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Insights into photocatalytic mechanism over a novel Cu2WS4/MoS2 S-scheme heterojunction

Rare Metals 2024年第7期43卷 3118-3133页

作者： Wei Zhao Ji-Hui Cao Jun-Jie Liao Yun Liu Xiao-Jun Zeng Jun-Yu Shen Xue-Kun Hong Yang Guo He-Hua Zeng Ya-Zi Liu School of Materials Engineering Jiangsu Key Laboratory of Advanced Functional MaterialsSchool of Electronic and Information EngineeringChangshu Institute of Technology School of chemistry and Chemical Engineering Changji University State Environmental Protection Key laboratory of Soil Environmental Management and Pollution Control Ministry of Ecology and EnvironmentNanjing Institute of Environmental Sciences School of Environment Jiangsu Engineering Lab of Water and Soil Eco-RemediationNanjing Normal University department of Chemical Engineering Curtin University

A novel efficient Cu2WS4/MoS2step-scheme（S-scheme） heterojunction photocatalyst was constructed for the first time and applied in the removal of environmental *** the as-prepared photocatalysts,the Cu2WS4/MoS2-8 % heterojunc tion photoc atalyst demonstrates the optimal photocatalytic performance,with the catalytic oxidation efficiency of tetracycline（TC） and the catalytic reduction efficiency of Cr6+reaching 93.3%and 82.1 %,*** excellent catalytic properties of Cu2WS4/MoS2heterojunction photocatalysts are attributed to the effective separation pathways of charges and the presence of S-scheme heterojunctions,together with stronger redox *** is speculated that the photogenerated carrier migration path of the Cu2WS4/MoS2catalyst follows the typical S-scheme photocatalytic mechanism,which is verified by the in-depth experimental study and simulated calculations including the electron paramagnetic resonance（EPR） analysis,free radical quenching experiments,charge density distribution,and simulated built-in electric field formation at the interface,which acts as driving force to promote the separation of photoinduced electrons and ***,the photocatalytic mechanism of S-scheme photogenerated carrier migration for the Cu2WS4/MoS2catalyst is revealed based on the systematic experimental techniques and simulated calculations,accounting for its superior photocatalytic oxidation and reduction *** study provides inspiring implications to develop high-efficient S-scheme photocatalytic systems for versatile applications in solarenergy conversion.

关键词： Cu 2 WS 4 /MoS 2 S-scheme Heterojunction Photocatalysis

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Enhanced charge separation by incomplete calcination modified co-doped TiO_(2)nanoparticle for isothiazolinone photocatalytic degradation

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Nano Research 2024年第6期17卷 4834-4843页

作者： Zhiren Guo Xiao Zhang Xinyuan Li Chang Cui Zilei Zhang Hansheng Li Dongxiang Zhang Jinying Li Xiyan Xu Jiatao Zhang School of chemistry and Chemical Engineering Beijing Institute of TechnologyBeijing 102488China department of chemistry MSU-BIT UniversityShenzhen 517182Chin

Photocatalytic oxidation techniques are promising for degradation of the highly ecotoxic and refractory isothiazolinone bactericides in relevant industrial ***,low charge separation and directional transport efficiency under solar light radiation restrain their practical ***,we report a nanostructured photocatalyst doped with Gd and B in TiO_(2)with carbon incorporation and defect formation through incomplete *** specific surface area,grain size,and hydrophilicity of TiO_(2)are improved,which is beneficial for the interfacial reaction between the photocatalyst and *** reduction of the bandgap,the broadening of the photo-absorption range,and the retarded electron-hole recombination promote the photocatalytic performance due to the improved oxygen vacancies based on the electron distribution *** difference in partial density of states(ΔPDOS)between the current catalyst and raw TiO_(2)indicates that the co-doping of Gd and B with incomplete calcination changes the electronic hybridization of conduction band and valence band near the Fermi level,and affects the band gap *** improved charge separation and directional transport efficiency and benefited the formation of main active species,including•OH and O_(2)•−,for the pollutant *** rate of photocatalytic removal of benzisothiazolinone(BIT)by the current photocatalyst reaches 1.25 h^(−1),being 4.31 times that of TiO_(2).The current work offers a constructive approach to the design and synthesis of nanostructured photocatalysts for the photocatalytic degradation of refractory organic pollutants.

