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An Unprecedented Efficiency with Approaching 21%Enabled by Additive‑Assisted Layer‑by‑Layer Processing in Organic Solar Cells

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Nano-Micro Letters 2025年第2期17卷 372-375页

作者： Shuai Xu Youdi Zhang Yanna Sun Pei Cheng Zhaoyang Yao Ning Li Long Ye Lijian Zuo Ke Gao Key laboratory of Advanced Green Functional Materials College of ChemistryChangchun Normal UniversityChangchun 130032People’s Republic of China Shandong Provincial Key laboratory for Science of Material Creation and Energy Conversion School of Chemistry and Chemical EngineeringShandong UniversityQingdao 266237People’s Republic of China College of Polymer Science and Engineering Sichuan UniversityChengdu 610065People’s Republic of China State Key laboratory and Institute of Elemento‑Organic Chemistry Centre of Nanoscale Science and Technology and Key Laboratory of Functional Polymer MaterialsRenewable Energy Conversion and Storage Center(RECAST)College of ChemistryNankai UniversityTianjin 300071People’s Republic of China Institute of Polymer Optoelectronic Materials and Devices State Key laboratory of Luminescent Materials and Devices South China University of TechnologyGuangzhou 510640People’s Republic of China Tianjin Key laboratory of Molecular Optoelectronic Sciences School of Materials Science and EngineeringTianjin UniversityTianjin 300350People’s Republic of China State Key laboratory of Silicon Materials MOE Key Laboratory of Macromolecular Synthesis and FunctionalizationDepartment of Polymer Science and EngineeringZhejiang UniversityHangzhou 310027People’s Republic of China

Recently published in Joule,Feng Liu and colleagues from Shanghai Jiaotong University reported a record-breaking 20.8%power conversion efficiency in organic solar cells(OSCs)with an interpenetrating fibril network active layer morphology,featuring a bulk p-in structure and proper vertical segregation achieved through additive-assisted layer-by-layer *** optimized hierarchical gradient fibrillar morphology and optical management synergistically facilitates exciton diffusion,reduces recombination losses,and enhances light capture *** approach not only offers a solution to achieving high-efficiency devices but also demonstrates the potential for commercial applications of OSCs.

关键词： Organic solar cells Additive-assisted layer-by-layer processing Three-dimensional fibril morphology Bulk p-i-n structure Optical management

Interfaced heterogeneous nanodimers

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National Science Review 2015年第3期2卷 329-348页

作者： Yugang Sun Center for nanoscale Materials Argonne National Laboratory

Dimerization of diferent nanocomponents in single nanoparticles becomes interesting due to not only inheritance of properties of both components but also generation of new properties associated with strong coupling of the two components. As a class of emerging nanomaterials, interfaced heterogeneous nanodimers(IHNDs) are atracting more atentions in the ield of materials research, in particular,nanoscience and nanotechnology. his review provides a timely and comprehensive overview on the general principles for the synthesis of IHNDs and typical examples of IHNDs made of various compositional combinations. he current challenges related to the synthesis and characterization of IHNDs are summarized at the end of the review and future research directions are also discussed.

关键词： nanoparticles nanodimers hybrid nanostructure heterogeneous nucleation/growth

Encapsulation of superparamagnetic Fe_3O_4@SiO_2 core/shell nanoparticles in MnO_2 microflowers with high surface areas

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Chinese Chemical Letters 2015年第2期26卷 233-237页

作者： Yu-Gang Sun Tu T.Truong Yu-Zi Liu Yong-Xing Hu Center for nanoscale Materials Argonne National Laboratory

Microflowers made of interconnected MnO2 nanosheets have been successfully synthesized in a microwave reactor through a hydrothermal reduction of KMnO4 with aqueous HCI at elevated temperatures in the presence of superparamagnetic Fe3O4SiO2 core-shell *** to the chemical compatibility between SiO2 and MnO2,the heterogeneous reaction leads to the spontaneous encapsulation of the Fe3O4@SiO2 core-shell nanoparticles in the MnO2 *** resulting hybrid particles exhibit multiple properties including high surface area associated with the MnO2nanosheets and superparamagnetism originated from the Fe3O4@SiO2 core-shell *** are beneficial for applications requiring both high surface area and magnetic separation.

