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Towards implementation of alloy-specific thermo-fluid modelling for laser powder-bed fusion of Mg alloys

Journal of Magnesium and Alloys 2024年第6期12卷 2327-2344页

作者： Mohammad Hoseini-Athar Mikael Ersson Peter Hedström Department of material Science and Engineering KTH Royal Institute of TechnologyStockholmSE-10044 Sweden

Multi-physics thermo-fluid modeling has been extensively used as an approach to understand melt pool dynamics and defect formation as well as optimizing the process-related parameters of laser powder-bed fusion(L-PBF).However,its capabilities for being implemented as a reliable tool for material design,where minor changes in material-related parameters must be accurately captured,is still in *** the present research,first,a thermo-fluid computational fluid dynamics(CFD)model is developed and validated against experimental *** the predicted material properties of the pure Mg and commercial ZK60 and WE43 Mg alloys,parametric studies are done attempting to elucidate how the difference in some of the material properties,i.e.,saturated vapor pressure,viscosity,and solidification range,can influence the melt pool *** is found that a higher saturated vapor pressure,associated with the ZK60 alloy,leads to a deeper unstable keyhole,increasing the keyhole-induced porosity and evaporation mass *** viscosity and wider solidification range can increase the non-uniformity of temperature and velocity distribution on the keyhole walls,resulting in increased keyhole instability and formation of ***,the WE43 alloy showed the best behavior in terms of defect formation and evaporation mass loss,providing theoretical support to the extensive use of this alloy in *** summary,this study suggests an approach to investigate the effect of materials-related parameters on L-PBF melting and solidification,which can be extremely helpful for future design of new alloys suitable for L-PBF.

关键词： Mg alloys Laser powder-bed fusion(L-PBF) Melt pool dynamics Computational fluid dynamics Fluid flow

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Fabrication of Core-Shell Hydrogel Bead Based on Sodium Alginate and Chitosan for Methylene Blue Adsorption

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Journal of Renewable materials 2024年第4期12卷 815-826页

作者： Xiaoyu Chen School of material Engineering Jinling Institute of TechnologyNanjing211169China

A novel core-shell hydrogel bead was fabricated for effective removal of methylene blue dye from aqueous *** core,made of sodium alginate-g-polyacrylamide and attapulgite nanofibers,was cross-linked by Calcium ions(Ca^(2+)).The shell,composed of a chitosan/activated carbon mixture,was then coated onto the *** transform infrared spectroscopy confirmed the grafting polymerization of acrylamide onto sodium *** electron microscopy images showed the core-shell *** core exhibited a high water uptake ratio,facilitating the diffusion of methylene blue into the *** the diffusion process,the methylene blue was first adsorbed by the shell and then further adsorbed by the *** tests showed that the coreshell structure had a larger adsorption capacity than the core *** shell effectively enhanced the adsorption capacity to methylene blue compared to the single *** blue was adsorbed by activated carbon and chitosan in the shell,and the residual methylene blue diffused into the core and was further adsorbed.

关键词： Core-shell structure hydrogel bead attapulgite nanofiber sodium alginate polyacrylamide methylene blue adsorption material

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Microstructure and Internal Friction Behavior of Laser 3D Printed Fe-Based Amorphous Composites

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Acta Metallurgica Sinica(English Letters) 2024年第1期37卷 196-204页

作者： Shuilong Huang Qingjun Chen Li Ji Kan Wang Guosheng Huang School of material Science and Engineering Nanchang Hangkong UniversityNanchang330063China State Key Laboratory for Marine Corrosion and Protection Luoyang Ship Material Research Institute(LSMRI)Qingdao266237China