关键词： TiO_(2)nanoparticle charge separation oxygen vacancies electron distribution modification photocatalytic degradation

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Confined Mnenables effective aerobic oxidation catalysis

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Science China chemistry 2024年

作者： Desheng Yuan Sicong Ma Xiao Kong Chi Zhang Lin Chen Chengsheng Yang Lihua Wang Zhen Liu Lin Ye Yongmei Liu Rui Ma Zhipan Liu Yifeng Zhu Yong Cao Xinhe Bao institute of Advanced Fluorine-Containing Materials Zhejiang Normal University department of Chemical Physics University of Science and Technology of China School of Materials and chemistry University of Shanghai for Science and Technology department of chemistry Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials Collaborative Innovation Center of Chemistry for Energy Materials Fudan University Key laboratory of Synthetic and Self-Assembly chemistry for Organic Functional Molecules Shanghai Institute of Organic ChemistryChinese Academy of Sciences Shanghai Synchrotron Radiation Facility Shanghai Advanced Research Institute Chinese Academy of Sciences State Key laboratory of Catalysis National Laboratory for Clean Energy Collaborative Innovation Center of Chemistry for Energy Materials Dalian Institute of Chemical Physics Chinese Academy of Sciences

Effective and mild activation of O2is essential but challenging for aerobic oxidation. In heterogeneous catalysis, high-valence manganese oxide(e.g., +4) is known to be active for the oxidation, whereas divalent MnO is ineffective due to its limited capacity to supply surface oxygen and its thermodynamically unstable structure when binding O2in reaction conditions. Inspired by natural enzymes that rely on divalent Mn2+, we discovered that confining Mn2+onto the Mn2O3surface through a dedicated calcination process creates highly active catalysts for the aerobic oxidation of 5-hydroxymethylfurfural, benzyl alcohol, and *** Mn2O3-confined Mn2+is undercoordinated and efficiently mediates O2activation, resulting in 2–3 orders of magnitude higher activity than Mn2O3alone. Through low-temperature infrared spectroscopy, we distinguished low-content Mn2+sites at Mn2O3surface, which are difficult to be differentiated by X-ray photoelectron spectroscopy. The combination of in-situ energydispersive X-ray absorption spectroscopy and X-ray diffraction further provides insights into the formation of the newly identified active Mn2+sites. By optimizing the calcination step, we were able to increase the catalytic activity threefold *** finding offers promising frontiers for exploring active oxidation catalysts by utilizing the confinement of Mn2+and oftenignored calcination skills.

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Grain Yield,Biomass Accumulation,and Leaf Photosynthetic Characteristics of Rice under Combined Salinity-Drought Stress

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Rice science 2024年第1期31卷 118-128,I0023页

作者： WEI Huanhe GENG Xiaoyu ZHANG Xiang ZHU Wang ZHANG Xubin CHEN Yinglong HUO Zhongyang ZHOU Guisheng MENG Tianyao DAI Qigen Jiangsu Key laboratory of Crop Cultivation and Physiology/Jiangsu Key laboratory of Crop Genetics and Physiology/Jiangsu Co-Innovation Center for Modern Production technology of Grain Crops/Key laboratory of Saline-Alkali Soil Reclamation and Utilization in Coastal Areas the Ministry of Agriculture and Rural Affairs of China/Research Institute of Rice Industrial Engineering TechnologyYangzhou UniversityYangzhou 225009China institute of Agricultural Science and technology Development/Joint International Research laboratory of Agriculture and Agri-Product Safety the Ministry of Education of ChinaYangzhou UniversityYangzhou 225009China

