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Tuning the interfacial reaction environment via pH-dependent and induced ions to understand C–N bonds coupling performance in NO3- integrated CO2 reduction to carbon and nitrogen compounds over dual Cu-based N-doped carbon catalyst

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Journal of Energy Chemistry 2025年第1期100卷 273-285页

作者： Tianhang Zhou Chen Shen Zhenghao Wu Xingying Lan Yi Xiao College of Carbon Neutrality Future Technology State Key Laboratory of Heavy Oil Processing China University of Petroleum (Beijing) institute of Materials Science TU Darmstadt Department of Chemistry Xi'an Jiaotong-Liverpool University Department of Mechanical and Mechatronics Engineering and Waterloo Institute of Nanotechnology University of Waterloo Waterloo

Dual atomic catalysts （DAC）,particularly copper （Cu2）-based nitrogen （N） doped graphene,show great potential to effectively convert CO2and nitrate （NO3-） into important industrial chemicals such as ethylene,glycol,acetamide,and urea through an efficient catalytical process that involves C–C and C–N ***,the origin of the coupling activity remained unclear,which substantially hinders the rational design of Cu-based catalysts for the N-integrated CO2reduction reaction （CO2RR）.To address this challenge,this work performed advanced density functional theory calculations incorporating explicit solvation based on a Cu2-based N-doped carbon (Cu2N6C10) catalyst for *** calculations are aimed to gain insight into the reaction mechanisms for the synthesis of ethylene,acetamide,and urea via coupling in the interfacial reaction *** to the sluggishness of CO2,the formation of a solvation electric layer by anions （F-,Cl-,Br-,and I-） and cations (Na+,Mg2+,K+,and Ca2+) leads to electron transfer towards the Cu *** process significantly accelerates the reduction of *** results reveal that*CO intermediates play a pivotal role in N-integrated ***,the Cu2-based N-doped carbon catalyst examined in this study has demonstrated the most potential for C–N coupling to *** findings reveal that through the process of a condensation reaction between*CO and NH2OH for urea synthesis,*NO3-is reduced to*NH3,and*CO2to*CCO at dual Cu atom *** dual-site reduction facilitates the synthesis of acetamide through a nucleophilic reaction between NH3and the ketene ***,we found that the I-and Mg2+ions,influenced by pH,were highly effective for acetamide and ammonia synthesis,except when F-and Ca2+were ***,the mechanisms of C–N bond formation were investigated via ab-initio molecular dynamics simulations,and we found that adjusting the micro-environment can change the dominant side reaction,shift

关键词： pH-dependent micro-environments C–N coupling Dual Cu-based nitrogen carbon catalysts Explicit solvation model Ion stabilizer AIMD

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Continuous high-temperature rapid nanomanufacturing of electrocatalysts

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Nano Research 2025年第1期18卷 225-235页

作者： Xiaoyang Wang Ziyi Luo Baihua Cui Ziqi Fu Yanchang Liu Weidi Liu Jia Ding Jianrong Zeng Yanan ChenWenbin Hu School of Materials Science and Engineering Tianjin UniversityTianjin 300350China Australian institute for Bioengineering and nanotechnology The University of QueenslandSt.LuciaBrisbane 4072Australia Shanghai Synchrotron Radiation Facility Shanghai Advanced Research InstituteChinese Academy of SciencesShanghai 201204China Shanghai institute of Applied Physics Chinese Academy of SciencesShanghai 201800China

Encapsulating metal nanoparticles in carbon shells(Metal@C)to enhance catalytic activity and stability has been certified ***,most existing methods for preparing Metal@C are complex,time-consuming,and lack of *** this study,a novel method that couples the high-temperature shock(HTS)with ultrasonic spray pyrolysis is reported,which can realize facile and scalable production of various Metal@C through the pyrolysis of glucose and metal chloride *** proposed HTS ultrasonic spray pyrolysis offers several advantages,including compact size,short reaction time(~120 ms),and uniform *** the Ni@C-40 nanocomposite as an example,the ultrasmall Ni nanoparticles(~10 nm)with thin carbon protective shells(~2 nm)are uniformly dispersed in the carbon matrix and applied for oxygen evolution reaction(OER)in alkaline *** Ni@C-40 optimized by tuning the thickness of carbon shell exhibits significantly enhanced OER activity with low overpotential of 242 mV at 10 mA·cm^(-2) and stability,which is attributed to the optimized interactions between Ni nanoparticles and carbon *** method also shows promise for continuous pyrolysis synthesis of various extreme materials at ultra-high temperatures using alternative electric heating materials.