关键词： Microwave synthesis Manganese oxide nanosheets Superparamagnetic nanoparticles Hybrid nanostructures Multifunctional nanostructures

Effect of nanocomposite structure on the thermoelectric properties of 0.7-at% Bi-doped Mg_2 Si nanocomposite

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Chinese Physics B 2011年第10期20卷 355-361页

作者：杨梅君沈强张联盟 Centre for Materials research and Analysis Wuhan University of Technology State Key laboratory of Advanced Technology for Materials synthesis and Processing Wuhan University of Technology

Nanocomposites offer a promising approach to the incorporation of nanostructured constituents into bulk thermo- electric materials. The 0.7-at% Bi-doped Mg2Si nanocomposites are prepared by spark plasma sintering of the mixture of nanoscale and microsized 0.7-at% Bi-doped Mg2Si powders. Microstructure analysis shows that the bulk material is composed of nano- and micrograins. Although the nanograin hinders electrical conduction, the nanocomposite struc- ture is more helpful to reduce thermal conductivity and increase the Seebeck coefficient, hence improving thermoelectric performance. A dimensionless figure of merit of 0.8 is obtained for the 0.7-at% Bi-doped Mg2Si nanocomposite with 50-wt % nanopowder, which is about twice larger than that of the sample without nanopowder.

关键词： intermetallic compounds nanostructures semiconductors thermoelectric effects

CVD synthesis of nitrogen-doped graphene using urea

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Science China(Physics,Mechanics & Astronomy) 2015年第10期58卷 94-99页

作者： ZHANG CanKun LIN WeiYi ZHAO ZhiJuan ZHUANG PingPing ZHAN LinJie ZHOU YingHui CAI WeiWei Department of Physics Laboratory of Nanoscale Condense Matter Physics and State Key Laboratory of Physical Chemistry of Solid SurfacesXiamen University

This work provides an effective low-cost synthesis and in-depth mechanistic study of high quality large-area nitrogen-doped graphene(NG) films. These films were synthesized using urea as nitrogen source and methane as carbon source, and were characterized by scanning electron microscopy(SEM), Raman spectroscopy and X-ray photoelectron spectroscopy(XPS). The N doping level was determined to be 3.72 at.%, and N atoms were suggested to mainly incorporated in a pyrrolic N configuration. All distinct Raman peaks display a shift due to the nitrogen-doping and compressive strain. The increase in urea concentration broadens the D and 2D peak's Full Width at Half Maximum(FWHM), due to the decrease of mean free path of phonons. The N-doped graphene exhibited an n-type doping behavior with a considerably high carrier mobility of about 74.1 cm2/(V s), confirmed by electrical transport measurements.

关键词： nitrogen-doped graphene chemical vapor deposition Raman spectroscopy X-ray photoemission spectroscopy

A Facile Controllable synthesis, Growth Mechanism, and Photocatalytic Properties of nanoscale BiOCl

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Chinese Journal of Structural Chemistry 2013年第3期32卷 458-468页

作者：王跃石永芳吴立明 State Key laboratory of Structural Chemistry Fujian Institute of Research on the Structure of MatterChinese Academy of Sciences Chongqing University of Education

nanoscale tetragonal BiOCl samples have been synthesized using Bi[SC12H25]3 and CHCl3 as bismuth and chlorine sources by solvothermal reactions. The structure, morphology, and formation process have been investigated by SEM, TEM, HRTEM, XRD, and EDX analyses. The layered crystal structure feature of BiOCl may induce the growth of nano plates, which can subsequently aggregate into 3D spherical or flower-like microstructures under the presence of ethanol. The reaction temperature and the identity of secondary solvent influence the morphology. The yield of BiOCl depends on the completeness of the reaction and the degree of a competition reduction of BiOCl to Bi by ethanol. The as-synthesized 3D quasi-spherical BiOCl sample has an optical band gap of 3.15 eV, and shows much better photocatalytic performance on the degradation of methyl orange than that of commercial P25.

关键词： synthesis mechanism photocatalytic nano BiOCl

Gold nanoparticles with surface-anchored chiral poly（acryloyI-L（D）-valine） induce differential response on mesenchymal stem cell osteogenesis

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Nano research 2016年第12期9卷 3683-3694页

作者： Jun Deng Honghao Zheng Xiaowen Zheng Mengyun Yao Zheng Li Changyou Gao MOE Key laboratory of Macromolecular synthesis and Functionalization Department of Polymer Science and Engineering ZhejiangUniversity Hangzhou 310027 China

Chirality is one of the most distinctive biochemical signatures of life, and plays crucial roles in maintaining normal functions of living cells or organisms. Pioneering work from another group has demonstrated the dependency of cell differentiation on the chirality of nano-coated substrates, but the effect of the chiral surface of nanoparticles on stem cell fates has not been investigated. In this study, the influence of molecular chiral poly（acryloyl-L（D）-valine）（L（D）- PAV）-anchored gold nanoparticles （L（D）-PAV-AuNPs） on the differentiation of mesenchymal stem cells （MSCs） was investigated. Though osteogenic differentiation of MSCs was not affected by D-PAV-AuNPs, it was significantly promoted by L-PAV-AuNPs in terms of calcium deposition, alkaline phosphatase （ALP） activity, and expression of collagen type I and osteocalcin （OCN） at both mRNA and protein levels. L-PAV-AuNPs could activate the P38 mitogen-activated protein kinase （MAPK） pathway, and may exert mechanical stress on MSCs because of high amounts of internalization. These results provide new insights on surface chirality at the nanoscale as a direct regulator to guide the differentiation of MSCs, and the use of these nanomaterials for strategic regenerative medicine.