Simultaneous stresses of salinity and drought often coincide during rice-growing seasons in saline lands,primarily due to insufficient water resources and inadequate irrigation ***,combined salinity-drought stress poses a major threat to rice *** this study,two salinity levels(NS,non-salinity;HS,high salinity)along with three drought treatments(CC,control condition;DJ,drought stress imposed at jointing;DH,drought stress imposed at heading)were performed to investigate their combined influences on leaf photosynthetic characteristics,biomass accumulation,and rice yield ***,drought,and their combination led to a shortened growth period from heading to maturity,resulting in a reduced overall growth *** yield was reduced under both salinity and drought stress,with a more substantial reduction under the combined salinity-drought *** combined stress imposed at heading caused greater yield losses in rice compared with the stress imposed at ***,the combined salinity-drought stress induced greater decreases in shoot biomass accumulation from heading to maturity,as well as in shoot biomass and nonstructural carbohydrate(NSC)content in the stem at heading and ***,it increased the harvest index and NSC remobilization *** and drought reduced the leaf area index and SPAD value of flag leaves and weakened the leaf photosynthetic characteristics as indicated by lower photosynthetic rates,transpiration rates,and stomatal *** reductions were more pronounced under the combined ***,drought,and especially their combination,decreased the activities of ascorbate peroxidase,catalase,and superoxide dismutase,while increasing the contents of malondialdehyde,hydrogen peroxide,and superoxide *** results indicated a more significant yield loss in rice when subjected to combined salinity-drought *** individual and combined stresses of salinity and dro

关键词： antioxidant defense system combined salinity-drought stress drought stress photosynthetic characteristics rice salinity stress

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Boring holes in Au nanoplates by active surface etching

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Nano Research 2024年第9期17卷 8610-8617页

作者： Haiyang Hu Yuntao Wang Qian Wang Xudong Peng An Su Hong Wang Hongyu Chen institute of Advanced Synthesis(IAS)and School of chemistry and Molecular Engineering Jiangsu National Synergetic Innovation Centre for Advanced MaterialsNanjing Tech UniversityNanjing 211816China department of Environmental Science and Engineering University of Science and Technology of ChinaHefei 230026China department of chemistry School of Science and Key Laboratory for Quantum Materials of Zhejiang ProvinceResearch Center for Industries of the FutureWestlake UniversityHangzhou 310030China institute of Natural Sciences Westlake Institute for Advanced StudyHangzhou 310024China

In contrast to the conventional etching that makes nanoparticles rounder and our previous sharpening etching mode that causes serrated edges,here,we developed a new boring etching mode that targets the faces of Au nanoplates to make *** critical factors are the pre-incubation step with the ligand 2-mercapto-5-benzimidazolecarboxylic acid(MBIA)and the subsequent removal of excess ligands in the ***,etching is focused onto the few sites with initial loss of ligands,which cannot be quickly *** choice of ligand MBIA is also of importance,as it carries negative charge and repels each *** inability of forming a dense layer probably plays a critical role in the site-selectivity for faces,because ligands at the higher curvature edges and corners are expected to have less *** etching results from the comproportionation reaction between Au3+and Au0 in the nanoplates,where Br-coordination to Au and the extra stabilization from cetyltrimethylammonium bromide(CTAB)are *** believe that the ability of boring holes is an important tool for future synthetic designs.

关键词： Au nanoplates active surface etching boring etching mode cetyltrimethylammonium bromide(CTAB)passivation holes

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A review of ^(17)O isotopic labeling techniques for solid-state NMR structural studies of metal oxides in lithium-ion batteries

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Magnetic Resonance Letters 2024年第2期4卷 46-53页

作者： Xiaoli Xia Lei Zhu Weiping Tang Luming Peng Junchao Chen School of chemistry and Chemical Engineering Shanghai Jiao Tong University800 Dongchuan RoadShanghai200240China Key laboratory of Mesoscopic chemistry of Ministry of Education and Collaborative Innovation Center of chemistry for Life Sciences School of Chemistry and Chemical EngineeringNanjing University163 Xianlin RoadNanjing210023China State Key laboratory of Space Power-Sources technology Shanghai Institute of Space Power-SourcesShanghai200245China

Recent advances in utilizing ^(17)O isotopic labeling methods for solid-state nuclear magnetic resonance(NMR)investigations of metal oxides for lithium-ion batteries have yielded extensive insights into their structural and dynamic ***,we commence with a brief introduction to recent research on lithium-ion battery oxide materials studied using ^(17)O solid-state NMR *** we delve into a review of ^(17)O isotopic labeling methods for tagging oxygen sites in both the bulk and surfaces of metal *** last,the unresolved problems and the future research directions for advancing the ^(17)O labeling technique are discussed.