关键词： ultrasonic spray pyrolysis high-temperature shock carbon shell oxygen evolution reaction Metal@C nanocomposite

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Bimetallic Single‑Atom Catalysts for Water Splitting

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Nano-Micro Letters 2025年第1期17卷 1-45页

作者： Megha A.Deshmukh Aristides Bakandritsos Radek Zbořil nanotechnology Centre Centre for Energy and Environmental TechnologiesVŠB–Technical University of Ostrava17.listopadu 2172/1570800 Ostrava‑PorubaCzech Republic Regional Centre of Advanced Technologies and Materials Czech Advanced Technology and Research Institute(CATRIN)Palacky University OlomoucŠlechtitelů241/2778371 Olomouc–HoliceCzech Republic

Green hydrogen from water splitting has emerged as a critical energy vector with the potential to spearhead the global transition to a fossil fuel-independent *** field of catalysis has been revolutionized by single-atom catalysts(SACs),which exhibit unique and intricate interactions between atomically dispersed metal atoms and their ***,bimetallic SACs(bimSACs)have garnered significant attention for leveraging the synergistic functions of two metal ions coordinated on appropriately designed *** offer an avenue for rich metal–metal and metal–support cooperativity,potentially addressing current limitations of SACs in effectively furnishing transformations which involve synchronous proton–electron exchanges,substrate activation with reversible redox cycles,simultaneous multi-electron transfer,regulation of spin states,tuning of electronic properties,and cyclic transition states with low activation *** review aims to encapsulate the growing advancements in bimSACs,with an emphasis on their pivotal role in hydrogen generation via water *** subsequently delve into advanced experimental methodologies for the elaborate characterization of SACs,elucidate their electronic properties,and discuss their local coordination ***,we present comprehensive discussion on the deployment of bimSACs in both hydrogen evolution reaction and oxygen evolution reaction,the two half-reactions of the water electrolysis process.

关键词： Single-atom catalysts Single-atom dimers Hydrogen evolution Oxygen evolution Water splitting

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A Facile Method for Dye and Heavy Metal Elimination by p H Sensitive Acid Activated Montmorillonite/Polyethersulfone Nanocomposite Membrane

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Chinese Journal of Polymer Science 2018年第1期36卷 49-57页

作者： Mehdi Mahmoudian Peyman Gozali Balkanloo Ehsan Nozad nanotechnology Research institute Urmia University

Modified clay/polyethersulfone（PES） mixed matrix membranes（MMMs） were prepared by acid activated montmorillonite（AA-MMT） with different concentrations and used to eliminate dyes and remove heavy metals from aqueous solution. The morphology and physiochemical properties of prepared clay nanoparticles and MMMs were characterized using X-ray diffraction（XRD）, Fourier transform infrared（FTIR） spectroscopy, scanning electron microscopy（SEM）, enegy dispersive X-ray（EDX） spectroscopy, Brunauer-Emmett-Teller（BET） analysis, atomic force microscopy（AFM）, contact angle measurement and fouling studies. The filtration study showed that removal of dyes and heavy metals was strongly dependent on p H so that dyes with positive and negative charges showed different separation efficiency in acidic and alkaline conditions. The modified membranes possessed better heavy metal removal in acidic and alkaline p Hs. When the rejection of heavy metals was measured in an alkaline environment, it was observed that the rejection had a great increase compared to the neutral values for Zn^（2＋） and Ni^（2＋） ions, while rejection of Cu^（2＋） and Cd^（2＋） did not undergo significant changes. So it can be concluded that modified membranes show good selectivity for elimination of Zn^（2＋） and Ni^（2＋） ions with respect to other cations.

