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Progress in the application of graphene material in oilfield chemistry:A review

Petroleum 2024年第2期10卷 175-190页

作者： Jinsheng Sun Yuanwei Sun Yong Lai Li Li Gang Yang Kaihe Lv Taifeng Zhang Xianfa Zhang Zonglun Wang Zhe Xu Zhiwen Dai Jingping Liu School of Petroleum Engineering China University of Petroleum(East China)Qingdao266580China CNPC Engineering Technology R&D company limited Changping10206China Nanchong Vocational and Technical College Nanchong637131China Oil&gas Technology Research Institute of Changqing Oilfield company Xi'an710000China CNPC Greatwall Drilling Fluids company Panjin124000China

Graphene is a single atom thick crystal composed of carbon *** is the lightest,thinnest,strongest material that conducts heat and electricity well *** terms of application,by introducing oxygen-containing groups,graphene can be well dispersed in solvents,can be chemically modified and functionalized,or connected with other electroactive substances through covalent bond or non-covalent bond to form composite materials,which is conducive to further processing and *** application of graphene in oilfield chemistry started late,but developed *** has played an active role in drilling fluid,cementing fluid,fracturing fluid,displacement fluid and other oilfield working *** can enhance the temperature and salt resistance of working fluid and improve the effect of working *** this paper,several directions of graphene applications in oilfield chemistry,such as modified graphene,graphene copolymers and graphene nanoparticles,are reviewed in detail from the synthesis methods,action mechanisms and effects of graphene and its derivatives,and the frontier cases at this stage are *** the basis of the existing research,suggestions for the development direction of graphene materials in oilfield chemistry are given for a variety of graphene materials,aiming to provide guidance for the application of graphene in oilfield chemistry.

关键词： Oilfield chemistry Graphene Action mechanism Application Prospect

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Fracture geometry and breakdown pressure of radial borehole fracturing in multiple layers

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Petroleum Science 2024年第1期21卷 430-444页

作者： Yu-Ning Yong Zhao-Quan Guo Shou-Ceng Tian Lu-Yao Ma Tian-Yu Wang Mao Sheng National Key Laboratory of Petroleum Resources and Engineering China University of Petroleum(Beijing)Beijing102249China Beijing Petroleum Machinery company limited CNPC Engineering Technology R&D Company LimitedBeijing102206China Smart Energy Co. LtdChina Xiongan GroupXiong’an New Area071000HebeiChina

Radial borehole fracturing that combines radial boreholes with hydraulic fracturing is anticipated to improve the output of tight oil and gas *** paper aims to investigate fracture propagation and pressure characteristics of radial borehole fracturing in multiple layers.A series of laboratory experiments with artificial rock samples(395 mm×395 mm×395 mm)was conducted using a true triaxial fracturing *** crucial factors corresponding to the vertical distance of adjacent radial borehole layers(vertical distance),the azimuth and diameter of the radial borehole are *** results show that radial borehole fracturing in multiple layers generates diverse fracture *** types of fractures are identified based on the connectivity between hydraulic fractures and radial *** vertical distance significantly influences fracture propagation perpendicular to the radial borehole *** increase in the vertical distance impedes fracture connection across multiple radial borehole layers and reduces the fracture propagation distance along the radial borehole *** azimuth also influences fracture propagation along the radial borehole *** the azimuth reduces the guiding ability of radial boreholes,which makes the fracture quickly curve to the maximum horizontal stress *** breakdown pressure correlates with diverse fracture geometries *** the fractures connect multi-layer radial boreholes,increasing the vertical distance decreases the breakdown *** the azimuth and increasing the diameter also decrease the breakdown *** extrusion force exists between the adjacent fractures generated in radial boreholes in multiple rows,which plays a crucial role in enhancing the guiding ability of radial boreholes and results in higher breakdown *** research provides valuable theoretical insights for the field application of radial borehole fracturing technology in tight oil and g

关键词： Multi-layer radial boreholes Hydraulic fracturing Fracture propagation Pressure characteristic

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Numerical Simulation on Unsteady Flow Mechanism of a 1.5-Stage Axial Transonic compressor

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Journal of Thermal Science 2024年第5期33卷 1851-1866页