Laser 3D printing,also known as laser additive manufacturing(LAM),is favored for its ability to form bulk metallic glass(BMG)and its composite materials(BMGcs)with freeform *** this work,two different kinds of Fe_(41)Co_(7)Cr_(15)Mo_(14)C_(15)B_(6)Y_(2)amorphous coatings(A and B)were prepared by using LAM technology under air-and water-cooled conditions,respectively;meanwhile,to reduce the cracks generated due to the residual thermal stresses,coating C obtained by air-sweep annealing of B with a low energy-density *** morphology and amorphous content and microstructure of the coatings were investigated,the results show many cracks in coating B deposited under water-cooled conditions,and its microstructure shows an amorphous-crystal-nanocrystalline mixed *** was suppressed in coating C,obtained by air-sweep annealing based on coating B,but the amorphous content was reduced from 32.6 to 13.4%.And the hardness and corrosion resistance of the coating will increase with the increase in the amorphous ***,the internal friction behavior of a BMGcs was prepared on the basis of the process of sample C is compared with that of as-cast amorphous *** results show that the low temperature internal friction behavior of BMGcs is affected by the defects produced during printing,and the high temperature internal friction behavior is affected by the precipitated hard phase.

关键词： Laser 3D printing Amorphous coating Microstructure Corrosion resistance Internal friction behavior

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Damping capacity of Fe_(83)Ga_(17) magnetostrictive alloy under magnetic field

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Rare Metals 2024年第1期43卷 402-409页

作者： Shao-Wen Yan Xing Mu Bing-Jie Liu Li-Hong Xu Shi-Hai Guo Yan Qi Hong-Ping Zhang Department of Functional material Research Central Iron and Steel Research InstituteBeijing 100081China

The damping performance of Fe_(83)Ga_(17) alloys has been investigated in the static magnetic field (H). The results demonstrate that the damping peak value can be adjusted between 0.020 and 0.085 under the magnetic f... 详细信息

关键词： alloy magnetic alloys

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Enhanced activity and durability of FeCoCrMoCBY nanoglass in acidic hydrogen evolution reaction

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Journal of materials Science & Technology 2024年第3期170卷 212-220页

作者： Mengyang Yan Shuangqin Chen Shangshu Wu Xuechun Zhou Shu Fu Di Wang Christian Kübel Horst Hahn Si Lan Tao Feng Herbert Gleiter institute of Nanoscience School of Material Science and EngineeringNanjing University of Science and TechnologyNanjing 210094China institute of Nanotechnology Karlsruhe Institute of TechnologyKarlsruhe 76021Germany

In the present work,a multi-element nanoglass(m-NG)of FeCoCrMoCBY is obtained first time by the laser ablation combined with inert gas condensation(laser-IGC)*** with the conventional rapid-quenched metallic glass(MG)with identical composition,the Fe-based m-NG demonstrates a superior performance as a self-supported electrocatalyst for hydrogen evolution reaction(HER)in acidic *** enhanced HER activity of m-NG is proposed to be closely related to its high en-ergy states,which is originated from the unique inhomogeneous nanostructures with a high density of low-coordinated ***,the Fe-based m-NG exhibits an outstanding comprehensive catalytic performance even beyond the commercial Pt/C catalyst in long-term test due to its self-optimization *** work not only opens the way to the preparation of m-NGs by the novel laser-IGC technique,but also makes a great contribution to developing low-cost,high-efficient,and super-durable HER electrocat-alysts in acidic environment.

关键词： Nanoglass Inert gas condensations High energy states Hydrogen evolution reactions

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Enhancing the mechanical properties of casting eutectic high -entropy alloys via W addition

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International Journal of Minerals,Metallurgy and materials 2024年第6期31卷 1364-1372页

作者： Xu Yang Dezhi Chen Li Feng Gang Qin Shiping Wu Ruirun Chen National Key Laboratory for Precision Hot Processing of Metals School of Material Science and EngineeringHarbin Institute of TechnologyHarbin 150001China

