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A high Li-ion diffusion kinetics in multidimensional and compact-structured electrodes via vacuum filtration casting

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Journal of Energy Chemistry 2024年第6期93卷 368-376,I0010页

作者： Jieqiong Li Ting Ouyang Lu Liu Shu Jiang Yongchao Huang M.-Sadeeq Balogun college of Materials Science and Engineering Hunan Joint International Laboratory of Advanced Materials and Technology for Clean EnergyHunan UniversityChangsha 410082HunanChina Institute of Environmental Research at Greater Bay Key Laboratory for Water Quality and Conservation of the Pearl River DeltaMinistry of EducationGuangzhou UniversityGuangzhou 510006GuangdongChina

Manufacturing process,diffusion co-efficient and areal capacity are the three main criteria for regulating thick electrodes for lithium-ion batteries(LIBs).However,simultaneously regulating these criteria for LIBs is desirable but remains a significant *** this work,niobium pentoxide(Nb_(2)O_(5))anode and lithium iron phosphate(LiFePO_(4))cathode materials were chosen as the model materials and demonstrate that these three parameters can be simultaneously modulated by incorporation of micro-carbon fibers(MCF)and carbon nanotubes(CNT)with both Nb_(2)O_(5) and LFP via vacuum filtration *** as-prepared MNC-20 anode and MLC-20 cathode achieves high reversible areal capacity of≈5.4 m A h cm^(-2)@0.1 C and outstanding Li-ion diffusion coefficients of≈10~(-8)cm~2 s~(-1)in the half-cell *** assembled MNC-20‖MLC-20 full cell LIB delivers maximum energy and power densities of244.04 W h kg^(-1)and 108.86 W kg^(-1),*** excellent electrochemical properties of the asprepared thick electrodes can be attributed to the highly conductive,mechanical compactness and multidimensional mutual effects of the MCF,CNT and active materials that facilitates rapid Li-ion diffusion ***,electrochemical impedance spectroscopy(EIS),symmetric cells analysis,and insitu Raman techniques clearly validates the enhanced Li-ion diffusion kinetics in the present architecture.

关键词： Thick electrodes Carbon nanotubes Li-ion diffusion co-efficient Vacuum filtration technique High areal capacity Lithium-ion batteries

Novel P-doping-tuned Pd nanoflowers/S,N-GQDs photo-electrocatalyst for high-efficient ethylene glycol oxidation

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Chinese Chemical Letters 2024年第6期35卷 541-545页

作者： Xiaoxiao Huang Zhi-Long He Yangpeng Chen Lei Li Zhenyu Yang Chunyang Zhai Mingshan Zhu School of Materials Science and Chemical Engineering Ningbo UniversityNingbo 315211China college of Biological Chemical Sciences and EngineeringJiaxing UniversityJiaxing 314001China Guangdong Key Lab oratory of Environmental Pollution and Health School of EnvironmentJinan UniversityGuangzhou 510632China

Traditional photo-electcatalyst structures of small noble metal nanoparticles assembling into large-scale photoactive semiconductors still suffer from agglomeration of noble metal nanoparticles,insufficient charge transfer,undesirable photoresponse ability that restricted the photo-electrocatalytic *** this end,a novel design strategy is proposed in this work,namely integrating small-scale photoactive materials(doped graphene quantum dots,S,N-GQDs)with large-sized noble metal(Pd P)nanoflowers to form novel photo-electrocatalysts for high-efficient alcohol oxidation *** expected,superior electrocatalytic performance of Pd P/S,N-GQDs for ethylene glycol oxidation is acquired,thanks to the nanoflower structure with larger specific surface area and abundant active ***,nonmetal P are demonstrated,especially optimizing the adsorption strength,enhancing the interfacial contact,reducing metal agglomeration,ensuring uniform and efficient doping of S,N-GQDs,and ultimately significantly boost the catalytic activity of photo-electrocatalysts.

关键词： Non-metallic P–doping Sulfur nitrogen co-doped graphene quantum dots Pd nanoflowers Photo-electrocatalytic Ethylene glycol oxidation

Multi-dimensional multiplexing optical secret sharing framework with cascaded liquid crystal holograms

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Opto-Electronic Advances 2024年第1期7卷 28-35页

作者： Keyao Li Yiming Wang Dapu Pi Baoli Li Haitao Luan Xinyuan Fang Peng Chen Yanqing Lu Min Gu Institute of Photonic Chips University of Shanghai for Science and TechnologyShanghai 200093China Centre for Artificial-Intelligence Nanophotonics School of Optical-Electrical and Computer EngineeringUniversity of Shanghai for Science and TechnologyShanghai 200093China National Laboratory of Solid State Microstructures and College of Engineering and Applied SciencesNanjing UniversityNanjing 210093China

