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Cotton pads-derived carbon materials/reduced graphene oxide modified with polypyrrole for electrode of supercapacitors

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Journal of Energy Chemistry 2024年第7期94卷 41-53页

作者： Ofelia MArias-Pinedo Elvis OLopez Ivonne EMonje RSoria-Martinez Antony Bazan-Aguilar Clemente Alfredo Luyo Caycho Gabriel Angel Planes Angelica Maria Baena-Moncada Laboratorio de Investigacion de Electroquimica Aplicada Facultad de Ciencias de la Universidad Nacional de IngenieriaAv.Tupac Amaru 210RimacLimaPeru department of Experimental Low Energy Physics Brazilian Center for Research in Physics(CBPF)Rio de Janeiro22290-180Brazi Universidad Tecnologica del Peri Av.Arequipa 26515046 LimaPeru Centeror theevelopmentof Adanced Materials and Nanotechlogy Universidad NacionaldeIngeneria33LimaP departamento de Quimica Universidad Nacional de Rio CuartoInstituto de Investigaciones en Tecnologias Energeticas y Materiales Avanzados(IITEMA)Ruta Nac.36Km 601(X5804BYA)RioCuartoCordobaArgentina

This study investigates the influence of electropolymerization conditions on the deposition of polypyrrole(PPy)onto cotton-derived carbon fiber(CF)modified with reduced graphene oxide(rGO)for supercapacitors applications using an experimental/theorical *** surface modification of CF by rGO and/or by PPy electrodeposited at 10,25 and 50 mV s^(-1) was thoroughly examined physicochemical and *** electrodes comprising CF-rGo-PPy,synthesized via electropolymerization at 25 mV s^(-1),demonstrated a remarkable increase in capacitance,showcasing~742 F g^(-1) compared to 153 F g^(-1) for ***,N_(2)-surface area,XPS,and TD-DFT approach revealed that the higher capacitance observed in CF-rGo-PPy electrodes underscores the influence of morphology and charged nitrogen species on the electrochemical performance of these modified ***,this electrode material achieves a specific capacitance retention of~96%of their initial capacitance after 10000 cycles at 0.5 A g^(-1) measured in a two-electrodes cell *** work also discusses the influence of the scan rate used for pyrrole electropolymerization on the pseudocapacitance contribution of PPy and its possible effect on the porosity of the *** results highlight the importance of appropriate electropolymerization conditions that allow obtaining the synergistic effect between CF,rGO and PPy.

关键词： Supercapacitors Cotton pads-derived carbon fibers rGO PPy TD-DFT

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Correction to:Preface:Special Issue on Modeling,Simulation,and Optimization in Operational Research

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Journal of the Operations Research Society of China 2024年第2期12卷 548-548页

作者： Gerhard-Wilhelm Weber J.Joshua Thomas Jose Antonio Marmolejo Saucedo Ugo Fiore Igor Litvinchev Pandian Vasant Poznan University of Technology PoznanPoland Institute of Applied Mathematics Middle East Technical UniversityAnkaraTurkey UOW Malaysia KDU Penang University CollegePetaling JayaMalaysia facultad de ingenieria Universidad PanamericanaMexico CityMexico Parthenope University and at Federico II University NaplesItaly Nuevo Leon State University San Nicolas de los GarzaMexico MERLIN Research Centre Ton Duc Thang UniversityHo Chi Minh CityVietnam

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Green Method, Optical and Structural Characterization of ZnO Nanoparticles Synthesized Using Leaves Extract of M. oleifera

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Journal of Renewable Materials 2022年第3期10卷 833-847页

作者： Jose Vulfrano Gonzalez-Fernandez Diego David Pinzon-Moreno Antony Alexander Neciosup-Puican Maria Veronica Carranza-Oropeza facultad de Quimica e ingenieria Quimica Universidad Nacional Mayor de San MarcosLima15081Peru Centro de Investigaciones Tecnologicas Biomedicas y MedioambientalesUniversidad Nacional Mayor de San MarcosLima15081Peru