关键词： chiralpoly(acryloyl-L(D)-valine) gold nanoparticles mesenchymal stem cells osteogenic differentiation

Solvent polarity-induced photoluminescence enhancement (SPIPE): A method enables several-fold increase in quantum yield of silicon nanoparticles

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Nano research 2019年第2期12卷 315-322页

作者： Xiao-Bin Shen Bin Song Bei Fang Xiao Yuan You-Yong Li Shun-Yi Wang Shun-Jun Ji Yao He laboratory of nanoscale Biochemical Analysis Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices Institute of Functional Nano and Soft Materials (FUNSOM) and Collaborative Innovation Center of Suzhou Nano Science and Technology (NANO-CIC) Soochow University Suzhou 215123 China Key laboratory of Organic synthesis of Jiangsu Province College of Chemistry Chemical Engineering and Materials Science Soochow University Suzhou 215123 China

Fluorescent silicon nanoparticles (SiNPs) bring exciting opportunities for long-awaited silicon-based optical application, while intrinsic indirect band gap of silicon severely limits photoluminescent quantum yield (PLQY) of SiNPs. To address this critical issue, we herein demonstrate a facile and general method, Le., solvent polarity-induced photoluminescence enhancement (SPIPE)1 yielding several-fold increase in quantum yield (QY) of SiNPs. Typically, different kinds of 4-substituented-1,8-naphthalic anhydride molecules, Le., 4-Br-1,8-naphthalic anhydride (BNA)1 4-triphenylamino-1,8-naphthalic anhydride (TPNA)1 and 4-dimethylamino-1,8-naphthalic anhydride (DMNA)1 are rationally designed and synthesized, which serve as surface ligands for the production of BNA-, TPNA-, and DMNA-capped small-sized (diameter:- 3.8-5.8 nm) SiNPs with QY of^8%,~15%,~16%, respectively. Of particular significance, QY of the resultant SiNPs could be greatly enhanced from^10% to^50% through the SPlPE strategy. Taken together with the theoretical calculation and the results of time-correlated single photon counting, we reveal that actived excited-state charge transfer interactions between surface-covered ligand and silicon oxide coating would be responsible for the observed QY enhancement. Moreover, other five kinds of solvents (i.e., methanol, isopropanol, dimethyl sulfoxide, N,N-dimethylformamide, and acetonitrile) are further employed for the SiNPs treatment, and similar improvement of QY values are observed, convincingly demonstrating the universal evidence of SPIPE of the SiNPs.

关键词： silicon nanoparticles quantum yield fluorescent surface ligand solvent polarity

Energy-dispersive X-ray Spectroscopy for the Quantitative Analysis of Pyrite Thin Specimens

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Journal of Wuhan University of Technology(Materials Science) 2023年第6期38卷 1304-1310页

作者： LUO Tingting GUO Yi DENG Zhao LIU Xiaoqing SUN Zhenya QI Yanyuan YANG Meijun Center for Materials research and Analysis Testing Wuhan University of Technology Wuhan 430070China State Key laboratory of Advanced Technology for Materials synthesis and Processing Wuhan University of TechnologyWuhan 430070Wuhan

To explore ways to improve the accuracy of quantitative analysis of samples in the micrometer to nanometer range of magnitudes,we adopted analytical transmission electron microscopy(AEM/EDS)for qualitative and quantitative analysis of pyrite ***,the k factor of pyrite is calculated *** develop an appropriate non-standard quantitative analysis model for pyrite materials,the experimentally calculated k factor is compared with that estimated from the non-standard quantitative analytical model of the instrument *** experimental findings demonstrate that the EDS attached to a TEM can be employed for precise quantitative analysis of micro-and nanoscale regions of pyrite ***,it serves as a reference for improving the results of the EDS quantitative analysis of other sulfides.

关键词： analytical transmission electron microscopy(AEM) energy dispersive X-ray spectroscopy(EDS) pyrite thin specimen quantitative analysis