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Preparation of Modified UiO-66 Catalyst and Its Catalytic Performance for NH_(3)-SCR Denitration

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Journal of Wuhan University of Technology(materials science) 2024年第2期39卷 261-267页

作者：吴彦霞梁海龙 CHEN Yufeng HU Liming WANG Chunpeng Ceramics science institute China Building Materials AcademyBeijing 100002China

Zirconium-based metal-organic framework UiO-66 was successfully prepared by solvothermal method,and UiO-66 was modified by adding regulators such as formic acid,acetic acid,and hydrochloric *** NH_(3)-SCR reactivity of the samples was evaluated by the denitration activity evaluation system,and the UiO-66 and the regulator-modified UiO-66 were characterized by XRD,SEM,BET,FTIR,TG,NH_(3)-TPD,etc.,the effects of regulator types on the structure and properties of UiO-66 were *** experimental results show that,after adding the modifier,the morphology of UiO-66 changes from irregular quadrilateral with serious agglomeration to particles with regular crystal shape and good dispersibility,and the crystal morphology of the catalyst is *** addition,after adding the modifier,UiO-66 has a larger specific surface area and stronger surface acidity,which optimizes the catalytic performance of *** catalytic performance test results of NH_(3)-SCR show that the low-temperature activity of UiO-66 is poor,and it only shows a certain catalytic activity at higher *** catalytic activity of UiO-66 was significantly improved after adding the *** them,the UiO-66-HCl modified with hydrochloric acid had the best catalytic activity,and the denitration rate reached 70%when the denitration temperature was 380℃.

关键词： UiO-66 catalyst catalytic denitration NH_(3)-SCR modified

Thermoelectric transport properties of p-type Bi_(2)Se_(3)-Sb_(2)Se_(3)-In_(2)Se_(3) high entropy compounds

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Rare Metals 2024年第7期43卷 3415-3421页

作者： Feng Jiang Cheng-Liang Xia Yong-Bin Zhu Jun Li Yue Chen Wei-Shu Liu Department of materials science and Engineering Southern University of Science and TechnologyShenzhen 518055China Department of Mechanical Engineering The University of Hong KongHong Kong 999077China Guangdong Provincial Key Laboratory of Functional Oxide materials and devices Southern University of Science and TechnologyShenzhen 518055China

The introduction of entropy concept into thermoelectric materials recently has attracted broad ***,we showed the phase diagram of the ternary systems of Bi_(2)Se_(3)-Sb_(2)Se_(3)-In_(2)Se_(3).Among the high entropy compounds (HECs),we have identified an intrinsic p-type region near our previously reported Bi_(0.8)Sb_(0.8)In_(0.4)Se_3 in the phase diagram.

关键词： entropy (3) compounds

Singular optical propagation properties of two types of one-dimensional anti-PT-symmetric periodic ring optical waveguide networks

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Chinese Physics B 2024年第3期33卷 355-362页

作者：樊阳龙杨湘波练华达陈润楷朱蓬勃邓冬梅刘宏展韦中超 Guangdong Provincial Key Laboratory of Nanophotonic Functional materials and devices School of Information and Optoelectronic Science and EngineeringSouth China Normal UniversityGuangzhou 510006China

Two types of one-dimensional(1D)anti-PT-symmetric periodic ring optical waveguide networks,consisting of gain and loss materials,are *** singular optical propagation properties of these networks are *** results show that the system composed of gain materials exhibits characteristics of ultra-strong transmission and bidirectional ***,the system composed of loss materials demonstrates equal transmittance and reflectance at some *** both the systems,a new type of total reflection phenomenon is *** the imaginary part of the refractive indices of waveguide segments is smaller than 10-5,the system shows bidirectional transparency with the transmittance tending to be 1 and reflectivity to be smaller than 10-8 at some *** the refractive indices of the waveguide segments are real,the system will be bidirectional transparent at the full *** findings may deepen the understanding of anti-PT-symmetric optical systems and optical waveguide networks,and possess potential applications in efficient optical energy storage,ultra-sensitive optical filters,ultra-sensitive all-optical switches,integrated optical chips,stealth physics,and so on.