关键词： ^(17)O solid-state NMR ^(17)O isotopic labeling methods Bulk and surfaces of metal oxides DFT calculation

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Strain‑Induced Surface Interface Dual Polarization Constructs PML‑Cu/Bi_(12)O_(17)Br_(2) High‑Density Active Sites for CO_(2) Photoreduction

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Nano-Micro Letters 2024年第5期16卷 169-183页

作者： Yi Zhang Fangyu Guo Jun Di Keke Wang Molly Meng‑Jung Li Jiayu Dai Yuanbin She Jiexiang Xia Huaming Li School of chemistry and Chemical Engineering Institute for Energy ResearchSchool of the Environment and Safety EngineeringJiangsu UniversityZhenjiang 212013People’s Republic of China State Key laboratory Breeding Base of Green chemistry‑Synthesis technology College of Chemical EngineeringZhejiang University of TechnologyHangzhou 310014People’s Republic of China College of Science and Hunan Key Laboratory of Extreme Matter and ApplicationsNational University of Defense TechnologyChangsha 410073People’s Republic of China department of Applied Physics The Hong Kong Polytechnic UniversityHung HomHong KongPeople’s Republic of China School of chemistry and Chemical Engineering National Special Superfine Powder Engineering Research CenterNanjing University of Science and TechnologyNanjing 210094People’s Republic of China Key laboratory of the Ministry of Education for Advanced Catalysis Materials Zhejiang Normal UniversityJinhua 321004People’s Republic of China

The insufficient active sites and slow interfacial charge trans-fer of photocatalysts restrict the efficiency of CO_(2) *** synchronized modulation of the above key issues is demanding and ***,strain-induced strategy is developed to construct the Bi–O-bonded interface in Cu porphyrin-based monoatomic layer(PML-Cu)and Bi_(12)O_(17)Br_(2)(BOB),which triggers the surface interface dual polarization of PML-Cu/BOB(PBOB).In this multi-step polarization,the built-in electric field formed between the interfaces induces the electron transfer from con-duction band(CB)of BOB to CB of PML-Cu and suppresses its reverse ***,the surface polarization of PML-Cu further promotes the electron converge in Cu *** introduction of PML-Cu endows a high density of dispersed Cu active sites on the surface of PBOB,significantly promoting the adsorption and activation of CO_(2) and CO *** conversion rate of CO_(2) photoreduction to CO for PBOB can reach 584.3μmol g-1,which is 7.83 times higher than BOB and 20.01 times than *** work offers valuable insights into multi-step polarization regulation and active site design for catalysts.

关键词： Bi_(12)O_(17)Br_(2) Porphyrin CO_(2)photoreduction Polarization Active sites

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Generating 1O2 and CoIV=O through efficient peroxymonosulfate activation by ZnCo_(2)O_(4)nanosheets for pollutant control

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Nano Research 2024年第9期17卷 8025-8035页

作者： Xiaoke Zhang Yangyang Zhang Jiaqi Tian Yadan Guo Zhongkui Zhou Zhongyi Liu Zaiwang Zhao Bin Liu Jun Li College of chemistry Henan Institute of Advanced TechnologyZhengzhou UniversityZhengzhou 450052China State Key laboratory of Coking Coal Resources Green Exploitation Zhengzhou UniversityZhengzhou 450001China School of Water Resources and Environmental Engineering East China University of TechnologyNanchang 330013China department of Materials Science and Engineering City University of Hong KongHong Kong 999077China College of Energy Materials and chemistry College of Chemistry and Chemical EngineeringInnerMongolia UniversityHohhot 010070China

Heterogeneous advanced oxidation processes(AOPs)based on non-radical reactive species are considered as a powerful technology for wastewater purification due to their long half-lives and high adaptation in a wide pH ***,we fabricate surface Co defect-rich spinel ZnCo_(2)O_(4)porous nanosheets,which can generate≡CoIV=O and 1O2 over a wide pH range of 3.81-10.96 by the formation of amphoteric≡Zn(OH)2 in peroxymonosulfate(PMS)activation *** functional theory(DFT)calculations show Co defect-rich ZnCo_(2)O_(4)possesses much stronger adsorption ability and more electron transfer to ***,the adsorption mode changes from terminal oxygen Co-O-Co to Co-O,accelerating the polarization of adjacent oxygen,which is beneficial to the generation of≡CoIV=O and *** defect-rich ZnCo_(2)O_(4)porous nanosheets exhibit highly active PMS activation activity and stability in p-nitrophenol(PNP)degradation,whose toxicity of degradation intermediates is significant *** Co defect-rich ZnCo_(2)O_(4)nanosheet catalyst sponge/PMS system achieved stable and efficient removal of PNP with a removal efficiency higher than 93%over 10 *** work highlights the development of functional catalyst and provides an atomic-level understanding into non-radical PMS activation process in wastewater treatment.

