remotely sensed data across spatial and temporal scales to measure variability in wet season chlorophyll-a:Great Barrier Reef lagoon(Queensland,Australia)

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Ecological Processes 2013年第1期2卷 328-349页

作者： Michelle J Devlin Eduardo Teixeira da Silva Caroline Petus Amelia Wenger Daniel Zeh Dieter Tracey Jorge GÁlvarez-Romero Jon Brodie Catchment to Reef research Group TropWaterJames Cook UniversityTownsvilleQLD4811Australia Australian research Council centre of Excellence for Coral Reef Studies James Cook UniversityTownsvilleQLDAustralia School of Marine and Tropical Biology James Cook UniversityTownsvilleQLDAustralia

Introduction:Combining in-situ data from single-point time series with remotely sensed spatial data allowed a greater elucidation of changes in chlorophyll-a concentrations through wet season conditions in the Great Barrier Reef coastal ***:Single-point time-series data were collected from 2006 to 2012 during high river flow conditions to assess changes in phytoplankton biomass(measured as chlorophyll-a).Additionally,three flood plume water types,derived from classified true-colour Aqua moderate resolution imaging spectroradiometer(MODIS)images,were used to group single-point time-series data for the phytoplankton biomass ***:Survey data illustrate the heterogeneity of chlorophyll-a distribution over seasonal and inter-annual cycles and the difficulty in describing community responses through the wet *** spatial data demonstrate distinct regional differences throughout the Great Barrier *** high chlorophyll-a concentrations measured in flood plume waters immediately adjacent to the inshore,highly turbid‘inner’flood plume are a product of sufficient light,given most of the suspended solids have settled from the plume,and the availability of sufficient nutrients,which drive higher phytoplankton production and characterise the formation of secondary stage flood *** formation and extent of these secondary flood plumes were mapped using MODIS true-colour satellite *** distance and the location of the secondary plume water are reliant on flow,coastal hydrodynamics,and biological ***:The combination of in-situ data and remotely sensed data provides information on the complexity of these coastal processes during the wet season and offers managers a more comprehensive understanding of the extent of nutrient enrichment in the Great Barrier Reef coastal area and the potential influence of flood plumes on coastal marine ecosystems.

关键词： Chlorophyll-a Great barrier reef Phytoplankton Monitoring Remote sensing MODIS