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Production of liquid bio-fuel from catalytic de-oxygenation:Pyrolysis of beech wood and flax shives

燃料化学学报 2019年第2期47卷 153-166页

作者： Chetna Mohabeer Luis Reyes Lokmane Abdelouahed Stéphane Marcotte Jean-Christophe Buvat Lucette Tidahy Edmond Abi-Aad Bechara Taouk normandie Univ INSA Rouen NormandieUNIROUENLaboratoire de Sécurité des Procédés Chimiques normandie Univ INSA Rouen NormandieUNIROUEN université du Littoral Cte d'Opale Unité de Chimie Environnementale et Interactions sur le Vivant

This study presents a detailed analysis of the catalytic de-oxygenation of the liquid and gaseous pyrolytic products of two biomasses (beech wood and flax shives) using different catalysts (commercial HZSM-5 and H-Y,and lab-synthesised Fe-HZSM-5,Fe-H-Y,Pt/Al2O3 and CoMo/Al2O3). The experiments were all conducted in a semi-batch reactor under the same operating conditions for all feed materials. BET specific surface area,BJH pore size distribution and FT-IR technologies have been used to characterise the catalysts,while gas chromatography-mass spectrometry (GC-MS),flame ionisation detection (GC-FID) and thermal conductivity detection (GC-TCD) were used to examine the liquid and gaseous pyrolytic products. It was firstly seen that at higher catalyst-to-biomass ratios of 4∶1,de-oxygenation efficiency did not experience any further significant improvement. FeHZSM-5 was deemed to be the most efficient of the catalysts utilised as it helped reach the lowest oxygen contents in the bio-oils samples and the second best was HZSM-5. It was also found that HZSM-5 and H-Y tended to privilege the decarbonylation route(production of CO),whilst their iron-modified counterparts favoured the decarboxylation one (production of CO2) for both biomasses studied. It was then seen that the major bio-oil components (carboxylic acids) underwent almost complete conversion under catalytic treatment to produce mostly unoxygenated aromatic compounds,phenols and gases like CO and CO2. Finally,phenols were seen to be the family most significantly formed from the actions of all catalysts.

关键词： pyrolysis biomass catalytic treatment de-oxygenation bio-oil upgrading

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Lighting the shades of hidden pain:a role for spinal cord neurons and microglia in vestibulodynia

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Neural Regeneration Research 2025年第10期20卷 2898-2900页

作者： Rosmara Infantino Francesca Gargano Serena Boccella Carmela Belardo Andrea Maria Morace Francesca Guida Sabatino Maione Livio Luongo Department of Experimental Medicine Division of PharmacologyUniversitàdegli Studi della Campania“L.Vanvitelli”Italy universitàCampus Bio-medico di Roma RomeItaly

Vulvodynia,a chronic pain disorder affecting the vulvar region,represents a significant challenge in both diagnosis and treatment within the field of women’s *** condition is characterized by chronic pain that significantly affects the quality of life of afflicted *** present perspective paper examines the role of spinal sensitization and microglial activation in vulvodynia.

关键词： pain diagnosis activation

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Simultaneous 3D temperature and velocity field measurements of micro-flow with laser-induced fluorescence and micro-digital holographic particle tracking velocimetry: Numerical study

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Chinese Optics Letters 2015年第7期13卷 105-109页

作者：姚龙超吴学成阳静吴迎春高翔陈玲红 Gérard Gréhan 岑可法 State Key Laboratory of Clean Energy Utilization Zhejiang University UMR 6614/CORIA CNRS Normandie Université

We propose a method for simultaneous 3D temperature and velocity measurement of a micro-flow field. The 3D temperature field is characterized with two-color laser-induced fluorescence particles which are tracked with micro-digital holographic particle tracking velocimetry. A diffraction-based model is applied to analyze defo- cused particles to determine the intensity ratio of two fluorescent dyes on the particle. The model is validated with experimental images. As the result shows that the intensity ratio nearly remains unchanged with respect to depth positions, defocused particles can be used as 3D temperature sensors. Numerical work is carried out to check the method, and 3D temperature and velocity field in a 120 μm × 120 μm× 80 μm test volume are retrieved.