关键词： Nanocomposite membranes Acid activated montmorillonite Heavy metal/dye elimination

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Preparation and characterization of colloidal dispersions of graphene-like structures from different ranks of coals

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燃料化学学报 2017年第8期45卷 897-907页

作者： D.P.Savitskii institute of Biochemical Technology and nanotechnology RUDN University

This paper focuses on preparation of colloidal solution of graphene-like structures from different ranks of coals: brown coal,bituminous coal,low-volatile bituminous coal,anthracite. It was found that brown coal thermo-oxidative destruction leads to formation of small d = 32 nm( V = 17%) and large d = 122 nm( V = 11%) fractions of nanoparticles. The thermo-oxidative destruction of bituminous coal leads to formation of nanoparticles d = 50 nm( V = 5.2%) and d = 164 nm( V = 16%). Thermooxidative destruction of low-volatile bituminous coal and anthracite leads to formation of nanoparticles,predominantly,d = 122-190 nm. Carbon nanostructures obtained from coal are negatively charged at pH= 2-12. Colloidal solution of carbon nanostructures at dispersed phase concentration 0. 01 mg/mL is stable for 1 month. Electron diffraction patterns and X-ray analysis of carbon nanostructures showed that nanostructure from brown coal is amorphous and nanostructure from anthracite is crystalline. Results of coal macromolecules modeling and graphene-like structures obtained from them are presented.

关键词：象 graphene 一样结构煤胶体的分散粒子尺寸分发 electrokinetic 潜力

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Nonrelativistic Lamb shift in a nano-sized conducting ring

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Science China(Physics,Mechanics & Astronomy) 2012年第8期55卷 1383-1388页

作者： OLESEN D. S. KELLER O. institute of Physics and nanotechnology Aalborg University

A theoretical calculation of the nonrelativistic Lamb shift in nano-sized semiconducting （GaAs） and metallic （AI） circular rings is carried out. On the basis of a flat one-electron potential with infinitely high barriers, the radiative back-action is obtained to second order in perturbation theory. Numerical results are presented for the radiative correction to the transition frequency between the ground state and first excited radial quantum states （initial state：（1,1,0）, final state：（2,1,0）） neglecting the curvature term in the Schr6dinger equation. Lamb shifts are calculated as functions of the inner ring radius, the ring thickness, and the temperature.

关键词： Lamb shift nano-ring mesoscopic quantum electrodynamics

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Space-time description of transverse photons: near-field aspects

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Science China(Physics,Mechanics & Astronomy) 2012年第8期55卷 1389-1393页

作者： KELLER O. institute of Physics and nanotechnology Aalborg University

A mean position state based on the gauge invariant transverse vector potential is used to convert single-photon states in Hilbert space to photon wave packets in direct space. The resulting photon wave-mechanical description leads to scalar products which relate to covariant integration on the light cone. A new correlation matrix displays the spatial localization problem for single photons in an explicit manner in space-time. The correlation matrix essentially is the projection of the time-ordered Feynman photon propagator onto the transverse photon subspace. The present photon wave-mechanical formalism is generalized to two-photon dynamics. In the diamagnetic limit the transverse photon becomes massive in its interaction with matter, and the correlation matrix for massivephoton interaction, which can be used in studies of evanescent-photon mediated couplings, is analyzed. On the basis of the present formalism the existence of a dynamical near-field Aharonov-Bohm effect is predicted.