作者： PENG Shuxuan ZHANG Xiaoyu WANG Wentao ZHANG Hongwu LI Xinlong High Efficiency and Low Carbon gas Turbine Digitalization Research Centre Nanjing Institute of Future Energy SystemNanjing 211135China Advanced gas Turbine Laboratory Institute of Engineering ThermophysicsChinese Academy of SciencesBeijing 100190China Key Laboratory of Advanced Energy and Power Chinese Academy of SciencesBeijing 100190China Innovation Academy for Light-Duty gas Turbine Chinese Academy of SciencesBeijing 100190China University of Chinese Academy of Sciences Beijing 100049China BYD Auto Industry company limited Shenzhen 518116China

In this paper,a numerical simulation method is used to calculate a 1.5-stage axial transonic compressor to explore its unsteady flow *** performance curve is compared with the experimental data to verify the calculation method with a high numerical accuracy,which shows that the unsteady calculation has good *** to the analysis of the data from the monitoring points under the near-stall condition,the unsteady disturbances originate from the tip region of blade and perform the strongest at the blade pressure surface with a broadband *** analysis is conducted by combining with the characteristics of the transient flow field at the tip of *** results show that the unsteady pressure fluctuations are caused by the migration of the new vortex *** new vortex cores are generated by the breakdown of leakage vortex in the downstream,which is induced by the leakage vortex and shock wave ***,the relationship between the unsteady flow characteristics and the working conditions is also *** leakage vortex intensity and the shock wave strength gradually increase with the decrease of flow *** the combination of the leakage vortex intensity and shock wave strength reaches the first threshold,a single frequency of unsteady disturbances appears at the blade *** the combination of the leakage vortex intensity and shock wave strength reaches the second threshold,the frequency of unsteady disturbances changes to a broadband.

关键词： numerical simulation axial transonic compressor unsteady flow vortex breakdown

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A micro-crosslinked amphoteric hydrophobic association copolymer as high temperature-and salt-resistance fluid loss reducer for water-based drilling fluids

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Petroleum Science 2024年第3期21卷 1980-1991页

作者： Jian Li Yu-Xi Ji Xiao-Xiao Ni Kai-He Lv Xian-Bin Huang Jin-Sheng Sun School of Petroleum Engineering China University of Petroleum(East China)Qingdao266580ShandongChina Key Laboratory of Unconventional Oil&gas Development China University of Petroleum(East China)Qingdao26650ShandongChina Inspection and Testing Center of Huabei Oil Field company PetroChinaRenqiu062552HebeiChina Drilling Fluid Research Institute CNPC Engineering Technology R&D Company LimitedBeijing102206China

During ultradeep oil and gas drilling,fluid loss reducers are highly important for water-based drilling fluids,while preparing high temperature-and salt-resistance fluid loss reducers with excellent rheology and filtration performance remains a ***,a micro-crosslinked amphoteric hydrophobic association copolymer(i.e.,DADC)was synthesized using N,N-dimethyl acrylamide,diallyl dimethyl ammonium chloride,2-acrylamido-2-methylpropane sulfonic acid,hydrophobic monomer,and pentaerythritol triallyl ether *** to the synergistic effects of hydrogen bonds,electrostatic interaction,hydrophobic association,and micro-crosslinking,the DADC copolymer exhibited outstanding temperature-and *** rheological experiments have shown that the DADC copolymer had excellent shear dilution performance and a certain degree of salt-responsive viscosity-increasing *** DADC copolymer could effectively adsorb on the surface of bentonite particles through electrostatic interaction and hydrogen bonds,which bring more negative charge to the bentonite,thus improving the hydration and dispersion of bentonite particles as well as the colloidal stability of the drilling ***,the drilling fluids constructed based on the DADC copolymer exhibited satisfactory rheological and filtration properties(FLHTHP=12 m L)after aging at high temperatures(up to200℃)and high salinity(saturated salt)***,this work provided new insights into designing and fabricating high-performance drilling fluid treatment agents,demonstrating good potential applications in deep and ultradeep drilling engineering.