ZnO nanoparticles(ZnO-NP)present innovative optical,electrical,and magnetic properties that depend on spe-cific characteristics,e.g.,size,distribution,and ***,these properties are essential to address various applications in areas such as electronics,medicine,energy,and *** addition,the performance of this ZnO-NP depends of their preparation which can be done by chemical,physical,and biological ***,nowadays,the main interest in developing ZnO-NP synthesis through biological methods bases on the decrease of use of toxic chemicals or energy applied to the procedures,making the process more cost-effective and environ-mentally ***,the large-scale production of nanoparticles by green synthesis remains a big challenge due to the complexity of the biological extracts used in chemical *** being the case,the preparation of ZnO-NP using Moringa oleifera extract as an alternative biological agent for capping and reduction in synthesis was evaluated in this ***,the results based on the analysis of the optical and structural characterization of the ZnO-NP obtained by employing UV-Vis,DLS,zeta potential,XRD,ATR-FTIR,and FE-SEM indicate mostly the presence of spherical nanosized material with a mean hydrodynamic diameter of 47.2 nm measured by DLS and a mean size diameter of 25 nm observed with FE-SEM ***,in FE-SEM images a homo-geneous dispersion and distribution is observed in the absence of agglutination,agglomeration,or generation of significant lumps of the *** XRD analysis showed that heat annealing induced the crystallite size favor-ing their *** obtained data confirm the synthesis of ZnO-NP and the absence of impurities associated with organic compounds in the annealed ***,those results and low-cost production pre-sent to the synthesized ZnO-NP by this biological method as a useful material in several applications.

关键词： ZnO nanoparticles green chemistry Moringa oleifera extract optical characterization structural characterization

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Fine‑tuning genomic and pedigree inbreeding rates in equine population with a deep and reliable stud book:the case of the Pura Raza Española horse

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Journal of Animal Science and Biotechnology 2023年第2期14卷 515-528页

作者： Davinia Isabel Perdomo‑Gonzalez Nora Laseca Sebastian demyda‑Peyras Mercedes Valera Isabel Cervantes Antonio Molina departamento Agronomia Escuela Tecnica Superior de Ingenieria AgromomicaUniversidad de SevillaCtra Utrera Km 141013 SevillaSpain departamento de Genetica Universidad de CordobaCordobaSpain facultad de Ciencias Veterinarias Universidad Nacional de La PlataLa PlataArgentina Consejo Nacional de Investigaciones Cientificas y Tecnicas(CONICET) La PlataArgentina departamento de Produccion Animal Facultad de VeterinariaUniversidad Complutense de MadridMadridSpain.

Background:Estimating inbreeding,which is omnipresent and inevitable in livestock populations,is a primary goal for management and animal breeding especially for those interested in mitigating the negative consequences of *** coefficients have been historically estimated by using pedigree information;however,over the last decade,genome-base inbreeding coefficients have come to the forefront in this *** Pura Raza Espanola(PRE)horse is an autochthonous Spanish horse breed which has been recognised since *** total PRE population(344,718 horses)was used to estimate Classical(F),Ballou’s ancestral,Kalinowski’s ancestral,Kalinowski’s new and the ancestral history coefficient *** addition,genotypic data from a selected population of 805 PRE individuals was used to determine the individual inbreeding coefficient using SNP-by-SNP-based techniques(methods of moments-FHOM-,the diagonal elements of the genomic-FG-,and hybrid matrixes-FH-)and ROH measures(FRZ).The analyse of both pedigree and genomic based inbreeding coefficients in a large and robust population such as the PRE horse,with proven parenteral information for the last 40 years and a high degree of completeness(over 90%for the last 70 years)will allow us to understand PRE genetic variability better and the correlations between the estimations will give the data greater ***:The mean values of the pedigree-based inbreeding coefficients ranged from 0.01(F for the last 3 generations-F3-)to 0.44(ancestral history coefficient)and the mean values of genomic-based inbreeding coefficients varied from 0.05(FRZ for three generations,FH and FHOM)to 0.11(FRZ for nine generations).Significant correlations were also found between pedigree and genomic inbreeding values,which ranged between 0.58(F3 with FHOM)and 0.79(F with FRZ).In addition,the correlations between FRZ estimated for the last 20 generations and the pedigree-based inbreeding highlight the fact that fewer generations of

关键词： Genomic inbreeding Horses Pedigree inbreeding

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Photolysis of a mixture of anthracene and benzo[a] pyrene at ultra-trace levels in natural water with disinfection purposes

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Journal of Environmental Sciences 2020年第6期32卷 79-94页

