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Electrochemical conversion of methane to bridge the gap in the artificial carbon cycle

Journal of Energy Chemistry 2025年第1期100卷 286-308页

作者： Yuhao Peng Yuefeng Song Ihar Razanau Juanxiu Xiao Wei Xiao Di Hu Guoxiong Wang College of Chemistry and Molecular Sciences Hubei Key Laboratory of Electrochemical Power Sources Wuhan University State key laboratory of Catalysis Dalian National Laboratory for Clean Energy iChEM (Collaborative Innovation Center of Chemistry for Energy Materials) Dalian Institute of Chemical Physics Chinese Academy of Sciences laboratory of Physical-Chemical Technologies SSPA Scientific and Practical Materials Research Centre of NAS of Belarus State key laboratory of Marine Resources Utilization in South China Sea Collaborative Innovation Center of Marine Science and Technology School of Marine Science and Engineering Hainan University Department of Chemical and Environmental engineering University of Nottingham Ningbo China

Methane, an abundant one-carbon（C1） resource, is extensively used in the industrial production of vital fuels and value-added chemicals. However, current industrial methane conversion technologies are energy-and carbon-intensive, mainly due to the high activation energy required to break the inert C–H bond, low selectivity, and problematic side reactions, including CO2emissions and coke deposition. Electrochemical conversion of methane（ECM） using intermittent renewable energy offers an attractive solution, due to its modular reactor design and operational flexibility across a broad spectrum of temperatures and pressures. This review emphasizes conversion pathways of methane in various reaction systems, highlighting the significance and advantages of ECM in facilitating a sustainable artificial carbon cycle. This work provides a comprehensive overview of conventional methane activation mechanisms and delineates the complete pathways of methane conversion in electrolysis contexts. Based on surface/interface chemistry, this work systematically analyzes proposed reaction pathways and corresponding strategies to enhance ECM efficiency towards various target products, including syngas, hydrocarbons, oxygenates, and advanced carbon materials. The discussion also encompasses opportunities and challenges for the ECM process, including insights into ECM pathways, rational electrocatalyst design, establishment of benchmarking protocols, electrolyte engineering, enhancement of CH4conversion rates, and minimization of CO2emission.

关键词： Methane Electrochemical conversion Reaction mechanism Catalyst design Electrode Electrocatalysis

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Acid mine drainage and heavy metal contamination in groundwater of metal sulfide mine at arid territory (BS mine,Western Australia)

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Transactions of Nonferrous Metals Society of China 2010年第8期20卷 1488-1493页

作者：雷良奇宋慈安谢襄漓李艳红王飞 School of Earth Science Guilin University of Technology key laboratory of geological engineering centre of guangxi province Guilin University of Technology

The issues of acid mine drainage （AMD） and heavy metals contamination in the metal sulfide mine in the add district were explored, through studying the acidification and the heavy metals distribution and evolution of groundwater in the black swan （BS） nickel sulfide mine （Western Australia）. The groundwater samples were collected from the drilling holes situated in the vicinity of tailings storage facility （TSF） and in the background of the mine （away from TSF）, respectively, and the pH and electric conductivity （Ec） were measured in site and the metal contents were analysed by ICP-MS and ICP-AES, quarterly in one hydrological year. The results disclose that the TSF groundwater is remarkably acidified （.pHmean=5, pHmin=3）, and the average contents of heavy metals （Co, Cu, Zn, Cd） and Al, Mn are of 1-2 orders of magnitude higher in TSF groundwater than in background groundwater. It may be due to the percolation of tailings waste water from miU process, which leads the tailings to oxidize and the deep groundwater to acidify and contaminate with heavy metals. Besides, the heavy metals concentration in groundwater may be controlled by pH mainly.