Secret sharing is a promising technology for information encryption by splitting the secret information into different ***,the traditional scheme suffers from information leakage in decryption process since the amount of available information channels is ***,we propose and demonstrate an optical secret sharing framework based on the multi-dimensional multiplexing liquid crystal(LC)*** LC holograms are used as spatially separated shares to carry secret *** polarization of the incident light and the distance between different shares are served as secret keys,which can significantly improve the information security and ***,the decryption condition is also restricted by the applied external voltage due to the variant diffraction efficiency,which further increases the information *** implementation,an artificial neural network(ANN)model is developed to carefully design the phase distribution of each LC *** the advantage of high security,high capacity and simple configuration,our optical secret sharing framework has great potentials in optical encryption and dynamic holographic display.

关键词： holographic encryption optical secret sharing cascaded liquid crystal hologram multi-dimensional multiplexing

用于膜分离的MXenes:从制备策略到先进应用

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Science Bulletin 2024年第1期69卷 125-140页

作者：黄正义赵蝶玲申利国林红军陈成徐艳超李必胜滕佳恒韩磊钟台生 college of Geography and Environmental Sciences Zhejiang Normal UniversityJinhua 321004China Department of Chemical and Biomolecular Engineering National University of SingaporeSingapore 117585Singapore

Transition metal carbides/nitrides/carbonitrides,commonly referred to as MXenes,have gained widespread attention since their discovery in 2011 as a promising family of two-dimensional(2D)*** impressive chemical,electrical,thermal,mechanical,and biological properties have fueled a surge in research focused on the synthesis and application of MXenes in various fields,including membranebased *** engineering the materials and membrane structures,MXene-based membranes have demonstrated remarkable separation performance and added functionalities,such as antifouling and photocatalytic *** this review,we aim to have a timely and critical review of research on their fabrication strategy and performance in advanced molecular separation and ion exchange,beginning with a brief introduction of the preparation and physicochemical properties of ***,outlooks and future works are outlined with the aims to provide valuable insights and guidance for advancing membranes'applications in different separation domains.

关键词： MXenes 2D materials Membrane separation Modification

Structural disruption of melanin-like polymers with boosted UV protection

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Science China Chemistry 2024年第5期67卷 1653-1663页

作者： Zhen Yang Xianheng Wang Wanjie Bai Zikun Zou Haoxing Wu Yiwen Li Department of Radiology Huaxi MR Research CenterFunctional and Molecular Imaging Key Laboratory of Sichuan ProvinceNational Clinical Research Center for GeriatricsWest China HospitalSichuan UniversityChengdu 610041China college of Polymer Science and Engineering State Key Laboratory of Polymer Materials EngineeringSichuan UniversityChengdu 610065China

Manipulating the energy structure of materials represents an efficient way to regulate their light absorption behaviors. For example, constructing donor-acceptor(D-A) structures to increase the polarizability and reduce the energy bandgap of local molecules has been widely used in the field of organic photovoltaics with ordered structures. Remarkably, even in disordered and chaotic systems such as melanin-like polydopamine(PDA), visible and near-infrared light absorption can be significantly improved using this strategy. However, there has been a noticeable dearth of research on the ultraviolet(UV) light absorption regulation of bioinspired polymers with disordered and chaotic architectures by tailoring the D-A microstructures. In this study, a series of benzoheterocyclic molecules with strong electron-donating features screened by molecular simulation calculations were involved in disrupting the D-A structures within PDA. The destruction of D-A structures promoted the increase of the energy band gap and finally boosted the UV absorption of PDA. The resulting PDA nanoparticles with enhanced UV absorption were further employed to fabricate UV shielding composite films to protect the growth of plants from harmful UV radiation. This research may open up new avenues for structural disruption of bioinspired polymers for enhanced photoprotection applications.

关键词： melanin-like polymers polydopamine D-A structure UV absorption photoprotection

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Cavity continuum

Photonics Research 2024年第3期12卷 391-398页

作者： FAN CHENG VLADIMIR SHUVAYEV MARK DOUVIDZON LEV DEYCH TAL CARMON School of Electrical Engineering Tel Aviv UniversityTel Aviv 6997801Israel Physics Department Queens College of CUNYFlushingQueensNew York 11367USA Solid State Institute Technion-Israel Institute of TechnologyHaifa 3200003Israel The Graduate Center of CUNY New YorkNew York 10016USA

We experimentally demonstrate and numerically analyze large arrays of whispering gallery *** fluorescent mapping,we measure the spatial distribution of the cavity ensemble’s resonances,revealing that light reaches distant resonators in various ways,including while passing through dark gaps,resonator groups,or resonator *** spatially decays exponentially in the *** practically infinite periodic array of resonators,with a quality factor(Q)exceeding 107,might impact a new type of photonic ensembles for nonlinear optics and lasers using our cavity continuum that is distributed,while having high-Q resonators as unit cells.