关键词： one-photon wave mechanics near-field optics correlation matrix transverse photon mass

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A Fully Self-Healing Piezoelectric Nanogenerator for Self-Powered Pressure Sensing Electronic Skin

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Research 2021年第1期2021卷 876-884页

作者： Maosen Yang Jinmei Liu Dong Liu Jingyi Jiao Nuanyang Cui Shuhai Liu Qi Xu Long Gu Yong Qin School of Advanced Materials and nanotechnology Xidian UniversityXi’an 710071China institute of Nanoscience and nanotechnology Lanzhou UniversityGansu 730000China

As an important way of converting mechanical energy into electric energy,a piezoelectric nanogenerator(PENG)has been widely applied in energy harvesting as well as self-powered sensors in recent ***,its robustness and durability are still severely challenged by frequent and inevitable mechanical impacts in real application ***,a fully selfhealing PENG(FS-PENG)as a self-powered pressure sensing electronic skin is *** self-healing piezoelectric composite and self-healing Ag NW electrode fabricated through mixing piezoelectric PZT particles and conductive Ag NWs into self-healing polydimethylsiloxane(H-PDMS)are assembled into the sandwich structure *** FS-PENG could not only effectively convert external stimulation into electrical signals with a linear response to the pressure but also retain the excellent self-healing and stable sensing property after multiple cycles of cutting and self-healing ***,a self-healing pressure sensor array composed of 9 FS-PENGs was attached on the back of the human hand to mimic the human skin,and accurate monitoring of the spatial position distribution and magnitude of the pressure was successfully realized.

关键词： piezoelectric healing generator

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Enhance of TiO_2 dopants incorporated reduced graphene oxide via RF magnetron sputtering for efficient dye-sensitised solar cells

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Rare Metals 2018年第11期37卷 919-928页

作者： Foo Wah Low Chin Wei Lai Kian Mun Lee Joon Ching Juan nanotechnology and Catalysis Research Centre Institute Postgraduate Studies University of Malaya

In particular, the dye-sensitised solar cells(DSSCs) have a high potential in the rational energy conversion efficiency to secure our sustainable energy *** the present study, advanced radio frequency(RF) magnetron sputtering technique was applied to incorporate titanium dioxide(TiO) dopants into reduced graphene oxide(rGO) nanosheet for improving the power conversion efficiency(PCE) of DSSCs device. An optimum TiOcontent incorporated onto rGO nanosheet plays an important role in improving the PCE of DSSCs by minimising the recombination losses of photo-induced charge *** on the results obtained, 40-s sputtering duration for incorporating TiOdopants onto rGO nanosheet exhibits a maximum PCE of 8.78% than that of pure rGO film(0.68%). In fact, the presence of optimum content of TiOdopants within rGO nanosheet could act as mediators for efficient separation photo-induced charge carriers. However, the excessive of sputtering duration(e.g. 60 s) of TiOdopants onto rGO nanosheet results higher charge recombination and lowers the PCE of DSSCs(5.39%).

关键词： Dye-sensitised solar cell RF magnetron sputtering Titanium dioxide Reduced graphene oxide

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Nonlinear vibration analysis of laminated composite Mindlin micro/nano-plates resting on orthotropic Pasternak medium using DQM

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Applied Mathematics and Mechanics(English Edition) 2015年第8期36卷 1033-1044页

作者： A.G.ARANI G.S.JAFARI Faculty of Mechanical Engineering University of Kashan institute of Nanoscience & nanotechnology University of Kashan

The nonlocal nonlinear vibration analysis of embedded laminated micro- plates resting on an elastic matrix as an orthotropic Pasternak medium is investigated. The small size effects of micro/nano-plate are considered based on the Eringen nonlocal theory. Based on the orthotropic Mindlin plate theory along with the von Kármán geo- metric nonlinearity and Hamilton＇s principle, the governing equations are derived. The differential quadrature method （DQM） is applied for obtaining the nonlinear frequency of system. The effects of different parameters such as nonlocal parameters, elastic me- dia, aspect ratios, and boundary conditions are considered on the nonlinear vibration of the micro-plate. Results show that considering elastic medium increases the nonlinear frequency of system. F^lrthermore, the effect of boundary conditions becomes lower at higher nonlocal parameters.

关键词： nonlinear vibration laminated micro-plate orthotropic Pasternak medium,differential quadrature method

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