关键词： nickel ore tailings acid mine drainage heavy metals groundwater contamination

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2D phosphides heterostructures on titanium microfiltration membrane for enhanced ampere-level current density overall seawater splitting

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Nano Research 2025年第1期18卷 249-259页

作者： Wenjing Dai Xin Wang Yulong Ma Sisi He Ming Chen Zhaohui Yin Shuheng Tian Maolin Wang Shixiang Yu Hang Zhang Yuanzhe Wang Hong Wang Jianxin Li Faming Gao Bowen Cheng Yun Wang Zhen Yin Ding Ma Tianjin key laboratory of Brine Chemical engineering and Resource Eco-utilization College of Chemical Engineering and Materials ScienceTianjin University of Science and TechnologyTianjin 300457China State key laboratory of Biobased Fiber Manufacturing Technology Tianjin University of Science and TechnologyTianjin 300457China Haian Institute of High-Tech Research Nanjing UniversityHaian 226600China Beijing National laboratory for Molecular Sciences College of Chemistry and Molecular EngineeringPeking UniversityBeijing 100871China State key laboratory of Separation Membranes and Membrane Processes Separation Membrane Science and Technology International Joint Research CentreTiangong UniversityTianjin 300387China centre for Catalysis and Clean Energy School of Environment and ScienceGold Coast CampusGriffith UniversitySouthportQueensland 4222Australia

The advancement of direct seawater electrolysis is a significant step towards sustainable hydrogen production,addressing the critical need for renewable energy sources and efficient resource ***,direct seawater electrolysis has to face several challenges posed by the corrosiveness of highly concentrated chloride and the competitive chlorine evolution reaction(ClER).To overcome these issues,we designed a novel NiP_(2)@CoP electrocatalyst on a porous titanium microfiltration(Ti MF)*** obtained bifunctional NiP_(2)@CoP catalyst outperforms the Pt/C and IrO_(2),as evidenced by its low overpotentials of 192 and 425 mV at a current density of 500 mA·cm^(-2) for hydrogen evolution reaction(HER)and oxygen evolution reaction(OER)in alkaline seawater(1 M KOH+0.5 M NaCl),***,only 231 and 569 mV overpotentials are required at the current density of 1500 mA·cm^(-2) towards HER and OER in alkaline seawater,*** importantly,no ClER was observed,demonstrating its excellent selectivity to *** selection of porous Ti MF membrane as an electrode substrate further enhances the performance by providing a robust structure that promotes the fast generation and release of gas *** promising outcomes obtained with NiP_(2)@CoP catalysts on Ti MF support,therefore,pave the way for the commercial viability of direct seawater electrolysis technologies at industrial-level current densities.

关键词： direct seawater electrolysis porous titanium microfiltration membrane phosphides heterostructures NiP_(2)@CoP electrocatalyst excellent selectivity to oxygen evolution reaction(OER)

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An Unprecedented Efficiency with Approaching 21%Enabled by Additive‑Assisted Layer‑by‑Layer Processing in Organic Solar Cells

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Nano-Micro Letters 2025年第2期17卷 372-375页

作者： Shuai Xu Youdi Zhang Yanna Sun Pei Cheng Zhaoyang Yao Ning Li Long Ye Lijian Zuo Ke Gao key laboratory of Advanced Green Functional Materials College of ChemistryChangchun Normal UniversityChangchun 130032People’s Republic of China Shandong Provincial key laboratory for Science of Material Creation and Energy Conversion School of Chemistry and Chemical EngineeringShandong UniversityQingdao 266237People’s Republic of China College of Polymer Science and engineering Sichuan UniversityChengdu 610065People’s Republic of China State key laboratory and Institute of Elemento‑Organic Chemistry Centre of Nanoscale Science and Technology and Key Laboratory of Functional Polymer MaterialsRenewable Energy Conversion and Storage Center(RECAST)College of ChemistryNankai UniversityTianjin 300071People’s Republic of China Institute of Polymer Optoelectronic Materials and Devices State key laboratory of Luminescent Materials and Devices South China University of TechnologyGuangzhou 510640People’s Republic of China Tianjin key laboratory of Molecular Optoelectronic Sciences School of Materials Science and EngineeringTianjin UniversityTianjin 300350People’s Republic of China State key laboratory of Silicon Materials MOE Key Laboratory of Macromolecular Synthesis and FunctionalizationDepartment of Polymer Science and EngineeringZhejiang UniversityHangzhou 310027People’s Republic of China

Recently published in Joule,Feng Liu and colleagues from Shanghai Jiaotong University reported a record-breaking 20.8%power conversion efficiency in organic solar cells(OSCs)with an interpenetrating fibril network active layer morphology,featuring a bulk p-in structure and proper vertical segregation achieved through additive-assisted layer-by-layer *** optimized hierarchical gradient fibrillar morphology and optical management synergistically facilitates exciton diffusion,reduces recombination losses,and enhances light capture *** approach not only offers a solution to achieving high-efficiency devices but also demonstrates the potential for commercial applications of OSCs.