作者： Ainhoa Rubio-Clemente Edwin Chica Gustavo A.Penuela facultad de Ciencias de La Salud.Universidad Catolica de Murcia(UCAM) Murcia 30107Spain Grupo GDCON Facultad de IngenieriaSede de Investigaciones Universitarias(SIU)Universidad de Antioquia(UdeA)Medellín 050010Colombia facultad de ingenieria Tecnologico de Antioquia-Institucion Universitaria(TdeA)Medellín 050034Colombia departamento de ingenieria Mecanica Facultad de IngenieriaUniversidad de Antioquia(UdeA)Medellín 050010Colombia

The photodegradation of anthracene(AN)and benzo[a]pyrene(BaP),two priority polycyclic aromatic hydrocarbons(PAHs),was examined at ultra-trace levels in surface water to elucidate their behaviour under several irradiance values and types of *** emitting flux and the spectrum of the lamps were found to develop a crucial role in AN and BaP degradation since removal efficiencies of the target contaminants higher than 99%were found after 15 min of irradiation under an ultraviolet C(UVC)irradiance of 0.63 mW/cm^2,corresponding to a fluence of 560.25 mJ/cm^*** the other hand,although ultraviolet A(UVA)lamps exhibited a higher irradiance compared to that of UVC lamps,they were not efficient for degrading the target *** removal kinetic studies corroborated these findings,being the AN elimination rate in surface water higher than that in deionized water at optimal operating *** potential was also measured.A rapid microbial load inactivation,in terms of total coliforms naturally contained in the water matrix studied,was evidenced within 15 min of treatment for the fluence ***,after 24 hr in the dark,a regrowth was ***,photolysis products more toxic than the parent compounds were found,which were not removed even by extending the treatment *** this regard,it can be concluded that the individual action of UVC light for removing AN and BaP with disinfection purposes is not an efficient treatment;therefore,the use of radiation in combination with other kinds of treatments is required.

关键词： Polycyclic aromatic hydrocarbon Photolysis Matrix constituent Intermediate product Disinfection Regrowth

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Insecticidal Effect of Green Bimetallic Nanoparticles from Crotalaria longirostrata on Cotton Mealybug,Phenacoccus solenopsis

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Journal of Renewable Materials 2022年第10期10卷 2543-2552页

作者： Vianey Mendez-Trujillo Benjamín Valdez-Salas Mario Curiel-Alvarez Ernesto Beltran-Partida Arnoldo Alfaro-Corres EsaúRuiz-Sanchez Gerardo Bautista-Trujillo Olivia Tzintzun Camacho Onecimo Grimaldo-Juarez Carlos Ceceña-Duran Carlos Ail-Catzin Daniel González-Mendoza facultad de Medicina de la Universidad Autónoma de Baja California Dr.Humberto Torres Sanginés S/NCentro CívicoMexicaliBaja CaliforniaMéxico instituto de Ingeniería de la Universidad Autónoma de Baja California Calle de la Normal S/N y Boulevard Benito JuárezMexicaliBaja CaliforniaMéxico instituto Tecnológico de Conkal División de Estudios de Posgrado e InvestigaciónAntigua Carretera Mérida-MotulConkalYucatánMéxico facultad de Medicina Veterinaria y Zootecnia de la Universidad Autónoma de Chiapas ChiapasMéxico Universidad Autónoma de Baja California Instituto de Ciencias AgrícolasBaja CaliforniaMéxico

The present study was conducted to evaluate the impact of bimetallic nanoparticles(NPs)of copper(Cu)and zinc(Zn)from Crotalaria longirostrata on the insect mortality and cell viability of Phenacoccus *** biosynthesis of bimetallic nanoparticles(Cu/Zn-NPs)from *** was confirmed by the presence of a single peak around 378 *** hydrodynamic diameter of the Cu/Zn nanoparticles varied from 59 to 119 nm and their zeta potential was found to be−30.90 *** EDX analysis showed a strong signal for Cu and Zn(8 and 8.6 keV,respectively).The Cu/Zn-NPs showed an effective insecticide activity against *** with 63%of insect mortality after 96 h ***,further studies about nanotoxicity of Cu/Zn-NPs from *** are needed to reveal the exact mechanism of nanoparticles toxicity in insects.