关键词： Fluid loss reducer Temperature-and salt-resistance Hydrophobic association Amphoteric Micro-crosslinking

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Evaluation of the Shallow gas Hydrate Production Based on the Radial Drilling-Heat Injection-Back Fill Method

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Journal of Ocean University of China 2024年第1期23卷 119-128页

作者： CHEN Qiang WAN Yizhao WU Nengyou SUN Jianye WANG Jian LIU Changling LI Yanlong LI Chengfeng HU Gaowei Key Laboratory of gas Hydrate Ministry of Natural ResourcesQingdao 266071China Laboratory for Marine Mineral Resources Laoshan LaboratoryQingdao 266071China CNPC Offshore Engineering company limited Beijing 100028China Technology Innovation Center for Marine Methane Monitoring Ministry of Natural ResourcesQingdao 266071China

It has been evidenced that shallow gas hydrate resources are abundant in deep oceans *** geological back-ground,occurrence,and other characteristics differ significantly from deep-seated *** of the high risk of well construction and low production efficiency,they are difficult to be recovered by using conventional oil production *** a result,this paper proposes an alternative design based on a combination of radial drilling,heat injection,and backfilling ***-branch holes are used to penetrate shallow gas hydrate reservoirs to expand the depressurization area,and heat injection is utilized as a supplement to improve gas *** information collected from an investigation site close to the offshore production well in the South China Sea is used to assess the essential components of this plan,including well construction stability and gas production *** demonstrates that the hydraulic fracturing of the 60mbsf overburden layer can be prevented by regulating the drilling fluid ***,the traditional well structure is unstable,and the suction anchor is advised for better mechanical *** gas produc-tion rate can be significantly increased by combining hot water injection and depressurization ***,the suitable produc-tion equipment already in use is discussed.

关键词： shallow gas hydrate trail production radial drilling-heat injection-back fill method experimental and numerical simulation

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Excess pore pressure behavior and evolution in deep coalbed methane reservoirs

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International Journal of Mining Science and Technology 2024年第6期34卷 763-781页

作者： Changqing Liu Zhaobiao Yang Yong Qin Xia Yan Yunhai Wang Zhe Wang Key Laboratory of Coalbed Methane Resources and Reservoir Formation Process Ministry of EducationChina University of Mining and TechnologyXuzhou 221008China School of Resources and Geosciences China University of Mining and TechnologyXuzhou 221116China National Engineering Research Center of Coalbed Methane Development&Utilization Beijing 100095China PetroChina Coalbed Methane company limited Beijing 102200China SINOPEC East China Oil and gas company Nanjing 210000China

Deep coalbed methane(DCBM),an unconventional gas reservoir,has undergone significant advancements in recent years,sparking a growing interest in assessing pore pressure dynamics within these *** some production data analysis techniques have been adapted from conventional oil and gas wells,there remains a gap in the understanding of pore pressure generation and evolution,particularly in wells subjected to large-scale hydraulic *** address this gap,a novel technique called excess pore pressure analysis(EPPA)has been introduced to the coal seam gas industry for the first time to our knowledge,which employs dual-phase flow principles based on consolidation *** technique focuses on the generation and dissipation for excess pore-water pressure(EPWP)and excess pore-gas pressure(EPGP)in stimulated deep coal *** have been developed respectively and numerical solutions have been provided using the finite element method(FEM).Application of this model to a representative field example reveals that excess pore pressure arises from rapid loading,with overburden weight transferred under undrained condition due to intense hydraulic fracturing,which significantly redistributes the weight-bearing role from the solid coal structure to the injected fluid and liberated gas within artificial pores over a brief ***,field application indicates that the dissipation of EPWP and EPGP can be actually considered as the process of well production,where methane and water are extracted from deep coalbed methane wells,leading to consolidation for the artificial ***,history matching results demonstrate that the excess-pressure model established in this study provides a better explanation for the declining trends observed in both gas and water production curves,compared to conventional practices in coalbed methane reservoir engineering and petroleum *** research not only enhances the understanding of DCBM re

关键词： Deep coalbed methane Consolidation Excess pore-water pressure Excess pore-gas pressure Production data analysis

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Tracing Sources of Geochemical Anomalies in a Deeply Buried Volcanic-Related Hydrothermal Uranium Deposit:the Daguanchang Deposit,Northern Hebei Province,North China Craton