关键词： anti-PT-symmetric waveguide networks bidirectional transparent

Heptagonal intramolecular-lock strategy enables high-performance thermally activated delayed fluorescence emitters

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science China Chemistry 2024年第4期67卷 1181-1186页

作者： Zhenmei Huang Dezhi Yang Dongge Ma Zhengyang Bin Jingsong You Key Laboratory of Green Chemistry and Technology of Ministry of Education College of ChemistrySichuan UniversityChengdu 610064China institute of Polymer Optoelectronic materials and devices State Key Laboratory of Luminescent Materials and DevicesSouth China University of TechnologyGuangzhou 510640China

The development of highly efficient thermally activated delayed fluorescence(TADF)emitters is persistently pursued for the application of organic light-emitting diodes(OLED)in full-colour display and solid-state ***,we present a heptagonal intramolecular-lock strategy to design high-performance TADF *** a proof-of-concept,a new type of tribenzotropone(TBP)acceptor has been designed and synthesized by a cascade decarboxylative cyclization of aryl oxoacetic acid derivative with biphenyl boronic *** with the unlocked benzophenone(BP)acceptor,the TBP acceptor has a highly twisted heptagonal geometry with moderate rigidity and flexibility,which enables a high-performance TADF emitter with a small single-triplet energy gap(ΔE_(ST))of 0.04 e V,a high photoluminescence quantum yield(Φ_(PL))of 99% and a large horizontal orientation factor(Θ_(//))of 84.0%.Consequently,highly efficient OLEDs with an external quantum efficiency as high as 33.8% are assembled,which is significantly higher than those of DPAC-BP with a highly rotatable BP acceptor(23.8%)as well as DPACFO with a rigid fluorenone(FO)acceptor(6.9%).

关键词： organic light-emitting diodes medium-ring intramolecular-lock thermally activated delayed fluorescence molecular orientation

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Pressure-induced magnetic phase and structural transition in SmSb2

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Chinese Physics B 2024年第6期33卷 484-489页

作者：李涛王舒阳陈绪亮陈春华房勇杨昭荣 science Island Branch of Graduate School University of Science and Technology of China Anhui Key Laboratory of Low-Energy Quantum materials and devices High Magnetic Field LaboratoryHFIPS Chinese Academy of Sciences Jiangsu Laboratory of Advanced Functional materials Department of Physics Changshu Institute of Technology institutes of Physical science and Information Technology Anhui University Collaborative Innovation Center of Advanced Microstructures

Motivated by the recent discovery of unconventional superconductivity around a magnetic quantum critical point in pressurized CeSb2,here we present a high-pressure study of an isostructural antiferromagnetic（AFM） SmSb2through electrical transport and synchrotron x-ray diffraction *** PC～2.5 GPa,we found a pressure-induced magnetic phase transition accompanied by a Cmca→P4/nmm structural phase *** the pristine AFM phase below PC,the AFM transition temperature of SmSb2is insensitive to pressure;in the emergent magnetic phase above PC,however,the magnetic critical temperature increases rapidly with increasing *** addition,at ambient pressure,the magnetoresistivity（MR） of SmSb2increases suddenly upon cooling below the AFM transition temperature and presents linear nonsaturating behavior under high field at 2 *** increasing pressure above PC,the MR behavior remains similar to that observed at ambient pressure,both in terms of temperature-and field-dependent *** leads us to argue an AFM-like state for SmSb2above *** the investigated pressure of up to 45.3 GPa and the temperature of down to 1.8 K,we found no signature of superconductivity in SmSb2.