关键词： Fluorescence Holography Laser optics Laser produced plasmas Numerical methods Velocimeters Velocity

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Cumulative unsupervised multi-domain adaptation for Holstein cattle re-identification

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Artificial Intelligence in Agriculture 2023年第4期10卷 46-60页

作者： Fabian Dubourvieux Guillaume Lapouge Angélique Loesch Bertrand Luvison Romaric Audigier universitéParis-Saclay CEA ListPalaiseau 91120France LITIS INSA RouenNormandie UniversitéSaint-Etienne-du-Rouvray 76801France

In dairy farming,ensuring the health of each cow and minimizing economic losses requires individual monitoring,achieved through cow Re-Identification(Re-ID).Computer vision-based Re-ID relies on visually dis-tinguishing features,such as the distinctive coat patterns of breeds like ***,annotating every cow in each farm is *** objective is to develop Re-ID methods applicable to both labeled and unlabeled farms,accommodating new individuals and diverse ***-supervised Domain Adaptation(UDA)techniques bridge this gap,transferring knowledge from labeled source domains to unlabeled target domains,but have only been mainly designed for pedestrian and vehicle Re-ID *** work introduces Cumulative Unsupervised Multi-Domain Adaptation(CUMDA)to address challenges of lim-ited identity diversity and diverse farm *** accumulates knowledge from all domains,enhanc-ing specialization in known domains and improving generalization to unseen *** contributions include a CUMDA method adapting to multiple unlabeled target domains while preserving source domain performance,along with extensive cross-dataset experiments on three cattle Re-ID *** experiments demonstrate significant enhancements in source preservation,target domain specialization,and generalization to unseen domains.

关键词： Re-identification Domain adaptation Holstein cattle Unsupervised learning Monitoring

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Like a G6-nal:transcriptional control of G-protein coupled receptors during oligodendroglial development

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Neural Regeneration Research 2025年第7期20卷 2001-2002页

作者： Tim Aberle Michael Wegner Institut für Biochemie Friedrich-Alexander-Universität Erlangen-NürnbergErlangenGermany

Multilayered control of myelination:Quick,saltatory conduction of action potentials along nerve fibers requires the electrical insulation of axons by myelinating *** the central nervous system,this role is taken up by *** are marked by the expression of the lineage determinants Sox10 and Olig2 and arise from oligodendrocyte precursor cells(OPCs)during embryonal *** the majority of OPCs differentiate into mature oligodendrocytes when nearby axonal segments require myelination,a small subpopulation of OPCs persist as a progenitor ***,the timing of myelination and maintenance of the OPC pool both need to be precisely *** transcription factors either positively or negatively affect oligodendrocyte differentiation and maintenance of the OPC pool as components of a complex gene regulatory network(reviewed in Sock and Wegner,2021).Network activity is additionally influenced by extracellular signaling molecules that bind to receptors on the oligodendroglial cell surface and activate intracellular signaling *** the receptors are linked to the network is poorly understood so far,but pivotal to understanding the overall regulation of central nervous system(CNS)myelination in response to environmental *** insights were recently gained for Gpr37(Schmidt et al.,2024),a G-protein coupled receptor(GPCR)with known relevance in differentiating oligodendrocytes(Yang et al,2016).

关键词： gained insulation conduction

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Methane-to-chemicals:a pathway to decarbonization

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National Science Review 2023年第9期10卷 56-71页

作者： Nikolai Nesterenko Izabel C.Medeiros-Costa Edwin B.Clatworthy Hugo Cruchade Stanislav V.Konnov Jean-Pierre Dath Jean-Pierre Gilson Svetlana Mintova Total Energies One Tech Belgium Zone Industrielle C Laboratoire Catalyse et Spectrochimie(LCS) ENSICAENCNRSNormandie Université

The utilization of methane for chemical production,often considered as the future of petrochemistry,historically could not compete economically with conventional processes due to higher investment *** sustainability and decarbonization of the downstream industry by integration with a methane-to-chemicals process may provide an opportunity to unlock the future for these ***-to-chemicals is an efficient tool to boost the decarbonization potential of renewable *** the current implementation of carbon capture utilization and storage(CCUS) technologies is of great importance for industrial decarbonization,a shift to greener CO2-free processes and CO2utilization from external sources for manufacturing valuable goods is highly *** review outlines potential options for how a methane-to-chemicals process could support decarbonization of the downstream industry.