The effect of W element on the microstructure evolution and mechanical properties of Al_(1.25)CoCrFeNi3 eutectic high-entropy alloy and Al_(1.25)CoCrFeNi_(3-x)W_(x)(x=0,0.05,0.1,0.3,and 0.5;atomic ratio)high-entropy alloys(HEAs)were *** show that the Al_(1.25)CoCrFeNi_(3-x)W_(x) HEAs are composed of face-centered cubic and body-centered cubic(BCC)*** W content increases,the microstructure changes from eutectic to *** addition of W lowers the nucleation barrier of the BCC phase,decreases the valence electron concentration of the HEAs,and replaces Al in the BCC phase,thus facilitating the nucleation of the BCC *** results show that the addition of W greatly improves the mechanical properties,and solid-solution,heterogeneous-interface,and second-phase strengthening are the main strengthening *** yield strength,tensile strength,and elongation of the Al_(1.25)CoCrFeNi2.95W0.05 HEA are 601.44 MPa,1132.26 MPa,and 15.94%,respectively,realizing a balance between strength and *** fracture mode of the Al_(1.25)CoCrFeNi_(3-x)W_(x) HEAs is ductile–brittle mixed fracture,and the crack propagates and initiates in the BCC *** eutectic lamellar structure impedes crack propagation and maintains plasticity.

关键词： high-entropy alloy microstructure mechanical property fracture behavior

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Surface Deposition of Ni（OH）2 and Lattice Distortion Induce the Electrochromic Performance Decay of NiO Films in Alkaline Electrolyte

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Energy & Environmental materials 2024年第3期7卷 261-271页

作者： Kejun Xu Liuying Wang Chaoqun Ge Long Wang Bin Wang Zhuo Wang Chuanwei Zhang Gu Liu Xi'an Research institute of High Technology School of material Science and Engineering Zhengzhou University School of Mechanical Engineering Xi'an University of Science and Technology

NiO,an anodic electrochromic material,has applications in energy-saving windows,intelligent displays,and military ***,its electrochromic mechanism and reasons for its performance degradation in alkaline aqueous electrolytes are complex and poorly understood,making it challenging to improve NiO thin *** studied the phases and electrochemical characteristics of NiO films in different states （initial,colored,bleached and after 8000 cycles） and identified three main reasons for performance ***,Ni（OH）2is generated during electrochromic cycling and deposited on the NiO film surface,gradually yielding a NiO@Ni（OH）2core-shell structure,isolating the internal NiO film from the electrolyte,and preventing ion ***,the core-shell structure causes the mode of electrical conduction to change from first-to second-rder conduction,reducing the efficiency of ion transfer to the surface Ni（OH）***,Ni（OH）2and NiOOH,which have similar crystal structures but different b-axis lattice parameters,are formed during electrochromic cycling,and large volume changes in the unit cell reduce the structural stability of the thin ***,we clarified the mechanism of electrochromic performance degradation of NiO films in alkaline aqueous electrolytes and provide a route to activation of NiO films,which will promote the development of electrochromic technology.

关键词： alkaline electrolyte electrochromism NiO film performance attenuation mechanism

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Silicon-based optoelectronic heterogeneous integration for optical interconnection

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Chinese Physics B 2024年第2期33卷 1-9页

作者：李乐良李贵柯张钊刘剑吴南健王开友祁楠刘力源 institute of Semiconductors Chinese Academy of SciencesBeijing 100083China Center of material Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China

The performance of optical interconnection has improved dramatically in recent ***-based optoelectronic heterogeneous integration is the key enabler to achieve high performance optical interconnection,which not only provides the optical gain which is absent from native Si substrates and enables complete photonic functionalities on chip,but also improves the system performance through advanced heterogeneous integrated *** paper reviews recent progress of silicon-based optoelectronic heterogeneous integration in high performance optical *** research status,development trend and application of ultra-low loss optical waveguides,high-speed detectors,high-speed modulators,lasers and 2D,2.5D,3D and monolithic integration are focused on.