关键词： antiferromagnet high pressure magnetoresistivity structural transition

MoS2-based anode materials for lithium-ion batteries:Developments and perspectives

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Particuology 2024年第4期87卷 240-270页

作者： Lianyu Zhao Yishan Wang Chuncheng Wei Xiaoxiao Huang Xueqian Zhang Guangwu Wena School of materials science and Engineering Shandong University of TechnologyZibo255000China Schoolof materials science and Engineering Harbin Institute of TechnologyHarbin10001China

In recent years,significant progress has been achieved in the creation of innovative functional materials for energy storage and *** to their distinct physicochemical characteristics,ultrathin nanosheets composed of common layered transition metal sulfide materials(MoS2)have demonstrated promise as high-capacity anode materials for lithium-ion batteries(LIBs).Nevertheless,their practical application is severely limited by the tendency of monolayer nanosheets to restack due to strong van der Waals forces,dramatic volume changes during successive cycles,and low intrinsic *** research advances have shown that composite structures and nanowire morphologies with specific morphologies effectively overcome these *** paper reviews the recent research progress on molybdenum disulfide-based composites as anode materials for LIBs and discusses in detail the struc-tural characteristics of pure molybdenum disulfide and other composite forms of molybdenum *** addition,the phase engineering,defect engineering,and lithium storage mechanisms of molybdenum disulfide and the synthesis of molybdenum disulfide-based nanocomposites by different preparation methods are focused ***,we review the design(structure),recent developments,and challenges of novel anode materials and consider their electrochemical performance in Li-ion batteries.

关键词： Lithium-ion battery MoS_(2)-Based anode composites Synthesis methods Defect engineering Lithium storage mechanism

Interactive effect of thermal aging and proton irradiation on microstructural evolution and hardening ofδ-ferrite in 308L stainless steel weld metal

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Journal of materials science & Technology 2024年第3期170卷 140-155页

作者： Xiaodong Gao Xiaodong Lin Tao Guo Lining Xu Yaolei Han Baolong Jiang Xingyuan Mei Qunjia Peng Lijie Qiao Beijing Advanced Innovation Center for materials Genome Engineering Institute of Advanced Materials and TechnologyUniversity of Science and Technology BeijingBeijing 100083China institute of materials Shanghai UniversityShanghai 200072China School of materials science and Engineering University of Science and Technology BeijingBeijing 100083China Suzhou Nuclear Power Research institute Suzhou 215004China State Key Laboratory for Advanced Metals and materials University of Science and Technology BeijingBeijing 100083China

In the harsh service environment of high temperature and intense neutron irradiation in water-cooled nuclear reactors,the austenitic stainless steel weld overlay cladding on the inner surface of the reactor pressure vessel suffers from thermal aging and irradiation damage simultaneously,which can induce microstructural evolution and hardening of the *** it is quite difficult to achieve this simul-taneous process out of the pile,two kinds of combined experiments,i.e.,post-irradiation thermal aging and post-aging irradiation were performed on 308 L stainless steel weld metals in this *** interactive effect of thermal aging and proton irradiation on microstructural evolution and hardening ofδ-ferrite in 308 L weld metal was investigated by combining atom probe tomography,transmission elec-tron microscopy and nanoindentation *** results revealed that thermal aging could eliminate the dislocation loops induced by irradiation and affect the phase transition process by accelerating spinodal decomposition and G-phase precipitation,thus enhancing hardening of irradiatedδ-*** the effect of irradiation on the microstructure and hardening of thermally agedδ-ferrite,however,intensive collision cascades can intensify G-phase precipitation and dislocation loop formation but decrease spinodal decomposition,leading to a limited effect on hardening of thermally agedδ-***,the interaction of thermal aging and irradiation can promote G-phase ***,the interaction can causeδ-ferrite hardening,which is mainly influenced by spinodal decomposition,followed by G-phase and dislocation loops,where spinodal decomposition and G-phase cause hardening by inducing strain fields.