关键词： Phytonanoparticles chipilin biocontrol agronanotechnology

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Solid-state synthesis of LnOCl/Ln_2O_3(Ln=Eu, Nd) by using chitosan and PS-co-P4VP as polymeric supports

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Journal of Rare Earths 2018年第12期36卷 1326-1332页

作者： C.Diaz D.Carrillo R.de la Campa A.Presa Soto M.L.Valenzuela departamento de Quimica Facultad de Quimica Universidad de Chile departamento de Quimica Organica e Inorganica (IUQOEM) Facultad de Quimica Universidad de Oviedo Universidad Autonoma de Chile Facultad de Ingenieria Instituto de Ciendas Quimicas Aplicadas Inorganic Chemistry and Molecular Material Center

A series of lanthanide materials of type LnOCl or Ln2O3(Ln = Eu, Nd) were successfully prepared via a convenient and straightforward two-step procedure. Firstly, and by using chitosan and PS-co-P4 VP as polymeric supports, macromolecular complexes of type chitosan ·LnCl3and PS-co-P4 VP·LnCl3 were prepared. These macro molecular complexes were treated in solid state at 800 ℃ under air, leading to the corresponding LnOCl or Ln2O3materials(Ln = Eu, Nd) with moderate to good yields. The nature of the asprepared lanthanide materials(LnOCl and/or Ln2O3) is strongly influenced by the polymeric template(i.e.,chitosan or PS-co-P4 VP), the lanthanide salt precursor, and the polymer/lanthanide molar ratio. Thus, when chitosan · EuCl3and PS-co-P4 VP·EuCl3are used as macromolecular precursors, a mixture of crystalline phases of both EuOCl and Eu2O3are obtained. However, when chitosan· NdCl3and PS-co-P4 VP· NdCl3are used, a sole pure crystalline phase of NdOCl is obtained. The nano structured lanthanide materials were characterized by means of XRD(X-ray diffraction of powder), SEM, EDS, TEM, and HRTEM. The luminescent spectra of the asprepared EuOCI/Eu2O3mixture materials show an emission pattern whose intensity is strongly influenced by the nature of the polymeric precursor, as well as on the metal/polymer molar ratios.

关键词： EuOCl/Eu_2O_3 NdOCl Solventless method Luminescence Lanthanides Rare earths

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SYNTHESIS AND PROPERTIES OF HOMOPOLYMER AND COPOLYMERS OBTAINED FROM 1-OCTAdeCENE WITH ZIRCONOCENE CATALYSTS

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Chinese Journal of Polymer Science 2000年第3期18卷 249-254页

作者： RaulQuijada JuanL.Guevara ReneRojas FrancoM.Rabagliati departamento de ingenieria Quimica Facultad de Ciencias Fisicasy Matematicas Universidad de Chile Casilla 2777 Santiago ChileDepartamento de Ingenieria Quimica Facultad de Ciencias Fisicasy Matematicas Universidad de Chile Casilla 2777 Santiago ChileDepartamento de Ingenieria Quimica Facultad de Ciencias Fisicasy Matematicas Universidad de Chile Casilla 2777 Santiago ChileDepartamento Ciencias Quimicas Facultad Quimicay Biologia Universidad de Santiago de Chile Casilla 40 Santiago Chile

Studies related to the behavior of different metallocene catalysts for the homopolymerization of 1-octadecene andits copolymerization with ethylene will be presented. The metallocenes: rac-Et(Ind)_2ZrCl_2, rac-Me_2Si(Ind)_2ZrCl_2 andPh_2C(Flu)(Cp)ZrCl_2 were chosen for the homopolymerization study. They show important differences in catalytic activity athigh temperatures (≥70℃), with rac-Et(Ind)_2ZrCl_2 showing the highest activity. At lower temperatures (≤30℃) thedifferences are negligible. For the copolymerization of ethylene with 1-octadecene only the catalysts rac-Et(Ind)_2ZrCl_2 andrac-Me_2Si(Ind)_2ZrCl_2 were studied. The results show that their catalytic activity is just like that for the homopolymerizationof 1-octadecene, with higher activity for the metallocene with the Et-bridged catalyst. ^(13)C-NMR analysis shows that thecomposition of the copolymerization products depends on the catalytic systems. Copolymers obtained with rac-Me_2Si(Ind)_2ZrCl_2 have greater comonomer incorporation. Thermal analysis shows that poly-1-octadecene synthesized withthe catalyst rac-Et(Ind)_2ZrCl_2 is very dependent on the polymerization temperature. The homopolymer obtained at 70℃presents two endothermal peaks at 41℃ and 53℃, as compared with the one obtained at 30℃ which presents one wider peakwith a maximum at 67℃. For the catalyst rac-Me_2Si(Ind)_2ZrCl_2 this trend is not observed. The type of metallocene and thereaction time do not significantly change the intrinsic viscosity, but the polymerization temperature changes it drastically,giving higher values at lower temperature. Viscosity measurements on the copolymers show that an increase of comonomerconcentration in the feed reduces the molecular weight of the copolymer, and it was also found that for homopolymer, themolecular weight is independent of the catalytic systems.