关键词： advanced oxidation processes ZnCo_(2)O_(4)nanosheets peroxymonosulfate activation CoIV=O,wastewater treatment

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Spontaneous mutations and mutational responses to penicillin treatment in the bacterial pathogen Streptococcus pneumoniae D39

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Marine Life Science & technology 2024年第2期6卷 198-211页

作者： Wanyue Jiang Tongtong Lin Jiao Pan Caitlyn ERivera Clayton Tincher Yaohai Wang Yu Zhang Xiang Gao Yan Wang Ho‑Ching T.Tsui Malcolm E.Winkler Michael Lynch Hongan Long institute of Evolution and Marine Biodiversity KLMMEOcean University of ChinaQingdao 266003China laboratory for Marine Biology and Biotechnology Laoshan LaboratoryQingdao 266237China department of Biology Indiana UniversityBloomingtonIN 47405USA School of Mathematics Science Ocean University of ChinaQingdao 266000China State Key laboratory of Microbial technology Microbial Technology InstituteSchool of Life ScienceShandong UniversityQingdao 266237China Biodesign Center for Mechanisms of Evolution Arizona State UniversityTempeAZ 85281USA

Bacteria with functional DNA repair systems are expected to have low mutation rates due to strong natural selection for genomic ***,our study of the wild-type Streptococcus pneumoniae D39,a pathogen responsible for many common diseases,revealed a high spontaneous mutation rate of 0.02 per genome per cell division in mutation-accumulation(MA)*** rate is orders of magnitude higher than that of other non-mutator bacteria and is characterized by a high mutation bias in the A/T *** high mutation rate may have resulted from a reduction in the overall efficiency of selection,conferred by the tiny effective population size in *** line with this,*** D39 also exhibited the lowest DNA mismatch-repair(MMR)efficiency among *** with the antibiotic penicillin did not elevate the mutation rate,as penicillin did not induce DNA damage and *** lacks a stress response *** findings suggested that the MA results are applicable to within-host scenarios and provide insights into pathogen evolution.

关键词： Neutral evolution Mutation spectrum Antibiotics DNA mismatch repair Oxidative damage repair

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Aspect-Level Sentiment Analysis Based on Deep Learning

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Computers, Materials & Continua 2024年第3期78卷 3743-3762页

作者： Mengqi Zhang Jiazhao Chai Jianxiang Cao Jialing Ji Tong Yi department of Communication University of New South WalesSydney2052Australia higher Vocational Education Publishing Division Higher Education PressBeijing100029China State Key laboratory of Media Convergence and Communication Communication University of ChinaBeijing100020China Key Lab of Education Blockchain and Intelligent technology Ministry of EducationGuangxi Normal UniversityGuilin541004China

In recent years,deep learning methods have developed rapidly and found application in many fields,including natural language *** the field of aspect-level sentiment analysis,deep learning methods can also greatly improve the performance of ***,previous studies did not take into account the relationship between user feature extraction and contextual *** address this issue,we use data feature extraction and deep learning combined to develop an aspect-level sentiment analysis *** be specific,we design user comment feature extraction(UCFE)to distill salient features from users’historical comments and transform them into representative user feature ***,the aspect-sentence graph convolutional neural network(ASGCN)is used to incorporate innovative techniques for calculating adjacency matrices;meanwhile,ASGCN emphasizes capturing nuanced semantics within relationships among aspect words and syntactic dependency ***,three embedding methods are devised to embed the user feature vector into the ASGCN *** empirical validations verify the effectiveness of these models,consistently surpassing conventional benchmarks and reaffirming the indispensable role of deep learning in advancing sentiment analysis methodologies.

关键词： Aspect-level sentiment analysis deep learning graph convolutional neural network user features syntactic dependency tree

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