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Journal of Earth Science 2024年第4期35卷 1186-1195页

作者： Yangyang Zhang Yuelong Chen Dapeng Li Huan Kang Mingliang Fang Yunliang Xu School of Earth Science and Resources China University of GeosciencesBeijing100083China State Key Laboratory of Earthquake Dynamics Institute of GeologyChina Earthquake AdministrationBeijing100083China Jinchuan Group company limited Jinchang737104China China-Explo Tian Cheng(Beijing)Technology company limited Beijing100093China

Radon(Rn)and helium(He)gases from uranium decay form distinct anomalies related to buried uranium *** order to trace the geochemical anomalous sources from the volcanic-related uranium deposits in deeply buried areas,systematical Rn contents and He isotope ratios were analyzed from the Daguanchang uranium *** soil gas Rn concentrations above the deep uranium are ten times higher than those in barren areas,indicating that instantaneous Rn content measurements can be used to detect deeply buried *** helium isotope ratios(^(3)He/^(4)He)of the unmineralized samples from the mineralized drill hole(ZK1)are relatively lower and uniform compared to those of the samples from no-mineral drill hole(ZK2).However,the Th and U contents of the drill core samples from ZK1 are slightly lower than those of the samples from ZK2,indicating that the lower 3He/4He ratios in ZK1 are most likely due to the addition of 4He from underlying uranium *** differences in the instantaneous Rn contents are consistent with the variations in the He isotope ratios of the drill core *** results demonstrate that soil gas Rn and ^(3)He/^(4)He ratios are useful tracers and can indicate the existence of deeply buried volcanic-related hydrothermal uranium ores.

关键词： tracers radon helium ^(3)He/^(4)He ratio uranium deposits Daguanchang deposit

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Investigation of pore structure alteration and permeability enhancement of shale matrix by supercritical water treatment after hydraulic fracturing

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Petroleum 2024年第2期10卷 265-274页

作者： Yili Kang Peisong Li Wangkun Cao Mingjun Chen Lijun You Jiang Liu Zhehan Lai State Key Laboratory of Oil and gas Reservoir Geology and Exploitation Southwest Petroleum UniversityChengdu610500China Institute of Engineering Technology Petro China Coalbed Methane Company LimitedXi'an710082China Chemical and Petroleum Engineering University of CalgaryCalgaryT2N 1N4Canada

Shale gas reservoirs are unconventional tight gas reservoirs,in which horizontal wells and hydraulic fracturing are required to achieve commercial *** fracture networks created by hydraulic fracturing can increase the drainage area extensively to enhance shale gas ***,large volumes of fracturing fluid that is difficult to flow back to the surface and remained in the shale formation,will inevitably lead to damages of the shale formations and limit the effectiveness of *** water(SCW)treatment after hydraulic fracturing is a new method to enhance shale gas recovery by using appropriate heat treatment methods to the specific formation to convert the retained fracturing fluid into a supercritical state(at temperatures in excess of 373.946°C and pressures in excess of 22.064 MPa).An experiment was conducted to simulate the reaction between shale and SCW,and the capacity of SCW treatment to enhance the permeability of the shale was evaluated by measuring the response of the shale porosity and permeability on SCW *** experimental results show that the shale porosity and permeability increase by 213.43%and 2198.37%,*** pore structure alteration and permeability enhancement of the shale matrix were determined by analyzing the changes in pore structure and mineral composition after SCW *** mechanisms that affect pore structure and mineral composition include oxidative catalysis decomposition of organic matters and reducing minerals,acid-catalyzed decomposition of carbonate minerals and feldspar minerals,hydrothermal catalysis induced fracture extension and cementation weakening induced fracture *** treatment converts harm into a benefit by reducing the intrusion of harmful substances into the shale formation,which will broaden the scope and scale of shale formation stimulation.