关键词： resonator cavity ensemble

Kinetically and thermodynamically expediting elementary steps via high-valence Cr-incorporated of nickel selenide for water electrolysis

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Nano Research 2024年第3期17卷 1199-1208页

作者： Huafeng Fan Dongxu Jiao Jinchang Fan Dewen Wang Bilal Zaman Wei Zhang Lei Zhang Weitao Zheng Xiaoqiang Cui State Key Laboratory of Automotive Simulation and Control School of Materials Science and EngineeringKey Laboratory of Automobile Materials of MOEJilin Provincial International Cooperation Key Laboratory of High-Efficiency Clean Energy MaterialsElectron Microscopy CenterJilin UniversityChangchun 130012China college of Chemistry Jilin UniversityChangchun 130012China

Designing high-performance electrocatalysts toward hydrogen evolution reaction(HER)and oxygen evolution reaction(OER)is essential to reduce the activation barrier and optimize free adsorption energy of reactive ***,we report that incorporating high-valence Cr into NiSe_(2)(Cr_(x)Ni_(1-x)Se_(2))kinetically and thermodynamically expedites elementary steps of both HER and *** as-prepared Cr_(0.05)Ni_(0.95)Se_(2) catalyst displays excellent HER and OER activities,with low overpotentials of 89 and 272 mV at the current density of 10 mA·cm^(-2)(j10),respectively,and remains stable during operation for 30 h.A low cell voltage of only 1.59 V is required to drive j10 in alkaline *** situ Raman spectroscopy reveals that Cr incorporation facilitates the formation of NiOOH active species during the OER ***,theoretical explorations demonstrate that high-valence Cr incorporation efficiently accelerates water dissociation kinetics and improves H*adsorption during HER process,lowering the activation barrier of OER and optimizing the adsorption energy of oxygen-based intermediate,thus kinetically and thermodynamically enhancing the intrinsic performance of NiSe_(2) for over water *** strategy provides a new horizon to design transition metal based electrocatalysts in the clean energy field.

关键词： nickel selenide electrocatalytic water splitting high-valence Cr density functional theory(DFT)calculation

Erratum to:Holocene temperature variation recorded by branched glycerol dialkyl glycerol tetraethers in a loess-paleosol sequence from the north-eastern Tibetan Plateau

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Frontiers of Earth Science 2024年第2期18卷 460-461页

作者： Tianxiao WANG Duo WU Tao WANG Lin CHEN Shilong GUO Youmo LI Chenbin ZHANG Key Laboratory of Western China’s Environmental Systems(Ministry of Education) College of Earth and Environmental SciencesLanzhou UniversityLanzhou 730000China Alpine Paleoecology and Human Adaptation Group(ALPHA) Institute of Tibetan Plateau ResearchChinese Academy of SciencesBeijing 100101China

Erratum to:*** *** 10.1007/s11707-023-1094-6 The original version of this article unfortunately contained a *** presentation of was *** corrected figure is given below.

关键词： alkyl corrected Plateau

Food nutrition and toxicology targeting on specific organs in the era of single-cell sequencing

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Food Science and Human Wellness 2024年第1期13卷 75-89页

作者： Xiaofei Wang Xiaowen Cheng Huiling Liu Xiaohuan Mu Hao Zheng National Engineering Technology Research Center for Fruit and Vegetable Processing Key Open Laboratory of Fruit and Vegetable ProcessingMinistry of Agriculture and Rural AffairsBeijing Key Laboratory of Food Non-Thermal ProcessingCollege of Food Science and Nutritional EngineeringChina Agricultural UniversityBeijing 100083China

Due to the complex natures of dietary food components,it is difficult to elucidate how the compounds affect host *** food often selectively presents its mechanism of action on different cell types,and participates in the modulation of targeted cells and their microenvironments within ***,the limitations of traditional in vitro assays or in vivo animal experiments cannot comprehensively examine cellular heterogeneity and the tissue-biased ***-cell RNA sequencing(sc RNA-seq)has emerged as an indispensable methodology to decompose tissues into different cell types for the demonstration of transcriptional profiles of individual *** RNA-seq applications has been summarized on three typical organs(brain,liver,kidney),and two representative immune-and tumor related health *** everincreasing role of sc RNA-seq in dietary food research with further improvement can provide sub-cellular information and the coupling between other cellular *** this review,we propose utilizing sc RNAseq to more effectively capture the subtle and complex effects of food chemicals,and how they may lead to health problems at single-cell *** novel technique will be valuable to elucidate the underlying mechanism of both the health benefits of food nutrients and the detrimental consequences food toxicants at the cellular level.

关键词： Dietary food Cellular heterogeneity Single-cell RNA sequencing Food nutrients Food toxicants