关键词： Austenitic stainless steel weld metals Thermal aging Proton irradiation Interaction Microstructural evolution Hardening

A high-sensitive and self-selective humanoid mechanoreceptor for spatiotemporal tactile stimuli cognition

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Nano Research 2024年第5期17卷 4400-4409页

作者： Shuxin Bi Xuan Zhao Fangfang Gao Xiaochen Xun Bin Zhao Liangxu Xu Tian Ouyang Qingliang Liao Yue Zhang Academy for Advanced Interdisciplinary science and Technology Beijing Advanced Innovation Center for Materials Genome EngineeringUniversity of Science and Technology(Beijing)Beijing 100083China Key Laboratory of Advanced materials and devices for Post-Moore Chips Ministry of EducationBeijing Key Laboratory for Advanced Energy Materials and TechnologiesSchool of Materials Science and EngineeringUniversity of Science and Technology BeijingBeijing 100083China

The cognition of spatiotemporal tactile stimuli,including fine spatial stimuli and static/dynamic temporal stimuli,is paramount for intelligent robots to feel their surroundings and complete manipulation ***,current tactile sensors have restrictions on simultaneously demonstrating high sensitivity and performing selective responses to static/dynamic stimuli,making it a challenge to effectively cognize spatiotemporal tactile ***,we report a high-sensitive and self-selective humanoid mechanoreceptor(HMR)that can precisely respond to spatiotemporal tactile *** HMR with PDMS/chitosan@CNTs(PDMS:polydimethylsiloxane;CNT:carbon nanotube)graded microstructures and polyurethane hierarchical porous spacer exhibits high sensitivity of 3790.8 kPa^(-1).The HMR demonstrates self-selective responses to static and dynamic stimuli with mono signal through the hybrid of piezoresistive and triboelectric ***,it can respond to spatiotemporal tactile stimuli and generate distinguishable and multi-type characteristic *** the assistance of the convolutional neural network,multiple target objects can be easily identified with a high accuracy of 99.1%.This work shows great potential in object precise identification and dexterous manipulation,which is the basis of intelligent robots and natural human-machine interactions.

关键词： mechanoreceptors self-selective high-sensitive spatiotemporal tactile stimuli cognition sensors

On-Chip Micro Temperature Controllers Based on Freestanding Thermoelectric Nano Films for Low-Power Electronics

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Nano-Micro Letters 2024年第7期16卷 98-108页

作者： Qun Jin Tianxiao Guo Nicolas Perez Nianjun Yang Xin Jiang Kornelius Nielsch Heiko Reith institute for Metallic materials Leibniz Institute for Solid State and Materials Research01069 DresdenGermany institute of materials Engineering University of Siegen57076 SiegenGermany institute of Applied Physics Technical University of Dresden01069 DresdenGermany institute of materials science Technical University of Dresden01069 DresdenGermany

Multidimensional integration and multifunctional com-ponent assembly have been greatly explored in recent years to extend Moore’s Law of modern ***,this inevitably exac-erbates the inhomogeneity of temperature distribution in microsystems,making precise temperature control for electronic components extremely ***,we report an on-chip micro temperature controller including a pair of thermoelectric legs with a total area of 50×50μm^(2),which are fabricated from dense and flat freestanding Bi2Te3-based ther-moelectric nano films deposited on a newly developed nano graphene oxide membrane *** tunable equivalent thermal resistance is controlled by electrical currents to achieve energy-efficient temperature control for low-power electronics.A large cooling temperature difference of 44.5 K at 380 K is achieved with a power consumption of only 445μW,resulting in an ultrahigh temperature control capability over 100 K mW^(-1).Moreover,an ultra-fast cooling rate exceeding 2000 K s^(-1) and excellent reliability of up to 1 million cycles are *** proposed on-chip temperature controller is expected to enable further miniaturization and multifunctional integration on a single chip for microelectronics.

关键词： Temperature control Low-power electronics On-chip micro temperature controller Freestanding thermoelectric nano films Temperature-sensitive components