关键词： Shale gas Formation damage control Formation heat treatment Supercritical water

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Analysis of mechanical strengths of extreme line casing joint considering geometric, material, and contact nonlinearities

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Petroleum Science 2024年第3期21卷 1992-2004页

作者： Ji-Yun Zhang Chi Peng Jian-Hong Fu Quan Cao Yu Su Jian-Yun Pang Zi-Qiang Yu Petroleum Engineering School Southwest Petroleum UniversityChengdu610500SichuanChina Engineering Technology Research Institute of CNPC Southwest Oil and gas Field company Chengdu610017SichuanChina

To address the challenges associated with difficult casing running,limited annular space,and poor cementing quality in the completion of ultra-deep wells,the extreme line casing offers an effective solution over conventional ***,due to its smaller size,the joint strength of extreme line casing is reduced,which may cause failure when running in the *** address this issue,this study focuses on the CST-ZTΦ139.7 mm×7.72 mm extreme line casing and employs the elastic-plastic mechanics to establish a comprehensive analysis of the casing joint,taking into account the influence of geometric and material nonlinearities.A finite element model is developed to analyze the forces and deformations of the extreme line casing joint under axial tension and external collapse *** model investigates the stress distribution of each thread tooth subjected to various tensile forces and external ***,the tensile strength and crushing strength of the extreme line casing joint are determined through both analytical and experimental *** findings reveal that,under axial tensile load,the bearing surface of each thread tooth experiences uneven stress,with relatively high equivalent stress at the root of each thread *** end thread teeth are valuable spots for *** is observed that the critical fracture axial load of thread decreases linearly with the increase of thread tooth *** external pressure,the circumferential stress is highest at the small end of the external thread,leading to yield *** tensile strength of the joint obtained from the finite element model exhibits a relative error of less than 7%compared to the analytical and experimental values,proving the reliability of the finite element *** tensile strength of the joint is 3091.9 k ***,in terms of anti-collapse capability,the joints demonstrate higher resistance to collapse compared to the casing body,which is consistent with the test resul

关键词： Extreme line casing Elastic-plastic mechanics Finite element analysis Tensile strength Collapse strength

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Implications for fault reactivation and seismicity induced by hydraulic fracturing

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Petroleum Science 2024年第2期21卷 1081-1098页

作者： Zi-Han Sun Ming-Guang Che Li-Hong Zhu Shu-Juan Zhang Ji-Yuan Lu Chang-Yu Jin Key Laboratory of Ministry of Education on Safe Mining of Deep Metal Mines School of Resources and Civil Engineering and Key Laboratory of Liaoning Province on Deep Engineering and Intelligent TechnologyNortheastern UniversityShenyang110819LiaoningChina Research Institute of Petroleum Exploration&Development PetroChina Company LimitedBeijing100084China The Exploration and Development Research Institute of Daqing Oilfield limited company Daqing163458HeilongjiangChina

Evaluating the physical mechanisms that link hydraulic fracturing(HF) operations to induced earthquakes and the anticipated form of the resulting events is significant in informing subsurface fluid injection operations. Current understanding supports the overriding role of the effective stress magnitude in triggering earthquakes, while the impact of change rate of effective stress has not been systematically addressed. In this work, a modified critical stiffness was brought up to investigate the likelihood, impact,and mitigation of induced seismicity during and after hydraulic fracturing by developing a poroelastic model based on rate-and-state fraction law and linear stability analysis. In the new criterion, the change rate of effective stress was considered a key variable to explore the evolution of this criterion and hence the likelihood of instability slip of fault. A coupled fluid flow-deformation model was used to represent the entire hydraulic fracturing process in COMSOL Multiphysics. The possibility of triggering an earthquake throughout the entire hydraulic fracturing process, from fracturing to cessation, was investigated considering different fault locations, orientations, and positions along the fault. The competition between the effects of the magnitude and change rate of effective stress was notable at each fracturing stage. The effective stress magnitude is a significant controlling factor during fracturing events, with the change rate dominating when fracturing is suddenly started or stopped. Instability dominates when the magnitude of the effective stress increases(constant injection at each fracturing stage) and the change rate of effective stress decreases(the injection process is suddenly stopped). Fracturing with a high injection rate, a fault adjacent to the hydraulic fracturing location and the position of the junction between the reservoir and fault are important to reduce the Coulomb failure stress(CFS) and enhance the critical stiffness as

关键词： Hydraulic fracturing Coulomb failure stress Rate-and-state fraction model Linear stability analysis Critical stiffness Seismically induced fault

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