关键词： Organic solar cells Additive-assisted layer-by-layer processing Three-dimensional fibril morphology Bulk p-i-n structure Optical management

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A novel active-passive protection strategy endows carbonyl iron with excellent intelligent anti-corrosion and microwave absorption dual functional characteristics

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Nano Research 2025年第1期18卷 487-500页

作者： Wei Tian Quanyuan Feng Linbo Zhang Yinfan Liu Xian Jian Longjiang Deng Institute of Microelectronics School of Information Science and TechnologySouthwest Jiaotong UniversityChengdu 611756China National engineering Researching centre of Electromagnetic Radiation Control Materials Key Laboratory of Multi-Spectral Absorbing Materials and Structures of Ministry of EducationState Key Laboratory of Electronic Thin Films and Integrated DevicesSchool of Electronic Science and EngineeringUniversity of Electronic Science and Technology of ChinaChengdu 611731China School of Materials and Energy University of Electronic Science and Technology of ChinaChengdu 611731China The Yangtze Delta Region Institute(Huzhou)&School of Electronic Science and engineering University of Electronic Science and Technology of ChinaHuzhou 313001China

Carbonyl iron absorbers(CI)face significant challenges in practical applications,such as corrosion,interface bonding failure,detachment,and high maintenance ***,we have developed intelligent self-healing technology based on proactive/passive mechanisms via in situ synthesis of self-healing factors(polydopamine/benzotriazole(PDA/BTA))and physical barrier layers(SiO_(2)/1,1,1,3,3,3-hexamethyl disilazane,SiO_(2)/HMDS)to enhance corrosion resistance,while also being compatible with efficient microwave absorption *** unique multiscale structure gives full play to the utilization of the roles of each functional layer,including the intelligent self-healing features of PDA/BTA,physical shielding and spatial confinement characteristics of SiO_(2)/HMDS,and magnetic-dielectric synergistic mechanism resulted from the good impedance matching characteristics,the conduction loss,the interfacial polarization loss and natural *** asfabricated composites achieved an exceptional minimum reflection loss value of-55.4 dB at 10.7 GHz and the effective absorption band of 7.6 ***,it still exhibits obvious self-healing and corrosion resistance characteristics after 360 h corrosion treatment,ascribed to the self-healing mechanism of PDA/BTA and the blocking intervention effect of SiO_(2)/*** work is considered to pave the way for the synthesis of high-performance magnetic absorbers,especially in enhancing their intelligent self-healing ability in corrosive environments.

关键词： microwave absorption intelligent self-healing technology carbonyl iron multiscale structure magneticdielectric synergistic mechanism

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REE behavior and effect factors in AMD-type acidic groundwater at sulfide tailings pond, BS nickel mine, W.A.

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中国有色金属学会会刊：英文版 2008年第4期18卷 955-961页

作者：雷良奇宋慈安谢湘漓李艳红 Department of Resources and Environment engineering Guilin University of TechnologyGuilin 541004ChinaKey Laboratory of Geological Engineering Centre of Guangxi ProvinceGuilin University of TechnologyGuilin 541004China Department of Resources and Environment engineering Guilin University of TechnologyGuilin 541004China