关键词： methane chemicals pathways decarbonization

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Monolithic crystalline silicon solar cells with SiN_x layers doped with Tb^(3+) and Yb^(3+) rare-earth ions

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Journal of Rare Earths 2019年第5期37卷 515-519页

作者： Ing-Song Yu Shao-Chun Wu Lucile Dumont Julien Cardin Christophe Labbé Fabrice Gourbilleau Department of Materials Science and Engineering National Dong Hwa University CIMAP CNRS/CEA/ENSICAEN/université de Caen normandie

In this study, we propose the fabrication of monolithic crystalline silicon solar cells with Tb^(3+) and Yb^(3+)-doped silicon nitride(SiN_x) layers by low-cost screen-printing methods. The performances of c-Si solar cells can be enhanced by rare-earth ions doped SiN_x layers via the mechanism of spectrum *** SiN_x doped and codoped thin films were deposited by reactive magnetron co-sputtering and integrated as the antireflection coating layers in c-Si solar cells. The characterizations of SiN_x, SiN_x:Tb^(3+) tand SiN_x:Tb^(3+)-Yb^(3+) thin films were conducted by means of photoluminescence, Rutherford backscattering spectroscopy, Ellipsometry spectroscopy and Fourier transform infrared measurements. Their composition and refractive index was optimized to obtain good anti-reflection coating layer for c-Si solar *** electron microscopy performs the uniform coatings on the textured emitter of c-Si solar cells. After the metallization process, we demonstrate monolithic c-Si solar cells with spectrum conversion layers, which lead to a relative increase by 1.34% in the conversion efficiency.

关键词： Crystalline silicon solar cell Spectrum conversion Silicon nitride Down-shifting Rare-earth ion Anti-reflection coating

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Machine learning for integrating combustion chemistry in numerical simulations

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Energy and AI 2021年第3期5卷 330-338页

作者： Huu-Tri Nguyen Pascale Domingo Luc Vervisch Phuc-Danh Nguyen CORIA-CNRS Normandie UniversitéINSA Rouen NormandieSaint-Etienne-du-Rouvray 76801France ArcelorMittal Global Research and Development Maiziéres-lés-Metz 57280France

A strategy based on machine learning is discussed to close the gap between the detailed description of combustion chemistry and the numerical simulation of combustion ***,the partial differential equations describ-ing chemical kinetics are stiffand involve many degrees of freedom,making their solving in three-dimensional unsteady simulations very *** is discussed in this work how a reduction of the computing cost by an order of magnitude can be achieved using a set of neural networks trained for solving *** ther-mochemical database used for training is composed of time evolutions of stochastic particles carrying chemical species mass fractions and temperature according to a turbulent micro-mixing problem coupled with complex *** novelty of the work lies in the decomposition of the thermochemical hyperspace into clusters to facilitate the training of neural *** decomposition is performed with the Kmeans algorithm,a local principal component analysis is then applied to every *** new methodology for combustion chemistry reduction is tested under conditions representative of a non-premixed syngas oxy-flame.

关键词： Combustion chemistry Micro-mixing modeling Principal component analysis Artificial neural network Chemistry reduction

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Origin of superconductivity in hole doped SrBiO_(3) bismuth oxide perovskite from parameter-free first-principles simulations

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npj Computational Materials 2023年第1期9卷 2044-2052页

作者： Julien Varignon Laboratoire CRISMAT CNRS UMR 6508ENSICAENNormandie Université6 boulevard Maréchal JuinF-14050Caen Cedex 4France