关键词： silicon-based heterogeneous integration heterogeneous integrated materials heterogeneous integrated packaging optical interconnection

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Effects of in-situZrB_2 nanoparticles and scandium on microstructure and mechanical property of 7N01 aluminum alloy

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Journal of Rare Earths 2024年第3期42卷 612-620,I0007页

作者： Xizhou Kai Yuhui Wang Ruikun Chen Yanjie Peng Anjun Shi Ran Tao Xiangfeng Liang Guirong Li Gang Chen Xiaojing Xu Yutao Zhao School of material Science and Engineering Jiangsu UniversityZhenjiang212013China institute for Advanced Manufacturing and Modern Equipment Technology Jiangsu UniversityZhenjiang212013China

In this study, the in-situ synthesized ZrB_(2) nanoparticles and rare earth Sc were introduced to enhance the strength and ductility of 7N01 aluminum alloy, via the generation of high-melting and uniform nanodispersoids. The microstructure and mechanical property evolution of the prepared composites and the interaction between ZrB_(2) and Sc were studied in detail. The microstructure investigation shows that the introduction of rare earth scandium(Sc) can promote the distribution of ZrB_(2) nanoparticles, by improving their wettability to the Al melt. Meanwhile, the addition of rare earth Sc also modifies the coarse Al Zn Mg Mn Fe precipitated phases, refines the matrix grains and generates high-melting Al_3(Sc,Zr)/Al_3Sc nanodispersoids. Tensile tests of the composites show that with the combinatorial introduction of ZrB_(2) and Sc, the strength and ductility of the composites are improved simultaneously compared with the corresponding 7N01 alloy, ZrB_(2) /7N01 composite and Sc/7N01 alloy. And the optimum contents of ZrB_(2) and Sc are 3 wt% and 0.2 wt% in this study. The yield strength, ultimate strength and elongation of(3 wt% ZrB_(2) +0.2 wt% Sc)/7N01 composite are 477 MPa, 506 MPa and 9.8%, increased about 18.1%, 12.2%and 38% compared to 7N01 alloy. Furthermore, the cooperation strengthening mechanisms of ZrB_(2) and Sc are also discussed.

关键词： 7N01 aluminum alloy In-situ ZrB_(2)nanoparticles Rare earth Sc Microstructure Mechanical property Mechanism

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High cerium content(Nd-Pr-Ce)_(2)Fe_(14)B melt-spun ribbons with high coercivity

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Journal of Rare Earths 2024年第4期42卷 690-695页

作者： Yujiang Zhong Junming Wang Zikai Yuan Ruijin Liu Minggang Zhu Zhe Liu Xin Chen Wei Li Zhaohui Guo Division of Functional materials Central Iron and Steel Research InstituteBeijing100081China Ningbo Jinji Strong Magnetic material Co. Ltd.Ningbo315172China Jiangxi Jiangwu Rare Metal New material Co. Ltd.Nanchang330013China

The effects of wheel speeds on the magnetic properties and microstructures of[(Nd,Pr)_(1-x)Ce_(x)]-Fe-B meltspun ribbons were *** to melt-spun ribbons with low cerium(Ce)content(x=0.2),amorphous formation can be suppressed at high wheel speed in the ribbons with a relatively high Ce content(x=0.8),and with the increase of the wheel speed,the magnetic properties of the ribbons with high Ce content raise *** high wheel speed,the coercivity mechanism of melt-spun ribbons is mainly pinning field,and the high wheel speed introduces a large number of defects into the matrix as pinning ***,ribbons with high Ce content form a fine and uniform grain structure,so the grain boundary area enlarges,which further hinders the movement of domain *** combined effects of the above factors enable ribbons with high Ce content to have excellent magnetic properties(Hcj=0.977 T,Mr=64 m^(2) A/kg)at the wheel speed of 35 m/s.

关键词： Wheel speed Cecontent Microstructure Magnetic properties Rare earths

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