AMD(Acid Mine Drainage)-type acidic groundwater (pH6.5, with lower total REE contents, Ce depletion). While the AMD contaminated groundwater (pH=4.0-6.5) around tailings pond is characterized by transition from acidic to setting groundwater in total REE content, and associated with Ce depletion (like setting groundwater). The light REE in all type groundwater shows up depletion, but its depleted extent in acidic groundwater is more remarkable. This work indicates that REE behavior in AMD-type acidic groundwater is controlled mainly by pH value and metal (Al, Mn and Fe) contents. And the critical pH value that affects REE behavior in ground acidic water would be 4, lower than the previous value (pH=5) that has been believed prevalently in surface acidic waters. The pH could affect REE behavior in groundwater by controlling the solubility of metal (Al, Mn and Fe) hydroxides and the valence of cerium. Finally, light REE depletion in acidic groundwater may due to element affinity. High content Al (affinity with heavy REE) and low content Fe (affinity with light REE) may lead to heavy REE enrichment while light REE relative depletion in water.

关键词：矿山酸性排水地下水污染硫化物残渣稀土金属

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Landslide integrated characteristics and susceptibility assessment in Rongxian county of guangxi,China

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Journal of Mountain Science 2019年第3期16卷 657-676页

作者： LIAO Li-ping ZHU Ying-yan ZHAO Yan-lin WEN Hai-tao YANG Yun-chuan CHEN Li-hua MA Shao-kun XU Ying-zi College of Civil engineering and Architecture Guangxi University key laboratory of Disaster Prevention and Structural Safety of Ministry of Education Guangxi University guangxi key laboratory of Disaster Prevention and engineering Safety Guangxi University key laboratory of Mountain Hazards and Surface Processes Institute of Mountain Hazards and EnvironmentChinese Academy of Sciences guangxi Zhuang Autonomous Region geological Environmental Monitoring Station

Landslides distribute extensively in Rongxian county, the southeast of guangxi province, China and pose great threats to this county. At present, hazard management strategy is facing an unprecedented challenge due to lack of a landslide susceptibility map. Therefore, the purpose of this paper was to construct a landslide susceptibility map by adopting three widely used models based on an integrated understanding of landslide’s *** models include a semi-quantitative method(SQM), information value model(IVM) and logistical regression model(LRM).The primary results show that(1) the county is classified into four susceptive regions, named as very low, low, moderate and high, which covered an area of 13.43%, 32.40%, 31.19% and 22.99% in SQM, 0.86%, 26.82%, 44.11%, and 28.21% in IVM, 9.88%, 17.73%, 46.36% and 26.03% in LRM;(2) landslides are likely to occur within the areas characterized by following obvious aspects: high intensity of human activities, slope angles of 25°～35°, the thickness of weathered soil is larger than 15 m; the lithology is granite, shale and mud rock;(3) the area under the curve of SQM, IVM and LRM is 0.7151, 0.7688 and 0.7362 respectively, and the corresponding success rate is 71.51%, 76.88% and 73.62%. It is concluded that these three models are acceptable because they have an effective capability of susceptibility assessment and can achieve an expected accuracy. In addition, the susceptibility outcome obtained from IVM provides a slightly higher quality than that from SQM, LRM.

关键词： Landslide characteristic Susceptibility zonation Prevention regionalization Rongxian county

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Molecular Structure Tailoring of Organic Spacers for High‑Performance Ruddlesden–Popper Perovskite Solar Cells

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Nano-Micro Letters 2025年第2期17卷 314-357页

作者： Pengyun Liu Xuejin Li Tonghui Cai Wei Xing Naitao Yang Hamidreza Arandiyan Zongping Shao Shaobin Wang Shaomin Liu School of Materials Science and engineering State Key Laboratory of Heavy Oil ProcessingChina University of Petroleum(East China)Qingdao 266580People’s Republic of China School of Chemistry and Chemical engineering Shandong University of TechnologyZibo 255049People’s Republic of China centre for Applied Materials and Industrial Chemistry(CAMIC) School of ScienceRMIT UniversityMelbourneVic 3000Australia WA School of Mines:Minerals Energy and Chemical Engineering(WASM‑MECE)Curtin UniversityPerthWA 6102Australia School of Chemical engineering The University of AdelaideAdelaideSA 5005Australia School of engineering Great Bay UniversityDongguan 523000People’s Republic of China