关键词： Homopolymerization Copolymerization Metallocene Catalytic activity Poly-l-octadecene

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Modeling egg development of the pest Clavipalpus ursinus （Coleoptera： Melolonthidae） using a temperature-dependent approach

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Insect Science 2012年第6期19卷 657-665页

作者： Andrea Escobar Rodrigo Gil Carlos Ricardo Bojaca Jaime Jimenez facultad de Ciencias Naturales e ingenieria departamento de Ciencias Basicas Universidad de Bogota Jorge Tadeo Lozano Bogota Direccion Tecnica de Sanidad Vegetal instituto Colombiano Agropecuario Bogota Colombia

Predicting the population dynamics of insects in natural conditions is es- sential for their management or preservation, and temperature-dependent development models contribute to achieving this. In this research the effects of temperature and soil moisture content on egg development and hatching of Clavipalpus ursinus （Blanchard） were evaluated. The eggs were exposed to seven temperature treatments with averages of 7.2, 13.0, 15.5, 19.7, 20.6, 22.0 and 25.3~C, in combination with three soil moisture contents of 40%, 60% and 80%. A linear and two non-linear （Lactin and Briere） models were evaluated in order to determine the thermal requirements of this developmental stage. Temperature affected significantly the time of development and egg hatching, while no significant effect was observed for moisture content. Thermal requirements were set as： 7.2℃ for lower developmental threshold, 20.6℃ for optimum developmental threshold, 25.3℃ for maximum temperature and 344.83 degree-days for the thermal constant. The linear model described satisfactorily egg development at intermediate temperatures; nev- ertheless, a slightly better fit of the observed data was obtained with the Lactin model. Egg development took place inside a narrow range of temperatures. Consequently, an increment of soil temperature could generate a negative impact on the population size of this species or changes in its biological parameters.

关键词： egg development pests soil moisture thermal requirements

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First assessment of Li_(2)O–Bi_（2）O_（3） ceramic oxides for high temperature carbon dioxide capture

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Journal of Energy Chemistry 2016年第5期25卷 754-760页

作者： E.M.Briz-Lopez M.J.Ramirez-Moreno I.C.Romero-Ibarra C.Gomez-Yanez H.Pfeiffer J.Ortiz-Landeros departamento de ingenieria en metalurgia y Materiales Escuela Superior de Ingenieria Quimica e Industrias ExtractivasIPNUPALMAv. Instituto Politecnico Nacional s/n CP 07738 Mexico DF Mexico instituto de Investigaciones en Materiales Universidad Nacional Autonoma de MexicoCircuito exterior s/nCd Universitaria Del. Coyoacan CP 04510Mexico DF Mexico Unidad Profesional Interdisciplinaria en ingenieria y Tecnologias Avanzadas IPNAv. Instituto Politecnico Nacional No. 2580 CP 07340 Mexico DE Mexico

在Li2O–Bi2O3系统中，在几种化学计量组成中测定了捕获Co2的能力。通过固相反应法合成了Li7BiO6、Li5BiO5、Li3BiO4和LiBiO2化合物，并用X射线衍射、扫描电子显微镜和N2吸附技术对其进行了表征。在CO2气氛下，在40至750℃的温度下对样... 详细信息

在Li2O–Bi2O3系统中，在几种化学计量组成中测定了捕获Co2的能力。通过固相反应法合成了Li7BiO6、Li5BiO5、Li3BiO4和LiBiO2化合物，并用X射线衍射、扫描电子显微镜和N2吸附技术对其进行了表征。在CO2气氛下，在40至750℃的温度下对样品进行热处理，以评估碳酸盐的形成，这表明了CO2的捕获能力。此外，Li7BIO6表现出优异的CO2捕获能力，为7。1mmol/G，明显高于已报道的其他陶瓷。Li7BIO6能够在240°C至约660°C的温度下与CO2反应，即使在CO2分压值低至0的情况下也表现出高动力学反应。05.

关键词： CO2捕获 LI7BIO6 铋酸锂热分析

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