The recent discovery of nickel oxide superconductors have highlighted the importance of first-principles simulations forunderstanding the formation of the bound electrons at the core of superconductivity. Nevertheless, superconductivity in oxides isoften ascribed to strong electronic correlation effects that density functional theory (DFT) cannot properly take into account,thereby disqualifying this technique. Being isostructural to nickel oxides, Sr_(1-x)K_(x)BiO_(3) superconductors form an ideal testbed forunveiling the lowest theory level needed to model complex superconductors and the underlying pairing mechanism yieldingsuperconductivity. Here I show that parameter-free DFT simulations capture all the experimental features and related quantities of Sr_(1-x)K_(x)BiO_(3) superconductors, encompassing the prediction of an insulating to metal phase transition upon increasing the K dopingcontent and of an electron-phonon coupling constant of 1.22 in sharp agreement with the experimental value of 1.3 ± 0.2. Theproximity of a disproportionated phase is further demonstrated to be a prerequisite for superconductivity in bismuthates.

关键词： superconductivity bismuth parameter

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Bladder-colon chronic cross-sensitization involves neuro-glial pathways in male mice

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World Journal of Gastroenterology 2022年第48期28卷 6935-6949页

作者： Karim Atmani Fabien Wuestenberghs Maximilien Baron Illona Bouleté Charlène Guérin Wafa Bahlouli David Vaudry Jean Claude do Rego Jean-Nicolas Cornu Anne-Marie Leroi Moïse Coëffier Mathieu Meleine Guillaume Gourcerol Nutrition Gut and Brain Unit(Inserm U1073)Institute for Research and Innovation in BiomedicineUniversitéde Rouen NormandieRouen 76000France Department of Gastroenterology and Hepatology UniversitéCatholique de LouvainCHU UCL NamurYvoir 5530Belgium Department of Physiology CHU RouenUniversitéde Rouen NormandieRouen 76031France Department of Urology CHU RouenUniversitéde Rouen NormandieRouen 76000France Inserm UMR 1245Team Epigenetics and Pathophysiology of Neurodevelopmental DisordersUniversitéde Rouen NormandieRouen 76000France Behavioural Analysis Platform(SCAC) HeRacLeS Inserm US51-CNRS UAR2026Institute for Research and Innovation in BiomedicineUniversitéde Rouen NormandieRouen 76000France Department of Nutrition CHU RouenUniversitéde Rouen NormandieRouen 76000France Inserm U1107 NeuroDolClermont Auvergne UniversityClermont-Ferrand 63000France

BACKGROUND Irritable bowel syndrome and bladder pain syndrome often overlap and are both characterized by visceral *** pelvic organs share common sensory pathways,it is likely that those syndromes involve a cross-sensitization of the bladder and the *** precise pathophysiology remains poorly *** To develop a model of chronic bladder-colon cross-sensitization and to investigate the mechanisms *** Chronic cross-organ visceral sensitization was obtained in C57BL/6 mice using ultrasound-guided intravesical injections of acetic acid under brief isoflurane *** sensitivity was assessed in conscious mice by measuring intracolonic pressure during isobaric colorectal ***,used as a marker of colorectal inflammation,was measured in the colon,and colorectal permeability was measured using chambers.c-Fos protein expression,used as a marker of neuronal activation,was assessed in the spinal cord(L6-S1 level)using *** fluorescent protein on the fractalkine receptor-positive mice were used to identify and count microglia cells in the L6-S1 dorsal horn of the spinal *** expression of NK1 receptors and MAPK-p38 were quantified in the spinal cord using western *** Visceral hypersensitivity to colorectal distension was observed after the intravesical injection of acetic acid vs saline(P<0.0001).This effect started 1 h post-injection and lasted up to 7 d *** increased permeability or inflammation was shown in the bladder or colon 7 d *** hypersensitivity was associated with the increased expression of c-Fos protein in the spinal cord(P<0.0001).In green fluorescent protein on the fractalkine receptor-positive mice,intravesical acetic acid injection resulted in an increased number of microglia cells in the L6-S1 dorsal horn of the spinal cord(P<0.0001).NK1 receptor and MAPK-p38 levels were increased in the spinal cord up to 7 d after

关键词： Cross-organ sensitization MAPK-p38 Microglia NK1 receptor Pain Visceral hypersensitivity

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