Layer-structured Ruddlesden–Popper(RP)perovskites(RPPs)with decent stability have captured the imagination of the photovoltaic research community and bring hope for boosting the development of perovskite solar cell(PSC)***,two-dimensional(2D)or quasi-2D RP PSCs are encountered with some challenges of the large exciton binding energy,blocked charge transport and poor film quality,which restrict their photovoltaic ***,these issues can be readily resolved by rationally designing spacer cations of *** review mainly focuses on how to design the molecular structures of organic spacers and aims to endow RPPs with outstanding photovoltaic *** firstly elucidated the important roles of organic spacers in impacting crystallization kinetics,charge transporting ability and stability of *** we brought three aspects to attention for designing organic ***,we presented the specific molecular structure design strategies for organic spacers of RPPs aiming to improve photovoltaic performance of RP *** proposed strategies in this review will provide new avenues to develop novel organic spacers for RPPs and advance the development of RPP photovoltaic technology for future applications.

关键词： Ruddlesden-Popper perovskites Low-dimensional perovskite solar cells Organic spacers Molecular structure Design strategies

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Runout of submarine landslide simulated with material point method

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Journal of Hydrodynamics 2017年第3期29卷 438-444页

作者： Youkou Dong Dong Wang Mark F.Randolph centre for Offshore Foundation Systems the University of Western Australia Shandong Provincial key laboratory of Marine Environment and geological engineering Ocean University of China

Most of the present knowledge on submarine landslides relies upon back-analysis of post-failure deposits identified using geophysical *** this paper,the runout of slides on rigid bases is explored using the material point method（MPM）with focus on the geotechnical aspects of the *** MPM,the sliding material and bases are discretised into a number of Lagrangian particles,and a background Eulerian mesh is employed to update the state of the *** morphologies of the slide can be reproduced by tracking the Lagrangian particles in the dynamic processes.A real case history of a submarine slide is back-analyzed with the MPM and also a depth-averaged *** of the slides from steep slopes to moderate bases are *** different combinations of soil and basal parameters are assumed to trigger runout mechanisms of elongation,block sliding and *** runout distances predicted by the MPM match well with those from large deformation finite element analysis for the elongation and block sliding *** and grabens are shaped in a spreading ***,the current MPM simulations for materials with high sensitivities are relatively mesh sensitive.

关键词： Submarine landslide runout morphology material point method large deformation

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Coordination-driven self-assembly of metallo-nanodrugs for local inflammation alleviation

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Nano Research 2023年第12期16卷 13259-13266页

作者： Lijuan Tang Zhenghan Di Jingfang Zhang Feiying Yin Lele Li Li Zheng guangxi key laboratory of Regenerative Medicine Guangxi Engineering Center in Biomedical Material for Tissue and Organ RegenerationCollaborative Innovation Centre of Regenerative Medicine and Medical BioResource Development nd Application Co-Constructed by the Province and MinistryThe First Affiliated Hospital of Guangxi Medical UniversityNanning 530021China Pharmaceutical College Guangxi Medical UniversityNanning 530021China CAS key laboratory for Biomedical Effects of Nanomaterials and Nanosafety National Center for Nanoscience and TechnologyBeijing 100190China

Developing dedicated nanomedicines to improve delivery efficacy of anti-inflammatory drugs is still a formidable *** this study,we present an extremely simple yet efficient approach to obtain hybrid nanodrugs through metal-drug coordination-driven self-assembly for carrier-free drug *** resulting metallo-nanodrugs exhibit well-defined morphology and high drug encapsulation capability,allowing for the combination of magnetic resonance imaging and anti-inflammatory *** the case of osteoarthritis(OA),the metallo-nanodrugs remarkably alleviate synovial inflammation,preventing cartilage destruction and extracellular matrix *** addition,it led to significantly improved therapeutic efficacy compared with intra-articular administration of the same dose of free drugs in OA mouse *** work provides a very simple approach for the development of anti-inflammatory nanoformulations by exploiting coordination-driven self-assembly.

关键词： drug delivery coordination-driven assembly nanomedicine anti-inflammation therapy

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